10km78.06%20.95%0.93%

1. 2. SO2

3. NO2SO24. 5.

3.1

SO2NOxCOSO2CO(CuCdPbZn)SO2SO2COH2SSO2H2SNOxNOxCONH3H2SNH3CS2SO2NOxH2S

12

0.01100 m

l0m

10m(PM10)

IPTSP

mg/m3g/m3 100mL/m3L/m3

:():(): :

3.2

TSPSO2NOxCOPM10F2HFB(a)PPbH2SCS2Cl2HCNNH3HgBe pHK+Na+Ca2+Mg2+NH4+SO42NO3Cl

()

()

12 3456

()

3.3

/SO2NOxTSP400720 3030 40

3.4 WHO()

/SO2NOxCO100221111100 400552222400 800884342>80010105453

() : 1.

2. 41020404884

3. 4.

3.1

3.2

3.3

3.5 50m

()5 102040

3.6

240.5 h1416 d12()240.5 h56 d12302 d12302 d12

3.7

SO2NOxNO214412TSPPM10Pb605SO2NOxNO2CO18 hTSPPM10B(a)PPb12 hSO2NOxNO2COO3145 minPb155F15 d70%12 h145 min

100mL

(

3.4

3.5 3.6

()

HClNaOH

3.7

3.8

aGDXb c

())

()

3.10

(0)-(-10)-(-72 )(-78.5)(-183)(-196)

1200020000 V

()

()

1. ()512 m()11.5 m302

3.11 3.12

2.

(HFSiF4)(NaFCaF2)

:

() 2 1.

1.2. 3. 1. 2.

1. 3.15

2. 1(TSP)80 mm100 mm80 mm7.29.6 m3/h100 mm11.315 m3/h

2( (PM10)PM1010m()

10

180

3.19

3.20

3.21

1 2

(min)(L/min)(L)()(kPa)(L)

SO2

-1HgCl2 + 2KCl = K2[HgCl4]-------

[HgCL4]2- + SO2 + H2O = [HgCl2SO3]2- + 2H+ + 2Cl-

---

[HgCl2SO3]2-

---.

[HgCl2SO3]2- + HCHO + 2H+ HgCl2 + HOCH2SO3H

+HOCH2SO3H

2 pH(1.60.11.20.1)(548nm575nm)3a.--b.Ac.

SO2 :CSO2(mg/m3)A A0 Bs(g/) V0(L) Vt(mL) Va(L)

(3)

2. -- SO2 NaOHSO2577nm CDTA)NaOH

3 SO2+H2O2 H2SO4 +BaClO4 BaSO4 Ba (ISO)SO2SO2 (520nm)

1 (W)(C)(R)()SO2NO2NO

()

SO2 + 2H2O = SO42- + 4H+ + 2e + 0.17V NO2 + H2O = NO3- + 2H+ + e + 0.80V NO + 2H2O = NO3- + 4H+ + 3e + 0.96V SO2NO2SO2O2 O2 + 4H + 4e = 2H2O

2SO2 + O2 + 2H2O = 2H2SO4

()SO2SO2

2-23 SO2

1. 2. 3. 4. 5. (W)6. (R)7. 8. 9. 10. 11.

(NOx)

NONO2NO2NO4

1.() 1 NO2NO2

NO2

Nox,

A

B

3.22 NO2NONOxA

B

()NONO2NO2540545 nmNONO2NOxNO2176

:

4. (1) (2) 30%70% (3) O30.250 mg/m31520 cm

0.1molL(pH7)0.3 molLNO2I-I2I2I_100NO2NO2NONO23-26

3.23 NOx

3.24 NOx

(CO)

CO

(GC)

GCCOCO2TDX-0l(36010)COCO2CH4COCH4CO2

3.25 CO

(hx)CO(CH4CO2)(cx) Cx = hx K

COCO180200CO CO3-28CO253.7nm

CO- COCH4H2COCO2

3.26 CO

0.269

-- O3 + 2I- + 2H+ = I2 + O2 + H2O 352 nmNOx

()- O3(O3)352 nmO3

NOx O3

()

O3352 nm

(O3)352 nmO3 O3

(SiF4)(CF4)(Na3A1F6)(CaF2)(A1F3)(NaF)[3Ca3(PO4)2CaF2]- -

1- -

0.8m

34()

(F,mg/m3)=W1(g) W2(g) W0(g/) Vn(L)

(F,mg/m3)=W3(g) W0(g)

2-

()

