apparel and footwear international rsl management...

DANH SCH cc cht bi hn chPhin bn 02 | 2017

Apparel and Footwear International RSL Management Group (Tp on Qun l RSL Quc t trong Giy dp v May mc hay AFIRM)

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Danh Sch Cc Cht Bi Hn Ch ca AFIRM | 2017

Mc lc

S mnh ca AFIRM ..................................................................................... 3Tm nhn ca AFIRM..................................................................................... 3Tuyn b Chnh sch .................................................................................... 3

Tuyn B Php L ......................................................................................... 4

Lin kt v Ti liu tham kho ....................................................................... 5

Nht K Thay i i Vi 2017 AFIRM RSL ................................................. 6

Cc Vt Liu Trong C Kh Nng Pht Hin Cc Cht Bi Hn Ch ....... 7

Xc inh Tui......................................................................................... 10

Danh Sch Cc Cht Bi Hn Ch ca AFIRM..............................................11

Ph lc A: Thuc Dit Cn Trng, Nng Nghip ......................................... 26

Apparel and Footwear International RSL Management (AFIRM) Group l tc gi ca tc phm ny.

Bn c th ti s dng hoc iu chnh tc phm ny, c hoc khng c quy cho Tp on AFIRM.

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S mnh ca AFIRMAFIRM l Apparel and Footwear International RSL Management (AFIRM) Working Group, c thnh lp vo nm 2004. S mnh ca AFIRM l "gim thiu vic s dng v nh hng ca cc cht c hi trong chui cung ng may mc v giy dp." Mc ch ca AFIRM l cung cp mt din n thc y vic qun l cc cht bi hn ch trn ton cu trong may mc v giy dp, truyn t thng tin v qun l ha cht n chui cung ng, tho lun v cc mi quan ngi, v trao i kin ci thin vic qun l ha cht.

tm nhn ca AFIRMAFIRM tip tc l mt trung tm xut sc ton cu c cng nhn, cung cp cc ngun lc cho php lin tc thc y cc thc tin qun l ha cht tt nht. Chng ti thc hin iu ny da trn tnh minh bch, khoa hc, v phi hp vi cc ngnh v cc chuyn gia c lin quan xy dng ha hc an ton hn v bn vng hn trong chui cung ng may mc v giy dp. iu ny c hiu rng trong vic p dng tm nhn ny, s mnh, cc mc tiu v d n ca AFIRM s tip tc tp trung vo sn phm hoc lin quan n RSL.

tuyn b chnh sch v cc cch S dng RSL nyAFIRM to ra Danh sch cc Cht bi Hn ch sau y gip v hng dn nhng ngi tham gia chui cung ng tm cch tng cng cht lng v s an ton ca sn phm hoc gim tc ng mi trng ca chng bng cch hn ch s dng cc cht nht inh (RSL ca AFIRM). Cc thng hiu thnh vin AFIRM c th khc nhau v thng s c nhn; nh cung cp nn kim tra vi khch hng v cc yu cu thng hiu c th. RSL ca AFIRM nn thc y s mnh ca AFIRM "gim thiu vic s dng v nh hng ca cc cht c hi trong chui cung ng may mc v giy dp" bng cch cung cp mt tp hp thng tin duy nht ti u v thc hin theo chiu su trong chui cung ng.

Mt s v d v cc cch s dng i vi RSL ca AFIRM, ty thuc vo cc mc tiu ca ngi s dng, bao gm:

Cung cp mt cng c cho cc nh cung cp thit lp kin thc v cc qu trnh qun l ha cht.

Xy dng c s tun th cc hn ch ha cht ca thnh vin AFIRM.

Cung cp mt c s chung cho cc sn phm th nghim, trong c th c nhiu thng hiu AFIRM chp nhn.

Cc cng ty thnh vin AFIRM xc inh v trao i vi cc nh cung cp ca h v cc yu cu th nghim ca h v nghim thu cc bo co th nghim.

bit thm thng tin v AFIRM, hy truy cp www.afirm-group.com.

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tuyn b Php l RSL ca AFIRM ch cu thnh thng tin t AFIRM v khng i din cho bt k thnh vin AFIRM c nhn. RSL thng hiu c nhn c th khc nhau cc thng s c th.

RSL ca AFIRM khng c inh v khng thit lp bt k tiu chun chm sc ca ngnh. RSL ca AFIRM khng th lun cung cp cch tip cn ph hp nht cho bt k chng trnh qun l ha cht ca tng cng ty. Nhiu thng hiu c hng dn thc hin, v cc nh cung cp phi tun theo cc hng dn nu bt buc. RSL ca AFIRM khng cu thnh t vn php l v khng thay th cho t vn php l. Khng c bo m, r rng hay ng , v s hon thin hoc tin ch ca thng tin cha trong RSL ca AFIRM ny, bao gm, nhng khng gii hn, vic thng tin l hin hnh v khng bi li. AFIRM t chi trch nhim php l di bt k hnh thc pht sinh t bt k vic s dng hoc tin tng vo RSL ca AFIRM.

