금호석유화학의미래와연구방향 · 2007. 12. 4. · 1973. 04 - sbr plant launched....

금호석유화학의금호석유화학의금호석유화학의금호석유화학의금호석유화학의금호석유화학의금호석유화학의금호석유화학의 미래와미래와미래와미래와미래와미래와미래와미래와 연구방향연구방향연구방향연구방향연구방향연구방향연구방향연구방향

2007. 10. 26

금호석유화학 중앙연구소장 김승수

2007. 10. 26

금호석유화학금호석유화학 중앙연구소장중앙연구소장 김승수김승수

I. Introduction to Kumho Asiana Group & KKPC

- Kumho Asiana Group and Affiliated Companies

- Corporate Milestones

- Business Fields & Sales Composition

- Global Partnership

II. Introduction to Kumho Petrochemical R&BD Center

- R&BD Strategy

- Nd-Br

- Porous Asphalt (Silent Asphalt) Modifier

- Carbon Nano Materials

- Computer-aided Research

- Electronic Materials

ContentsContents

I. Introduction toI. Introduction to

KumhoKumho AsianaAsiana Group & KKPCGroup & KKPC

Who is Who is KumhoKumho AsianaAsiana Group?Group?

� http://www.kumho.co.kr

Affiliated CompaniesAffiliated Companies

2005년

12월말

2006년

12월말

� 1970. 12 - Korea Synthetic Rubber Industries Co., Ltd. established.

� 1973. 04 - SBR plant launched. (Ulsan 25,000MT)

� 1979. 10 - BD plant launched. (Yeosu 50,000MT)

� 1980. 03 - BR plant launched. (Yeosu 25,000MT)

� 1984. 03 - SBR Latex plant launched. (Ulsan)

� 1985. 06 - Company name changed to Korea Kumho Petrochemical Co., Ltd.

� 1985. 06 - Kumho Petrochemical Research Center established.

� 1988. 12 - Multi-purpose BR plant launched.

� 1994. 02 - Kumho Chemical Laboratories opened in Daedeok Technovalley.

� 1994. 08 - Thermoplastic elastomer(SBS) production started.

� 1995. 08 - ISO 14001 certification acquired

� 1997. 07 - Combined heat & power plant in Yeosu built.

� 1998. 11 - Asan plant(Electronic material division) launched.

� 2001. 01 - Merged with Kumho Chemicals, Inc.

� 2003. 01 - Recieved the Environment Management Award.

� 2003. 08 - Kumho Chemical Laboratory and Ichon Laboratory merged

� 2003. 08 - into Kumho Petrochemical R&BD Center.

� 1970. 12 - Korea Synthetic Rubber Industries Co., Ltd. established.

� 1973. 04 - SBR plant launched. (Ulsan 25,000MT)

� 1979. 10 - BD plant launched. (Yeosu 50,000MT)

� 1980. 03 - BR plant launched. (Yeosu 25,000MT)

� 1984. 03 - SBR Latex plant launched. (Ulsan)

� 1985. 06 - Company name changed to Korea Kumho Petrochemical Co., Ltd.

� 1985. 06 - Kumho Petrochemical Research Center established.

� 1988. 12 - Multi-purpose BR plant launched.

� 1994. 02 - Kumho Chemical Laboratories opened in Daedeok Technovalley.

� 1994. 08 - Thermoplastic elastomer(SBS) production started.

� 1995. 08 - ISO 14001 certification acquired

� 1997. 07 - Combined heat & power plant in Yeosu built.

� 1998. 11 - Asan plant(Electronic material division) launched.

� 2001. 01 - Merged with Kumho Chemicals, Inc.

� 2003. 01 - Recieved the Environment Management Award.

� 2003. 08 - Kumho Chemical Laboratory and Ichon Laboratory merged

� 2003. 08 - into Kumho Petrochemical R&BD Center.

