84

1

( s1

).

.

.

()

( )

3

94

.

.

. s p

.

.

s4 .

( ) .

5p3 2s3 6p2 2s2 2s1 : lC71

6p3 2s3 6p2 2s2 2s1 : rA81

1s4 6p3 2s3 6p2 2s2 2s1 : K91

.

( ) .

.

.

( )

.

.

.

.

.

.

.

05

1

.

2

-2S , +2eB , +aN , -rB

.

1 +1 2

+2 .

61

-2 71 -1

.

.

1 ( * .)

+1

*

+H

+iL

+aN

+K

+sC

+ gA

-1

*

-H

-F

-lC

-rB

-I

+2

*

+2gM

+2aC

+2 rS

+2 aB

+2 nZ

-2

-2O

-2S

-3 +3lA +3*

-3N

15

.

.

1 .

+1 -1 +2 gM

-2 O . 2+gM ++ gM

.

(+aN) (+2 gM).

( )

(- lC) (-2 S) (-3 N).

. ( .)

.

+2 +3 +1 +2 +2 +3 .

( II) ( III) ( I) ( II)

( II) ( III) .

.

+1 +2

.

( II) . 1 .

2 .

+H

+iL

+aN

+K

+bR

+sC

+2gM

+2aC

+2rS

+2aB

+2rC

+3rC+2nM

+3nM+2oC

+3oC+2eF+3eF

+uC

+2uC

+ gA

+2nZ

+2dC

+2gH

+3lA

F 2O 3N

lC 2S

rB

I

1

2

921 11 01 7 4 3

61 51 41 31

81 71

H

+2iN

+3iN

1

2

3

4

5

6

+3V +2 iT +3cS

8 6 5

1

25

2 .

+2 rC

+3 rC

+2 nM

+3 nM

+2 eF

+3 eF

+2 oC

+3 oC

+uC

+2 uC

* (II)

(III) (II)

* (III) (II) (III) (II)

* (III)

(I) (II)

* .

.

. (+K) 42) OPH) (+aN) (-lC)

.

(+2 gM) .

.

. (II)(+2 eF)

() . (+2 aC)

.

.

lCaN .

. 1

.

6%

.

.+2 nS( ) (II) +4 nS ( ) (VI).

35

. .

71 .

2

.

.

3.

.

. C 108 C 3141 .

.

2

.

(lCaN) .

.

3

.

.

.

.

.

.

.

4 .

.

e71

e

e81

p11

e01

e11

p11

p71+p71

++

+

45

12

3

4

5

6

.

.

4 .

.

4

.

.( )

.

67/1 -lC+aN .

lCaN

.

.

.

. (

)

.

.

.

(-lC)

( +aN )

+aN-lC

55

.

5.

5 .

() ()

.

.

( )

4.

. 1-lom.Jk 5/787 .

Jk 5/787 + )s)lCaN )g)-lC + )g)+aN

. 3 .

4

+2+3 .

.

65

-F -2O

+aN 3291842

+2gM 75921973

+3lA 294561951

3

(1-lom.Jk) 4

(1-lom.Jk)

-F -lC-rB-I

+iL6301358708757

+aN329787747407

+K 128517286946

+bR587986066036

+sC047956136406

3 4 .

)

1 .

2 .

3 .

4 .

)

OaC OgM

.

5.

.

5

/C / C

lCaNlCbRFKrBK

108517858437

3141093150515341

lC aN

aNrB

l aN

787

747

407

75

.

: 3 5 .

.

.

.

.

.

.

6.

.

.

.

.

.

lCsC +sC -lC

OaC +2 aC -2 O

.

.

.

+aN -lC 1 1 +2 aC

-2 O 1 1 .

+2 aC - lC

6 . . .

.. .

()

()

()

()

85

.

1 2 2lCaC .

.

4lC2aC .

12

2lCaC .

.

:

1) +3 lA -2 O .

2)

: -2 O+3 lA

3) 6(23)

6 +3 lA 6 -2 O .

+3 lA -2 O 2 3 3O2lA .

.

.

.

. .

6 .

95

.

.

.

3OC2K

. 1 +1 .

-2 +K . 3OC

-2 .

32 OC

-2

.

( ) ( )

. 4+HN +1 .

3ON -1 .

+1 -1 .

3ON4HN

lCaN 1 1 .

.

.

.

6

3ON

2ON

3OCH

4OSH

HO

-1

32 OC

O rC2

27

42 OS32 OS

-2

-3

+1

43 OP

4+HN

+1

K

+1

K

C

O

O O

2

H

NH

H

H

N

O

O O

1

06

1 ( 4+HN ) ( 32 OC )

: 3 42 +OC HN

2

3OC2(4HN) .

.

1 :

) O 2iL ) OnM ) 3O 2eF

) 2lCaC ) 2)2ON(aC ) 2)HO(eF

) 4OP 3aN ) 4OS 2)4HN(

2 :

) (III) ) ) (II)

) ) (II) )

) )

.

.

(II) O2H5 .4OSuC .

. (II)

C

O

O O

+1

2

3 2 4OC ) HN(

H

N

HH H

+1H

N

HH H

2 )HO( gM

H O

gMH O

N

O

aNO O

3 ON aN

16

O2H5.4OSuC 8.

.

8 (II)

) )

.

:

:

:

.

1 .

.

.

5

. .

( 10/0 ) .

2 5

.

3

26

.

5 ( )

.

. .

4 5

. .

10/0

.

. .

.

.

5 .

.

1 (

).

2 .

( _________________ = )

3 .

4 .

(_______________ = )

5 :

)g)O2Hn + )s)2lCaB )s)O2Hn.2lCaB

(n)

.

.

36

.

:

1

2

3

g g

)

.

) g802

X .

. O2H01 .4OS2aN

. O2H7 .4OSgM

. .

.

O2H01 .4OS2aN

O2H2 .4OSaC

O2H7 .4OSgM

O2H7 .4OSeF (II)

O2H5 .4OSuC (II)

O2H6 .4OSoC (II)

O2H01 .3OC2aN O2H7 .4OSeF

.

84/1

46/1

80/2

62/1

04/187/1

46

.

.

.

(O2H .3O4N3H5CaN) ( )

. .

.

() () .