2010 annual report · five (5) monitoring wells around the perimeter of the site and one (1)...

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2010 ANNUAL REPORT RED ROCK WASTE DISPOSAL SITE (A412307) TOWNSHIP OF KILLALOE, HAGARTY AND RICHARDS COUNTY OF RENFREW, ONTARIO Prepared for THE CORPORATION OF THE TOWNSHIP OF KILLALOE, HAGARTY AND RICHARDS March 29, 2011 Greenview File: 107.10.004 Greenview Environmental Management Limited 69 Cleak Avenue, PO Box 100 Bancroft, Ontario K0L 1C0 tel: (613) 332-0057 fax: (613) 332-1767 email: [email protected]

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Page 1: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

22001100 AANNNNUUAALL RREEPPOORRTT RREEDD RROOCCKK WWAASSTTEE DDIISSPPOOSSAALL SSIITTEE ((AA441122330077)) TTOOWWNNSSHHIIPP OOFF KKIILLLLAALLOOEE,, HHAAGGAARRTTYY AANNDD RRIICCHHAARRDDSS CCOOUUNNTTYY OOFF RREENNFFRREEWW,, OONNTTAARRIIOO

Prepared for

TTHHEE CCOORRPPOORRAATTIIOONN OOFF TTHHEE TTOOWWNNSSHHIIPP OOFF KKIILLLLAALLOOEE,, HHAAGGAARRTTYY AANNDD RRIICCHHAARRDDSS

March 29, 2011

Greenview File: 107.10.004

Greenview Environmental Management Limited 69 Cleak Avenue, PO Box 100 Bancroft, Ontario K0L 1C0 tel: (613) 332-0057 fax: (613) 332-1767 email: [email protected]

Page 2: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page i

EEXXEECCUUTTIIVVEE SSUUMMMMAARRYY

This report has been prepared to document the results of the 2010 environmental monitoring program for

the Township of Killaloe, Hagarty and Richards Red Rock waste disposal site, located on Part Lot 11,

Concession 7, within the geographic Township of Richards, in the amalgamated Township of Killaloe,

Hagarty and Richards. The site is located approximately 24 kilometres north of the Village of Killaloe,

accessed by Beechnut Lake Road, extending north from County Road 58.

The Red Rock waste disposal site operates in accordance with Provisional Certificate of Approval

A412307, for the transfer of municipal solid waste generated within the Township of Killaloe, Hagarty and

Richards. The site consists of 1.0 hectare of approved landfilling area, within 3.583 hectares of total

property area. In accordance with Condition 40 of the Provisional Certificate of Approval, the Township of

Killaloe, Hagarty and Richards acquired lands from the Crown for the landfilling area, operational buffer and

contaminant attenuation zone purposes on May 11, 2010; the Certificate of Requirement for the Red Rock

site was registered on title on December 10, 2010, in accordance with Condition 42 of the Provisional

Certificate of Approval for the Red Rock site.

In 2010, groundwater quality immediately downgradient of the waste mound continues to exhibit impacts

from landfill-derived leachate. Consistent with historical results, exceedances of the Ontario Drinking

Water Standards were observed for alkalinity (low), dissolved organic carbon, field-tested pH (low), and

iron at select wells.

The exceedances of the Reasonable Use Concept for field-tested pH (low) at monitoring wells MW06-7

and MW06-8 are interpreted to be related to low alkalinity concentrations in the background resultant of

naturally-occurring conditions at the site. The dissolved organic carbon concentration at MW06-7 which

was observed in August 2010 to equal the Reasonable Use Concept is interpreted to be related to landfill-

leachate; however, the dissolved organic carbon concentration is similar to historical results and is not

interpreted to represent an increasing trend. Further monitoring is required to confirm the relationship

between dissolved organic carbon concentrations at MW06-7 and the Red Rock site. Based on the

aforementioned interpretations of groundwater quality at the downgradient contaminant attenuation zone

boundary, the Red Rock site is interpreted to meet the intent of the Ontario Ministry of Environment

Guideline B-7 and the Reasonable Use Concept in 2010.

Based on Township of Killaloe, Hagarty and Richards records, approximately 4,621 vehicles visited the

Red Rock site in 2010, with approximately 4,026 bags of residential waste received for transfer to the

Township’s Killaloe site for disposal. Additionally based on Township records, 1,897 bags of containers

Page 3: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page ii

(tin/aluminum/plastic/glass), and 949 bags of fibres were collected at the Red Rock site in 2010 and

transferred to the Township’s Killaloe site for pickup by Beaumen Waste Management Systems Ltd.

Recycling tonnage records provided by Beaumen Waste Management Systems Ltd. and the Township of

Killaloe, Hagarty and Richards indicate that a total of approximately 204 tonnes of recyclable material was

received at the Killaloe waste disposal site in 2010. Recyclable quantities contributing to this total included

approximately 65 tonnes of containers (tin/aluminum/plastic/glass), and 79 tonnes of fibres. Recycling

tonnages noted above for the Killaloe waste disposal site include quantities of recycling received and

transported to the Beaumen Waste Management Systems Ltd. in Renfrew, Ontario from the Township’s

Round Lake and Red Rock sites, and the Township’s curbside service in the Village of Killaloe in 2010.

Page 4: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page iii

TTAABBLLEE OOFF CCOONNTTEENNTTSS

1.0 INTRODUCTION ...................................................................................................... 1

1.1 SITE INFORMATION .................................................................................................................... 1

1.2 BACKGROUND ............................................................................................................................ 1

1.3 PURPOSE AND SCOPE .............................................................................................................. 2

2.0 SITE DESCRIPTION ................................................................................................. 3

2.1 TOPOGRAPHY AND DRAINAGE ................................................................................................ 3

2.2 HYDROGEOLOGICAL CONDITIONS .......................................................................................... 3

2.3 OPERATIONAL SETTING ............................................................................................................ 4

3.0 2010 ENVIRONMENTAL MONITORING PROGRAM ...................................................... 5

3.1 GROUNDWATER MONITORING ................................................................................................ 5

3.2 SURFACE WATER MONITORING .............................................................................................. 6

3.3 ANALYTICAL LABORATORY ACCREDITATION ........................................................................ 6

3.4 LANDFILL GAS MONITORING .................................................................................................... 6

3.5 OPERATIONAL MONITORING .................................................................................................... 6

4.0 ENVIRONMENTAL MONITORING RESULTS ................................................................. 8

4.1 GROUNDWATER QUALITY ASSESSMENT ............................................................................... 8

4.1.1 Groundwater Configuration ....................................................................................................... 8

4.1.2 Groundwater Quality .................................................................................................................. 8

4.1.3 Reasonable Use Concept Assessment ................................................................................... 11

4.2 OPERATIONS SUMMARY ......................................................................................................... 12

4.2.1 Site Operations ........................................................................................................................ 13

4.2.2 Waste Disposal / Transfer Summary ....................................................................................... 13

4.2.3 Site Inspections and Maintenance ........................................................................................... 14

4.2.4 Complaints ............................................................................................................................... 14

5.0 CONCLUSIONS AND RECOMMENDATIONS ............................................................... 15

6.0 CLOSING ............................................................................................................. 17

7.0 REFERENCES ...................................................................................................... 18

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page iv

LLIISSTT OOFF TTAABBLLEESS

Table 1 2010 Groundwater Monitoring Program

Table 2 Groundwater Elevations

Table 3 Groundwater Quality

LLIISSTT OOFF FFIIGGUURREESS

Figure 1 Regional Location Plan

Figure 2 Environmental Monitoring Location Plan

Figure 3 Existing Site Conditions Plan

LLIISSTT OOFF AAPPPPEENNDDIICCEESS

Appendix A Provisional Certificate of Approval A412307

Appendix B MNR Land Use Permit LUP1675-1006299

Appendix C Correspondence

Appendix D Borehole Logs

Appendix E Field Sampling Records

Appendix F Laboratory Certificates of Analysis

Appendix G Statement of Service Conditions and Limitations

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 1

11..00 IINNTTRROODDUUCCTTIIOONN

1.1 SITE INFORMATION

The Red Rock waste disposal site is currently operating as a municipal solid waste and recycling transfer

station under Provisional Certificate of Approval (PC of A) A412307, as amended December 5, 2007

(Appendix A), and services the residents of the Township of Killaloe, Hagarty, and Richards. The Red

Rock site is located approximately three (3) kilometres (km) north of Bonnechere Provincial Park on Part

Lot 11, Concession VII, in the geographic Township of Richards, in the amalgamated Township of Killaloe,

Hagarty and Richards (Township), in Renfrew County. The site is accessed from Beechnut Lake Road

(Figure 1), and prior to May 11, 2010, the site was situated on Crown land which was leased to the

Township by the Ontario Ministry of Natural Resources (MNR) under Land Use Permit (LUP) 1675-

1006299 (Appendix B). The Red Rock site is approved for the operation of a 1.0 hectare (ha) landfill and

transfer station (Appendix A); on May 11, 2010, the Township acquired 3.58 ha of land from the Crown for

landfilling area, operational buffer and contaminant attenuation zone (CAZ) purposes in order to satisfy

Condition 40 of the PC of A (Appendix C).

Waste and recyclables collected at the Red Rock site are transferred to the Township’s Killaloe waste

disposal site for final disposal and processing.

1.2 BACKGROUND

The Red Rock waste disposal site had received domestic waste for landfilling from within the geographic

Township of Richards since 1979; however, in March 2004, the Ontario Ministry of the Environment (MOE)

issued a Provincial Officer Order (P142086) indicating that landfilling practices at the time were not

consistent with the PC of A for the site. As a result of the Provincial Officer Order, and as instructed in

correspondence from the MOE dated March 30, 2004, the Township ceased landfilling operations at the

site in 2004, and established a mobile municipal solid waste and recycling transfer station at the Red Rock

site.

Further to MOE approval of the property area for CAZ purposes, received in correspondence dated

August 24, 2007 (Greenview, 2008), the Township continued negotiations with the MNR for the acquisition

of the 3.583 ha approved CAZ (Figure 2) in order to satisfy Condition 40 of the PC of A. On May 11, 2010,

the Township acquired the 3.583 ha from the Crown for landfilling area, operational buffer, and CAZ

purposes (Appendix A and C). In order to satisfy Condition 42 of the PC of A, the Certificate of

Requirement was registered on title on December 10, 2010, which the Township subsequently submitted to

the MOE Director and the MOE Ottawa District Office (Appendix A and C).

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 2

Greenview was retained by the Township to complete the 2010 environmental monitoring and reporting

program at the Red Rock waste disposal site.

1.3 PURPOSE AND SCOPE

The purpose of this report is to provide an overview of the annual environmental monitoring, environmental

compliance, and operations at the Red Rock waste disposal site, per Condition 43 of the site PC of A,

including the following:

• Groundwater quality assessment and Reasonable Use Concept (RUC; MOE Guideline B-7) compliance

(Section 4.1).

• Site operational overview and capacity assessment (Section 4.2).

• Conclusions and recommendations for future monitoring programs at the site (Section 5.0).

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 3

22..00 SSIITTEE DDEESSCCRRIIPPTTIIOONN

The following sections present a summary of the physical characteristics for the Red Rock waste disposal

site.

2.1 TOPOGRAPHY AND DRAINAGE

The Red Rock waste disposal site is located on a relatively flat, sandy plain area, surrounded by forested

Crown lands, and situated approximately 1.5 km northeast of Round Lake. There are no surface water

courses in the immediate vicinity of the waste mound, however approximately 100 metres (m) north and

upgradient of the Red Rock site is a pond, which represents the only sizable surface water body in the

immediate area (Figure 2). A small creek discharges from the eastern end of the pond, which flows

southeast and under County Road 58. Approximately 325 m southeast of County Road 58, the small

tributary converges with another small creek originating from Jacks Lake. Following convergence, the

creek flows to the southwest, eventually discharging into Round Lake.

2.2 HYDROGEOLOGICAL CONDITIONS

Overburden at the Red Rock waste disposal site was investigated and characterized by the installation of

five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste

mound, in August 2004 (SGS Lakefield Research Limited [SGS], 2005; Figure 2). The monitoring wells

were installed in fine-grained, brown to grey sand, to depths ranging from 6.1 to 8.2 m below ground

surface (bgs). Groundwater elevations ranged from 4.49 to 7.16 m bgs during the initial groundwater

sampling event in August 2004, following the monitoring well installations (SGS, 2005; Appendix D).

As part of the 2006 environmental work program at the site, two (2) additional monitoring wells (MW06-7

and MW06-8) were installed at the Crown land boundary, slightly upgradient (north) of the County Road 58

right-of-way (Greenview, 2007; Figure 2). Overburden in this area is similar to that in the vicinity of the site

with a shallow layer of dark organic soil overlaying layers of brown to grey fine to medium sand, and

localized pockets of light brown medium to coarse sand, and sub-angular to sub-rounded gravels.

