cheminform abstract: synthesis of β-dimethylsulfonium- and β-methylthio-substituted vinyl...
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1997 mercaptans, thioethers
mercaptans, thioethers (acyclic compounds)P 0430
34 - 081Synthesis of β-Dimethylsulfonium- and β-Methylthio-SubstitutedVinyl Triflates by Reaction of Acetylenes with Dimethyl SulfideDitriflate. — The title reagent (III) is found to be a highly reactiveS-electrophile in addition reactions with acetylenes. Successful demethylationof the resulting triflates is achieved with nucleophiles or dimethylamine. —(NENAJDENKO, V. G.; VERTELEZKIJ, P. V.; BALENKOVA, E. S.; Synthe-sis (1997) 3, 351-355; Dep. Chem., Lomonosov Moscow State Univ., Moscow119899, Russia; EN)
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