() (San Carlos De La) 1978 07 11 (San Carlos De La) 1978 07 11 (propylene) 282 90%

1 1. (Barcelona) (Valencia) 3 km 200 m 30 m 60 m 2 10,000 m 800 2 2. 1973 44.4 m3 19 ton 2 3. (1 atm, 25) 47.7 185.2 0 1 1.46 1.49

108 (LEL-UEL) 211 vol% 497 3-4 3. 1978 07 11 12 35 23.5 ton 2 30 125 m 90% 2 4. 1 2 3 100 182 50 % 282 215 67 2 1. 2. 3. 1-2

1 2

2 2

3 2

1. 19 ton 23.5 ton 1982 (1) (Fireball) (2) Carrasco

Carrasco Carrasco (1) 5.6/ (2)

2.5 2.5 5.6/=14 5 6 4 2. 1983 Hymes Hymes (Boiling Liquid Expanding Vapor Explosion, BLEVE) BLEVE ChemsPlus 1 1 23,500 Kg 182 m2 299 m 13.4 s 197 m 390 m

197 m 390 m BLEVE Hymes 3. (1) (2) (3) (4) 2

2 81 10 12 81 10 14 81 12 23 82 01 20 82 06 12 205 m 4 ton 4 44 18 ton () 11

82 10 15

83 01 15

87 01 21

87 02 27

87 09 04 87 11 22

88 10 31

89 02 27

89 03 31

1. 5 2. 5 3. 5 4. 6 5. 6 6. 7 7. 8

1978 (CNS) 7248 7 1. (1) (2) 4 (CNS) 7248

4

10

9 (1) CNS 2947 CNS 4271 CNS 2673 CNS 3828 9-10 (2) 11 t1 = PD +C 200 1.2P

t3 =

VPD +C 200S 1.2P

(3)

t1 (mm) t2 (mm) t3 (mm) P (kgf/cm2) C 0 mm W3+ n n 4

V2 + m2 m 6

(1) (2)

t2 =

WPD +C 200S 1.2P

D 3 S 4 5 3 D9

mm mm mm

(5) 6 11, 13 W= 1 37100A 0.82

(3) 375 mm 375 mm 275 mm 12 (4) 5 3 m3 3.2 mmSS41 9- 12

(1) (2)

a=

W M CKP ZT

5 9

W (g/hr) A (m2) 6 a (cm2) C 6 K (0.65) M 6 P 6 T 6

6 9 4 9 1 .7 r r 2 40 kgf/mm 2 r 0.7 0.7 1 0.4 4 5 9 A B 25 % 1.00 0.95

6 13 kcal/kg C 61 61 76 68 64 247 245 234 244 244 (g/mole) 42 44 54 58 56 K 0.58 0.63 1 0.79 1 348 347 356 357 347

(6) 1.4 mm 1.11.5 3070 40 14 (7) 11 (8) 1 BC B10 ABCB12 9 (9) 5.5 mm2

12 (10) 200 mm 10 (11) ABS (Speed Limit) 11 (12) 7 12 2. 7

7 12

7 (1)

(2)

(3)

(4)

(5)

(6)

(7)

(8)

7 7 14 15 15 16 16

OSPCT 15, 17 (9) 16 (10) 18-20 (11) 5 (12) 21-23 (13) GIS/GPS Global Information System / Global Position System 24 (14)

(Safety and Quality Assessment System, SQAS) 25 (15) 25

1.Lees, F.P., Loss Prevention in the Process Industries 2nd Edition, ISBN 0-7506-1547-8, Butterworth-Heinemann,Oxford, UK, Vol. 3 Appendix 16/2-5 (1996). 2.Marshall,V.C., Major Chemical Hazards 1st Edition Ellis Horwood Limited, ISBN 0-85321-969-X, West Sussex, UK, p.184-202 (1987). 3. 791 81 05 4.Kirk-Othmer, propylene, in Encyclopedias of Chemical Technology, Vol. 20, p. 249-270. 5. 37 11 10-13 77 11 6. 21 55-70 59 10

7. 19 69-75 70 10 8. 87 05 9. CNS 7248 Z3018 82 1-37 83 10. 11. 448609 12. 20 10-13 87 10 13. 7199-116 7010 14. 8704 15. 8704 16. OSPCT 1826-3084 1215 17.John Withers, Major Industrial

Hazards 1st Edition Halsted Press, ISBN 0-470-21067-2,605 Third Avenue, N.Y., USA, p. 188198 (1988). 18. 4045-49 (86) 19. 4138-41 86 20.LPG 1 113-1278801 21. 20 23-2987 22. ( 870619) 23. 4440-50 (8903 20) 24. 8705 25.American Society of Mechanical Engineers, USA, Boiler and Pressure Vessel Code Section Div UG 125-130 (1995).