Available borehole logs for monitoring wells are provided in Appendix D.

Historically, the direction of groundwater flow within the shallow overburden unit at the Red Rock site is to

the south and southeast (Figure 2).

Further to MOE TSS groundwater comments dated August 24, 2007 (Greenview, 2008), one (1) seasonal

residence is located within 500 m of the landfill; however, it is located upgradient of the interpreted direction

of groundwater flow and is not considered to be impacted by landfill-related activities (Figure 2).

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 4

2.3 OPERATIONAL SETTING

Prior to May 11, 2010, the Red Rock waste disposal site consisted of an approved waste disposal area of

1.0 ha within a total property area of 1.7 ha, situated on Crown land under lease from the MNR under LUP

1675-1006299 (Appendix B). Following the Township’s acquisition of Crown land for landfilling area,

operation buffer, and CAZ purposes on May 11, 2010, the Red Rock site currently is situated on 3.58 ha of

total property area (Appendix C; Figure 2). Adjacent to the eastern boundary of the Red Rock site is a

former Ontario Ministry of Transportation (MTO) Works Yard (Figure 2).

The Township installed two (2) additional monitoring wells at the Red Rock site in 2006 per MOE

recommendations (Greenview, 2007). As part of the 2008 environmental monitoring program at the site,

and further to the MOE TSS groundwater review memorandum dated August 24, 2007, in which the lands

proposed for CAZ (Figure 2) were deemed to be sufficient, the Township continued negotiations with the

MNR to acquire the lands for the landfilling area, operational buffer, and CAZ purposes downgradient of the

site (Greenview, 2008). On May 11, 2010, the Township completed the acquisition of the approved CAZ

lands from the Crown, and subsequently the Certificate of Requirement was registered on title on

December 10, 2010 and submitted to the MOE (Appendix C).

The site currently operates as a municipal solid waste and recycling transfer station, and has been closed

to landfilling operations since 2004. As part of waste transfer operations at the site, the Township

maintains a site attendant’s office, and during operational hours, a mobile compactor truck and recycling

depot (Figure 3). Domestic waste and blue box recyclables received at the site are deposited in the mobile

compactor truck and recycling totes for disposal and transfer at the Killaloe waste disposal site, as

applicable to the waste type.

Bulk recyclables such as scrap metal, white goods, tires, etc., as well as brush and clean wood are not

accepted at the Red Rock site; these materials are directed to the Killaloe waste disposal site for disposal

and management. Old corrugated cardboard (OCC) from the entire Township is directed to the Killaloe site

for management.

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 5

33..00 22001100 EENNVVIIRROONNMMEENNTTAALL MMOONNIITTOORRIINNGG PPRROOGGRRAAMM

The following sections present a methodology of the environmental monitoring conducted at the Red Rock

waste disposal site in 2010.

3.1 GROUNDWATER MONITORING

As part of the 2010 environmental monitoring program, groundwater monitoring and sampling was

completed at the Red Rock site by Greenview on May 10, 2010 and August 17, 2010 from the network of

existing groundwater monitoring wells (Table 1). All eight (8) monitoring wells were sampled as part of the

2010 environmental monitoring program, and groundwater elevations were measured at each monitoring

well using an electronic water level tape prior to sampling. Based on the groundwater elevation a well

purge volume equivalent to approximately three (3) borehole volumes was calculated in-situ using a

standard conversion factor relevant to the respective well diameter.

Groundwater samples were collected from each monitoring well using dedicated polyethylene tubing and

inertial lift foot-valves, and were analyzed for the parameter suite listed in Table 1. Samples were collected

into appropriate sample bottles as provided by an accredited laboratory and the designated sample bottle

for metal parameters was field-filtered using a dedicated High Capacity 45 micron filter to reduce the

potential for turbidity-induced bias in the analytical results for the metal parameters.

Volatile organic compounds (VOCs) were not sampled as part of the 2010 groundwater monitoring program

at the site; the next scheduled sampling event for VOCs at the Red Rock site is in 2011 (Table 1).

A duplicate groundwater sample for Quality Assurance and Quality Control (QA/QC) purposes was

obtained from monitoring well BH04-1 for the May 10, 2010 sampling event and from BH04-4 for the

August 17, 2010 sampling event.

Field measurements of pH, dissolved oxygen (DO), conductivity, and temperature were recorded at each

respective groundwater well immediately following the collection of the groundwater samples. Field

sampling records completed during the 2010 monitoring program are included in Appendix E. The

groundwater samples were recorded on a laboratory Chain of Custody Form, and the samples were placed

in coolers packed with contained ice for preservation during transport to the analytical laboratory.

The results of the 2010 groundwater monitoring program are presented in Section 4.1.

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 6

3.2 SURFACE WATER MONITORING

As documented in the 2006 Annual Report (Greenview, 2007), and further to MOE TSS surface water

review comments dated October 20, 2005, a surface water monitoring program was established at the Red

Rock site as part of the 2006 environmental monitoring program (Greenview, 2007).

Based on the results of the 2006 surface water monitoring program at the site, which were presented in the

2006 Annual Report (Greenview, 2007), it was determined that the Red Rock waste disposal site was not

having an impact on adjacent surface water systems at/near the site. As such, and in accordance with

MOE TSS surface water review comments on the 2006 Annual Report (Greenview, 2007) dated

November 28, 2007, in which the results of the 2006 surface water program were confirmed, the surface

water monitoring program was discontinued at the site in 2007 (Greenview, 2008). The amendments to the

environmental monitoring program at the site, including the discontinuation of the surface water monitoring

program, were detailed in correspondence to the MOE Environmental Assessment and Approvals Branch

(EAAB) dated May 8, 2007 (Greenview, 2008), and were approved in an amendment to the PC of A

(A412307) dated December 5, 2007 (Appendix A).

3.3 ANALYTICAL LABORATORY ACCREDITATION

Collected groundwater samples were submitted for analysis to the SGS Environmental Laboratory (SGS),

located in Lakefield, Ontario. SGS is accredited by the Standards Council of Canada (SCC) and the

Canadian Association for Laboratory Accreditation (CALA), for specific environmental testing procedures

listed in the scope of accreditation. SGS is licensed by the MOE to perform analysis on Drinking Water in

Ontario in accordance with the Safe Drinking Water Act.

3.4 LANDFILL GAS MONITORING

Landfill gas monitoring is not part of the current environmental monitoring program for the site. The waste

mound at the Red Rock site is covered with porous soil materials allowing natural gas flux to the

atmosphere. Overburden geology at and adjacent to the site is characterized by shallow, sandy materials,

with localized pockets of minor gravel, which, coupled with the extended distance to the nearest residence,

provide a minimal risk of landfill gases impinging off-site receivers.

3.5 OPERATIONAL MONITORING

Operational monitoring at the Red Rock site is minimal given that the site operates as a mobile municipal

solid waste and recycling transfer station only, with received domestic waste and recyclables transported to

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 7

the Township’s Killaloe site for final disposal and/or processing. Due to the Red Rock site’s operations, a

topographic survey of the waste mound was not required in 2010.

Daily waste records for the Red Rock site are completed as part of regular site operations to monitor

vehicular traffic, and recycling depot operations. The Township submits annual waste diversion reports in

accordance with the Waste Diversion Ontario (WDO) Municipal Datacall, inclusive of the Red Rock site, to

WDO.

The results of the 2010 operational monitoring are presented in Section 4.2.

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 8

44..00 EENNVVIIRROONNMMEENNTTAALL MMOONNIITTOORRIINNGG RREESSUULLTTSS

The following sections present a summary of the environmental monitoring results obtained during the Red

Rock waste disposal site 2010 environmental monitoring program.

4.1 GROUNDWATER QUALITY ASSESSMENT

The results of the 2010 groundwater monitoring program conducted at the site are presented as follows.

4.1.1 GROUNDWATER CONFIGURATION

Historically, the groundwater configuration at the site has been interpreted to flow towards the south and

southeast, in the general direction of Round Lake (Figure 2). The direction of groundwater flow within the

shallow overburden unit at the Red Rock site with the inclusion of 2010 groundwater elevations is

consistent with historical interpretations, and is interpreted to be toward the south and southeast (Figure 2).

Groundwater elevation data obtained during the 2010 groundwater monitoring program at the site is

provided in Table 2. Average horizontal gradients in the vicinity of the waste mound, and southeast of the

waste mound were calculated in May 2010 to be 0.016 and 0.015, respectively.

4.1.2 GROUNDWATER QUALITY

The results of the 2010 groundwater monitoring program are presented in Table 3 and the accredited

laboratory Certificates of Analysis are attached in Appendix F. Analytical data obtained from respective

groundwater wells have been compared to the Ontario Drinking Water Standards (ODWS; MOE, 2003),

background water quality at the site, and MOE Guideline B-7 and the RUC (MOE, 1994a).

Background groundwater quality at the Red Rock site has historically been interpreted from sampling at

monitoring wells BH04-1 and BH04-3, as these wells are located upgradient of the waste mound (Figure 2).

The water quality results from the background wells correspond with historical results (Table 3); however,

some trends are apparent. Monitoring well BH04-1 was observed to have minor decreasing trends for

barium, chloride, and conductivity, whereas monitoring well BH04-3 was interpreted to have a minor

decreasing trend with respect to sodium (Table 3). Consistent with historical results (Greenview, 2010),

monitoring well BH04-1 was observed to exceed ODWS for alkalinity (low) in May and August 2010 and

field-tested pH (low) in August 2010; however, lab-tested pH did not exceed ODWS for the same sampling

event (Table 3). Similarly, monitoring well BH04-3 exceeded ODWS for alkalinity (low) in May and August

2010, and field-tested pH (low) in August 2010; however, lab-tested pH did not exceed ODWS for the same

sampling event (Table 3). Groundwater quality at monitoring wells BH04-1 and BH04-3 remains

representative of background water quality in the area of the site.

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 9

Monitoring well BH04-2 is located within the waste mound, and has historically been used to determine

the leachate quality at the Red Rock site; however, consistent with 2009 results (Greenview, 2010),

groundwater quality in 2010 suggests that downgradient monitoring well BH04-5 is most impacted from

landfill-leachate (Table 3; Figure 2). When compared with background water quality, most parameter

concentrations remain elevated above background levels at BH04-2 (Table 3). During both the May and

August 2010 sampling events, concentrations of iron exceed ODWS, though iron has consistently

exceeded ODWS limits since August 2004 (Table 3; Greenview, 2010). Additionally, field-tested pH (low)

was noted to exceed ODWS in August 2010; however, lab-tested pH did not exceed ODWS for the same

time period (Table 3). Similar to historical reports, monitoring well BH04-2 was observed to have

decreasing trends for alkalinity, ammonia, barium, dissolved organic carbon (DOC), and sodium following

the inclusion of 2010 results (Table 3). Monitoring well BH04-2 continues to present characteristics

indicative of landfill-related activities in 2010.

Groundwater quality immediately downgradient of the waste disposal site is characterized by monitoring

wells BH04-4, BH04-5, and BH04-6 (Figure 2).

Groundwater monitoring well BH04-4 is located along the eastern CAZ boundary, near the south-eastern

corner of the approved waste disposal area (Figure 2). Consistent with historical interpretations, most

parameter concentrations remain elevated above background levels at monitoring well BH04-4

(Greenview, 2010; Table 3). Monitoring well BH04-4 was observed to exceed ODWS for field-tested

pH (low) in May and August 2010; however, lab-tested pH values were noted to be within the acceptable

ODWS range for the same sampling period (Table 3). Following the inclusion of 2010 data, a decreasing

trend was observed for sulphate at monitoring well BH04-4 (Table 3). Monitoring well BH04-4 continues to

exhibit slight landfill-related impacts with the inclusion of 2010 water quality; however, BH04-4 may be

impacted from off-site sources, as it is located adjacent to a former MTO Works Yard (Figure 2).

Monitoring well BH04-5 is located approximately 10 m south and downgradient of the approved waste

disposal area at the Red Rock site (Figure 2). Consistent with historical results, monitoring well BH04-5

exhibits most parameter concentrations elevated above background levels, with some parameters

observed to be higher in concentration than at monitoring well BH04-2, which is located directly within

the waste mound (Table 3; Figure 2). In May and August 2010, monitoring well BH04-5 was observed

to have ODWS exceedances of DOC and iron, which is consistent with historical results

(Table 3; Greenview, 2010). Additionally, field-tested pH (low) was noted to exceed ODWS in

August 2010; however, the lab-tested pH value was noted to be within the acceptable ODWS range for the

same sampling period (Table 3). A decreasing trend was observed at monitoring well BH04-5 for chloride

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 10

following the inclusion of 2010 data (Table 3). Monitoring well BH04-5 continues to exhibit groundwater

quality that appears to be most impacted from landfill-leachate at the site (Table 3).