Corporate Milestones of KKPCCorporate Milestones of KKPC

Plants and Research CenterPlants and Research Center

Seoul Head Office

Electronic Chemicals

Division (Asan)

R&BD Center

(Daejeon)

Yeosu Plant(Synthetic Rubbers)

Yeosu Plant(Fine Chemicals)

Ulsan Plant(Synthetic Resins)

Ulsan Plant(Synthetic Rubbers)

Combined Heat

& Power Plant

Business FieldBusiness Field

Business Area Products Capacity (MT/y)

SBR (Emulsion Styrene Butadiene Rubber) 185,000

NBR (Acrylonitrile Butadiene Rubber) 30,000

HSR (High Styrene Resiin Masterbatch) 10,000

BR (Polybutadiene Rubber) 140,000

S-SBR, SBS (Styrene-Butadiene-Styrene copolymer) 70,000

SB Latex (Styrene Butadiene Latex) 70,000

BD (Butadiene) 205,000

Total 710,000

PS (Polystyrene) 175,000

ABS (Acrylonitrile Butadiene Styrene) 220,000

ASA (Acrylonitrile Styrene Acrylate) 10,000

EP (Engineering Plastics) 20,000

EPS (Expandable Polystyrene) 90,000

PPG (Polypropylene glycol) 40,000

SAN (Strene Acrylonitrile) 34,000

Total 589,000

Fine Chemicals Antioxidants & Vulcanization Accelerators 21,000

Electronic Chemicals Stipper, Developer & Photoresist 3,045

Synthetic

Rubbers

Synthetic

Resins

Sales Composition & VolumeSales Composition & Volume

140.4143.0Others

892.1896.6Synthetic

Rubbers

720.5669.7Synthetic

Resins

1,753.01,709.3Total

20062005Sales

Volume

(KRW in billions)

※※※※ Others: Fine Chemicals, Electronic Materials & Combined Heat and Power Plants

Synthetic resin Synthetic rubber Others

41.1% 50.9%

Market PositionMarket Position

1) Global capacity for synthetic rubber

� Unit: 1,000 ton

� Standard: SBR, BR

WorldWorld’’s 3s 3rdrd Production CapacityProduction Capacity

KoreaKorea’’s No.1 in M/Ss No.1 in M/S

Market PositionMarket Position

1) Global capacity for synthetic rubber

Sales Breakdown by ApplicationSales Breakdown by Application

Automobile

Affiliated Companies Affiliated Companies (Chemical companies)

1) Kumho P&B Chemicals, Inc.

� Established in April 1976

� Joint-venture: KKPC(51%), Nippon Steel Chemical(28%), Sumitomo Corp.(20%)

� Product: Phenol, Acetone, Bispheno-A, MIBK, Epoxy resin, Cumene

2) Kumho Polychem Co., Ltd.

� Established in June 1985

� Joint-venture: KKPC(50%), JSR(35%), Exxon(15%)

� Product: EP rubber

3) Kumho Mitsui Chemicals, Inc.

� Established in March 1989

� Joint-venture: KKPC(50%), Mitsui Chemicals Co., Ltd.(50%)

� Product: MDI, Aniline

4) Shanghai Kumho Sunny Plastics Co., Ltd.

� Established in October 2000

� Joint-venture: KKPC(50%), Shanghai Sunny New Technology Development Co., Ltd.(50%)

� Product: Raw material of the modified engineering plastics of styrene monomer series

Global PartnershipGlobal Partnership

Overseas office & Tech. Center

Technology Export

Technology Import

LA/

San DiegoShanghai

GBPC(1999~)ABS Plant

SINOPEC(1993)ABS/SAN Plant

P.T.RBI (1992)P.T.ALL(1994,1996)ABS/SAN Plant

FINA (PS/HIPS)

Dow Chem. (Polyol)Sekisui Plastics (EPS)

JSR (Synthetic Rubber)

Guangzhou

Hongkong

Nippon A&L (ABS)

II. Introduction toII. Introduction to

KumhoKumho Petrochemical R&BD CenterPetrochemical R&BD Center

NdNd--BR BR (Neodymium Butadiene Rubber)

NdBR

Ultra High Cis Polybutadiene

– devolopment of Nd Catalyst for Butadiene Polymerization

Core : the engine of Golf Ball, convert impact energy to flying distance.

