cheminform abstract: copper-catalyzed enantioselective conjugate addition of dialkylzinc reagents to...

ChemInform 2009, 40, issue 06 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Addition reactions O 0060 Copper-Catalyzed Enantioselective Conjugate Addition of Dialkylzinc Reagents to α'-Oxy Enones. — The method constitutes an advanced entry to enantioenriched β-branched carboxylic acids and aldehydes with a broad R2Zn and functional group tol- erance. — (GARCIA, J. M.; GONZALEZ, A.; KARDAK, B. G.; ODRIOZOLA, J. M.; OIARBIDE, M.; RAZKIN, J.; PALOMO*, C.; Chem. Eur. J. 14 (2008) 29, 8768-8771; Dep. Quim. Org., Fac. Quim., Univ. Pais Vasco, E-20080 San Sebastian, Spain; Eng.) — Bartels 06- 035

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Page 1: ChemInform Abstract: Copper-Catalyzed Enantioselective Conjugate Addition of Dialkylzinc Reagents to α′-Oxy Enones

www.cheminform.wiley-vch.de

Addition reactionsO 0060 Copper-Catalyzed Enantioselective Conjugate Addition of Dialkylzinc Reagents

to α'-Oxy Enones. — The method constitutes an advanced entry to enantioenriched β-branched carboxylic acids and aldehydes with a broad R2Zn and functional group tol-erance. — (GARCIA, J. M.; GONZALEZ, A.; KARDAK, B. G.; ODRIOZOLA, J. M.; OIARBIDE, M.; RAZKIN, J.; PALOMO*, C.; Chem. Eur. J. 14 (2008) 29, 8768-8771; Dep. Quim. Org., Fac. Quim., Univ. Pais Vasco, E-20080 San Sebastian, Spain; Eng.) — Bartels

06- 035

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