Groundwater monitor BH04-6 is located south and downgradient of the waste mound, and approximately

75 m west of monitoring well BH04-5 (Figure 2). Consistent with historical results, most parameter

concentrations at monitoring well BH04-6 were elevated above background concentrations in 2010

(Greenview, 2010; Table 3). In 2010, ODWS exceedances were observed for field-tested pH (low) in May

and August 2010, and for alkalinity (low) in August 2010; however, lab-tested pH values were noted to be

within the acceptable ODWS range for the same sampling period (Table 3). Following inclusion of 2010

results, no significant trends were noted at BH04-6 (Table 3). Groundwater quality at monitoring well

BH04-6 may be slightly impacted by leachate; however, the majority of parameter concentrations are

significantly decreased in magnitude from values found at monitoring well BH04-5 (Table 3; Figure 2).

Monitoring wells MW06-7 and MW06-8 are located downgradient of the site at the southern CAZ boundary,

and approximately 20 m north of County Road 58 (Figure 2). Monitoring well MW06-7 is situated near the

south-eastern corner of the CAZ, whereas MW06-8 is positioned near the mid-point of the southern extent

of the CAZ. Many of the parameter concentrations were observed to be slightly elevated above

background groundwater quality at both monitoring wells; however, parameter concentrations are

significantly decreased in magnitude from water quality data obtained from monitoring wells closer to the

site, indicating that attenuation is occurring downgradient of the waste mound (Table 3). In many cases,

concentrations observed at MW06-7 and MW06-8 are comparable to background groundwater quality at

the site.

For the 2010 environmental monitoring program, monitoring wells MW06-7 and MW06-8 were observed to

have ODWS exceedances for alkalinity (low) and field-tested pH (low) for both the May and August 2010

sampling events; however, lab-tested pH values were noted to be within the acceptable ODWS range for

the same sampling periods (Table 3). Following the inclusion of 2010 data, no significant trends were

observed at monitoring well MW06-7, and monitoring well MW06-8 was noted to have decreasing trends

for calcium, chloride, conductivity, sodium, and total dissolved solids (TDS; Table 3). Ultimately, the

majority of parameter concentrations at MW06-7 and MW06-8 are decreased in magnitude from monitoring

wells in close proximity to the site, indicating that attenuation is occurring downgradient of the waste

mound.

The blind duplicate samples collected at monitoring well BH04-1 in May 2010, and at BH04-4 in

August 2010 were similar to the identified samples indicating that the results of the 2010 groundwater

monitoring program can be interpreted with confidence.

Page 16: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 11

4.1.3 REASONABLE USE CONCEPT ASSESSMENT

In an effort to assess potential leachate impacts migrating beyond the CAZ boundary, the MOE’s RUC was

used as an assessment tool to monitor downgradient impacts from the waste disposal site. Downgradient

impacts are typically assessed using the MOE RUC at monitoring wells located at, or in close proximity to,

the downgradient CAZ boundary. The downgradient monitoring wells located near the CAZ boundary were

compared to trigger concentrations for specific parameters as determined by leachate quality at the site

using the MOE’s RUC for groundwater (MOE Procedure B-7-1, 1994a).

The MOE Procedure B-7-1: Determination of Contaminant Limits and Attenuation Zones iterates that in

accordance with the appropriate criteria for particular uses, a change in groundwater quality on an adjacent

property as a result of landfilling activities will only be accepted by the MOE as follows:

The quality cannot be degraded by an amount in excess of 50% of the difference

between background and the Ontario Drinking Water Standards for non-health related

parameters and in excess of 25% of the difference between background and the Ontario

Drinking Water Standards for health related parameters. Background is considered to

be the quality of the groundwater prior to any man made contamination.

MOE Procedure B-7-1

The RUC assessment was conducted using the concepts and procedures outlined in MOE Procedure

B-7-1 (MOE, 1994a), specifically using the median value of individual background parameter

concentrations from monitoring wells BH04-1 and BH04-3, to characterize natural groundwater quality at

the site. Groundwater monitoring wells MW06-7 and MW06-8 were used to monitor downgradient water

quality south of the Red Rock site on the north side of County Road 58, for assessing site compliance with

the MOE RUC at the CAZ boundary (Figure 2).

All parameters tested as part of the established annual monitoring program were used as groundwater

triggers, and a respective RUC criteria value was calculated for each parameter at the Red Rock waste

disposal site. The trigger concentrations used to assess RUC compliance for the groundwater regime at

the site is based on the MOE RUC for each of the respective parameters.

The RUC values for individual parameters should be generated each year based on analytical results

obtained from the groundwater monitoring program. If RUC exceedances are noted, then action will be

undertaken as appropriate and necessary in accordance with a defined groundwater contingency plan for

the site. In cases where a groundwater contingency plan is not defined, a meeting with representatives of

Page 17: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 12

the MOE District Office should be held to develop an appropriate contingency plan, as necessary and

appropriate for the particular site.

Monitoring well MW06-7 was observed to exceed the RUC for field-test pH (low) in May and August 2010;

however, lab-tested pH did not exceed the RUC for the same time period (Table 3). Monitoring well

MW06-7 was noted to be equal to the RUC for DOC (3.0 mg/L) in August 2010 (Table 3). Since field-

tested pH (low) was noted to be below the RUC limits at both background monitoring wells (BH04-1 and

BH04-3) in August 2010, and low alkalinity concentrations are historically noted at MW06-7 and in the

background monitoring wells BH04-1 and BH04-3, the exceedances of RUC for field-tested pH (low) at

MW06-7 in 2010 are interpreted to be the result of naturally-occurring conditions at the site (Table 3). The

DOC concentration equalling the RUC at MW06-7 in August 2010 is interpreted to be partially related to

landfill-leachate from the Red Rock site; however, the DOC concentrations observed in 2010 are

comparable to historical results and do not appear to have an increasing trend (Table 3). Further

monitoring of groundwater quality at MW06-7 is required to determine the significance of the observed

DOC concentrations at the downgradient monitoring well. Therefore, with the exception of DOC equalling

the RUC at MW06-7, the Red Rock site is interpreted to meet the intent of MOE Guideline B-7 at

monitoring well MW06-7 located at the downgradient CAZ boundary in 2010.

Monitoring well MW06-8 was noted to exceed RUC for field-tested pH (low) in May and August 2010

following inclusion of 2010 results; however, lab-tested pH did not exceed the RUC for the same time

period (Table 3). Since field-tested pH (low) was noted to be below the RUC limits at both background

monitoring wells (BH04-1 and BH04-3) in August 2010, and low alkalinity concentrations are historically

noted at MW06-8 and in the background monitoring wells, the exceedances of RUC for field-tested pH

(low) at MW06-8 in 2010 are interpreted to be the result of naturally-occurring conditions at the site

(Table 3). Therefore, the Red Rock site is interpreted to be in compliance with RUC and conformance with

MOE Guideline B-7 at monitoring well MW06-8 at the downgradient CAZ boundary in 2010.

Based on the results of the 2010 environmental monitoring program, the Red Rock site is interpreted to

meet the intent of MOE Guideline B-7 at the downgradient CAZ boundary in 2010.

4.2 OPERATIONS SUMMARY

A summary of 2010 waste management operations at the Red Rock waste disposal site is presented

below.

Page 18: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 13

4.2.1 SITE OPERATIONS

The site currently operates as a mobile municipal solid waste and recycling transfer station, servicing the

residents within the geographic boundaries of the Township of Killaloe, Hagarty, and Richards

(PC of A A412307). The site has been closed to landfilling operations since 2004.

A sign is posted at the entrance to the site which provides the PC of A number, the Waste Management

By-law number for the Township, permitted users, accepted waste and recycling materials, hours of

operation, and emergency contact information.

Hours of operation at the Red Rock site, are as follows:

Operational Hours

Thursday 12:30 p.m. – 4:00 p.m.

Sunday 12:30 p.m. – 4:00 p.m.

Holiday Monday (May – October) 2:00 p.m. – 6:00 p.m.

The majority of the Red Rock waste disposal site is well screened with surrounding trees and thick

vegetation. A lockable gate is present at the site entrance, controlling access to the waste mound and

facilities on-site, while a page wire fence exists around the perimeter of the site (Figure 3).

The access roads at the site entrance and within the Red Rock site have sufficient width to allow for

unimpeded winter travel and access for emergency and snow removal equipment. The site access road

was observed to be in serviceable condition during the routine site inspections conducted by Greenview

during various site visits throughout 2010.

4.2.2 WASTE DISPOSAL / TRANSFER SUMMARY

The Red Rock waste disposal site is currently closed to active landfilling operations; however, the site

operates as a mobile solid waste and recycling transfer station, with all domestic waste and recyclables

transferred to the Township’s Killaloe site for final disposal/market.

The Red Rock site is currently approved in accordance with PC of A A412307 (Appendix A) to receive up

to a maximum of 16 cubic metres (m3) of non-hazardous municipal waste in a mobile compactor vehicle,

and for segregation of regular blue-box recyclables into a maximum of eighteen (18) 360 litre (L) bins on a

mobile-trailer unit. Bulk recyclables such as scrap metal, white goods, tires, etc., as well as brush and

clean wood are not accepted at the Red Rock site, and are directed to the Killaloe waste disposal site for

management. OCC is also directed to the Killaloe site for management.

Page 19: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 14

Based on Township records, approximately 4,621 vehicles visited the Red Rock site in 2010, with

approximately 4,026 bags of residential waste received for transfer to the Township’s Killaloe site for

disposal. Additionally, based on Township records 1,897 bags of containers (tin/aluminum/plastic/glass),

and 949 bags of fibres were received at the Red Rock site in 2010 and transferred to the Township’s

Killaloe site for pickup by Beaumen Waste Management Systems Ltd. (Beaumen).

Recycling tonnage records provided by Beaumen and the Township indicate that a total of approximately

204 tonnes of recyclable material were received at the Killaloe waste disposal site in 2010. Recyclable

quantities contributing to this total included approximately 65 tonnes of containers

(tin/aluminum/plastic/glass), and 79 tonnes of fibres. Recycling tonnages noted above for the Killaloe

waste disposal site include quantities of recycling received and transported to Beaumen in Renfrew,

Ontario from the Township’s Round Lake and Red Rock sites in 2010, and the Township’s curbside

collection within the Village of Killaloe.

4.2.3 SITE INSPECTIONS AND MAINTENANCE

Site inspections of the waste disposal area and property at the Red Rock site were conducted by

Greenview on May 10, 2010 and August 17, 2010 during the spring and summer 2010 sampling events.

The Township also conducted periodic investigations to verify the compliance status of the site.

The site inspections included a cursory investigation of housekeeping/litter control aspects, monitoring well

maintenance requirements in accordance with O. Reg. 903 (Wells), as amended, and a general site

overview for MOE regulatory compliance issues. There were no compliance action items requiring

immediate action on the part of the Township observed during the routine site inspections completed in

2010.

4.2.4 COMPLAINTS

Based on Township records, there were no complaints received by the Township with respect to waste

management operations at the Red Rock site in 2010.

Page 20: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 15

55..00 CCOONNCCLLUUSSIIOONNSS AANNDD RREECCOOMMMMEENNDDAATTIIOONNSS

Based on the results of the 2010 environmental monitoring program completed for the Red Rock waste

disposal site, the following conclusions are provided:

• The groundwater configuration at the site is similar to historical results with the direction of

groundwater flow in the shallow overburden unit being to the south and southeast.

• In 2010, groundwater quality immediately downgradient of the waste mound continues to exhibit

impacts from landfill-derived leachate. Consistent with historical results, exceedances of the ODWS

were observed for alkalinity (low), DOC, field-tested pH (low), and iron at select wells. Monitoring well

BH04-5 exhibits water quality parameter concentrations interpreted to be most impacted by landfill-

leachate, and monitoring wells BH04-4 and BH04-6 were observed to have parameter concentrations

significantly decreased in magnitude in comparison with monitoring well BH04-5. Groundwater quality

at the southern CAZ boundary, which is assessed with monitoring wells MW06-7 and MW06-8,

appears to be slightly impacted from landfill-derived leachate in 2010; however, the majority of

concentrations were observed to be decreased in magnitude from those at monitoring wells in close

proximity to the waste mound, indicating that attenuation downgradient of the waste mound is

occurring. In many cases, concentrations observed at MW06-7 and MW06-8 are comparable to

background groundwater quality at the site.

