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Applied Thermodynamics

應用熱力學

Chapter IIntroduction

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化學工業程序 混合、分離；

操作狀態條件的控制

化學工廠常見的分離操作程序 蒸餾

→ 氣液平衡、氣液液平衡 萃取 → 液液平衡 吸收 → 氣液平衡 結晶 → 固液平衡 吸附

→ 吸附相與流體相之平衡 超臨界萃取

→ 氣液平衡、氣固平衡

Chapter 1 Introduction

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流體熱物性與工程上之相關性

儲槽設計 → 密度、飽和壓力

蒸餾塔模擬與設計→ 氣液平衡、熱焓

程序效率分析與最適化計算→ 熱焓、熵

煤液化程序設計→ 密度、蒸氣壓、熱焓、氣液平衡、固液平衡、化學反應平衡、黏度、熱傳導度、擴散係數

Chapter 1 Introduction

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哈伯程序

魯奇煤的氣化程序

Fischer - Tropsch 程序

Chapter 1 Introduction

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煤的氣化與重要衍生程序

Chapter 1 Introduction

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History of human 1914 ~ 1918 (War I) 1939 ~ 1945 (War II)

Oh ! Human ! Ya ! Human !

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Haber – Bosch Process Fritz Haber (left, 1.0 Nobel prizes in 1918) and Carl Bosch

(right, 0.5 Nobels in 1931) have probably had a greater impact than anyone in the past 100 years, including Hitler, Gandhi, Einstein, etc. Their Haber-Bosch process has often been called the most important invention of the 20th century (e.g., V. Smil, Nature, July 29 1999, p 415) as it "detonated the population explosion," driving the world's population from 1.6 billion in 1900 to 6 billion in 2000.

Haber – Bosch Process

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History (from Google) Since the invention of the original process by the Germa

n researchers Franz Fischer and Hans Tropsch, working at the Kaiser Wilhelm Institute in the 1920s, many refinements and adjustments have been made, and the term "Fischer-Tropsch" now applies to a wide variety of similar processes (Fischer-Tropsch synthesis or Fischer-Tropsch chemistry). Fischer and Tropsch filed a number of patents, e.g. US patent no. 1,746,464, applied 1926, published 1930 [4].

Fischer-Tropsch Process

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Coal

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Lurgi coal gasification Synthesis gas

Synthesis gas Methanol synthesis Acetic acid synthesis Water-gas shift reaction Haber proces

s Fischer-Tropsch synthesis

The derivative Processfrom Synthesis Gas

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煤液化程序之架構示意圖

Coal Liquefaction Process

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劇情如何發展？敬請期待！