a rapid and stereoselective route to the trans-hydrindan ring system
TRANSCRIPT
2004
Indan derivativesQ 1050 A Rapid and Stereoselective Route to the trans-Hydrindan Ring System. — The
synthesis of the title ring system present in many biologically active natural products is achieved via In-mediated allylation of the aldehyde (I), 6-endo-trig cyclization of the bromides (III) and (IV), and selective cleavage of the α-diketones (VII), (XI), and (XV). — (KHAN*, F. A.; SATAPATHY, R.; DASH, J.; SAVITHA, G.; J. Org. Chem. 69 (2004) 16, 5295-5301; Dep. Chem., Indian Inst. Technol., Kanpur 208 016, India; Eng.) — Jannicke
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