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Lin kt v ti liu tham kho Hy ch ng! Cc lin kt ny c th cung cp thng tin quan trng b sung v nn truy cp thng xuyn.

nh ngha v vt liu v cc thng s th nghim c lin quan www.afirm-group.com/wp-content/uploads/2013/04/AFIRMSupplierToolkit.pdf

b dng c nh cung cp AFIRM www.afirm-group.com/toolkit/

C sn cc bn dich ting Trung, ting Vit v ting Ty Ban Nha.

cc cht b hn ch b sung cng mc ph hp c th c http://echa.europa.eu

Danh sch cc cht ng vin c mi lo ngi rt cao (SVhc) http://echa.europa.eu/de/candidate-list-table

tng quan v cc gii hn php l ca ha cht v nc xut x https://www.wewear.org/industry-resources/restricted-substances-list/

cc kh nh knh flo ha c quy nh, Ec 842/2006 http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2006:161:0001:0011:EN:PDF

VOcs c quy nh, Ec 1005/2009 http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2009:286:0001:0030:EN:PDF

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cAS s cht iu chnh trang98-86-2 Acetophenone Phng php kim tra c thay i thnh: Trch xut trong acetone GC/MS, phn on siu m trong

30 pht 60 C 11617-94-7 2-Phenyl-2-Propanol

Khc Alkylphenol (AP) v Alkylphenol Ethoxylates (APEOs), bao gm tt c cc ng phnPhng php kim tra i vi hng dt may c thay i thnh: EN ISO 18254-1:2016, xc inh AP dng LC/MS hoc GC/MS 11

Khc Azo-amines Phng php kim tra i vi hng dt may c thay i thnh: prEN ISO 14362-1:2015 12

80-05-7 Bisphenol-A Phng php kim tra i vi trch xut c thay i thnh: 1 g mu/20 ml methanol, phn on siu m trong 60 70 C 13

Khc Paraffin Clo ho Phng php kim tra c thay i thnh: EN ISO 18219:2016 13

Khc Chlorophenol Phng php kim tra c thay i thnh: 1 M Tch chit KOH, 12-15 gi 90 C, dn xut v phn tch; 64 LFGB B 82.02-08 hoc DIN EN ISO 17070:2015 13

68-12-2 Dimethylformamide (DMFa) Cu bi xa: DMFa c mi mnh trong thnh phm. 15

624-49-7 Dimethylfumarate (DMFu) Phng php kim tra c thay i thnh: CEN ISO/TS 16186:2012 15

50-00-0 Formaldehyde Phng php kim tra i vi da c thay i thnh: ISO 17226-1:2008 vi phng php xc nhn ISO 17226-2:2008 trong trng hp c sai s 18

7440-39-3 Kim loi Nng, Bari Gii hn b sung 1000 ppm c th trch xut 19

18540-29-9 Kim Loi Nng, Chrom VI Gii hn c th trch xut c sa thnh: Da: 3 ppm; Hng an dnh cho tr s sinh: 0,5 phn triu 20

100-42-5 Monomer, Styrene Gii hn b sung 500 ppm 21

Khc N-Nitrosamines Thm vo phng php kim tra GB/T 24153-2009: Xc inh dng GC/MS hoc LC/MS/MS 21

Khc Cc Hp cht Organotin Phng php kim tra c thay i thnh: CEN ISO/TS 16179: 2012 21

Khc Cc cht ph hy tng ozone Phng php kim tra c thay i thnh: Khong trng GC/MS 120 C trong 45 pht 22

Khc Phthalat Phng php chun bi mu c thay i thnh: CPSC-CH-C1001-09.3 23

Khc Cc Hp cht Hu c D bay hi (VOC) Phng php kim tra c thay i thnh: i vi sng lc VOC chung: Khong trng GC/MS 120 C, 45 pht. i vi DMAC: DIN CEN ISO/TS 16189:2013 25

nht K thay i i Vi 2017 AFIRM RSL

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cc Vt Liu trong c Kh nng Pht hin cc cht b hn chTrong chui cung ng qun o v giy dp, cc loi vi v vt liu nht inh c kh nng cao cha cc cht bi hn ch. Nhiu thng hiu yu cu phi kim tra sn phm trc khi vn chuyn m bo rng cc sn phm tun th RSL; thng tin ny c a vo cc yu cu ty theo thng hiu.A

Cc thng hiu trong Tp on AFIRM nht tr v cc ha cht c a vo AFIRM RSL, gii hn c php, v phng php kim tra. Tng thng hiu vn chiu trch nhim qun l chng trnh kim tratrong phi kim tra cc ha cht hn ch s dng c th trong cc vt liu c th v tn sut kim tra.

Bng ri ro c cho bit trong Bng 1, trang tip theo, nhn mnh nhng ri ro v cc cht bi hn ch lin quan n cc loi vi v vt liu khc nhau, v c trnh by nh mt cng c hng dn. Bng ny da trn nhiu nm kinh nghim ca chng ti trong gin xut v qun l cc cht bi hn ch cc vt liu khc nhau. Bng s dng m mu sau y:

Mu cho bit rng mt ha cht c s dng rng ri v/hoc thng c pht hin trong mt vt liu c th.

Mu cam cho bit rng mt ha cht c s dng c ch ch v/hoc i khi c pht hin trong mt vt liu c th.

Mu vng cho bit c xc sut l thuyt rt thp l mt ha cht c th c s dng v/hoc pht hin.

Mu trng cho bit chng ti cho rng c ri ro hu nh khng ng k v vic mt ha cht c s dng v/hoc pht hin.

Mc ch ca bng ri ro l cung cp thng tin v cc cht trc y c s dng c ch ch hoc c pht hin l cht phn ng/tp cht trong cc vt liu khc nhau.B Bng ny khng th hin s khuyn co kim tra, v tng thng hiu v hng sn xut cn phi tin hnh nh gi ri ro chi tit v cc sn phm v thnh phn ca mnh.

Phng n thng nht ca AFIRM RSL s cho php cc thng hiu thnh vin chia s d liu kim tra mt cch d dng hn, v chng ti d kin rng bng ri ro ny s thay i phn nh nhng ri ro thc t vo bt k thi im c th no.

A. Xem Phn 5 ca B Cng C Dnh Cho Nh Cung Cp ca AFIRM bit thm thng tin v kim tra v Ph Lc C ca B Cng C Dnh Cho Nh Cung Cp bit chng trnh kim tra mu nu khch hng ca bn khng c chng trnh ring.

