conductive adhesive sheet tsc200 - 欣于實業有限公司€¦ · this electrical conductive...

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Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved. Conductive Adhesive sheet TSC200 CONFIDENTIAL TOYOCHEM CO.,LTD. Converting material Div. Ver.1s 2012.7

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Page 1: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Conductive Adhesive sheetTSC200

CONFIDENTIAL

TOYOCHEM CO.,LTD.

Converting material Div.

Ver.1s

2012.7

Page 2: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Conductive Adhesive Sheet TSC200This electrical conductive adhesive sheet for FPC has excellent humidity resistance /

excellent flexibility / excellent electrical conductivity

Ideal for Mobile Phone Hinge, which requires less noise / Camera Module

Release filmConductive adhesive layer

Single Release film type

CONFIDENTIAL

Page 3: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Structure

CONFIDENTIAL

Release Film

Conductive Adhesive Layer

Structure material / feature Thickness

Release film White PET one side non-silicone resin coated 54μm

Conductive adhesive layerUrethane based containing conductive

filler(Isotropic conductive)

40μm;Before press60μm;Before press

Toyo original Urethane based

Dispersion conductive filler

Page 4: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Properties

CONFIDENTIAL

Product name TSC200

Release film 54μm PETConductive adhesive layer Urethane resin basedThickness of Adhesive layer 40μm ±5 (before press)/60μm±5 (before press)Surface resistance Less than 300mΩ/□Peel Strength (PI) More than 10 N/cmPeel Strength (Cu) More than 10 N/cmSolder resistance260℃ solder floating

Excellent(More than 60sec.)

Resin flow amount170℃,2MPa,5min.press

50μm

Page 5: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Features

CONFIDENTIAL

1.Excellent adhesion for PI, SUS, Cu, Ni-Gold plate

2.Excellent Heat durability

3.Electorical conductive reliability

4.Storage stability

Page 6: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Adhesive and Solder test

CONFIDENTIAL

180°peel

[Adhesive test condition]Sample width:10mmPeel speed:50mm/minPeel angle:180°

[Solder reflow Profile] [Solder floating]

Page 7: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Test TSC200 CBF300

1)Peel Strength180°Peel 50mm/min

15 N/cm 11 N/cm

2)Solder reflow260℃20second peak reflow 2pass

Appearance OK OK

Peel Strength 14 N/cm 13 N/cm

3)Solder floating260℃5second 3pass

Appearance OK OK

Peel Strength 14 N/cm 13 N/cm

4)Solder floating288℃5second 3pass

Appearance OK OK

Peel Strength 13 N/cm 13 N/cm

Picture after peel test TSC200Between TSC200 and SUS

Picture after peel test CBF300Between CBF300 and SUS

Adhesive and Solder test-1 / PI cover-lay

CONFIDENTIAL

CCLPolyimide cover-layTSC200/CBF300SUS(nickel‐plated)

Test Structure

Page 8: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Test TSC200 CBF300

1)Peel Strength180°Peel 50mm/min

9 N/cm 6 N/cm

2)Solder reflow260℃20second peak reflow 2pass

Appearance OK NG

Peel Strength 8 N/cm Delaminate

3)Solder floating260℃5second 3pass

Appearance OK NG

Peel Strength 8 N/cm Delaminate

4)Solder floating288℃5second 3pass

Appearance OK NG

Peel Strength 8 N/cm Delaminate

Picture after peel test TSC200Between TSC200 and Ni-Gold plate

Picture after peel test CBF300Between CBF300 and Ni-Gold plate

Adhesive and Solder test-2 / Ni-gold plate

CONFIDENTIAL

CCLNi-Gold plate(Ni;1um,Gold;0.3um)TSC200/CBF300SUS(nickel‐plated)

Test Structure

Page 9: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

3) Solder floating 260℃3PassBetween PI and Cu (CCL)

4) Solder floating 288℃3PassBetween PI and Cu (CCL)

2) Solder reflow 2passBetween TSC200 and Ni-Gold plate

Adhesive and Solder test-2 / Ni-Gold pate TSC

CONFIDENTIAL

PI(CCL)

TSC200

SUS(nickel‐plated)

Nickel Gold

CCL

TSC200

SUS(nickel‐plated)

Nickel Gold Cu (CCL)

