0304 1130 oldoilpalmtrunksaspromisingfeedstockforbiofuel&bioplastics(jircas)
TRANSCRIPT
Old Oil Palm Trunks as Promising Feedstock
for
Biofuel and Bioplastics
JIRCAS
4th BMWS 2007.11
In collaboration with University of Science Malaysia
and Forest Research Institute Malaysia
Yutaka Mori
Problems occurred by introduction of bio-ethanol fuel
� Competition
with food
� Shortage of feedstock
� Price hike in grain and
feedstock
Feedstock: corn, wheat, cassava, sugar cane, molasses
Second-generation ethanol that
does not compete with food
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
1963
/196
419
65/1
966
1967
/196
819
69/1
970
1971
/197
219
73/1
974
1975
/197
619
77/1
978
1979
/198
019
81/1
982
1983
/198
419
85/1
986
1987
/198
819
89/1
990
1991
/199
219
93/1
994
1995
/199
619
97/1
998
1999
/200
020
01/2
002
2003
/200
420
05/2
006
2007
/200
8
100
0t
Source:USDA PSD Online 2008
Worldwide Palm Oil Production
0
5000
10000
15000
20000
25000
国
10
00
t
Palm Oil Production in Each Country (2007)
Source:USDA PSD Online 2008
Indonesia
Malaysia
Country
� 1911: Introduced from Africa
� 1917: Commercial Production started
� Exports: 2007
36,292M RM=13 billion US dollars
� Employment: more than 500,000
� Cultivation area: 430M ha (2007: 13% of total land)
peninsula(236Mha), Saba(128Mha), Sarawak(66Mha)
� Palm oil production (2007): 17.7M ton
� Kernel oil production (2007): 2M ton
� Productivity: 3.4-4.9 ton/ha (palm oil)
0.7-1.2 ton/ha (kernel oil)
Palm Oil Industry in Malaysia
Plywood Production from Old Palm TrunkYoung’s Modulus
2 4 (GPa)
16 7 62 43
11
10
9
15
14
13
Young’s Modulus
2 4 (GPa)
16 7 62 43
11
10
9
15
14
13
16 7 62 43
11
10
9
15
14
13
Moisture Content of Oil Palm Trunk
A
B
CBark
Inner part of the stem
MoistureA
(core)83%
B(middle)
75%
C(outer)
68%
A B C
Sucrose 20.6 23.6 22.1
Glucose 68.4 60.8 54.7
Fructose 23.3 27.0 30.9
Total sugars 113 112 108
Sugars contained in oil palm sap(g / L)
0.0
2.0
4.0
6.0
8.0
10.0
0 10 20 30 40 50
Time, h
Redu
cing
suga
r, %
0.0
1.0
2.0
3.0
4.0
5.0
6.0
EtO
H, %
Reducing sugar, %
EtOH, %
Ethanol production from oil palm sap
Lactic Acid Production from Oil Palm Sap
○,●:sap □,■:reference
0
10
20
30
40
50
60
70
0 12 24 36 48
0
10
20
30
40
50
60
70
Glu
cose
,
Lactic acid
, g/L
(●,■
)
0
10
20
30
40
50
60
70
0 12 24 36 48
0
10
20
30
40
50
60
70
5
inches2
ft
Upper
most
(centre)
half
half
5
inches
5
inches
5
inches
8
ft
Sugar content and
composition at
different height
� Same amount and
composition throughout the
height except uppermost
part
�Approximately 20% less at
uppermost part
0 1 3 7 15 30 60 90 120
days
2
’
’
2
’
’
2
’
’
2
’
’
Accumulation of sugars during storage of OPT
2
inches
L
1/2
L
1/2
L
ABC
We found out:
sugars in the sap increase significantly during storage.
Comparison of Oil Palm Trunk with Sugar Cane
Sugar Cane
Oil Palm Trunk( after proper aging)
A (中心) B (中間) C (外層)
Moisture content70% 83% 75%
68%×0.8
Sugar content in juice or sap
16% 16% 14% 15%
Amount of sugarscontained
112g/kg 95.4g/kg ⇒ 107.8 kg/trunk
Cane or trunk produced per area
60-90ton/ha
154-168 ton/ha (136-148 trunks/ha)
Possible ethanol yield 4.5-7.2kL/ha
9.5-10.3 kL/ha
Sugar Cane
Oil Palm Trunk( after proper aging)
A (Core) B (Middle) C (Outer)
Moisture content70% 83% 75%
68%×0.8
Sugar content in juice or sap
16% 16% 14% 15%
Amount of sugarscontained
112g/kg 95.4g/kg ⇒ 107.8 kg/trunk
Cane or trunk produced per area
60-90ton/ha
154-168 ton/ha (136-148 trunks/ha)
Possible ethanol yield 4.5-7.2kL/ha
9.5-10.3 kL/ha
Oil palm sap squeezing system
Trunk
Sap Tank
Fermentation
water
Plywood material
Shredder Squeezer
Peeler
Squeezer
Specs:
3 roller hydraulic press
Size of roller:φ240mm, 340 w
Capacity: 500kg/h
7.5kw x 2 (AC415Vx50Hz)
8RPM variable
2450 x 2030W x 1800H
Ethanol production from parenchyma hydrolysate
0
1
2
3
4
0 10 20 30 40
time, h
Glu
cose
, %
0
0.5
1
1.5
EtO
H, %
A5
A6
A7
A8
Ethanol yield A8) 86%
control: 80%)
A5 hydrolysateA6 hydrolysate + 1% polypeptone, 0.5% yest extract
A7 hydrolysate + 1% (NH4)2SO4
A8 hydrolysate + 1% polypeptone, 0.5% yeast extract
Control glucose + 1% polypeptone, 0.5% yeast extract)
Possible amount of ethanol and lactate produced from oil palm trunk
Heat
etc.
Fermentable sugars:16.8kg(core)39.7kg(middle)51.3kg(outer)
From one trunk
Solids(317kg)
Parenchyma(174kg)
Vascular bundles
(143kg)
Fermentable
sugars
(63.9kg)
Fermentable
sugars
(59.6kg)
Fermentable sugars
(107.8kg)
Ethanol 69.8L
41.4L
Diameter:38cm
Length:10m
sp. gr.:1.0
Sap
Lactate: 107.8kg
63.9kg
Characteristics and advantages of the OPT as the
resource for fuel ethanol and lactic acid production
• Large amounts of sap
• High sugar content
• Easily degradable
parenchyma
Promising feedstock for ethanol and lactic acid
• Constantly discharged waste
• Very large amount
• Available all year around
Potential: Malaysia (4.3M ha) 2.7M kL (1.7M kL ) ethanol /year
4.2M ton (2.6M ton) lactate /year
Indonesia (7.0M ha)* 4.4M kL (2.8M kL) ethanol /year
6.8M ton (4.3M) lactate /year