B. Nu mt cht l thnh phn ca mt vt liu kt hp (v d, thnh phn nhiu lp nh vt liu polymer material + lp lt vi), chng ti khuyn co nn kim tra theo cc loi vt liu khc nhau.

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2

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cht

Vi t

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Acetophenone v 2-Phenyl-2-Propanol 2D

Alkylphenol (AP) v Alkylphenol Ethoxylates (APEOs), bao gm tt c cc ng phn 1 1 1 1 1 1 1 1 3 1

Azo-amines 1 1 1 1 1 1 1 1

Bisphenol-A 3

Chlorinated Paraffin, SCCP (C10-C13) v MCCP (C14-C17) 3 3 3 3 1 3 2

Chlorophenol (Tri-, Tetra-, v Pentachlorophenol) 3 3 3 3 3 3

Cht mang Clo hu c 2 2 3

Dimethylformamide (DMFa) 2 2 2

Dimethylfumarate (DMFu) 3 3 3 3 3 3 3

Thuc nhum, Bi cm v Phn tn 2 2 2 2

Thuc nhum, Xanh Hi qun 3 3 3 3

Cht chng chy 3 (Nu p dng hon thin)

Kh Nh knh cha Flo

Formaldehyde 1 1 1 1 1 1 1 1

Kim Loi Nng, Chrom VI 3 1

cc Vt Liu trong c Kh nng Pht hin cc cht b hn ch

bng 1 bng Ri Ro

C. Ngoi ra, Styrene (Monomer) l 'Vng mc ri ro 3' i vi cc vt liu ny.D. mc ri ro 1 ch p dng cho bt xp Ethylene-Vinyl Acetate (EVA).

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Kim Loi Nng, Gii Phng Nikel 1

Kim Loi Nng, Tng Cadimi 3 3 3 3

Kim Loi Nng, Tng Ch 3 3 3E 3

Kim Loi Nng, Tng B Sung (Hg & As) 3 3 3 3

Kim Loi Nng, C Th Trch Xut 2 2 2 2 2 2 2

N-Nitrosamines 2

Cc Hp cht Organotin 3 3 3 3 3 3 3 3

Ortho-phenylphenol (OPP) 2 2 2 2 2 2

Cc cht ph hy tng ozone 3

Cc Hot cht Perfluorinated v Polyfluorinated (PFCs) 2 (Nu p dng hon thin chng nc hoc chng )

Thuc tr su, Nng nghip 3 3 3

Phthalat 1 1 1 1

Hydrocacbon Thm a vng (Polycyclic Aromatic Hydrocarbons - PAHs) 1 1 1 1

Cc Hp cht Hu c D bay hi (VOC) 2 2 2 2 2 2 2 2

E. Tng ch trong bt xp l Cam mc ri ro cao 2.

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tui

Em b 0 n 36 thng

Tr em 36 thng n 14 tui

Ngi ln T 14 tui tr ln

nh ngha v tui tcCc quc gia khc nhau inh ngha cc thut ng "em b", "tr em", v "ngi ln" khc nhau. Cn c vo php lut, tui c lit k trong Bng 2 p ng cc yu cu ton cu hn ch nht.

bng 2 nh ngha v tui tc

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cAS s cht Gii hn Nguyn liu Th &Thnh phm

tim nng S dngGia cng Dt cho Trang phc & Giy dp

Phng php th nghim Ph hpChun bi Mu v o lng

Acetophenone v 2-Phenyl-2-Propanol

98-86-2 Acetophenone50 phn triu mi loi

Sn phm phn hy tim nng trong bt EVA khi s dng dicumyl peroxide lm cht to lin kt cho.

Tch chit trong acetone GC/MS, phn on siu m trong 30 pht 60 C 617-94-7 2-Phenyl-2-Propanol

Alkylphenol (AP) v Alkylphenol Ethoxylates (APEOs), bao gm tt c cc ng phn

104-40-5

Nonylphenol (NP), cc ng phn hn hp

Tng: 100 phn triu

APEO c th c s dng lm hoc c tm thy trong cht ty ra, cht ty, du quay, cht thm t, cht lm mm, cht nh ha/phn tn dng cho thuc nhum v in n, cht tm, kh keo sn xut t, thuc nhum v cc ch phm bt mu, m lt polyester v cht n y lng v (lng nhung/lng mnh).

APEO v cc cng thc c cha APEO u bi cm s dng trong sut chui cung ng v quy trnh sn xut. Chng ti tha nhn rng nng d hoc nh APEO vn c th c tm thy cc mc vt qu 100 phn triu v cn c nhiu thi gian hn chui cung ng loi b chng hon ton. Gii hn ny phn nh lut php EU d kin v c thit lp cung cp cho cc nh cung cp cc cnh bo trc v inh hng ci tin lin tc.

Dt may: EN ISO 18254-1: 2016, xc inh AP dng LC/MS hoc GC/MSDa: EN ISO 18218-1:2015

11066-49-2

25154-52-3

84852-15-3

140-66-9

Octylphenol (OP), cc ng phn hn hp1806-26-4

27193-28-8

9002-93-1

Octylphenol ethoxylates (OPEOs)

Tng: 100 phn triu

9036-19-5

68987-90-6

9016-45-9

Nonylphenol ethoxylates (NPEOs)

26027-38-3

37205-87-1

68412-54-4

127087-87-0

Danh sch cc cht b hn ch ca AFIRM

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Azo-amines

92-67-1 4-Aminobiphenyl

20 phn triu mi loi

Thuc nhum v bt mu Azo l cc cht to mu kt hp mt hoc nhiu nhm azo (-N=N-) gn vi cc hp cht thm. Hng nghn thuc nhum azo tn ti, nhng ch nhng loi phn hy hnh thnh cc amine c th phn ra lit k mi bi hn ch. Thuc nhum azo gii phng cc amine ny c quy inh v khng cn c s dng nhum vi dt.

