cheminform abstract: structure elucidation and synthesis of...
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2000 other natural products
other natural productsU 0800
48 - 231Structure Elucidation and Synthesis of (4S,5S,6Z,8E)-5-Hydroxydeca-6,8-dien-4-olide [(S,S)-Sapinofuranone B] – A Novel γ-LactoneMetabolite of Acremonium strictum. — The structure of the titlecompound (VII) is determined by spectroscopic means and chemical transfor-mation. Its synthesis is achieved via condensation of the aldehyde (II) with theiodide (III), Stille coupling with the stannane (V), and lactonization of the ester(VI). — (CLOUGH, SARAH; RAGGATT, MAIRI E.; SIMPSON, THOMASJ.; WILLIS, CHRISTINE L.; WHITING, ANDREW; WRIGLEY, STEPHENK.; Perkin 1 (2000) 15, 2475-2481; Sch. Chem., Univ. Bristol, Cantock’s Close,Bristol BS8 1TS, UK; EN)
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