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2000 cleavage reactions, decomposition reactions, pyrolysis cleavage reactions, decomposition reactions, pyrolysis O 0100 10 - 050 Palladium-Catalyzed Arylation of tert-Cyclobutanols with Aryl Bro- mide via C–C Bond Cleavage: New Approach for the γ-Arylated Ke- tones. — Monocyclic and bicyclic cyclobutanols with a tertiary alcohol group undergo a novel palladium-catalyzed arylation with aryl bromides involving C–C bond cleavage to give γ-arylated ketones. Besides phenyl bromide, this arylation is also successfully carried out with p-bromotoluene, p-bromochlorobenzene, and 2-bromonaphthalene. — (NISHIMURA, TAKAHIRO; UEMURA, SAKAE; J. Am. Chem. Soc. 121 (1999) 47, 11010-11011; Dep. Energy Hy- drocarbon Chem., Grad. Sch. Eng., Kyoto Univ., Sakyo, Kyoto 606, Japan; EN) 1

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Page 1: ChemInform Abstract: Palladium-Catalyzed Arylation of tert-Cyclobutanols with Aryl Bromide via C—C Bond Cleavage: New Approach for the γ-Arylated Ketones

2000 cleavage reactions, decomposition reactions, pyrolysis

cleavage reactions, decomposition reactions, pyrolysisO 0100

10 - 050Palladium-Catalyzed Arylation of tert-Cyclobutanols with Aryl Bro-mide via C–C Bond Cleavage: New Approach for the γ-Arylated Ke-tones. — Monocyclic and bicyclic cyclobutanols with a tertiary alcohol groupundergo a novel palladium-catalyzed arylation with aryl bromides involving C–Cbond cleavage to give γ-arylated ketones. Besides phenyl bromide, this arylationis also successfully carried out with p-bromotoluene, p-bromochlorobenzene,and 2-bromonaphthalene. — (NISHIMURA, TAKAHIRO; UEMURA,SAKAE; J. Am. Chem. Soc. 121 (1999) 47, 11010-11011; Dep. Energy Hy-drocarbon Chem., Grad. Sch. Eng., Kyoto Univ., Sakyo, Kyoto 606, Japan; EN)

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