Dt may: (EU): prEN ISO 14362-1:2015Da: (EU): CEN ISO/TS 17234-1:2015

p-Aminoazobenzene: Dt may: EN 14362-3:2015Da: 17234-2:2011

92-87-5 Benzidine

95-69-2 4-Chloro-o-toluidine

91-59-8 2-Naphthylamine

97-56-3 o-Aminoazotoluene

99-55-8 2-Amino-4-nitrotoluene

106-47-8 p-Chloraniline

615-05-4 2,4-Diaminoanisole

101-77-9 4,4-Diaminodiphenylmethane

91-94-1 3,3-Dichlorobenzidine

119-90-4 3,3-Dimethoxybenzidine

119-93-7 3,3-Dimethylbenzidine

838-88-0 3,3-dimethyl-4,4-diaminodiphenylmethane

120-71-8 p-Cresidine

101-14-4 4,4-Methylen-bis(2-chloraniline)

101-80-4 4,4-Oxydianiline

139-65-1 4,4-Thiodianiline

95-53-4 o-Toluidine

95-80-7 2,4-Toluylendiamine

137-17-7 2,4,5-Trimethylaniline

95-68-1 2,4 Xylidine

87-62-7 2,6 Xylidine

90-04-0 2-Methoxyaniline (= o-Anisidine)

60-09-3 p-Aminoazobenzene

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bisphenol-A

80-05-7 Bisphenol-A (BPA) 1 phn triu

c s dng trong sn xut nha epoxy, nha polycarbonate, cht chng chy v PVC.

Bi cm s dng trong cc hp ng thc phm v ung, v cc mt hng c inh tip xc vi khoang ming.

Chun bi mu: Trch xut: 1 g mu/20 ml methanol, phn on siu m trong 60 70 Co lng: DIN EN ISO 18857-2 (mod)

Paraffin clo ho

85535-84-8 Paraffin clo ho chui ngn (Short-chain chlorinated Paraffins hay SCCP) (C10-C13) 1000 phn triu C th c s dng lm cht chng chy hoc cht lng bo trong sn xut da. Chng cng c th c s dng lm cht lm do.

EN ISO 18219:201685535-85-9 Paraffin clo ho chui trung bnh (Medium-chain chlorinated Paraffins hay MCCP) (C14-C17) 1000 phn triu

chlorophenol

15950-66-0 2,3,4-Trichlorophenol

0,5 phn triu mi loi

Chlorophenol l cc hp cht polychlorinated c s dng lm cht bo qun hoc thuc tr su. Pentachlorophenol (PCP) v tetrachlorophenol (TeCP) i khi c s dng chng nm mc v dit cn trng khi trng bng v khi lu tr/vn chuyn vi. PCP v TeCP cng c th c s dng lm cht bo qun trong bt nho in n.

1 M Tch chit KOH, 12-15 gi 90 C, dn xut v phn tch; 64 LFGB B 82.02-08 hoc DIN EN ISO 17070:2015






4901-51-3 2,3,4,5-Tetrachlorophenol (TeCP)



87-86-5 Pentachlorophenol (PCP)

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cht mang clo hu c

95-49-8 2-Chlorotoluene

Tng: 1 phn triu

Chlorobenzenes v chlorotoluenes (Hydrocacbon thm c clo ha) c th c s dng lm cht mang trong qu trnh nhum polyester hoc si len/polyester. Chng cng c th c s dng lm dung mi.

DIN 54232:2010



32768-54-0 2,3-Dichlorotoluene





2077-46-5 2,3,6-Trichlorotoluene

6639-30-1 2,4,5-Trichlorotoluene

76057-12-0 2,3,4,5-Tetrachlorotoluene

875-40-1 2,3,5,6-Tetrachlorotoluene

877-11-2 Pentachlorotoluene

541-73-1 1,3-Dichlorobenzene

106-46-7 1,4-Dichlorobenzene

87-61-6 1,2,3-Trichlorobenzene



634-66-2 1,2,3,4-Tetrachlorobenzene



608-93-5 Pentachlorobenzene

118-74-1 Hexachlorobenzene

95-50-1 1,2-Dichlorobenzene 10 phn triu

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Dimethylformamide

68-12-2 Dimethylformamide (DMFa) 500 phn triu

DMFa l mt dung mi c s dng trong nha, cao su, v cht ph polyurethane (PU). PU da trn nc khng cha DMFa v do l mt li th.

DIN CEN ISO/TS 16189:2013

Dimethylfumarate

624-49-7 Dimethylfumarate (DMFu) 0,1 phn triu

DMFu l mt cht chng nm mc c s dng trong cc ti trong ng gi ngn s tch t nm mc, c bit l trong qu trnh vn chuyn.

CEN ISO/TS 16186:2012

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thuc nhum, b cm v Phn tn

2475-45-8 C.I. Xanh da tri Phn tn 1

75 phn triu mi loi

Thuc nhum phn tn l mt loi thuc nhum khng tan trong nc xm nhp vo h thng si ca cc si tng hp hoc c ch to v c gi li bi cc lc lng vt l m khng hnh thnh lin kt ha hc. Thuc nhum phn tn c s dng trong si tng hp (chng hn nh olyester, acetate, polyamide). Thuc nhum phn tn bi hn ch bi nghi ng gy phn ng di ng v bi cm s dng nhum vi dt.

