cheminform abstract: ruthenium-mediated oxidation under buffered conditions: a simple and useful...

ChemInform 2009, 40, issue 34 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Bridged compounds Q 0060 Ruthenium-Mediated Oxidation under Buffered Conditions: A Simple and Useful Protocol for the Synthesis of Norbornyl α-Diketones with Acid Sensitive Function- alities. — The 1,2-dihaloalkene moiety in tetrahalonorbornenyl derivatives possessing acid labile functionalities is converted into the corresponding α-diketo moiety. The method is successfully applied to the syntheses of diastereomeric cyclopenta-annulated δ-lactones (V) and (VIII) derived from D-mannitol. — (KHAN*, F. A.; SUDHEER, C.; Adv. Synth. Catal. 351 (2009) 6, 939-944; Dep. Chem., Indian Inst. Technol., Kanpur 208 016, India; Eng.) — Klein 34- 051

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Page 1: ChemInform Abstract: Ruthenium-Mediated Oxidation under Buffered Conditions: A Simple and Useful Protocol for the Synthesis of Norbornyl α-Diketones with Acid Sensitive Functionalities

www.cheminform.wiley-vch.de

Bridged compoundsQ 0060 Ruthenium-Mediated Oxidation under Buffered Conditions: A Simple and Useful

Protocol for the Synthesis of Norbornyl α-Diketones with Acid Sensitive Function-alities. — The 1,2-dihaloalkene moiety in tetrahalonorbornenyl derivatives possessing acid labile functionalities is converted into the corresponding α-diketo moiety. The method is successfully applied to the syntheses of diastereomeric cyclopenta-annulated δ-lactones (V) and (VIII) derived from D-mannitol. — (KHAN*, F. A.; SUDHEER, C.; Adv. Synth. Catal. 351 (2009) 6, 939-944; Dep. Chem., Indian Inst. Technol., Kanpur 208 016, India; Eng.) — Klein

34- 051

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