0 pp1-4 表紙 序 目次 改1 - 一般社団法人 日本産業機 …¼23－...
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19
1
1.1
30 40
CO2
1.2
1982
1-1
1-1
37
20
1982
2
2.1
NaA cage 0.41nm4.1
0.41nm4.1
0.35nm3.5
2-1 16mm
1150mm 2.7
2-1
21
NaA
2-2 SEM
a
b
c
d
e
a
Re
be
2-3
2-2 SEM
53.5 5
3.5
4.0
22
HDSTM
a.
2-4
PVVP
2
VP
VP
2-3
2-4 PV VP
Steam
Retentae
Permeate
Pervaperation (PV)
Vapor Permeation (VP)
)
Retentate
Steam
Retentae
Permeate
Pervaperation (PV)
Vapor Permeation (VP)
)
Retentate
Retentate
23
2-22-4
Retentate
HDS
2008
b.
2-4
VP2-5
2-6
1L
2-53,100kJ/L2-6
4,340kJ/L
2-5
2-5
EtOH
10wt%
99.5wt%
3,100kJ/L
91wt%
3,100kJ/L-EtOH
24
2.2
24
2.3
2.7
2-7
A2B6.5
2-79010wt%130
VPAB
2-7
1,000
Re130
VP2-8Re
Re
2-6
10wt%
3,573kJ/L
92wt%
99.5wt%
EtOH4,340kJ/L-EtOH
767kJ/L
25
Re
2-750 kg/m2h
2-8Re
2.4
2
1
2
0
10
20
30
40
50
60
Hitz (
B(
/kg
/(m
2hr)
6.5
2
VP-130E/W=90/10wt/wt
0
10
20
30
40
50
60
Hitz (
B(
/kg
/(m
2hr)
6.5
2
VP-130E/W=90/10wt/wt
[k
g/m
2h]
[k
g/m
2hP
a]
Re
2-7 2-8 Re
26
2.5
2-9
PSA 2-10
3
2-9
8,00010,000 kJ/L
PSAPressure Swing Adsorption
A
70% 2-10 72wt%
4,860 kJ/L 2-6
PSA 11% 26%
2-1
500kL/day15
6/kWhPSA
1.5
2-1 500kL/day 15
HDSTM PSA
1099.5% 4,340 kJ/L 4,860 kJ/L 8,00010,200 kJ/L
92%99.5% 767 kJ/L 1,044 kJ/L
+PSA
1.5
27
2.6
2.5PSA
HDSHDS
PSA
HDS
PSA
HDS2-11PSA
2-9
2-10 PSA
3050%
94%
10wt%
3000kJ/L
99.5wt%
EtOH
8,00010,200kJ/L-EtOH
1500kJ/L
30003200kJ/L
5002500kJ/L
92wt%
10wt%
72wt%3,816kJ/L
99.5wt%
EtOH
1,044kJ/L
4,860kJ/L-EtOH
()()
28
HDSPSA2.5
70%
PSAHDS
2-11PSAHDS
HDS
IPA
2.7
2-12
2-11 PSA
HDS
EtOH
EtOH
()()
29
2-12
a
b
c
d
abd
c
2
2-12
:
Hitz
30
12
2.3
2.8
3
NaA
3-1
3-1
SiAl
NaA 1.0 4.0
NaY 3.0 7.5
CO2
MOR 810 6.0
ZSM-5 1012 5.5
1CO2
CO2
CO2
CO2
CO2CCS
31
CCS
2
GTL
CO2
CO2 3H2 CH3OH H2O
CH3OH H2O