DIN 54231:2005








23355-64-8 C.I. Nu Phn tn 1

2581-69-3 C.I. Cam Phn tn 1

730-40-5 C.I. Cam Phn tn 3

82-28-0 C.I. Cam Phn tn 11

12223-33-5

C.I. Cam Phn tn 37/76/5913301-61-6

51811-42-8

85136-74-9 C.I. Cam Phn tn 149

2872-52-8 C.I. Phn tn 1

2872-48-2 C.I. Phn tn 11

3179-89-3 C.I. Phn tn 17

61968-47-6 C.I. Phn tn 151

119-15-3 C.I. Vng Phn tn 1

2832-40-8 C.I. Vng Phn tn 3

6300-37-4 C.I. Vng Phn tn 7

6373-73-5 C.I. Vng Phn tn 9

6250-23-3 C.I. Vng Phn tn 23

12236-29-2 C.I. Vng Phn tn 39

54824-37-2 C.I. Vng Phn tn 49

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thuc nhum, b cm v Phn tn, tip theo

54077-16-6 C.I. Vng Phn tn 56

75 phn triu mi loi

Thuc nhum phn tn l mt loi thuc nhum khng tan trong nc xm nhp vo h thng si ca cc si tng hp hoc c ch to v c gi li bi cc lc lng vt l m khng hnh thnh lin kt ha hc. Thuc nhum phn tn c s dng trong si tng hp (chng hn nh olyester, acetate, polyamide). Thuc nhum phn tn bi hn ch bi nghi ng gy phn ng di ng v bi cm s dng nhum vi dt.

DIN 54231:2005

3761-53-3 C.I. Axit 26

569-61-9 C.I. C bn 9

569-64-2

C.I. Xanh l cy C bn 42437-29-8

10309-95-2

548-62-9 C.I. Tm C bn 3

632-99-5 C.I. Tm C bn 14

2580-56-5 C.I. Xanh da tri C bn 26

1937-37-7 C.I. en trc tip 38

2602-46-2 C.I. Xanh da tri Trc tip 6

573-58-0 C.I. Trc tip 28

16071-86-6 C.I. Nu Trc tip 95

60-11-7 4-Dimethylaminoazobenzene (Vng Dung mi 2)

6786-83-0 C.I. Xanh da tri Dung mi 4

561-41-1 Cn 4,4'-bis(dimethylamino)-4''-(methylamino)trityl

thuc nhum, Xanh hi qun

118685-33-9 Thnh phn 1: C39H23ClCrN7O12S.2Na75 phn triu mi loi

Thuc nhum mu xanh hi qun c quy inh v bi cm s dng nhum vi dt. (Ch mc 611-070-00-2)

DIN 54231:2005Khng c phn b Thnh phn 2: C46H30CrN10O20S2

.3Na

18





cht chng chy

126-72-7 Tris(2,3,-dibromopropyl) phosphate (TRIS)

Tng: 5 phn triu

Cc ha cht chng chy t c s dng p ng yu cu v tnh d chy qun o tr em v cc sn phm dnh cho ngi ln. Cc ha cht ny khng cn c s dng trong may mc v giy dp.

Tch chit methanol, GC/MS

545-55-1 Tris(1-aziridinyl)phosphine oxide) (TEPA) LC-MS

32534-81-9 Pentabromodiphenyl ether (PentaBDE)

Tch chit acetonitril, LC-DAD-MS, v xc nhn vi GC/MS

32536-52-0 Octabromodiphenyl ether (OctaBDE)

1163-19-5 Decabromodiphenyl ether (DecaBDE)

79-94-7 Tetrabromobisphenol A (TBBP A)

115-96-8 Tris(2-chloroethyl)phosphate (TCEP)

Tch chit methanol, GC/MS

59536-65-1 Polybromobiphenyls (PBB)

5412-25-9 Bis(2,3-dibromopropyl) phosphate (BDBPP)

3194-55-6 Hexabromocyclododecane (HBCDD)

3296-90-0 2,2-bis(bromomethyl)-1,3-propanediol (BBMP)

13674-87-8 Tris(1,3-dichloro-isopropyl) phosphate (TDCPP)

25155-23-1 Trixylyl phosphate (TXP)

Kh nh knh cha Flo

Khc Xem Quy inh (EC) s 842/2006 c danh sch y . 0,1 phn triu mi loi

Chun bi mu: Cht hp th kh (purge and trap) gii hp nhit hay SPMEo lng: GC/MS

Formaldehyde

50-00-0 FormaldehydeNgi ln v tr em: 75 phn triuEm b: 16 phn triu

c s dng trong dt may di dng mt cht chng nhn v chng co. Cng thng c s dng trong nha polymer.

Dt may: JIS L 1041-1983 A (Lut Nht Bn 112) hay EN ISO 14184-1:2011Da: ISO 17226-1:2008 vi phng php xc nhn ISO 17226-2:2008 trong trng hp c sai s

19





Kim loi nng

7440-36-0 Antimon (Sb) C th tch chit: 30 phn triu

c tm thy trong hoc c s dng lm cht xc tc trong polyme ha polyester, cht chng chy, thuc hm, bt mu v hp kim.

Chun bi mu: EN ISO 105-E04:2013 o lng: EN ISO 17294-2:2014

7440-38-2 Asen (As)C th tch chit: 0,2 phn triu

Tng: 100 phn triu

Asen v cc hp cht ca Asen c th c s dng trong cc cht bo qun, thuc tr su v cht dit c s dng cho bng, si tng hp, sn, mc, trang tr v nha.

Chun bi mu: C th tch chit: Dt may: EN ISO 105-E04:2013 Da: DIN EN ISO 17072-1:2014 Tng: Ph mu bng vi sng vi H2O2/HNO3 o lng: EN ISO 17294-2 :2014

7440-39-3 Bari (Ba) C th tch chit: 1000 phn triu

Bari v cc hp cht ca n c th c s dng trong cc sc t cho mc, plastic, lp ph b mt, cng nh thuc nhum, cht ty, cht m trong plastic, hon thin hng dt may, v thuc da.