• The exceedances of the RUC for field-tested pH (low) at monitoring wells MW06-7 and MW06-8 are

interpreted to be related to low alkalinity concentrations in the background resultant of naturally-

occurring conditions at the site. The DOC concentration at MW06-7 that was observed in August 2010

to equal the RUC (3.0 mg/L) is interpreted to be related to landfill-leachate; however, the DOC

concentration is similar to historical results and is not interpreted to represent an increasing trend.

Further monitoring is required to confirm the relationship between DOC concentrations at MW06-7 and

the Red Rock site. Based on the aforementioned interpretations of groundwater quality at the

downgradient CAZ boundary, the Red Rock site is interpreted to meet the intent of the MOE

Guideline B-7 and the RUC.

• Based on Township records, approximately 4,621 vehicles visited the Red Rock site in 2010, with

approximately 4,026 bags of residential waste received for transfer to the Township’s Killaloe site for

disposal. Additionally, based on Township records 1,897 bags of containers (tin/aluminum/plastic),

and 949 bags of fibres were collected at the Red Rock site in 2010 and transferred to the Township’s

Killaloe site for pickup by Beaumen.

Page 21: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 16

• Recycling tonnage records provided by Beaumen and the Township indicate that a total of

approximately 204 tonnes of recyclable material were received at the Killaloe waste disposal site in

2010. Recyclable quantities contributing to this total included approximately 65 tonnes of containers

(tin/aluminum/plastic/glass), and 79 tonnes of fibres. Recycling tonnages noted above for the Killaloe

waste disposal site include quantities of recycling received and transported to the Beaumen in

Renfrew, Ontario from the Township’s Round Lake and Red Rock sites in 2010, and the Township’s

curbside service in the Village of Killaloe.

The following recommendations are provided to the Township for consideration as part of the 2011 work

program for the Red Rock waste disposal site:

• The 2011 groundwater monitoring program for the site should include sampling events in the spring

and summer of all monitoring wells using the parameter suite provided in Table 1, to continue to

monitor the groundwater regime at the site.

Page 22: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited
Page 23: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011 Page 18

77..00 RREEFFEERREENNCCEESS

Greenview Environmental Management Limited, 2007. 2006 Annual Report, Red Rock Waste Disposal

Site (A412307). March 27, 2007.

Greenview Environmental Management Limited, 2008. 2007 Annual Report, Red Rock Waste Disposal

Site (A412307). March 26, 2008.

Greenview Environmental Management Limited, 2009. 2008 Annual Report, Red Rock Waste Disposal

Site (A412307). March 20, 2009.

Greenview Environmental Management Limited, 2010. 2009 Annual Report, Red Rock Waste Disposal

Site (A412307). March 25, 2010.

Ontario Ministry of the Environment, 1994a. MOE Procedure B-7-1: Determination of Contaminant Limits

and Attenuation Zones. 1994.

Ontario Ministry of the Environment, 1994b. Water Management: Policies, Guidelines, Provincial Water

Quality Objectives of the Ministry of Environment and Energy. July, 1994.

Ontario Ministry of the Environment, 2003. Technical Support Document for Ontario Drinking Water

Standards, Objectives and Guidelines. June, 2003.

SGS Lakefield Research Ltd., 2004. Design and Operations Plan, Municipal Solid Waste Transfer Station,

Red Rock Waste Disposal Site. June 23, 2004.

SGS Lakefield Research Ltd., 2005. Investigative Report, Red Rock Waste Disposal Site. January 21,

2005.

SGS Lakefield Research Ltd., 2006. 2005 Annual Report, Red Rock Waste Disposal Site. March 24,

2006.

Page 24: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011

TTAABBLLEESS

Page 25: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Table 1 Red Rock Waste Disposal Site 2010 Groundwater Monitoring Program Location Frequency Parameters Groundwater BH04-1, BH04-2, BH04-3, BH04-4, BH04-5, BH04-6, MW06-7, MW06-8 1 QA/QC

Twice (Spring and Summer) Field Measurements (pH, Conductivity, Temperature)

Alkalinity, ammonia, barium, boron, calcium, chloride, conductivity, iron, magnesium, nitrate, pH, sodium, TDS, sulphate, COD, DOC

BH04-2

Twice (Spring and Summer) VOC’s Next in 2011

BOD, TSS EPA 624 VOC’s

Page 26: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Tabl

e 2

Gro

undw

ater

Ele

vatio

nsR

ed R

ock

Was

te D

ispo

sal S

ite

11-M

ay-0

510

-Aug

-05

8-M

ay-0

614

-Aug

-06

30-A

pr-0

79-

Aug

-07

20-M

ay-0

821

-Aug

-08

6-M

ay-0

910

-Aug

-09

10-M

ay-1

017

-Aug

-10

BH

04-1

184.

630.

7418

3.8

7.68

176.

1217

9.58

179.

4317

9.57

179.

5517

9.79

179.

7517

9.97

179.

6417

9.59

179.

5517

9.50

179.

22B

H04

-218

6.36

0.83

185.

459.

1617

6.29

179.

3817

9.23

179.

3717

9.37

179.

5617

9.53

179.

7417

9.42

179.

3817

9.36

179.

3017

9.05

BH

04-3

184.

690.

6518

3.88

6.89

176.

9917

9.63

179.

4317

9.59

179.

5217

9.73

179.

6617

9.88

179.

5617

9.60

179.

5517

9.55

179.

28B

H04

-418

5.11

20.

6818

4.43

8.37

176.

0617

8.51

178.

4017

8.53

178.

4917

8.66

178.

6417

8.86

178.

5417

8.49

178.

4617

8.43

178.

22B

H04

-518

4.41

0.74

183.

556.

9517

6.60

178.

6717

8.56

178.

6717

8.67

178.

8517

8.82

179.

0117

8.70

178.

6317

8.63

178.

5717

8.36

BH

04-6

184.

330.

5018

3.68

7.66

176.

0217

8.90

178.

7917

8.91

178.

9217

9.12

179.

1217

9.30

179.

0017

8.89

178.

8917

8.80

178.

57

MW

06-7

318

3.78

0.87

182.

918.

3617

4.55

--

177.

5417

7.55

177.

7117

7.73

177.

8717

7.61

177.

5917

7.51

177.

4217

7.26

MW

06-8

318

3.57

0.83

182.

747.

2617

5.48

--

178.

1017

8.14

178.

3017

8.35

178.

4617

8.22

178.

0917

8.09

177.

9917

7.81

Not

es:

1. S

urve

yed

by S

GS

on

Sep

tem

ber 1

3, 2

004.

2. M

easu

ring

poin

t not

sur

veye

d, c

alcu

late

d us

ing

orig

inal

gro

und

elev

atio

n an

d or

igin

al s

tick

up.

3. O

rigin

al g

roun

d an

d to

p of

pip

e el

evat

ions

sur

veye

d by

Tra

nsen

co L

imite

d on

May

2, 2

006.

All

elev

atio

ns a

re m

eter

s ab

ove

sea

leve

l (m

asl),

rela

tive

to a

site

spe

cific

ben

chm

ark

elev

atio

n of

184

.10

m.

"-" d

enot

es w

ater

leve

l not

ava

ilabl

e.

Mea

sure

d D

epth

of

Wel

l (m

)El

evat

ion

at B

ase

of W

ell (

m)

Top

of P

ipe

Elev

atio

n (m

) 1O

rigin

al

Stic

k-up

(m)

Orig

inal

Gro

und

Elev

atio

n (m

) 1M

onito

rG

roun

dwat

er E

leva

tion

(m)

Page 27: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Tabl

e 3

Gro

undw

ater

Qua

lity

Red

Roc

k W

aste

Dis

posa

l Site

11-A

ug-0

419

-Oct

-04

11-M

ay-0

510

-Aug

-05

8-M

ay-0

614

-Aug

-06

30-A

pr-0

79-

Aug-

0720

-May

-08

21-A

ug-0

86-

May

-09

10-A

ug-0

910

-May

-10

17-A

ug-1

0Al

kalin

ity (a

s C

aCO

3)25

530

- 50

026

2212

1512

138

79

810

99

10Am

mon

ia, T

otal

(N

)N

/LN

/L<

0.1

< 0.

1<

0.1

< 0.

10.

070.

6<

0.1

< 0.

11.

50.

2<

0.1

0.2

< 0.

10.

1Ba

rium

0.26

1.0

0.00

70.

006

0.00

80.

008

0.01

40.

011

0.01

50.

010

0.00

90.

007

0.00

712

0.00

715

0.00

640

0.00

550

Boro

n1.

35.

0<

0.01

< 0.

01<

0.01

< 0.

01<

0.00

30.

010.

004

< 0.

002

0.00

40.

004

0.00

330.

0039

0.00

700.

0050

Biol

ogic

al O

xyge

n D

eman

dN

/LN

/L--

---

---

---

---

---

---

---

---

---

---

---

---

---

-C

alci

umN

/LN

/L7

4.37

4.69

5.06

6.71

6.03

6.92

3.81

3.98

2.97

3.16

2.58

2.67

4.03

Chl

orid

e12

6.4

250

2.8

7.3

6.1

5.6

1211

177.

95.

72.

65.

04.

32.

54.

0C

hem

ical

Oxy

gen

Dem

and

N/L

N/L

8<

8<

8<

8<

6<

8<

8<

8<

8<

8<

88

< 8

< 8

Con

duct

ivity

(µS/

cm) 3

N/L

N/L

6668

5371

6762

5646

4237

5439

3639

Dis

solv

ed O

rgan

ic C

arbo

n3.

05

< 1

< 1

< 1

< 1

1.0

0.8

1.2

< 1

< 1

2.0

1.1

< 1.

0<

1.0

< 1.

0Iro

n0.

20.

3<

0.02

< 0.

02<

0.02

< 0.

02<

0.01

< 0.

01<

0.01

< 0.

01<

0.01

0.01

0.02

0.06

0.08

0.01

Mag

nesi

umN

/LN

/L1.

51.

341.

671.

511.

941.

882.

131.

301.

300.

980.

910

0.77

80.

776

1.17

0N

itrat

e2.

510

0.66

0.66

1.2

0.63

0.73

0.44

< 0.

050.

12<

0.05

< 0.

050.

05<

0.05

0.1

0.06

Nitr

ite0.

31

---

---

---

---

< 0.

06<

0.06

---

---

---

---

---

---

---

---

Nitr

ate

+ N

itrite

(as

Nitr

ogen

)2.

710

---

---

---

---

---

0.44

---

---

---

---

---

---

---

---

pH (u

nits

)6.

5 - 8

.56.

5 - 8

.5--

---

---

---

-6.

566.

936.

826.

486.

156.

576.

486.

476.

746.

82pH

(uni

ts) 3

6.5

- 8.5

6.5

- 8.5

6.38

6.71

6.5

6.79

6.00

6.95

6.98

7.69

7.67

7.64

6.76

6.83

6.71

5.98

Sodi

um10

1.7

200

5.32

6.02

6.31

7.30

8.14

6.48

9.94

8.68

8.07

6.93

6.50

6.34

5.50

6.08

Sulp

hate

253.

750

08.

27.

47.

18.

86.

57.

39.

49.

513

119.

29.

18.

58.

9To

tal D

isso

lved

Sol

ids

273

500

6360

6977

8377

< 30

4649

46<

30<

3046

< 30

Tota

l Sus

pend

ed S

olid

sN

/LN

/L--

---

---

---

---

---

---

---

---

---

---

---

---

---

-N

otes

:1.

Rea

sona

ble

Use

Con

cept

(RU

C) c

riter

ia.

2. O

ntar

io D

rinki

ng W

ater

Sta

ndar

ds (O

DW

S).

3. R

esul

t fro

m fi

eld

anal

ysis

.

Res

ults

exp

ress

ed in

mg/

L un

less

oth

erw

ise

note

d.B

old

and

shad

ed v

alue

s ex

ceed

OD

WS

.B

old

and

Italic

val

ues

exce

ed R

UC

lim

its.

N/L

indi

cate

s N

o Li

mit.

"---

" par

amet

er n

ot a

naly

zed.

BH

04-1

Para

met

erO

DW

S 2

RU

C 1

Page 28: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Tabl

e 3

Gro

undw

ater

Qua

lity

Red

Roc

k W

aste

Dis

posa

l Site

Alka

linity

(as

CaC

O3)

255

30 -

500

Amm

onia

, Tot

al (

N)

N/L

N/L

Bariu

m0.

261.

0Bo

ron

1.3

5.0

Biol

ogic

al O

xyge

n D

eman

dN

/LN

/LC

alci

umN

/LN

/LC

hlor

ide

126.

425

0C

hem

ical

Oxy

gen

Dem

and

N/L

N/L

Con

duct

ivity

(µS/

cm) 3

N/L

N/L

Dis

solv

ed O

rgan

ic C

arbo

n3.

