금호석유화학의미래와연구방향 - cheric · 2007-12-04 · sbr (emulsion styrene...
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금호석유화학의금호석유화학의금호석유화학의금호석유화학의금호석유화학의금호석유화학의금호석유화학의금호석유화학의 미래와미래와미래와미래와미래와미래와미래와미래와 연구방향연구방향연구방향연구방향연구방향연구방향연구방향연구방향
2007. 10. 26
금호석유화학 중앙연구소장 김승수
2007. 10. 26
금호석유화학금호석유화학 중앙연구소장중앙연구소장 김승수김승수
I. Introduction to Kumho Asiana Group & KKPC
- Kumho Asiana Group and Affiliated Companies
- Corporate Milestones
- Business Fields & Sales Composition
- Global Partnership
II. Introduction to Kumho Petrochemical R&BD Center
- R&BD Strategy
- Nd-Br
- Porous Asphalt (Silent Asphalt) Modifier
- Carbon Nano Materials
- Computer-aided Research
- Electronic Materials
ContentsContents
I. Introduction toI. Introduction to
KumhoKumho AsianaAsiana Group & KKPCGroup & KKPC
Who is Who is KumhoKumho AsianaAsiana Group?Group?
� http://www.kumho.co.kr
Affiliated CompaniesAffiliated Companies
2005년
12월말
2006년
12월말
� 1970. 12 - Korea Synthetic Rubber Industries Co., Ltd. established.
� 1973. 04 - SBR plant launched. (Ulsan 25,000MT)
� 1979. 10 - BD plant launched. (Yeosu 50,000MT)
� 1980. 03 - BR plant launched. (Yeosu 25,000MT)
� 1984. 03 - SBR Latex plant launched. (Ulsan)
� 1985. 06 - Company name changed to Korea Kumho Petrochemical Co., Ltd.
� 1985. 06 - Kumho Petrochemical Research Center established.
� 1988. 12 - Multi-purpose BR plant launched.
� 1994. 02 - Kumho Chemical Laboratories opened in Daedeok Technovalley.
� 1994. 08 - Thermoplastic elastomer(SBS) production started.
� 1995. 08 - ISO 14001 certification acquired
� 1997. 07 - Combined heat & power plant in Yeosu built.
� 1998. 11 - Asan plant(Electronic material division) launched.
� 2001. 01 - Merged with Kumho Chemicals, Inc.
� 2003. 01 - Recieved the Environment Management Award.
� 2003. 08 - Kumho Chemical Laboratory and Ichon Laboratory merged
� 2003. 08 - into Kumho Petrochemical R&BD Center.
� 1970. 12 - Korea Synthetic Rubber Industries Co., Ltd. established.
� 1973. 04 - SBR plant launched. (Ulsan 25,000MT)
� 1979. 10 - BD plant launched. (Yeosu 50,000MT)
� 1980. 03 - BR plant launched. (Yeosu 25,000MT)
� 1984. 03 - SBR Latex plant launched. (Ulsan)
� 1985. 06 - Company name changed to Korea Kumho Petrochemical Co., Ltd.
� 1985. 06 - Kumho Petrochemical Research Center established.
� 1988. 12 - Multi-purpose BR plant launched.
� 1994. 02 - Kumho Chemical Laboratories opened in Daedeok Technovalley.
� 1994. 08 - Thermoplastic elastomer(SBS) production started.
� 1995. 08 - ISO 14001 certification acquired
� 1997. 07 - Combined heat & power plant in Yeosu built.
� 1998. 11 - Asan plant(Electronic material division) launched.
� 2001. 01 - Merged with Kumho Chemicals, Inc.
� 2003. 01 - Recieved the Environment Management Award.
� 2003. 08 - Kumho Chemical Laboratory and Ichon Laboratory merged
� 2003. 08 - into Kumho Petrochemical R&BD Center.