Chun bi mu: C th tch chit: Dt may: EN ISO 105-E04:2013 Da: DIN EN ISO 17072-1:2014o lng: EN ISO 17294-2 :2014

7440-43-9 Cadimi (Cd)

C th tch chit: 0,1 phn triu

Tng: Ngi ln: 75 phn triu Tr em v em b: 40 phn triu

Hp cht cadimi c s dng lm bt mu (c bit l mu , mu cam, mu vng v mu xanh l cy); lm cht n inh cho PVC; v trong phn bn, cht dit khun v cc loi sn.Tng gii hn cho tt c s c gim n 40 ppm trong mt bn cp nht trong tng lai.

Chun bi mu: C th tch chit: Dt may: EN ISO 105-E04:2013 Da: DIN EN ISO 17072-1:2014 Tng: Ph mu bng vi sng vi H2O2/HNO3 o lng: EN ISO 17294-2:2014

7440-47-3 Crom (Cr)

C th tch chit cho hng dt may: 1 phn triu

Giy dp da cho em b: 60 phn triu

Hp cht crom c th c s dng lm cht ph gia nhum, cht c inh thuc nhum, bn mu sau khi x l, thuc nhum cho len, la v polyamide (c bit l mu ti) v thuc da.

Chun bi mu: EN ISO 105-E04:2013o lng: EN ISO 17294-2:2014

20





Kim loi nng, tip theo

18540-29-9 Crom VI

C th tch chit: Da: 3 phn triuHng an dnh cho tr s sinh: 0,5 phn triu

Mc d thng c kt hp vi thuc da, Crom VI cng c th c s dng trong nhum len (sau qu trnh m crom).

Chun bi mu: Dt may: EN ISO 105-E04:2013 Gi ha da: Cc iu kin gi ha da: 24 gi, 80 C, ti a 5% m tng i, khng c thng gi; EN 17075-1:2015o lng: Dt may: EN ISO 17294-2 Da: EN 17075-1:2015 Th nghim gi ha c s dng ty tng thng hiu.

7440-48-4 Coban (Co) C th tch chit: 1 phn triu

Coban v cc hp cht ca Coban c th c s dng trong cc hp kim, bt mu, dng c nhum, v vic sn xut nt nha.

Chun bi mu: EN ISO 105-E04:2013o lng: EN ISO 17294-2

7440-50-8 ng (Cu) C th tch chit: 25 phn triu

C th tm thy ng v cc hp cht ca ng trong cc hp kim v bt mu, v trong dt may di dng cht khng khun.


7439-92-1 Ch (Pb)

C th tch chit: Ngi ln v tr em: 1 phn triu Em b: 0,2 phn triuTng: 90 phn triu

C th c kt hp vi nha, sn, mc, bt mu v cht ph b mt.

Chun bi mu: C th tch chit: EN ISO 105-E04:2013 Tng: Ph mu bng vi sng vi H202/HNO3Ch trong sn v cht ph b mt: CPSIA Mc 101 16 CFR 1303 o lng: EN ISO 17294-2:2014

7439-97-6 Thy ngn (Hg)C th tch chit: 0,02 phn triuTng: 0,5 phn triu

Cc hp cht thy ngn c th hin din trong thuc tr su v cc cht gy nhim nh trong xt (NaOH). Cc hp cht ny cng c th c s dng trong sn.

Chun bi mu: C th tch chit: EN ISO 105-E04:2013Tng: Ph mu bng vi sng vi H202/HNO3 o lng: EN ISO 17294-2:2014

7440-02-0 Niken (Ni)

C th tch chit: 1 phn triuGii phng: Tip xc vi da ko di: 0,5 g/cm/tunPhn c l: 0,2 g/cm/tun

Niken v cc hp cht ca Niken c th c s dng m hp kim v ci thin kh nng chng n mn v cng ca hp kim. Chng cng c th xut hin di dng cc tp cht trong bt mu v hp kim.

Chun bi mu: Dt may: EN ISO 105-E04:2013 Phn kim loi: EN 12472:2005+ A1:2009 o lng: Dt may: EN ISO 17294-2:2014 Phn kim loi: EN 1811:2015

21





Kim loi nng, tip theo

7782-49-2 Selen (Se) C th tch chit: 500 phn triuC th c tm thy trong cc si tng hp, sn, mc, nha v trang tr kim loi.


Monomer

100-42-5 Styrene 500 phn triu

Styrene l cht tin thn cho phn ng polymer ha v c th hin din trong nhiu styrene-copolymer khc nhau nh nt plastic.

Trch xut dung mi, khong trng 120 C trong 1 giGC-MS; Trch xut methanol 60 C

n-nitrosamines

62-75-9 N-nitrosodimethylamine (NDMA)

0,5 phn triu mi loiC th c hnh thnh di dng sn phm ph trong sn xut cao su.

GB/T 24153-2009: xc inh dng GC/MS hoc LC/MS/MS

55-18-5 N-nitrosodiethylamine (NDEA)

621-64-7 N-nitrosodipropylamine (NDPA)

924-16-3 N-nitrosodibutylamine (NDBA)

100-75-4 N-nitrosopiperidine (NPIP)

930-55-2 N-nitrosopyrrolidine (NPYR)

59-89-2 N-nitrosomorpholine (NMOR)

614-00-6 N-nitroso N-methyl N-phenylamine (NMPhA)

612-64-6 N-nitroso N-ethyl N-phenylamine (NEPhA)

cc hp cht Organotin

Khc Dibutyltin (DBT)

1 phn triu mi loi

Loi ha cht c cha thic v cht hu c nh cc nhm butyl v phenyl. Organotin ch yu c tm thy trong mi trng di dng cht chng bn trong sn hng hi, nhng chng cng c th c s dng lm cht dit sinh vt (v d, cht khng khun), cht xc tc trong sn xut nha v keo v cht n inh nhit trong nha/cao su. Trong dt may v may mc, organotin c kt hp vi nha/cao su, mc, sn, cht lm kim long lanh, cc sn phm polyurethane v vt liu truyn nhit.