05

Iron

0.2

0.3

Mag

nesi

umN

/LN

/LN

itrat

e2.

510

Nitr

ite0.

31

Nitr

ate

+ N

itrite

(as

Nitr

ogen

)2.

710

pH (u

nits

)6.

5 - 8

.56.

5 - 8

.5pH

(uni

ts) 3

6.5

- 8.5

6.5

- 8.5

Sodi

um10

1.7

200

Sulp

hate

253.

750

0To

tal D

isso

lved

Sol

ids

273

500

Tota

l Sus

pend

ed S

olid

sN

/LN

/LN

otes

:1.

Rea

sona

ble

Use

Con

cept

(RU

C) c

riter

ia.

2. O

ntar

io D

rinki

ng W

ater

Sta

ndar

ds (O

DW

S).

3. R

esul

t fro

m fi

eld

anal

ysis

.

Res

ults

exp

ress

ed in

mg/

L un

less

oth

erw

ise

note

d.B

old

and

shad

ed v

alue

s ex

ceed

OD

WS

.B

old

and

Italic

val

ues

exce

ed R

UC

lim

its.

N/L

indi

cate

s N

o Li

mit.

"---

" par

amet

er n

ot a

naly

zed.

Para

met

erO

DW

S 2

RU

C 1

11-A

ug-0

419

-Oct

-04

11-M

ay-0

510

-Aug

-05

8-M

ay-0

614

-Aug

-06

30-A

pr-0

79-

Aug-

0720

-May

-08

21-A

ug-0

86-

May

-09

10-A

ug-0

910

-May

-10

17-A

ug-1

020

324

312

717

012

316

113

811

812

211

811

113

198

304.

66.

94.

13.

43.

64.

65.

54.

14.

12.

72.

02.

01.

20.

80.

180.

232

0.15

30.

136

0.12

20.

206

0.17

20.

126

0.15

40.

118

0.11

60.

133

0.09

70.

0255

0.23

0.34

0.07

0.21

0.07

0.24

0.12

0.16

0.10

0.17

0.11

80.

146

0.09

20.

0238

5<

14

< 1

---

---

13

4<

2<

4<

4<

4<

461

.065

.040

.650

.437

.352

.542

.532

.539

.938

.437

.550

.840

.711

.333

2415

2120

126

67

2311

1230

7.8

4224

1322

1619

1113

1711

1123

14<

849

538

228

748

729

836

630

323

829

827

526

731

728

410

26.

26.

63.

36.

43.

85.

92.

52.

53.

34.

03.

64.

32.

6<

1.0

41.7

37.7

29.1

39.2

26.2

33.5

21.3

19.0

23.6

23.6

26.2

35.1

30.1

8.17

11.4

10.8

7.41

10.3

07.

5610

.20

6.57

5.04

6.07

5.97

5.43

7.39

6.32

1.68

< 0.

05<

0.05

< 0.

05<

0.05

< 0.

050.

06<

0.05

< 0.

05<

0.05

< 0.

05<

0.05

< 0.

050.

05<

0.05

---

---

---

---

< 0.

06<

0.06

---

---

---

---

---

---

---

---

---

---

---

---

---

0.06

---

---

---

---

---

---

---

---

---

---

---

---

6.97

7.43

7.59

7.52

6.68

6.93

6.90

7.02

7.04

7.14

6.25

6.57

6.9

6.28

5.90

6.54

6.41

6.60

6.75

6.57

6.66

6.85

6.53

6.45

15.7

17.3

16.5

14.5

10.6

16.6

11.0

11.7

11.5

10.3

8.13

9.74

7.60

4.99

1718

2214

2013

2016

3511

3422

1710

317

314

231

266

237

240

166

160

189

191

209

186

203

100

2521

912

538

---

---

3018

2047

027

1050

913

5034

242

2

BH

04-2

Page 29: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Tabl

e 3

Gro

undw

ater

Qua

lity

Red

Roc

k W

aste

Dis

posa

l Site

Alka

linity

(as

CaC

O3)

255

30 -

500

Amm

onia

, Tot

al (

N)

N/L

N/L

Bariu

m0.

261.

0Bo

ron

1.3

5.0

Biol

ogic

al O

xyge

n D

eman

dN

/LN

/LC

alci

umN

/LN

/LC

hlor

ide

126.

425

0C

hem

ical

Oxy

gen

Dem

and

N/L

N/L

Con

duct

ivity

(µS/

cm) 3

N/L

N/L

Dis

solv

ed O

rgan

ic C

arbo

n3.

05

Iron

0.2

0.3

Mag

nesi

umN

/LN

/LN

itrat

e2.

510

Nitr

ite0.

31

Nitr

ate

+ N

itrite

(as

Nitr

ogen

)2.

710

pH (u

nits

)6.

5 - 8

.56.

5 - 8

.5pH

(uni

ts) 3

6.5

- 8.5

6.5

- 8.5

Sodi

um10

1.7

200

Sulp

hate

253.

750

0To

tal D

isso

lved

Sol

ids

273

500

Tota

l Sus

pend

ed S

olid

sN

/LN

/LN

otes

:1.

Rea

sona

ble

Use

Con

cept

(RU

C) c

riter

ia.

2. O

ntar

io D

rinki

ng W

ater

Sta

ndar

ds (O

DW

S).

3. R

esul

t fro

m fi

eld

anal

ysis

.

Res

ults

exp

ress

ed in

mg/

L un

less

oth

erw

ise

note

d.B

old

and

shad

ed v

alue

s ex

ceed

OD

WS

.B

old

and

Italic

val

ues

exce

ed R

UC

lim

its.

N/L

indi

cate

s N

o Li

mit.

"---

" par

amet

er n

ot a

naly

zed.

Para

met

erO

DW

S 2

RU

C 1

11-A

ug-0

419

-Oct

-04

11-M

ay-0

510

-Aug

-05

8-M

ay-0

614

-Aug

-06

30-A

pr-0

79-

Aug-

0720

-May

-08

21-A

ug-0

86-

May

-09

10-A

ug-0

910

-May

-10

17-A

ug-1

023

1010

137

79

99

67

77

60.

1<

0.1

< 0.

10.

1<

0.04

< 0.

1<

0.1

0.2

0.2

0.2

< 0.

1<

0.1

< 0.

10.

20.

007

0.01

40.

010

0.01

20.

010

0.01

00.

013

0.01

10.

008

0.00

80.

0083

70.

0078

60.

0086

00.

0098

1<

0.01

< 0.

01<

0.01

< 0.

01<

0.00

30.

010.

006

< 0.

002

0.00

40.

005

0.00

470.

0054

0.00

400.

0042

---

---

---

---

---

---

---

---

---

---

---

---

---

---

6.54

4.71

3.85

3.44

3.80

3.91

4.26

3.64

3.15

2.97

2.68

2.85

2.45

3.59

2.2

2.8

2.3

1.7

1.0

0.9

0.8

1.1

1.0

7.7

0.6

1.4

0.4

0.6

< 8

< 8

< 6

< 8

< 6

< 8

< 8

< 8

< 8

< 8

< 8

< 8

< 8

< 8

7433

3148

3826

3028

2020

2625

1927

< 1

< 1

< 1

< 1

1.8

0.8

< 1

< 1

< 1

4.6

1.3

< 1.

0<

1.0

1.0

0.08

0.1

0.03

< 0.

02<

0.01

< 0.

01<

0.01

0.02

< 0.

010.

020.

020.

040.

040.

032

2.03

1.52

1.22

1.08

1.06

1.04

1.27

1.22

1.02

0.98

0.79

90.

859

0.74

01.

050

< 0.

050.

98<

0.05

< 0.

05<

0.05

< 0.

05<

0.05

< 0.

05<

0.05

< 0.

05<

0.05

< 0.

050.

151.

55--

---

---

---

-<

0.06

< 0.

06--

---

---

---

---

---

---

---

---

---

---

---

---

-<

0.06

---

---

---

---

---

---

---

---

---

---

---

---

6.60

6.90

6.88

6.83

6.03

6.38

6.31

6.32

6.60

6.68

6.73

6.59

7.0

6.77

6.26

6.58

6.50

7.07

6.77

6.97

6.33

8.02

6.51

6.05

1.80

1.81

2.14

1.62

3.00

2.98

3.37

3.21

2.81

1.95

1.25

1.29

1.20

1.67

7.3

65.

96.

26.

27.

58.

17.

04.

043

.05.

35.

23.

53.

463

4971

7143

37<

3051

< 30

< 30

< 30

< 30

< 30

49--

---

---

---

---

---

---

---

---

---

---

---

---

---

-

BH

04-3

Page 30: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Tabl

e 3

Gro

undw

ater

Qua

lity

Red

Roc

k W

aste

Dis

posa

l Site

Alka

linity

(as

CaC

O3)

255

30 -

500

Amm

onia

, Tot

al (

N)

N/L

N/L

Bariu

m0.

261.

0Bo

ron

1.3

5.0

Biol

ogic

al O

xyge

n D

eman

dN

/LN

/LC

alci

umN

/LN

/LC

hlor

ide

126.

425

0C

hem

ical

Oxy

gen

Dem

and

N/L

N/L

Con

duct

ivity

(µS/

cm) 3

N/L

N/L

Dis

solv

ed O

rgan

ic C

arbo

n3.

05

Iron

0.2

0.3

Mag

nesi

umN

/LN

/LN

itrat

e2.

510

Nitr

ite0.

31

Nitr

ate

+ N

itrite

(as

Nitr

ogen

)2.

710

pH (u

nits

)6.

5 - 8

.56.

5 - 8

.5pH

(uni

ts) 3

6.5

- 8.5

6.5

- 8.5

Sodi

um10

1.7

200

Sulp

hate

253.

750

0To

tal D

isso

lved

Sol

ids

273

500

Tota

l Sus

pend

ed S

olid

sN

/LN

/LN

otes

:1.

Rea

sona

ble

Use

Con

cept

(RU

C) c

riter

ia.

2. O

ntar

io D

rinki

ng W

ater

Sta

ndar

ds (O

DW

S).

3. R

esul

t fro

m fi

eld

anal

ysis

.

Res

ults

exp

ress

ed in

mg/

L un

less

oth

erw

ise

note

d.B

old

and

shad

ed v

alue

s ex

ceed

OD

WS

.B

old

and

Italic

val

ues

exce

ed R

UC

lim

its.

N/L

indi

cate

s N

o Li

mit.

"---

" par

amet

er n

ot a

naly

zed.

Para

met

erO

DW

S 2

RU

C 1

11-A

ug-0

419

-Oct

-04

11-M

ay-0

510

-Aug

-05

8-M

ay-0

614

-Aug

-06

30-A

pr-0

79-

Aug-

0720

-May

-08

21-A

ug-0

86-

May

-09

10-A

ug-0

910

-May

-10

17-A

ug-1

087

111

8373

7373

7882

120

130

104

132

9366

< 0.

1<

0.1

< 0.

10.

20.

060.

20<

0.1

< 0.

10.

4<

0.1

< 0.

10.

2<

0.1

< 0.

10.

038

0.04

80.

022

0.02

10.

032

0.02

20.

035

0.03

10.

039

0.03

30.

0431

0.04

540.

0313

0.01

790.

080.

080.

070.

090.

060.

070.

190.

140.

310.

330.

249

0.20

80.

224

0.14

7--

---

---

---

---

---

---

---

---

---

---

---

---

---

-42

.559

.436

.928

.645

.931

.249

.046

.961

.655

.840

.348

.242

.326

.23.

14

3.7

2.7

3.9

4.0

3.1

5.8

9.4

11.0

4.0

13.0

3.1

3.5

< 8

< 8

< 6

< 8

< 6

< 8

< 8

< 8

< 8

< 8

911

< 8

826

024

219

423

125

916

722

320

826

427

730

024

920

316

32.

81.

2<

11.

11.

71.

21.

22.

12.

27.

22.

82.

42.

21.

50.

02<

0.02

< 0.

02<

0.02

< 0.

01<

0.01

< 0.

010.

02<

0.01

0.01

0.17

0.08

0.04

0.01

210

.514

11.1

8.16

12.1

07.

7611

.79.

7711

.40

9.51

6.99

7.67

7.73

5.83

1.89

2.33

1.1

0.5

1.24

1.00

1.97

2.20

0.28

0.50

1.49

2.10

3.06

2.98

---

---

---

---

< 0.