Corporate Milestones of KKPCCorporate Milestones of KKPC
Plants and Research CenterPlants and Research Center
Seoul Head Office
Electronic Chemicals
Division (Asan)
R&BD Center
(Daejeon)
Yeosu Plant(Synthetic Rubbers)
Yeosu Plant(Fine Chemicals)
Ulsan Plant(Synthetic Resins)
Ulsan Plant(Synthetic Rubbers)
Combined Heat
& Power Plant
Business FieldBusiness Field
Business Area Products Capacity (MT/y)
SBR (Emulsion Styrene Butadiene Rubber) 185,000
NBR (Acrylonitrile Butadiene Rubber) 30,000
HSR (High Styrene Resiin Masterbatch) 10,000
BR (Polybutadiene Rubber) 140,000
S-SBR, SBS (Styrene-Butadiene-Styrene copolymer) 70,000
SB Latex (Styrene Butadiene Latex) 70,000
BD (Butadiene) 205,000
Total 710,000
PS (Polystyrene) 175,000
ABS (Acrylonitrile Butadiene Styrene) 220,000
ASA (Acrylonitrile Styrene Acrylate) 10,000
EP (Engineering Plastics) 20,000
EPS (Expandable Polystyrene) 90,000
PPG (Polypropylene glycol) 40,000
SAN (Strene Acrylonitrile) 34,000
Total 589,000
Fine Chemicals Antioxidants & Vulcanization Accelerators 21,000
Electronic Chemicals Stipper, Developer & Photoresist 3,045
Synthetic
Rubbers
Synthetic
Resins
Sales Composition & VolumeSales Composition & Volume
140.4143.0Others
892.1896.6Synthetic
Rubbers
720.5669.7Synthetic
Resins
1,753.01,709.3Total
20062005Sales
Volume
(KRW in billions)
※※※※ Others: Fine Chemicals, Electronic Materials & Combined Heat and Power Plants
Synthetic resin Synthetic rubber Others
41.1% 50.9%
Market PositionMarket Position
1) Global capacity for synthetic rubber
� Unit: 1,000 ton
� Standard: SBR, BR
WorldWorld’’s 3s 3rdrd Production CapacityProduction Capacity
KoreaKorea’’s No.1 in M/Ss No.1 in M/S
Market PositionMarket Position
1) Global capacity for synthetic rubber
Sales Breakdown by ApplicationSales Breakdown by Application
Automobile
Affiliated Companies Affiliated Companies (Chemical companies)
1) Kumho P&B Chemicals, Inc.
� Established in April 1976
� Joint-venture: KKPC(51%), Nippon Steel Chemical(28%), Sumitomo Corp.(20%)
� Product: Phenol, Acetone, Bispheno-A, MIBK, Epoxy resin, Cumene
2) Kumho Polychem Co., Ltd.
� Established in June 1985
� Joint-venture: KKPC(50%), JSR(35%), Exxon(15%)
� Product: EP rubber
3) Kumho Mitsui Chemicals, Inc.
� Established in March 1989
� Joint-venture: KKPC(50%), Mitsui Chemicals Co., Ltd.(50%)
� Product: MDI, Aniline
4) Shanghai Kumho Sunny Plastics Co., Ltd.
� Established in October 2000
� Joint-venture: KKPC(50%), Shanghai Sunny New Technology Development Co., Ltd.(50%)
� Product: Raw material of the modified engineering plastics of styrene monomer series
Global PartnershipGlobal Partnership
Overseas office & Tech. Center
Technology Export
Technology Import
LA/
San DiegoShanghai
GBPC(1999~)ABS Plant
SINOPEC(1993)ABS/SAN Plant
P.T.RBI (1992)P.T.ALL(1994,1996)ABS/SAN Plant
FINA (PS/HIPS)
Dow Chem. (Polyol)Sekisui Plastics (EPS)
JSR (Synthetic Rubber)
Guangzhou
Hongkong
Nippon A&L (ABS)
II. Introduction toII. Introduction to
KumhoKumho Petrochemical R&BD CenterPetrochemical R&BD Center
NdNd--BR BR (Neodymium Butadiene Rubber)
NdBR
Ultra High Cis Polybutadiene
– devolopment of Nd Catalyst for Butadiene Polymerization
Core : the engine of Golf Ball, convert impact energy to flying distance.