Neodymium-Polybutadiene Rubber

“ A game whose aim is to hit a very small ball into an even smaller hole”

-Winston Churchill

Cover: Spin (feeling)Cover: Spin (feeling)

Core: DistanceCore: Distance

NdNd--BR BR (Neodymium Butadiene Rubber)

““Distance is a big thingDistance is a big thing””

배수성배수성배수성배수성배수성배수성배수성배수성////////저소음저소음저소음저소음저소음저소음저소음저소음 아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트 개질제개질제개질제개질제개질제개질제개질제개질제

배수성배수성배수성배수성 포장포장포장포장 일반일반일반일반 밀입도밀입도밀입도밀입도 포장포장포장포장

�������� 배수성배수성배수성배수성배수성배수성배수성배수성 아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트 개질제개질제개질제개질제개질제개질제개질제개질제

일반 포장에 비해 공극률을 크게 하여 빗물이

도로 표면에 고여 있지 않고 표층 내부로 빠르게

침투할 수 있도록 설계된 포장체

SBS

based

binder

�������� 일반일반일반일반일반일반일반일반 포장과포장과포장과포장과포장과포장과포장과포장과 배수성배수성배수성배수성배수성배수성배수성배수성 포장의포장의포장의포장의포장의포장의포장의포장의 비교비교비교비교비교비교비교비교

배수성배수성배수성배수성배수성배수성배수성배수성////////저소음저소음저소음저소음저소음저소음저소음저소음 아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트 개질제개질제개질제개질제개질제개질제개질제개질제

�������� 배수성배수성배수성배수성배수성배수성배수성배수성 아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트아스팔트 시범시범시범시범시범시범시범시범 포장포장포장포장포장포장포장포장

� Totally, about 61 kilometers (conversed to 2-lane road) on 21 sites

Carbon Carbon NanoNano MaterialsMaterials

Carbon Nano Tube

(CNT)

Carbon Nano Fiber

(CNF)

Single wall Multi wall

양산성 순도/수율/생산성 저하 양산화 진행 양산화 진행

가격, USD/g 100~500 1~50 0.5~10

� 소재시장의 급격한 성장 예상, 2010년 세계시장 약 1.8 조원 (AAGR:~30%)

� 대량생산체제의 진전과 가격하락 등이 근래에 급속히 진행되고 있으며 산업성장기 진입이 임박한 것으로

예상되고 있음

� 물질 특허 이슈 / 응용 기술 개발 필요

ComputerComputer--aided Research aided Research

�������� Computational chemistryComputational chemistry

금호금호금호금호 슈퍼컴슈퍼컴슈퍼컴슈퍼컴 3호기호기호기호기 (SGI Altix 4700, 80DualCPU)

ComputerComputer--aided Research aided Research

�������� Computational chemistry Computational chemistry - Length and Time scale

femto

pico

micro

milli

min

year

QM

MD

CoarseGrain

Modeling

Process

Sim.

Eng.

Design

Time

Distance

1 A 10 A 100 A 1 micro 1 cm m

Atomic Approach

Schrodinger Eq.Newtonian Eq.

Continuum Mech.

Navier-Stock Eq.

Maxwell’s Eq.

Mesoscale

Simulation

5:5

Iso-propene

Styrene

8:2

9:1

ComputerComputer--aided Research aided Research

�������� Diblock(PIDiblock(PI--PS) morphology PS) morphology 계산계산계산계산계산계산계산계산 (MesoDyn 이용이용이용이용)

ComputerComputer--aided Research aided Research

�������� CCAD/CAM/CAEAD/CAM/CAE

Region of high shear stress

is large, probability of mold

crack should be high.

Region of high shear stress

is smaller than the original

model, probability of mold

crack should be low.

Filling pattern Shear stress

Original model

Filling pattern Shear stress

Recomended model

Electronic Chemicals Electronic Chemicals

TFT-LCD MATERIALSOver Coating, Hard coat, Sealant

OTHER MATERIALSPhoto-acid Generator

SEMICONDUCTOR MATERIALS

ArF Photoresist, ArF BARC

ElectronicElectronic

MaterialsMaterials

� ArFArFArFArF PhotoresistPhotoresistPhotoresistPhotoresist 개발개발개발개발

� 기타기타기타기타 반도체반도체반도체반도체 및및및및 LCD LCD LCD LCD 공정공정공정공정 재료재료재료재료