PowerPoint ,

1.
1.
2000 . ,
1 oxygenases enzyme
Hydrocarbon

Key enzyme
iso-
cyclo-
Aromatics
mono-
Di-Oxygenase
Di-
PAHs
1.
2,000 . ·
(1)


*
1.
, , , Feedback inhibition
(2)
HC + O2
+ N/P +
1.
, Diesel Jet Fuel Cyclic Alkane 5-7%
, .
Carboxylic Acid , - () TPH ,
,
(3)
[ ]
Base Line .
(Oudot et al. 1998)
1.
[ () ]
SA
AR
ASP
I.S.
(30 day, 558ppm)
2.

feedback inhibition
1.
3.
. .
(%)
4.


. 3 (YS-7, SBS-8, SBS-10) .

Chart10
SBS-1
SBS-1
SBS-1
10.3
10.3
10.6
10.6
5.6
5.6
SBS-2
SBS-2
SBS-2
5.3
5.3
15.3
15.3
10.2
10.2
SBS-3
SBS-3
SBS-3
3.3
3.3
9.6
9.6
2.3
2.3
SBS-8
SBS-8
SBS-8
5.3
5.3
2.3
2.3
5.8
5.8
SBS-10
SBS-10
SBS-10
10.2
10.2
10.6
10.6
9.6
9.6
SBS-12
SBS-12
SBS-12
2.3
2.3
15.6
15.6
12.5
12.5
OB-4
OB-4
OB-4
2.6
2.6
20.5
20.5
6.3
6.3
OB-8
OB-8
OB-8
5.6
5.6
14.3
14.3
16.6
16.6
RS-1
RS-1
RS-1
5.8
5.8
3.2
3.2
20.3
20.3
RS-4
RS-4
RS-4
4.5
4.5
5.2
5.2
6.5
6.5
Aliphatics
Aromatics
25.3
14.3
-10.2
10.3
15.2
-10.2
6.9
15.8
-11.3
43.3
10.3
30.2
37.2
15.3
23.5
30.2
16.3
10.3
15.3
12.3
-13.2
20.3
17.3
-15.3
20.6
25.3
-19.9
16.8
30.6
-13.6
Initial
Resin
rate(%)
SD
SBS-1
10.4
2.5
SBS-2
15.9
2.1
SBS-3
10.8
0.8
SBS-8
39.4
5.9
SBS-10
32.1
3.6
SBS-12
13.2
2.4
OB-4
15.2
1.1
OB-8
30.1
5.2
RS-1
12.4
2.9
RS-4
15.9
4.8
Initial
2.5
2.5
2.1
2.1
0.8
0.8
5.9
5.9
3.6
3.6
2.4
2.4
1.1
1.1
5.2
5.2
2.9
2.9
4.8
4.8
Strain
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
NaN
rate(%)
(c): SBS-10, (d): OB-8, (e): Resin 3

Resin

%
(a)
(b)
(c)
(d)
(e)
(a)
70.6
4.
Microcosm test :
16 : BS (4.5%), BA (32.8%), BA+R (59.2%)
TPH 566ppm .

*
Chart1
0
0
0
1
1
1
5
5
5
12
12
12
16
16
16
NA
BS
BA
Days
mg/kg)
14790
14790
14790
14505
12415
12138
14167
11681
8662
14065
9640
6554
14054
9440
5737
Sheet1
Days
NA
BS
BA
0
14,790
14,790
14,790
1
14,505
12,415
12,138
5
14,167
11,681
8,662
12
14,065
9,640
6,554
16
14,054
9,440
5,737
Sheet1
NA
BS
BA
Days
mg/kg)
Sheet2
Sheet3
.
    o :BTEX 1,050ppm, TPH 28,945ppm ( )
    o : 590
    o :
    o : 2006. 5.28 ~ 2007.  3. 22.
    o :
5.wmf
1.5
m
2.5
m
3.5
m
4.5
m
5.5
m
5. ()
30 .
( TPH 30,000mg/kg “” 15, 6 ).
*
5. (SK, )
- : (, , C)
- TPH : 1,580±133 mg/kg
- C18/phytane: 1.5
- :
- : 7,200


5. (SK, )

Sample ID
Initial
Initial
11-7
LF(S)
21days
21days
5. (SK, )
: 16.2%, : 23.2%, pH: 7.8, TPH: 7,956±1,311 mg/kg
: 5.4×106 CFU/g, : 0.9×105 MPN/g
Microcosm test :
28 :
(4%), (21%), +resin (61%)
resin TPH 187 mg/kg .
resin 4 .
n-alkane
5. (SK, )
5. (SK, )


*
5. (SK, )



5. (SK, )
5. (SK, )
12 (TPH)
18 (TPH)
25 (TPH)
33 (TPH) (2 )
41 C17/pritane C18/Phytane (2)
48 (TPH) (2 )
48 C17/pritane C18/Phytane (2)
68 (TPH) (2 )
68 C17/pritane C18/Phytane (2)
*
5. (SK, )
1 FISH , .
SBS-10
SBS-8
Chart5
0
397073.880615014
397073.880615014
0
147612.104291394
147612.104291394
0
369052.841744919
369052.841744919
8
441434.0267809
441434.0267809
8
336500
336500
8
387093.104341283
387093.104341283
14
1164644.294767
1164644.294767
14
1083740.89769342
1083740.89769342
14
137106.580023405
137106.580023405
21
623423.612000701
623423.612000701
21
459271.887520526
459271.887520526
21
817958.041187234
817958.041187234
28
661732.259553162
661732.259553162
28
470558.179187229
470558.179187229
28
132496.630684924
132496.630684924
35
898421.393333885
898421.393333885
35
806721.761203948
806721.761203948
35
42
438738.722552121
438738.722552121
42
633613.972909899
633613.972909899
42
#4-1
#4-2
#4-3
WL-1
WLH-1
WLH-2
WLH-3
WL-2
DJ-1
DJ-3
CL180
KH3-2
DJ-2
YS-7
IC-10
0
0.2
0.4
0.6
0.8
1
1.2
1.4
1.6
0
20
40
60
80
100
Hydrophobicity (%)
WL-1
WLH-1
WLH-2
WLH-3
WL-2
DJ-1
DJ-3
CL180
KH3-2
DJ-2
YS-7
IC-10
-60
-40
-20
0
20
40
60
80
100
SBS-1SBS-2SBS-3SBS-8SBS-10SBS-12OB-4OB-8RS-1RS-4
Aliphatics
Aromatics