06<

0.06

---

---

---

---

---

---

---

---

---

---

---

---

---

1.00

---

---

---

---

---

---

---

---

---

---

---

---

7.02

7.50

7.65

7.42

7.88

6.84

6.92

6.96

7.20

7.47

6.1

6.27

6.7

6.6

5.94

7.03

6.47

6.71

6.60

6.53

6.25

6.40

6.42

6.07

9.14

9.78

6.84

8.81

7.51

6.84

7.96

7.37

8.17

8.63

15.9

17.1

11.5

9.78

6910

749

3896

3985

6857

5558

3743

2122

329

119

418

926

315

418

623

118

922

920

922

620

913

1--

---

---

---

---

---

---

---

---

---

---

---

---

---

-

BH

04-4

Page 31: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Tabl

e 3

Gro

undw

ater

Qua

lity

Red

Roc

k W

aste

Dis

posa

l Site

Alka

linity

(as

CaC

O3)

255

30 -

500

Amm

onia

, Tot

al (

N)

N/L

N/L

Bariu

m0.

261.

0Bo

ron

1.3

5.0

Biol

ogic

al O

xyge

n D

eman

dN

/LN

/LC

alci

umN

/LN

/LC

hlor

ide

126.

425

0C

hem

ical

Oxy

gen

Dem

and

N/L

N/L

Con

duct

ivity

(µS/

cm) 3

N/L

N/L

Dis

solv

ed O

rgan

ic C

arbo

n3.

05

Iron

0.2

0.3

Mag

nesi

umN

/LN

/LN

itrat

e2.

510

Nitr

ite0.

31

Nitr

ate

+ N

itrite

(as

Nitr

ogen

)2.

710

pH (u

nits

)6.

5 - 8

.56.

5 - 8

.5pH

(uni

ts) 3

6.5

- 8.5

6.5

- 8.5

Sodi

um10

1.7

200

Sulp

hate

253.

750

0To

tal D

isso

lved

Sol

ids

273

500

Tota

l Sus

pend

ed S

olid

sN

/LN

/LN

otes

:1.

Rea

sona

ble

Use

Con

cept

(RU

C) c

riter

ia.

2. O

ntar

io D

rinki

ng W

ater

Sta

ndar

ds (O

DW

S).

3. R

esul

t fro

m fi

eld

anal

ysis

.

Res

ults

exp

ress

ed in

mg/

L un

less

oth

erw

ise

note

d.B

old

and

shad

ed v

alue

s ex

ceed

OD

WS

.B

old

and

Italic

val

ues

exce

ed R

UC

lim

its.

N/L

indi

cate

s N

o Li

mit.

"---

" par

amet

er n

ot a

naly

zed.

Para

met

erO

DW

S 2

RU

C 1

11-A

ug-0

419

-Oct

-04

11-M

ay-0

510

-Aug

-05

8-M

ay-0

614

-Aug

-06

30-A

pr-0

79-

Aug-

0720

-May

-08

21-A

ug-0

86-

May

-09

10-A

ug-0

910

-May

-10

17-A

ug-1

061

136

337

048

940

449

256

236

135

135

627

531

033

234

50.

219

.521

.516

.917

.119

.827

.417

.915

.98.

610

.510

.211

.111

.50.

370

0.27

00.

249

0.33

40.

274

0.35

40.

466

0.27

80.

280

0.26

70.

200

0.21

70.

271

0.24

70.

650.

450.

240.

420.

300.

440.

570.

280.

230.

250.

214

0.25

70.

406

0.31

6--

---

---

---

---

---

---

---

---

---

---

---

---

---

-12

784

.183

.711

7.0

85.0

103.

011

6.0

74.9

72.0

75.3

53.0

60.6

75.6

79.0

4022

2220

4531

3333

2920

169

1716

6034

3357

4152

5726

2635

2932

3931

995

497

628

104

705

537

881

650

622

604

563

540

590

640

21.8

10.3

7.8

15.5

8.3

16.1

16.9

7.2

6.0

12.7

5.7

5.5

9.1

8.8

46.5

22.3

34.9

54.5

38.5

50.2

43.1

29.8

40.7

47.4

34.4

42.8

43.3

42.0

32.3

17.1

15.1

22.2

22.8

26.0

27.7

18.8

14.9

19.2

13.5

15.5

20.2

19.2

< 0.

05<

0.05

< 0.

05<

0.05

< 0.

05<

0.05

0.18

< 0.

05<

0.05

0.05

< 0.

05<

0.05

0.07

0.15

---

---

---

---

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06<

0.06

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-7.

147.

507.

877.

668.

207.

117.

037.

077.

307.

456.

516.

87.

26.

356.

016.

876.

236.

706.

966.

516.

686.

536.

656.

4742

.833

.526

.431

.826

.629

.034

.626

.621

.223

.922

.622

.528

.124

.06.

512

1314

109.

512

1417

1319

1918

1268

639

741

158

648

655

460

037

138

641

732

935

140

044

6--

---

---

---

---

---

---

---

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---

---

---

---

-

BH

04-5

Page 32: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Tabl

e 3

Gro

undw

ater

Qua

lity

Red

Roc

k W

aste

Dis

posa

l Site

Alka

linity

(as

CaC

O3)

255

30 -

500

Amm

onia

, Tot

al (

N)

N/L

N/L

Bariu

m0.

261.

0Bo

ron

1.3

5.0

Biol

ogic

al O

xyge

n D

eman

dN

/LN

/LC

alci

umN

/LN

/LC

hlor

ide

126.

425

0C

hem

ical

Oxy

gen

Dem

and

N/L

N/L

Con

duct

ivity

(µS/

cm) 3

N/L

N/L

Dis

solv

ed O

rgan

ic C

arbo

n3.

05

Iron

0.2

0.3

Mag

nesi

umN

/LN

/LN

itrat

e2.

510

Nitr

ite0.

31

Nitr

ate

+ N

itrite

(as

Nitr

ogen

)2.

710

pH (u

nits

)6.

5 - 8

.56.

5 - 8

.5pH

(uni

ts) 3

6.5

- 8.5

6.5

- 8.5

Sodi

um10

1.7

200

Sulp

hate

253.

750

0To

tal D

isso

lved

Sol

ids

273

500

Tota

l Sus

pend

ed S

olid

sN

/LN

/LN

otes

:1.

Rea

sona

ble

Use

Con

cept

(RU

C) c

riter

ia.

2. O

ntar

io D

rinki

ng W

ater

Sta

ndar

ds (O

DW

S).

3. R

esul

t fro

m fi

eld

anal

ysis

.

Res

ults

exp

ress

ed in

mg/

L un

less

oth

erw

ise

note

d.B

old

and

shad

ed v

alue

s ex

ceed

OD

WS

.B

old

and

Italic

val

ues

exce

ed R

UC

lim

its.

N/L

indi

cate

s N

o Li

mit.

"---

" par

amet

er n

ot a

naly

zed.

Para

met

erO

DW

S 2

RU

C 1

11-A

ug-0

419

-Oct

-04

11-M

ay-0

510

-Aug

-05

8-M

ay-0

614

-Aug

-06

30-A

pr-0

79-

Aug-

0720

-May

-08

21-A

ug-0

86-

May

-09

10-A

ug-0

910

-May

-10

17-A

ug-1

025

2631

4035

2722

1727

1525

1530

280.

10.

10.

1<

0.1

0.07

3.2

0.2

< 0.

10.

4<

0.1

< 0.

1<

0.1

< 0.

1<

0.1

0.01

20.

019

0.06

10.

025

0.03

60.

014

0.01

30.

012

0.02

50.

015

0.02

930.

0174

0.02

650.

0214

0.01

0.01

0.55

0.12

0.58

0.04

0.01

0.00

30.

230.

020.

206

0.01

60.

202

0.09

01--

---

---

---

---

---

---

---

---

---

---

---

---

---

-11

.112

.535

.916

.726

.110

.08.

88.

625

.19.

316

.412

.121

.117

.717

1816

2014

109.

915

1417

2028

2025

< 8

< 8

9<

8<

6<

8<

8<

8<

8<

8<

8<

810

< 8

113

8020

316

619

778

7164

133

7918

210

671

140

< 1

< 1

3.2

23.

00.

9<

1<

11.

46.

51.

5<

1.0

1.4

1.3

0.04

0.04

0.03

< 0.

02<

0.01

0.03

0.02

0.03

0.03

0.02

0.13

0.12

0.08

0.10

32.

842.

756.

223.

675.

882.

662.

362.

453.

952.

644.

583.

606.

204.

940.

590.

692.

472.

603.

420.

940.

780.

791.

750.

681.

670.

841.

001.

16--

---

---

---

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0.06

< 0.

06--

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94--

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-7.

007.

217.

307.

026.

466.

726.

536.

867.

167.

126.

666.

466.

36.

635.

886.

986.

526.

856.

716.

986.

576.

576.

466.

026.

558.

8121

.20

12.0

013

.60

9.15

9.18

10.1

014

.80

9.73

15.4

8.3

11.0

10.9

1011

8715

5110

9.6

8.8

35.0

8.2

387

3522

117

111

223

146

209

8931

7410

686

134

120

129

123

---

---

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---

---

BH

04-6

Page 33: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Tabl

e 3

Gro

undw

ater

Qua

lity

Red

Roc

k W

aste

Dis

posa

l Site

Alka

linity

(as

CaC

O3)

255

30 -

500

Amm

onia

, Tot

al (

N)

N/L

N/L

Bariu

m0.

261.

0Bo

ron

1.3

5.0

Biol

ogic

al O

xyge

n D

eman

dN

/LN

/LC

alci

umN

/LN

/LC

hlor

ide

126.

425

0C

hem

ical

Oxy

gen

Dem

and

N/L

N/L

Con

duct

ivity

(µS/

cm) 3

N/L

N/L

Dis

solv

ed O

rgan

ic C

arbo

n3.

05

Iron

0.2

0.3

Mag

nesi

umN

/LN

/LN

itrat

e2.

510

Nitr

ite0.

31

Nitr

ate

+ N

itrite

(as

Nitr

ogen

)2.

710

pH (u

nits

)6.

5 - 8

.56.

5 - 8

.5pH

(uni

ts) 3

6.5

- 8.5

6.5

- 8.5

Sodi

um10

1.7

200

Sulp

hate

253.

750

0To

tal D

isso

lved

Sol

ids

273

500

Tota

l Sus

pend

ed S

olid

sN

/LN

/LN

otes

:1.

Rea

sona

ble

Use

Con

cept

(RU

C) c

riter

ia.

2. O

ntar

io D

rinki

ng W

ater

Sta

ndar

ds (O

DW

S).

3. R

esul

t fro

m fi

eld

anal

ysis

.

Res

ults

exp

ress

ed in

mg/

L un

less

oth

erw

ise

note

d.B

old

and

shad

ed v

alue

s ex

ceed

OD

WS

.B

old

and

Italic

val

ues

exce

ed R

UC

lim

its.

N/L

indi

cate

s N

o Li

mit.

"---

" par

amet

er n

ot a

naly

zed.

Para

met

erO

DW

S 2

RU

C 1

8-M

ay-0

614

-Aug

-06

30-A

pr-0

79-

Aug-

0720

-May

-08

21-A

ug-0

86-

May

-09

10-A

ug-0

910

-May

-10

17-A

ug-1

025

2417

87

136

616

250.

061.

40.

2<

0.1

0.6

< 0.

10.

7<

0.1

< 0.

1<

0.1

0.00

80.

007

0.01

00.

005

0.01

40.

006

0.00

792

0.01

760

0.01

190

0.00

969

0.01

0.02

0.01

< 0.

002

0.01

0.00

70.

0111

0.00

840.

0130

0.01

82--

---

---

---

---

---

---

---

---

---

-8.

289.

757.

664.

444.

274.

052.

954.

826.

258.

961.

52.

51.

11.

01.

18.

50.

51.

00.

61.

418

1519

1415

< 8

9<

818

1075

5945

3431

3330

3437

511.

92.

61.

61.

41.

37.

71.

01.

12.

23.

00.

050.

030.

130.

040.

160.

040.

100.

160.

060.

029

3.02

3.55

2.79

1.71

1.63

1.73

1.06

1.72

2.34

3.52

0.28

0.83

0.08

< 0.

05<

0.05

0.08

< 0.

053.

280.

621.

54<

0.06

< 0.

06--

---

---

---

---

---

---

---

---

-0.

83--

---

---

---

---

---

---

---

-6.

847.

277.

216.

756.

596.

596.

296.

186.

757.

086.

126.

826.

446.

716.

866.

826.

076.

886.

235.

695.

375.

164.

644.

083.

498.

981.

852.

112.

252.

6214

1412

1212

139.

49.

08.

812

106

8994

126

236

1150

134

5760

54--

---

---

---

---

---

---

---

---

---

-

MW

06-7

Page 34: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Tabl

e 3

Gro

undw

ater

Qua

lity

Red

Roc

k W

aste

Dis

posa

l Site

Alka

linity

(as

CaC

O3)

255

30 -

500

Amm

onia

, Tot

al (

N)

N/L

N/L

Bariu

m0.