Neodymium-Polybutadiene Rubber
“ A game whose aim is to hit a very small ball into an even smaller hole”
-Winston Churchill
Cover: Spin (feeling)Cover: Spin (feeling)
Core: DistanceCore: Distance
NdNd--BR BR (Neodymium Butadiene Rubber)
““Distance is a big thingDistance is a big thing””
배수성배수성배수성배수성배수성배수성배수성배수성////////저소음저소음저소음저소음저소음저소음저소음저소음 아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트 개질제개질제개질제개질제개질제개질제개질제개질제
배수성배수성배수성배수성 포장포장포장포장 일반일반일반일반 밀입도밀입도밀입도밀입도 포장포장포장포장
�������� 배수성배수성배수성배수성배수성배수성배수성배수성 아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트 개질제개질제개질제개질제개질제개질제개질제개질제
일반 포장에 비해 공극률을 크게 하여 빗물이
도로 표면에 고여 있지 않고 표층 내부로 빠르게
침투할 수 있도록 설계된 포장체
SBS
based
binder
�������� 일반일반일반일반일반일반일반일반 포장과포장과포장과포장과포장과포장과포장과포장과 배수성배수성배수성배수성배수성배수성배수성배수성 포장의포장의포장의포장의포장의포장의포장의포장의 비교비교비교비교비교비교비교비교
배수성배수성배수성배수성배수성배수성배수성배수성////////저소음저소음저소음저소음저소음저소음저소음저소음 아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트 개질제개질제개질제개질제개질제개질제개질제개질제
�������� 배수성배수성배수성배수성배수성배수성배수성배수성 아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트 시범시범시범시범시범시범시범시범 포장포장포장포장포장포장포장포장
� Totally, about 61 kilometers (conversed to 2-lane road) on 21 sites
Carbon Carbon NanoNano MaterialsMaterials
Carbon Nano Tube
(CNT)
Carbon Nano Fiber
(CNF)
Single wall Multi wall
양산성 순도/수율/생산성 저하 양산화 진행 양산화 진행
가격, USD/g 100~500 1~50 0.5~10
� 소재시장의 급격한 성장 예상, 2010년 세계시장 약 1.8 조원 (AAGR:~30%)
� 대량생산체제의 진전과 가격하락 등이 근래에 급속히 진행되고 있으며 산업성장기 진입이 임박한 것으로
예상되고 있음
� 물질 특허 이슈 / 응용 기술 개발 필요
ComputerComputer--aided Research aided Research
�������� Computational chemistryComputational chemistry
금호금호금호금호 슈퍼컴슈퍼컴슈퍼컴슈퍼컴 3호기호기호기호기 (SGI Altix 4700, 80DualCPU)
ComputerComputer--aided Research aided Research
�������� Computational chemistry Computational chemistry - Length and Time scale
femto
pico
micro
milli
min
year
QM
MD
CoarseGrain
Modeling
Process
Sim.
Eng.
Design
Time
Distance
1 A 10 A 100 A 1 micro 1 cm m
Atomic Approach
Schrodinger Eq.Newtonian Eq.
Continuum Mech.
Navier-Stock Eq.
Maxwell’s Eq.
Mesoscale
Simulation
5:5
Iso-propene
Styrene
8:2
9:1
ComputerComputer--aided Research aided Research
�������� Diblock(PIDiblock(PI--PS) morphology PS) morphology 계산계산계산계산계산계산계산계산 (MesoDyn 이용이용이용이용)
ComputerComputer--aided Research aided Research
�������� CCAD/CAM/CAEAD/CAM/CAE
Region of high shear stress
is large, probability of mold
crack should be high.
Region of high shear stress
is smaller than the original
model, probability of mold
crack should be low.
Filling pattern Shear stress
Original model
Filling pattern Shear stress
Recomended model
Electronic Chemicals Electronic Chemicals
TFT-LCD MATERIALSOver Coating, Hard coat, Sealant
OTHER MATERIALSPhoto-acid Generator
SEMICONDUCTOR MATERIALS
ArF Photoresist, ArF BARC
ElectronicElectronic
MaterialsMaterials
� ArFArFArFArF PhotoresistPhotoresistPhotoresistPhotoresist 개발개발개발개발
� 기타기타기타기타 반도체반도체반도체반도체 및및및및 LCD LCD LCD LCD 공정공정공정공정 재료재료재료재료
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