cheminform abstract: synthesis of β-dimethylsulfonium- and β-methylthio-substituted vinyl...

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1997 mercaptans, thioethers mercaptans, thioethers (acyclic compounds) P 0430 34 - 081 Synthesis of β-Dimethylsulfonium- and β-Methylthio-Substituted Vinyl Triflates by Reaction of Acetylenes with Dimethyl Sulfide Ditriflate. The title reagent (III) is found to be a highly reactive S-electrophile in addition reactions with acetylenes. Successful demethylation of the resulting triflates is achieved with nucleophiles or dimethylamine. (NENAJDENKO, V. G.; VERTELEZKIJ, P. V.; BALENKOVA, E. S.; Synthe- sis (1997) 3, 351-355; Dep. Chem., Lomonosov Moscow State Univ., Moscow 119899, Russia; EN) 1

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Page 1: ChemInform Abstract: Synthesis of β-Dimethylsulfonium- and β-Methylthio-Substituted Vinyl Triflates by Reaction of Acetylenes with Dimethyl Sulfide Ditriflate

1997 mercaptans, thioethers

mercaptans, thioethers (acyclic compounds)P 0430

34 - 081Synthesis of β-Dimethylsulfonium- and β-Methylthio-SubstitutedVinyl Triflates by Reaction of Acetylenes with Dimethyl SulfideDitriflate. — The title reagent (III) is found to be a highly reactiveS-electrophile in addition reactions with acetylenes. Successful demethylationof the resulting triflates is achieved with nucleophiles or dimethylamine. —(NENAJDENKO, V. G.; VERTELEZKIJ, P. V.; BALENKOVA, E. S.; Synthe-sis (1997) 3, 351-355; Dep. Chem., Lomonosov Moscow State Univ., Moscow119899, Russia; EN)

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