CEN ISO/TS 16179: 2012

Khc Dioctyltin (DOT)

Khc Monobutyltin (MBT)

Khc Tributyltin (TBT)0,5 phn triu mi loi

Khc Triphenyltin (TPhT)

Khc Tt c cc hp cht Organotin c ba nhm th 1 phn triu mi loi

22





Ortho-phenylphenol

90-43-7 Ortho-phenylphenol (OPP) 1000 phn triu

OPP c th c s dng v cc c tnh bo qun ca n trong da hoc di dng cht mang trong qu trnh nhum.

Chun bi Mu: 64 BVL B 82.02.08 o lng: GC-MS, LC-MS xc nhn

cc cht ph hy tng ozone

Khc Xem Quy inh (EC) s 1005/2009 c danh sch y . Cc cht ph hy tng ozone bi cm s dng. Khong trng GC/MS 120 C trong 45 pht

cc hot cht Perfluorinated v Polyfluorinated (PFcs)

2795-39-3 Perfluorooctane Sulfonate (PFOS)

1 g/m2 mi loi

PFOA v PFOS c th hin din di dng cc sn phm ph d kin trong cc cht chng thm nc, du v bn thng mi chui di. PFOA cng c th c s dng trong cc polyme nh polytetrafluoroethylene (PTFE)

CEN/TS 15968:2014

3825-26-1 Axit Perfluorooctanoic (PFOA) v cc mui v este ca n

thuc tr su, nng nghip

Khc Xem Ph lc A c danh sch y . 0,5 phn triu mi loi C th c tm thy trong si t nhin, ch yu l cotton.

ISO 15913/DIN 38407 F2 hoc EPA 8081/EPA 8151A hoc BVL L 00.00-34:2010-09

23





Phthalat

28553-12-0 Di-Iso-nonylphthalate (DINP)

500 phn triu mi loiTng: 1000 phn triu

Este ca axit orthophthalic (phthalat) l mt loi hp cht hu c thng c thm vo nha tng tnh linh hot. i khi chng c s dng to thun li cho vic c nha bng cch gim nhit nng chy ca n.C th tm thy phthalat trong:

Cc thnh phn bng nha do (v d, PVC)

Bt nho in n Cht kt dnh Nt nha ng cch in nha Cht ph bng nha polyme

Cc phthalat c lit k l nhng loi thng c s dng cho cc ngnh cng nghip. Tm thm thng tin v cc phthalat bi hn ch theo lut php trong danh sch REACH SVHC, c cp nht thng xuyn.

Chun bi mu: CPSC-CH-C1001-09.3o lng: Dt may: GC-MS, EN ISO 14389:2014 Da: GC-MS

117-84-0 Di-n-octylphthalate (DNOP)

117-81-7 Di(2-ethylhexyl)-phthalate (DEHP)

26761-40-0 Diisodecylphthalate (DIDP)

85-68-7 Butylbenzylphthalate (BBP)

84-74-2 Dibutylphthalate (DBP)

84-69-5 Diisobutylphthalate (DIBP)

68515-42-4 Di(C7-C11 alkyl) phthalate (DHNUP), tuyn tnh + mch nhnh

71888-89-6 Di(C6-C8 alkyl) phthalate (DIHP), mch nhnh, giu C7

117-82-8 Di(2-methoxyethyl) phthalate (DMEP)

84-75-3 Di-n-hexylphthalate (DnHP)

84-66-2 Diethylphthalate (DEP)

605-50-5 Diisopentylphthalate (DIPP)

776297-69-9 n-Pentylisopentylphthalate (NPIPP)

131-18-0 Di-n-pentylphthalate (DPP)

68515-50-4 Dihexylphthalate, mch nhnh + tuyn tnh

131-11-3 Dimethylphthalate (DMP)

84777-06-0 Axit 1,2-Benzenedicarboxylic, dipentylester, mch nhnh + tuyn tnh

24





hydrocacbon thm a vng (Polycyclic Aromatic hydrocarbons - PAhs)

83-32-9 Acenaphtene

Khng c gii hn ring

Tng: 10 phn triu

PAHs l nhng thnh phn t nhin ca du th v l cc d lng ph bin t qu trnh lc du. PAHs c mi c trng tng t nh ca lp xe hoc nha ng. D lng du c cha PAHs c thm vo cao su v nha di dng cht lm mm hoc cht m rng v c th c tm thy trong cao su, nha, sn v cht ph. PAHs thng c tm thy trong ngoi ca giy dp v trong bt nho in n in mn hnh. PAHs c th hin hu di dng cc tp cht trong Than en. Chng cng c th c hnh thnh t s phn hy nhit ca vt liu ti ch trong qu trnh ti ch

**Naphthalene: Cc cht phn tn dng cho thuc nhum trong dt may c th cha nng naphthalene cn cao do vic s dng cc dn xut naphthalene cht lng thp (chng hn nh cc sn phm c c naphthalene sulphonate formaldehyde cht lng km).

