ch07 - wofford collegewebs.wofford.edu/hilljb/chem123/ch07.pdf · ch07.ppt author: hilljb created...

14
1

Upload: lamtram

Post on 10-Feb-2018

223 views

Category:

Documents


3 download

TRANSCRIPT

Page 1: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

1

Page 2: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

2

Page 3: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

3

Page 4: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

4

Page 5: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

5

E = hν

E = hν

Page 6: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

6

De Broglie (1924) reasoned that e- is both a particle and a wave.

Why is e- energy quantized?

λ = h/(mu)

u = velocity of e-

m = mass of e-

Page 7: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

7

Page 8: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

8

Page 9: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

9

Energy of orbitals in a one-electron atom

Page 10: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

10

Energy of orbitals in a multi-electron atom Energy depends on n and l

Page 11: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

11

Page 12: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

12

Page 13: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

13

Page 14: Ch07 - Wofford Collegewebs.wofford.edu/hilljb/Chem123/Ch07.pdf · Ch07.ppt Author: hilljb Created Date: 11/13/2009 3:47:08 AM

14