261.

0Bo

ron

1.3

5.0

Biol

ogic

al O

xyge

n D

eman

dN

/LN

/LC

alci

umN

/LN

/LC

hlor

ide

126.

425

0C

hem

ical

Oxy

gen

Dem

and

N/L

N/L

Con

duct

ivity

(µS/

cm) 3

N/L

N/L

Dis

solv

ed O

rgan

ic C

arbo

n3.

05

Iron

0.2

0.3

Mag

nesi

umN

/LN

/LN

itrat

e2.

510

Nitr

ite0.

31

Nitr

ate

+ N

itrite

(as

Nitr

ogen

)2.

710

pH (u

nits

)6.

5 - 8

.56.

5 - 8

.5pH

(uni

ts) 3

6.5

- 8.5

6.5

- 8.5

Sodi

um10

1.7

200

Sulp

hate

253.

750

0To

tal D

isso

lved

Sol

ids

273

500

Tota

l Sus

pend

ed S

olid

sN

/LN

/LN

otes

:1.

Rea

sona

ble

Use

Con

cept

(RU

C) c

riter

ia.

2. O

ntar

io D

rinki

ng W

ater

Sta

ndar

ds (O

DW

S).

3. R

esul

t fro

m fi

eld

anal

ysis

.

Res

ults

exp

ress

ed in

mg/

L un

less

oth

erw

ise

note

d.B

old

and

shad

ed v

alue

s ex

ceed

OD

WS

.B

old

and

Italic

val

ues

exce

ed R

UC

lim

its.

N/L

indi

cate

s N

o Li

mit.

"---

" par

amet

er n

ot a

naly

zed.

Para

met

erO

DW

S 2

RU

C 1

8-M

ay-0

614

-Aug

-06

30-A

pr-0

79-

Aug-

0720

-May

-08

21-A

ug-0

86-

May

-09

10-A

ug-0

910

-May

-10

17-A

ug-1

07

329

2212

129

108

80.

060.

50.

20.

10.

2<

0.1

< 0.

10.

1<

0.1

< 0.

10.

010

0.00

30.

006

0.00

30.

004

0.00

40.

0029

60.

0072

80.

0025

0.00

306

< 0.

003

0.01

0.01

< 0.

002

0.00

70.

007

0.00

650.

0055

0.00

60.

0058

---

---

---

---

---

---

---

---

---

---

8.21

2.50

5.96

1.60

3.93

3.98

1.39

1.68

1.63

2.29

2115

1310

118

5.3

5.0

2.6

3.2

< 6

< 8

< 8

13<

8<

8<

8<

88

< 8

9110

667

5265

4961

5538

391.

310

.81.

11.

5<

110

.4<

1.0

1.3

1.2

1.1

0.01

0.04

0.02

0.03

0.04

0.04

0.14

0.34

0.18

0.18

2.71

0.55

2.72

0.92

1.86

1.79

0.68

50.

672

0.83

0.99

80.

060.

06<

0.05

0.12

< 0.

05<

0.05

< 0.

05<

0.05

< 0.

05<

0.05

< 0.

06<

0.06

---

---

---

---

---

---

---

---

---

0.06

---

---

---

---

---

---

---

---

6.72

7.47

6.92

7.07

6.85

6.44

6.61

6.72

6.63

6.80

6.10

6.71

6.57

6.51

6.88

6.55

6.55

7.04

6.46

5.67

7.00

35.3

09.

1123

.50

12.0

013

.60

10.7

9.9

7.83

5.99

9.6

2013

1415

1312

1211

1111

418

6077

900

272

325

< 30

237

79<

30--

---

---

---

---

---

---

---

---

---

-

MW

06-8

Page 35: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Tabl

e 3

Gro

undw

ater

Qua

lity

Red

Roc

k D

ispo

sal S

ite

8-M

ay-0

614

-Aug

-06

Ben

zene

0.00

5<

0.00

1<

0.00

1B

rom

odic

hlor

omet

hane

N/L

< 0.

001

< 0.

001

Bro

mof

orm

N/L

< 0.

001

< 0.

001

Bro

mom

etha

neN

/L<

0.00

5<

0.00

5C

arbo

n Te

trach

lorid

e0.

005

< 0.

005

< 0.

005

Mon

ochl

orob

enze

ne0.

08<

0.00

5<

0.00

5C

hlor

oeth

ane

N/L

< 0.

005

< 0.

005

Chl

orof

orm

N/L

< 0.

001

< 0.

001

Chl

orom

etha

neN

/L<

0.00

5<

0.00

5D

ibro

moc

hlor

omet

hane

N/L

< 0.

001

< 0.

001

Dic

hlor

omet

hane

(Met

hyle

ne C

hlor

ide)

N/L

< 0.

005

< 0.

005

1,2-

Dic

hlor

oben

zene

0.2

< 0.

001

< 0.

001

1,3-

Dic

hlor

oben

zene

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Page 36: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011

FFIIGGUURREESS

Page 37: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Greenview Environmental Management Limited 69 Cleak Avenue, P.O. Box 100 Bancroft, Ontario K0L 1C0 tel: (613) 332-0057 fax: (613) 332-1767 email: [email protected]

CREATED BY: ESD

CLIENT: TOWNSHIP OF KILLALOE, HAGARTY AND

RICHARDS

PROJECT NO.:

107.10.004 CHECKED BY: THP

DATE: MARCH 2011

SITE/TITLE:

REGIONAL LOCATION PLAN

FIGURE:

1 SCALE: NTS

Killaloe Waste Disposal Site

Red Rock Waste Disposal

Site

Round Lake Waste Disposal Site

ALGONQUIN PROVINCIAL PARK

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011

AAPPPPEENNDDIIXX AA

PPrroovviissiioonnaall CCeerrttiiffiiccaattee ooff AApppprroovvaall AA441122330077

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011

AAPPPPEENNDDIIXX BB

MMNNRR LLaanndd UUssee PPeerrmmiitt LLUUPP 11667755--11000066229999

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011

AAPPPPEENNDDIIXX CC

CCoorrrreessppoonnddeennccee

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011

AAPPPPEENNDDIIXX DD

BBoorreehhoollee LLooggss

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2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011

AAPPPPEENNDDIIXX EE

FFiieelldd SSaammpplliinngg RReeccoorrddss

Page 78: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

FIELD SAMPLING RECORD - GROUND WATER

LOCATION: Red Rock Waste Disposal Site DATE: May 10, 2010 SAMPLED BY: D. Hagan, E. Drost

PROJECT NO.: 107.10.004 WEATHER (SAMPLE DAY): Sunny, 13oC WEATHER (PREVIOUS DAY): Overcast, 10oC

Needed Obtained Colour Clarity Odour Sheen Comments

BH04-1 5.13 7.64 0.77 50.8 15 15 7.12 6.71 36 8.70 brown opaque none none GW QA/QC

BH04-2 7.06 9.02 0.82 50.8 12 12 9.30 6.53 284 6.88 clear clear none none

BH04-3 5.14 6.87 0.74 50.8 10 10 6.24 6.51 19 8.40 brown opaque none none

BH04-4 6.68 8.26 0.69 50.8 9 9 7.24 6.42 203 7.29 brown opaque none none

BH04-5 5.84 6.92 0.76 50.8 6 6 8.58 6.65 590 8.82 grey opaque sulphur none

BH04-6 5.53 7.57 0.45 50.8 12 12 7.57 6.46 71 11.72 brown opaque none none

MW06-7 6.36 7.13 0.76 50.8 5 5 7.31 6.23 37 14.07 brown opaque none none Very Silty

MW06-8 5.58 7.03 0.70 50.8 9 9 6.50 6.46 38 11.78 brown opaque none none Very Silty

MonitoringLocation

StaticWaterLevel

BoreholeDepth

(m)

Stick - Up (m)

Temperature(oC)

BoreholeDiameter

(mm)

ObservationsConductivity(mS)

DissolvedOxygen(mg/L)

pH(units)

Purge Volumes (L)

Page 79: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

FIELD SAMPLING RECORD - GROUND WATER

LOCATION: Red Rock Waste Disposal Site DATE: August 17, 2010 SAMPLED BY: D. Hagan, E. Drost

PROJECT NO.: 107.10.004 WEATHER (SAMPLE DAY): Sunny, 20oC WEATHER (PREVIOUS DAY): Rain and sun, 23oC

Needed Obtained Colour Clarity Odour Sheen Comments

BH04-1 5.41 7.62 0.77 50.8 13 13 7.86 5.98 39 7.70 white cloudy none none

BH04-2 7.31 9.16 0.82 50.8 11 11 9.70 6.45 102 5.57 clear cloudy none none

BH04-3 5.41 6.86 0.74 50.8 9 9 8.10 6.05 27 6.79 yellow opaque none none

BH04-4 6.89 8.28 0.69 50.8 8 8 8.50 6.07 163 4.84 grey cloudy none none GW QA/QC

BH04-5 6.05 6.89 0.76 50.8 5 5 9.72 6.47 640 6.09 grey opaque sulphur none

BH04-6 5.76 7.58 0.45 50.8 11 11 8.12 6.02 140 9.82 brown opaque none none Silty

MW06-7 6.52 7.13 0.76 50.8 4 4 9.55 5.69 51 10.78 brown/grey opaque none none Very Silty - Pumped Dry

MW06-8 5.76 7.18 0.70 50.8 9 9 8.12 5.67 39 10.82 brown/grey opaque none none Very Silty - Pumped Dry

ObservationsConductivity(mS)

DissolvedOxygen(mg/L)

pH(units)

Purge Volumes (L)MonitoringLocation

StaticWaterLevel

BoreholeDepth

(m)

Stick - Up (m)

Temperature(oC)

BoreholeDiameter

(mm)

Page 80: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011

AAPPPPEENNDDIIXX FF

LLaabboorraattoorryy CCeerrttiiffiiccaatteess ooff AAnnaallyyssiiss

Page 81: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Greenview Environmental Management Attn : Tyler Peters

PO Box 100, 69 Cleak Ave.Bancroft, ONK0L 1C0,

Phone: 613-332-0057Fax:613-332-1767, pdf, excel

Tuesday, August 24, 2010

Date Rec. : 18 August 2010 LR Report: CA10091-AUG10 Reference: Red Rock GW

Copy: #1

CERTIFICATE OF ANALYSIS

Final Report Analysis 3:

AnalysisApproval

Date

4:AnalysisApproval

Time

7:BH04-1

8:BH04-2

9:BH04-3

10:BH04-4

11:BH04-5

12:BH04-6

13:MW06-7

14:MW06-8

15:QA/QC

Sample Date & Time 17-Aug-10 17-Aug-10 17-Aug-10 17-Aug-10 17-Aug-10 17-Aug-10 17-Aug-10 17-Aug-10 17-Aug-10Temperature Upon Receipt [°C] -- --- 13.0 13.0 13.0 13.0 13.0 13.0 13.0 13.0 13.0BOD [mg/L] 23-Aug-10 12:56 --- < 4 --- --- --- --- --- --- ---Tot. Suspended Solids [mg/L] 23-Aug-10 12:17 --- 422 --- --- --- --- --- --- ---Alkalinity [mg/L as CaCO3] 20-Aug-10 13:40 10 30 6 66 345 28 25 8 67pH [no unit] 20-Aug-10 13:40 6.82 7.14 6.68 7.47 7.45 7.12 7.08 6.80 7.45Conductivity [uS/cm] 20-Aug-10 13:40 63 115 44 220 709 205 102 61 208Solids (Total Dissolved) [mg/L] 20-Aug-10 11:23 < 30 100 49 131 446 123 54 < 30 120COD [mg/L] 20-Aug-10 12:02 < 8 < 8 < 8 8 31 < 8 10 < 8 < 8Ammonia+Ammonium (N) [mg/L] 20-Aug-10 12:10 0.1 0.8 0.2 < 0.1 11.5 < 0.1 < 0.1 < 0.1 < 0.1Sulphate [mg/L] 20-Aug-10 10:02 8.9 10 3.4 21 12 22 12 11 21Chloride [mg/L] 23-Aug-10 12:43 4.0 7.8 0.6 3.5 16 25 1.4 3.2 3.2Nitrate (as nitrogen) [mg/L] 19-Aug-10 14:18 0.06 < 0.05 1.55 2.98 0.15 1.16 1.54 < 0.05 2.81Dissolved Organic Carbon [mg/L] 20-Aug-10 08:54 < 1.0 < 1.0 1.0 1.5 8.8 1.3 3.0 1.1 1.9Barium [mg/L] 24-Aug-10 12:02 0.00550 0.0255 0.00981 0.0179 0.247 0.0214 0.00969 0.00306 0.0167Boron [mg/L] 24-Aug-10 12:02 0.0050 0.0238 0.0042 0.147 0.316 0.0901 0.0182 0.0058 0.144Calcium [mg/L] 23-Aug-10 15:28 4.03 11.3 3.59 26.2 79.0 17.7 8.96 2.29 23.2

SGS Canada Inc. P.O. Box 4300 - 185 Concession St. Lakefield - Ontario - KOL 2HO Phone: 705-652-2000 FAX: 705-652-6365

OnLi

ne

LIM

S

Page 1 of 2 Data reported represents the sample submitted to SGS. Reproduction of this analytical report in full or in part is prohibited without prior written approval. Please refer to SGS General Conditions of Services located at

http://www.sgs.com/terms_and_conditions_service.htm. (Printed copies are available upon request.) Test method information available upon request. “Temperature Upon Receipt” is representative of the whole shipment and may not reflect the temperature of individual samples.

