± ¼ p%ê4ß « b4 )f · 2017-03-04 · ± ¼ p%ê4ß « b4 )f e 30 b9× ð Ø#'1ß c&Å...

2
PM2.5 HNO3 /NO-O3 SD-CL 1-2) HNO3 2 CH1 CH2 CH1 Mo NOy NO NOx Thermo fisher scientific , Model 42i-TL NOy CH2 Mo NaCl NOy HNO3 CH1 CH2 HNO3 HNO3 ACSA-08 PM10-2.5 PM2.5 NO3 - PM2.5 35 μg/m 3 2 22 2 22 23 60 μg/m 3 1 NO3 - PM2.5 2 22 23 20 μg/m 3 2 22 23 NOx 80 ppb 3 2 27 100 ppb 22 23 PM2.5 NOx 1) Sadanaga, Y., Yuba, A., Kawakami, J., Takenaka, N., Yamamoto, M., Bandow, H.: A gaseous nitric acid analyzer for the remote atmosphere based on the scrubber difference/NO-Ozone chemiluminescence Method, Anal. Sci., 24, 967-971 (2008) 2) Sadanaga, Y., Imabayashi, H., Suzue, T., Kimoto, H., Kimoto, T., Takenaka, N., Bandow, H.: Quantitative reduction of particulate nitrate to nitric oxide by a molybdenum catalyst: Implications for NOy measurements in the marine boundary layer, Geophys. Res. Lett., 35, doi:10.1029/2008GL035557 (2008)

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Page 1: ± ¼ p%ê4ß « b4 )F · 2017-03-04 · ± ¼ p%ê4ß « b4 )F  E 30 b9× ð Ø#'1ß c&Å ä Ø _$Î#Õ M G \ @ ¨ C z0[ ^ ì Û B (

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PM2.5

HNO3

/NO-O3 SD-CL 1-2) HNO3 2

CH1 CH2 CH1 Mo

NOy NO NOx Thermo fisher scientific , Model 42i-TL

NOy CH2 Mo NaCl NOy

HNO3 CH1 CH2 HNO3

HNO3 ACSA-08

PM10-2.5 PM2.5 NO3-

PM2.5 35 μg/m3 2 22

2 22 23 60

μg/m3 1 NO3-

PM2.5 2 22 23 20 μg/m3

2 22 23

NOx 80 ppb 3 2 27 100 ppb

22 23 PM2.5

NOx

1) Sadanaga, Y., Yuba, A., Kawakami, J., Takenaka, N., Yamamoto, M., Bandow, H.: A gaseous nitric acid analyzer for the remote

atmosphere based on the scrubber difference/NO-Ozone chemiluminescence Method, Anal. Sci., 24, 967-971 (2008) 2) Sadanaga, Y., Imabayashi, H., Suzue, T., Kimoto, H., Kimoto, T., Takenaka, N., Bandow, H.: Quantitative reduction of particulate

nitrate to nitric oxide by a molybdenum catalyst: Implications for NOy measurements in the marine boundary layer, Geophys. Res. Lett., 35, doi:10.1029/2008GL035557 (2008)

Page 2: ± ¼ p%ê4ß « b4 )F · 2017-03-04 · ± ¼ p%ê4ß « b4 )F  E 30 b9× ð Ø#'1ß c&Å ä Ø _$Î#Õ M G \ @ ¨ C z0[ ^ ì Û B (

���

1 2015 2 22 28 PM2.5 PM2.5 NO3- 2 22

35 μg/m3 22 23

60 μg/m3 PM2.5 NO3- 3

2

PM2.5 2 22 23 20 μg/m3

22 23

3 NOx NOx NO NO2

1 PM2.5 22 23 NOx 80 ppb

27 100 ppb PM2.5 20 μg/m3

10 μg/m3 22 23 NOx