AFPS GS 2014

208-96-8 Acenaphthylene

120-12-7 Anthracene

191-24-2 Benzo(g,h,i)perylene

86-73-7 Fluorene

206-44-0 Fluoranthene

193-39-5 Indeno(1,2,3-cd)pyrene

91-20-3 Naphthalene**

85-01-8 Phenanthrene

129-00-0 Pyrene

56-55-3 Benzo(a)anthracene

1 phn triu mi loiHng chm sc tr em: 0,5 phn triu mi loi

50-32-8 Benzo(a)pyrene

205-99-2 Benzo(b)fluoranthene

192-97-2 Benzo[e]pyrene

205-82-3 Benzo[j]fluoranthene

207-08-9 Benzo(k)fluoranthene

218-01-9 Chrysene

53-70-3 Dibenzo(a,h)anthracene

25





cc hp cht hu c D bay hi (VOc)

71-43-2 Benzen 5 phn triu

Khng nn s dng cc VOC ny trong cc ch phm ha cht dt ph tr. Chng cng lin quan n qu trnh da trn dung mi v d nh cht ph polyurethane da trn dung mi v cc loi keo/cht kt dnh. Khng nn s dng cc hp cht ny cho bt k hnh thc v sinh c s hoc v sinh ti ch.

i vi sng lc VOC chung: Khong trng GC/MS trong 45 pht 120 C i vi DMAC: DIN CEN ISO/TS 16189:2013

56-23-5 Cacbon tetraclorua

Tng: 1000 phn triu

67-66-3 Chloroform

107-06-2 1,2-Dichloroethane

75-35-4 1,1-Dichloroethylene

127-19-5 Dimethylacetamide (DMAC)

76-01-7 Pentachloroethane

630-20-6 1,1,1,2- Tetrachloroethane

79-34-5 1,1,2,2- Tetrachloroethane

127-18-4 Tetrachloroethylene (PER)

108-88-3 Toluene

71-55-6 1,1,1- Trichloroethane

79-00-5 1,1,2- Trichloroethane

79-01-6 Trichloroethylene

1330-20-7 Xylene (meta-, ortho-, para-)

26


115-32-2 Dicofol

141-66-2 Dicrotophos

60-57-1 Dieldrine

60-51-5 Dimethoate

88-85-7 Dinoseb, cc mui v acetat ca n

57648-21-2 DTTB (Timiperone)

115-29-7 Endosulfan

959-98-8 Endosulfan I (alpha)

33213-65-9 Endosulfan II (beta)

72-20-8 Endrine

66230-04-4 Esfenvalerate

106-93-4 Ethylendibromid

56-38-2 Ethylparathione

51630-58-1 Fenvalerate

1336-36-3Biphenyl halogen ha, bao gm c Polychlorinatedbiphenyl (PCB)53469-21-9

Khc

Khc Terphenol halogen ha, bao gm c polychlorinated terphenyl (PCT)

Khc Naphthalene halogen ha, bao gm c polychlorinated naphthalenes (PCNs)

Khc Diarylalkane halogen ha

99688-47-8 Cc diphenyl methane halogen ha, bao gm c Monomethyl-dibromo-diphenyl methane, Monomethyl-dichloro-diphenyl methane, v Monomethyl-tetrachloro-diphenyl methane

81161-70-8

76253-60-6

76-44-8 Heptachlor

1024-57-3 Heptachloroepoxide

36355-01-8 Hexabromobiphenyl

319-84-6 a-Hexachlorocyclohexane c v khng c Lindane

319-85-7 b-Hexachlorocyclohexane c v khng c Lindane

319-86-8 g-Hexachlorocyclohexane c v khng c Lindane

118-74-1 Hexachlorobenzene

465-73-6 Isodrine

4234-79-1 Kelevane

143-50-0 Kepone

7784-40-9 Asenat hydro ch

58-89-9 Lindane

121-75-5 Malathione

94-74-6 MCPA

94-81-5 MCPB

93-65-2 Mecoprop

10265-92-6 Metamidophos

72-43-5 Methoxychlor

2385-85-5 Mirex

6923-22-4 Monocrotophos

56-38-2 Parathion

298-00-0 Parathion-methyl

608-90-2 Pentabromobenzene

1825-21-4 Pentachloroanisole

52645-53-1 Permethrine

7786-34-7 Phosdrin/Mevinphos

72-56-0 Perthane

31218-83-4 Propethamphos

41198-08-7 Profenophos

13593-03-8 Quinalphos

82-68-8 Quintozene

8001-50-1 Strobane

297-78-9 Telodrine

8001-35-2 Toxaphene

731-27-1 Tolylfluanide

1582-09-8 Trifluraline

Ph lc A: thuc tr su, nng nghipcAS s tn thuc tr su cAS s tn thuc tr su cAS s tn thuc tr su

93-72-1 2-(2,4,5-trichlorophenoxy) axit propionic, cc mui v hp cht ca axit

93-76-5 2,4,5-T

93-72-1 2,4,5-TP

94-75-7 2,4-D

309-00-2 Aldrine

86-50-0 Azinophosmethyl

2642-71-9 Azinophosethyl

4824-78-6 Bromophos-ethyl

2425-06-1 Captafol

63-25-2 Carbaryl

510-15-6 Chlorbenzilat

57-74-9 Chlordane

6164-98-3 Chlordimeform

470-90-6 Chlorfenvinphos

1897-45-6 Chlorthalonil

56-72-4 Coumaphos

68359-37-5 Cyfluthrin

91465-08-6 Cyhalothrin

52315-07-8 Cypermethrin

78-48-8 S,S,S-Tributyl phosphorotrithioate (Tribufos)

52918-63-5 Deltamethrin

53-19-0DDD

72-54-8

3424-82-6DDE

72-55-9

50-29-3DDT

789-02-6

333-41-5 Diazinone

1085-98-9 Dichlofluanide

120-36-5 Dichloroprop

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