Page 82: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Analysis 3:AnalysisApproval

Date

4:AnalysisApproval

Time

7:BH04-1

8:BH04-2

9:BH04-3

10:BH04-4

11:BH04-5

12:BH04-6

13:MW06-7

14:MW06-8

15:QA/QC

Iron [mg/L] 23-Aug-10 15:28 0.012 8.17 0.032 0.012 42.0 0.103 0.029 0.180 0.016Magnesium [mg/L] 23-Aug-10 15:28 1.17 1.68 1.05 5.83 19.2 4.94 3.52 0.998 5.47Sodium [mg/L] 23-Aug-10 15:28 6.08 4.99 1.67 9.78 24.0 10.9 2.62 5.99 9.36

__________________________

Brian Graham B.Sc.Project Specialist Environmental Services, Analytical

SGS Canada Inc. P.O. Box 4300 - 185 Concession St. LR Report : CA10091-AUG10

Lakefield - Ontario - KOL 2HO Phone: 705-652-2000 FAX: 705-652-6365

OnLi

ne

LIM

S

Page 2 of 2 Data reported represents the sample submitted to SGS. Reproduction of this analytical report in full or in part is prohibited without prior written approval. Please refer to SGS General Conditions of Services located at

http://www.sgs.com/terms_and_conditions_service.htm. (Printed copies are available upon request.) Test method information available upon request. “Temperature Upon Receipt” is representative of the whole shipment and may not reflect the temperature of individual samples.

Page 83: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Greenview Environmental Management Attn : Tyler Peters

PO Box 100, 69 Cleak Ave.Bancroft, ONK0L 1C0,

Phone: 613-332-0057Fax:613-332-1767, pdf, excel

Thursday, May 20, 2010

Date Rec. : 12 May 2010 LR Report: CA10107-MAY10 Reference: 107.10.004 Red Rock GW

Copy: #1

CERTIFICATE OF ANALYSIS

Final Report Analysis 3:

AnalysisApproval

Date

4:AnalysisApproval

Time

7:BH04-1

8:BH04-2

9:BH04-3

10:BH04-4

11:BH04-5

12:BH04-6

13:MW06-7

14:MW06-8

15:GW QA/QC

Sample Date & Time 10-May-10 10-May-10 10-May-10 10-May-10 10-May-10 10-May-10 10-May-10 10-May-10 10-May-10Temperature Upon Receipt [°C] -- --- 8.0 8.0 8.0 8.0 8.0 8.0 8.0 8.0 8.0BOD [mg/L] 19-May-10 21:57 --- < 4 --- --- --- --- --- --- ---Tot. Suspended Solids [mg/L] 19-May-10 13:28 --- 342 --- --- --- --- --- --- ---Alkalinity [mg/L as CaCO3] 17-May-10 12:56 9 98 7 93 332 30 16 8 10pH [no unit] 17-May-10 12:56 6.74 7.04 6.60 7.20 7.30 7.16 6.75 6.63 6.80Conductivity [uS/cm] 17-May-10 12:56 53 329 27 304 719 207 63 55 52Solids (Total Dissolved) [mg/L] 17-May-10 11:54 46 203 < 30 209 400 129 60 79 37COD [mg/L] 17-May-10 13:08 < 8 14 < 8 < 8 39 10 18 8 < 8Ammonia+Ammonium (N) [mg/L] 17-May-10 12:07 < 0.1 1.2 < 0.1 < 0.1 11.1 < 0.1 < 0.1 < 0.1 < 0.1Sulphate [mg/L] 19-May-10 15:11 8.5 17 3.5 43 18 35 8.8 11 8.9Chloride [mg/L] 20-May-10 10:34 2.5 30 0.4 3.1 17 20 0.6 2.6 2.6Nitrate (as nitrogen) [mg/L] 17-May-10 13:38 0.10 0.05 0.15 3.06 0.07 1.00 0.62 < 0.05 0.05Dissolved Organic Carbon [mg/L] 18-May-10 10:07 < 1.0 2.6 < 1.0 2.2 9.1 1.4 2.2 1.2 < 1.0Barium [mg/L] 18-May-10 09:38 0.0064 0.0972 0.0086 0.0313 0.271 0.0265 0.0119 0.0025 0.0059Boron [mg/L] 18-May-10 09:38 0.007 0.092 0.004 0.224 0.406 0.202 0.013 0.006 0.003Calcium [mg/L] 18-May-10 09:38 2.67 40.7 2.45 42.3 75.6 21.1 6.25 1.63 2.91

SGS Canada Inc. P.O. Box 4300 - 185 Concession St. Lakefield - Ontario - KOL 2HO Phone: 705-652-2000 FAX: 705-652-6365

OnLi

ne

LIM

S

Page 1 of 2 Data reported represents the sample submitted to SGS. Reproduction of this analytical report in full or in part is prohibited without prior written approval. Please refer to SGS General Conditions of Services located at

http://www.sgs.com/terms_and_conditions_service.htm. (Printed copies are available upon request.) Test method information available upon request. “Temperature Upon Receipt” is representative of the whole shipment and may not reflect the temperature of individual samples.

Page 84: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

Analysis 3:AnalysisApproval

Date

4:AnalysisApproval

Time

7:BH04-1

8:BH04-2

9:BH04-3

10:BH04-4

11:BH04-5

12:BH04-6

13:MW06-7

14:MW06-8

15:GW QA/QC

Iron [mg/L] 18-May-10 09:38 0.08 30.1 0.04 0.04 43.3 0.08 0.06 0.18 0.04Magnesium [mg/L] 18-May-10 09:38 0.776 6.32 0.740 7.73 20.2 6.20 2.34 0.832 0.819Sodium [mg/L] 18-May-10 09:38 5.50 7.60 1.20 11.5 28.1 11.0 2.25 7.83 5.69

__________________________

Brian Graham B.Sc.Project Specialist Environmental Services, Analytical

SGS Canada Inc. P.O. Box 4300 - 185 Concession St. LR Report : CA10107-MAY10

Lakefield - Ontario - KOL 2HO Phone: 705-652-2000 FAX: 705-652-6365

OnLi

ne

LIM

S

Page 2 of 2 Data reported represents the sample submitted to SGS. Reproduction of this analytical report in full or in part is prohibited without prior written approval. Please refer to SGS General Conditions of Services located at

http://www.sgs.com/terms_and_conditions_service.htm. (Printed copies are available upon request.) Test method information available upon request. “Temperature Upon Receipt” is representative of the whole shipment and may not reflect the temperature of individual samples.

Page 85: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

2010 Annual Report

Red Rock Waste Disposal Site (A412307)

Township of Killaloe, Hagarty and Richards

March 2011

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Page 86: 2010 ANNUAL REPORT · five (5) monitoring wells around the perimeter of the site and one (1) monitoring well directly in the waste mound, in August 2004(SGS Lakefield Research Limited

GGRREEEENNVVIIEEWW EENNVVIIRROONNMMEENNTTAALL MMAANNAAGGEEMMEENNTT LLIIMMIITTEEDD -- SSTTAATTEEMMEENNTT OOFF SSEERRVVIICCEE CCOONNDDIITTIIOONNSS AANNDD LLIIMMIITTAATTIIOONNSS Provision of Services and Payment Upon documented acceptance of Greenview’s proposed services, costs and associated terms by the client, Greenview may commence work on the proposed services directly. Upon retention of Greenview’s services related to this project, the client agrees to remit payment for the services rendered for the specified period within (30) days of receipt as invoiced by Greenview on a typical monthly basis, unless otherwise arranged between the client and Greenview. In the event of non-payment by the client, Greenview reserves the right, without external influence or expense, to discontinue services and retain any documentation, data, reports, or other project information until such time as payment is received by Greenview.

Warranty, Limitations, and Reliance Greenview relies on background and historical information from the client to determine the appropriate scope of services to meet the client’s objectives, in accordance with applicable legislation, guidelines, industry practices, and accepted methodologies.

Greenview provides its services under the specific terms and conditions of a specific proposal (and where necessary formal contract), in accordance with the above requirements and the Limitations Act 2002, only.

The hypotheses, results, conclusions, and recommendations presented in documentation authored by Greenview are founded on the information provided by the client to Greenview in preparation for the work. Facts, conditions, and circumstances discovered by Greenview during the performance of the work requested by the client are assumed by Greenview to be part of preparatory information provided by the client as part of the proposal stage of the project. Greenview assumes that, until notified or discovered otherwise, that the information provided by, or obtained by Greenview from, the client is factual, accurate, and represents a true depiction of the circumstances that exist related to the time of the work.

Greenview relies on its clients to inform Greenview if there are changes to any related information to the work. Greenview does not review, analyze or attempt to verify the accuracy or completeness of the information or materials provided, or circumstances encountered, other than in accordance with applicable accepted industry practice. Greenview will not be responsible for matters arising from incomplete, incorrect or misleading information or from facts or circumstances that are not fully disclosed to or that are concealed from Greenview during the period that services, work, or documentation preparation was performed by Greenview.

Facts, conditions, information and circumstances may vary with time and locations and Greenview’s work is based on a review of such matters as they existed at the particular time and location indicated in its documentation. No assurance is made by Greenview that the facts, conditions, information, circumstances or any underlying assumptions made by Greenview in connection with the work performed will not change after the work is completed and documentation is submitted. If any such changes occur or additional information is obtained, Greenview should be advised and requested to consider if the changes or additional information affect its findings or results.

When preparing documentation, Greenview considers applicable legislation, regulations, governmental guidelines and policies to the extent they are within its knowledge, but Greenview is not qualified to advise with respect to legal matters. The presentation of information regarding applicable legislation, regulations,

governmental guidelines, and policies is for information only and is not intended to and should not be interpreted as constituting a legal opinion concerning the work completed or conditions outlined in a report. All legal matters should be reviewed and considered by an appropriately qualified legal practitioner.

Greenview’s services, work and reports are provided solely for the exclusive use of the client which has retained the services of Greenview and to which its reports are addressed. Greenview is not responsible for the use of its services, work or reports by any other party, or for the reliance on, or for any decision which is made by any party using the services or work performed by or a report prepared by Greenview without Greenview’s express written consent. Any party that uses, relies on, or makes a decision based on services or work performed by Greenview or a report prepared by Greenview without Greenview’s express written consent, does so at its own risk. Except as set out herein, Greenview specifically disclaims any liability or responsibility to any third party for any loss, damage, expense, fine, penalty or other such thing which may arise or result from the use of, reliance on or decision based on any information, recommendation or other matter arising from the services, work or reports provided by Greenview.

Site Assessments A site assessment is created using data and information collected during the investigation of a site and based on conditions encountered at the time and particular locations at which fieldwork is conducted. The information, sample results and data collected represent the conditions only at the specific times at which and at those specific locations from which the information, samples and data were obtained and the information, sample results and data may vary at other locations and times. To the extent that Greenview’s work or report considers any locations or times other than those from which information, sample results and data were specifically received, the work or report is based on a reasonable extrapolation from such information, sample results and data but the actual conditions encountered may vary from those based on extrapolations.

Only conditions, and substances, at the site and locations chosen for study by the client are evaluated; no adjacent or other properties are evaluated unless specifically requested by the client. Any physical or other aspects of the site that were not chosen for study by the client, or any other matter not specifically addressed in a report prepared by Greenview, are beyond the scope of the work performed by Greenview and such matters have not been investigated or addressed.

Confidentiality Greenview provides proposals, reports, assessments, designs, and any other work for the sole party identified as the client or potential client in the case of proposals.

For proposals specifically, the information contained therein is confidential, proprietary information, and shall not be reproduced or disclosed to any other party than to that of the addressee of the original proposal submission, without prior written permission of Greenview.