cheminform abstract: a facile p—c bond cleavage of 2-fluoro-2-phosphonyl-1,3-dicarbonyl compounds...

2000 cleavage reactions, decomposition reactions, pyrolysis cleavage reactions, decomposition reactions, pyrolysis O 0100 33 - 043 A Facile P–C Bond Cleavage of 2-Fluoro-2-phosphonyl-1,3-dicarbonyl Compounds on Silica Gel. — α-Fluoro-β-keto esters and α- ﬂuoromalonates (II) are smoothly prepared by P–C bond cleavage of (I) on wet silical gel in very good yields higher than 85%. — (KIM, DAE YOUNG; Synth. Commun. 30 (2000) 7, 1205-1212; Dep. Chem., Soonchun- hyang Univ., Chungnam 336-600, S. Korea; EN) 1

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Page 1: ChemInform Abstract: A Facile P—C Bond Cleavage of 2-Fluoro-2-phosphonyl-1,3-dicarbonyl Compounds on Silica Gel

2000 cleavage reactions, decomposition reactions, pyrolysis

cleavage reactions, decomposition reactions, pyrolysisO 0100

33 - 043A Facile P–C Bond Cleavage of 2-Fluoro-2-phosphonyl-1,3-dicarbonylCompounds on Silica Gel. — α-Fluoro-β-keto esters and α-fluoromalonates (II) are smoothly prepared by P–C bond cleavage of (I)on wet silical gel in very good yields higher than 85%. — (KIM, DAEYOUNG; Synth. Commun. 30 (2000) 7, 1205-1212; Dep. Chem., Soonchun-hyang Univ., Chungnam 336-600, S. Korea; EN)

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