[F, g/(100cm2d)]=W(g) W0(g) S(cm2) n0.1d

SO2H2SH2SO4 ---

1- : SO2H2SBaCl2BaSO4l00 cm2SO3

SO2 + PbO2 PbSO4 H2S + PbO2 PbO + H2O + S PbO2 + S + O2 PbSO42 (1) PbO2PbO2100 cm2 (2) PbO2302 dPbO2

(3) PbO2CO2BaCl2BaSO4105

[SO3 mg/(100 cm2PbO2d)=WsBaSO4(mg) W0BaSO4(mg) SPbO2(cm2) n0.1 d SO3BaSO4(0.343)

PbO2PbO2

-SO2BaCl2BaSO4

--

- (500)253.7nm3-29

()

3.27 -

() -

4.0 molL-15 L6.610-6 mg/m3

(C1C8)(THC)(NMHC)

3.28 3-30 1. 23912. 45. (1mL)6.GDX-5027. 8. FID10. 11. 13.

3.29

3.30

ht() hshaGDX-502(hm)(hs)

(CH4mg/m3)= (mg/m3)=cs(mg/m3)

GDX-502

(mg/m3)=ht(mm) hm(mm) hSl(mm) hS2GDX-502(mm) Cs(mg/m3)

(mg/m3)=(CH4mg/m3)=ht(mm) hm(mm) hSl(mm) hS2GDX-502(mm)Cs(mg/m3)

(VOCs) VOCs133.32PaVOCs

VOCs (VOCs)3.31

() 1

Fe3+ + (630 nm ) ()630 nm

2pH=6-423 nm

3 2,4-6201OV-1

4-() (1605)

(API)

SO2NOxTSPAPIAPI50100200500

(Ii)

CiIii ci,jIi,j ij (3.8 )ci,j+1Ii,j+1 ij+1

3.8

3.9

05051100101200201300300

100um

(TSP) TSP

(1.11.7 m3/min)(50150 L/min)13L/min24 hTSP WTSP(mg/m 3)= Qn t

WTSP(mg)

Qn(m 3 /min)

t(min)

()

TSP

(PM10) 10m30mPM10

PM10PM10(f=f)f= f-f=0

(f)(f)PM10(f) f = KM

3-35 PM101. 2. 3. 4. 5. 6. 7. 8.

3.34 PM10

()30g/cm230

500 mL1020 mL1055 [g/(cm230d)]=

W11055(g) W01055(g) Wa(g) S(cm2) n(0.1d)

() 600600600(g/cm230d)

3.35

(TSP) 1. 2.

(

6.19 1

2. 3.36

.

(4 : 4 : 1) 3.37

(2) 1020()

. (a) (1) -(a)(a)

1

abcd()X

-

F = KC(130 pH

2

-367 nm(a)405 nmF405402408 nm405 nm402408 nm(F402F408)(F)BaP BaP(g/m3)=F2 F0 F1 MBaP(g) R Vn(m3)

BaP(g/m3)=F2 F0 F1 MBaP(g) R Vn(m3)

(2) (HPLC)

3.38

(GB13580.292)12

3.40 3.39

1()()()()8:0024 h 21.2m 3

IpHK+Na+Ca2+Mg2+NH4+SO42NO2NO3FCl

1. pH(pH5.6-5.7)2. 3. () 4. 5. 6. 7. 8.

(kg/h)

.

3.1

3-9

(m)()(D)123456789104.050.0260.0820.1460.2260.3420.6580.7740.8540.9180.974

3.2 ()

3-10 ()

(m2)(m)0.10.5

13-44 1. 2. 3. 4.

(Pt)(Ps)(Pv)Pt =Ps + Pv

3-4590 (1) S3-45 1. 2. 3. 4. 5.

3-46 S

S(3-46)

S

3.41 3.42 (2) U

(vs) vsm/s Kp pvPa kg/m3

Qsm3/h Sm2Qnd m3/h psPa paPa xw%

: 3.43

: 3:

3.44

2A

B

VndL Q L/min Msd/kmol tr tmin

mg/m3 Gg VndL mg/m3 v1, v2,, vnm/s 1, 2, ,nmg/m3 S1 , S2 , , Snm2

() /h=mg/m3 Qsnm3/h

3.47 3.48

2. 3.49 3.50

1

() 3.51

HC3.10 GB14761.593

CO()/ %HC/10-61995713.54.09001200650070001995714.04.510001500700078001995714.55.012002000800090001995713.03.5600900600065001995713.54.07001000650070001995714.54.5900120075008000

100mL--NOx

1 2

1. 20 L

3.54

Cmg/m3VimLb%P0KPaPUKPaVLMg/molVmolL/mol

CC0mg/m3 QQ0mL/min

3.58