19th Taiwan NChO201042ndIChO201143rd IChO

(2010) 999912:~14:00

2010(2011)

() ()

()----- ()

()

() () () () ()

()

() () () ()

()-

() () ()

()

() () ()

()

() () () ()() ()()

2011

:1.2010 42nd IChO2.19:(2011) 43rd (

20th TWN NChO), IUPAC2011-1911(

)2011---- (Green Chemistry) (Sustainability) ()(),2011(Next 43rd 2011 IChOhttp://www.icho2011.metu.edu.tr/ )::2010 IChO422011 43rd (20th TWNNChO):(1) (2) (3)4010;

102(4)124(5)42(2011) 43rd (20th TWN NChO)201143()pdf (ppt)

: 2016,

201042ndIChO

201143rd IChO

(999912:30,)

,scchemts@ntnu.edu.tw()

()2010 42nd IChOhttp://icho.chem.ntnu.edu.tw

(IChO)

(2010 IChO-42):

432011(July 9~18) IChO

:1.42nd IChO (19th TWN NChO)2.

1988 Finland-201987 Hungary-191986 The Netherlands-181985 Czechoslovakia-171984 West Germany-161983 Romania-151982 Sweden-141981 Bulgaria-131980 Austria-121979 Soviet Union-111978 Poland-101977 Czechoslovakia-91976 East Germany-81975 Hungary-71974 Romania-61973 Bulgaria-51972 Soviet Union-41970 Hungary-31969 Poland-21968 Czechoslovakia-1

2015 Spain-47 (24th )2014 Viet Nam-46 (23th )2013 Russia-45 (22nd )2012 USA-44 (21th )2011 Turkey-43 (20th ) Next2010 Japan-42 (19th) just passed2009 United Kingdom-41 (18th )2008 Hungary-40 (17th)2007 Russia-39 (16th)2006 South Korea-38 (15th)

2005 -37 (14th)2004 Germany-36 (13rd)2003 Greece-35 (12nd)2002 The Netherlands-34 (11st)2001 India-33 (10th)2000 Denmark-32 (9th)1999 Thailand-31 (8th)1998 Australia-30 (7th)1997 Canada-29 (6th)1996 Russia-28 (5th)1995 China-27 (4th)1994 Norway-26 (3rd)1993 Italy-25 (2nd)1992 USA-24 (1st)

1991 Poland-231990 France-221989 East Germany-21

1(1968-2015)*

(IChO)

+

_

(24th~42th IChO): 30 35 1024 ( 6) (#11)

25 ( 1) (#1)26 ( 8) (#31)

27 ( 13) (#28)28 ( 7) (#16)29 ( 1) (#10)

30 ( 8) (#7)31 ( 5) (#19)32 ( 3) (#5)

33 ( 9) (#24)34 ( 3) (#7, #13)35 ( 10) (#18)36 ( 7) (#14)37 ( 5) (#8)38 ( 2) (#2 , #2)

39 ( 3) (#6)40 ( 5) (#21) 41 ( 1) (#3)42 ( 4) (#10)

(2010 IChO-42) 68

19(,1)(, 2)(, 4)2010719281502010(,3)(, 2) (, 3)(, 4)68267(5)( 10/267)( 32/267) ; ( 43/267)( 47/267) 6819303510

85.182()

86.581()

88.756()

92.809()

42nd 2010 IChO()

28.45828.04830.60835.88540%42nd IChO

38.046.050.048.650(16)P3.

22.0(49%)4.0(9%)22.0(49%)30.0(67%)45(11)P2.Fe(II)Fe(III)

33.638.028.440.040(13)P1.

(40%)

56.72458.52858.14856.91260%42nd IChO

3034333434(7)9NMR

2020201920(6)8.

2324212124(7)7.tetrodotoxin

2326262426 (6)6.C8H

10O

1717181718(7)5. H2

88878(6)4.

9899973.COD

171919192062.

161716171781.

(3 )(4 )( 2)( 1)()

TPE-S4TPE-S3TPE-S2TPE-S1

(60%)

Table 2. (60%)

0.8810.9710.62T -9

1110.950.62T -8

1110.880.71T -7

0.88110.920.55T -6

0.940.9410.940.61T -5

1110.880.58T -4

11110.72T -3

0.850.950.950.950.82T -2

0.9410.9410.75T -1

ST4

ST3

ST2

ST1

0.76 0.92 10.97 0.65 P-3

0.49 0.09 0.49 0.67 0.65 P-2

0.84 0.950.71 10.69 P-1

ST4

ST3

ST2

ST1

Table 4. (40)

85.19

86.58

88.76

92.81

28.46

28.05

30.61

35.89

(40)

56.73

58.53

58.15

56.92

(60)

ST4

ST3

ST2

ST1

Table 5.

CombatJuly 7(),8() 2010)

()::

57

719731

192040

1.41 4284, 10%!

2. 1942

3.IUPAC 2011-1911()2011---- (Green Chemistry)(Sustainability) ()(), 2011

(Next 43rd 2011 IChO http://www.icho2011.metu.edu.tr/ )

43IChO -(20th TWN ChO)

99.12.3~12.10

R.1()

99.12.18

R.2(50)(502)

12100.2.7 ~ 2.19

(44)

100.6.6 ~ 7.03

99.7.9 ~ 7.18

R.3 (123)

100.4.25 ~ 5. 15

10

2(?)100. 12. 9~11()

40(10)

12(4)

4(2)

100: 2011127~28