Page 10: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

CONFIDENTIAL

Adhesive and Solder test-2 / Ni-Gold plate CBF

3) Solder floating 260℃3Pass 4) Solder floating 288℃3Pass2) Solder reflow 2pass

Gold

CCL

CBF300

SUS(nickel‐plated)

Nickel

Delaminate at between CBF and Ni-Gold plate in any conditions

Page 11: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Conductivity

CONFIDENTIAL

TSC200 CBF300

Surface resistance After press 84 mΩ/□ N/A

Ground connected resistance

Land diameter 1.2mmφ

X-Y 53 mΩ 240 mΩ

Z 50 mΩ 233 mΩ

[Ground connected resistance]

Cu:18um

Surface: Ni-Gold Plate

Cover-lay : PI25um,Adhesive 35um(total:60um)

Cover-lay Land diameter : 1.2mmφ

Distance of pole : 4mm

Width of Adhesive sheet : 10mm

Press conditions

170℃-2MPa-5min press and 160℃-1hr baking

Comparison conductive performance

Page 12: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Ground connected resistance

CONFIDENTIAL

0

10

20

30

40

50

60

1 2 3

Land diameter mmφ

Resi

stac

e [

TSS200

CBF300

0

10

20

30

40

50

60

1 2 3

Land diameter mm□

Resi

stac

e [

TSS200

CBF300

X-Y, Land diameter:1mm,2mm,3mm

Land shape “Circle” Land shape “Square”

[Ground connected resistance]

Width of Adhesive sheet : 10mm

Surface: Ni/Gold Plate

Cover-lay : PI12.5um,Adhesive 15um(total:37.5um)

Page 13: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Ground connected resistance / 85℃85%RH

CONFIDENTIAL

0

50

100

150

200

250

300

350

400

450

500

0 100 200 300 400 500 600

Time [hour]R

esi

stac

e [

TSC200

CBF300

Humidity resistance 85℃85%RHGround connected resistance (Land diameter:1mmφ)

0

20

40

60

80

100

120

140

0 100 200 300 400 500 600

Time [hour]

Resi

stac

e [

TSC200

CBF300

X-Y Z

[Ground connected resistance]

Width of Adhesive sheet : 10mm

Surface: Ni/Gold Plate

Cover-lay : PI12.5um,Adhesive 15um(total:37.5um)

Land diameter : 1mmφ(circle)

SUS : Ni plate treated SUS (Thickness 0.3mm)

Page 14: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Cross-section SEM images

CONFIDENTIAL

CBF300

Air gap

TSC200

No Air gap

Conductive adhesive sheet

Conductive filler

Page 15: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Flexibility / Embedment

CONFIDENTIAL

CBF300

Large air gap

Comparison 200um embedment ( Cross-section image x100)

~200um

50um PI film

TSC

Press conditions

170℃-2MPa-5min.press

And 160℃-1hr baking

200μmSmall air gap

TSC200

200μm

section

Page 16: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

0

500

1000

1500

2000

2500

0 10 20 30 40 50times

Res

ista

nce

[mΩ

]Bending test / Conductivity

CONFIDENTIAL

Cu:18um

Surface: Ni/Gold Plate

Cover-lay : PI25um,Adhesive 35um

Cover-lay Land diameter : 1.2mmφ

Distance of pole : 4mm

Width of EMI : 15mm

Press conditions170℃-2MPa-5min.press and 160℃-1hr baking.

CBF300

TSC200

Cu

Cu

Cover-lay(60um)TSC

Bending test at 360°

Page 17: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Shielding performance

CONFIDENTIAL

Frequency:500MHz~18GHzASTM D4935Network-analyzer E8361ACondition:28℃60%RH

Electromagnetic wave

Test piece

Page 18: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

Comparison

CONFIDENTIAL

TSC200 CBF-300

Adhesive for PI,SUS ○ ○

Adhesive for Ni-Gold plate ○ ×

Solder ◎ △

Ground conductivity ◎ △

Ground conductivityHumidity conditions

○ ×

Shielding performance ○ ○

Storage Stability ○ ×

Page 19: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

How to use

CONFIDENTIAL

SUS Stiffener

①Laminate on SUS Stiffener.

②Remove the release film,then laminate on FPC

for temporary fastening.

③Heat press undervacuumed condition.

Then, post cure.

SUS stiffener

FPCRelease Film

TSC

SUS stiffener

FPC

Electric oven

FPC

TSC

SUS stiffener

TSC

* If pressing time is over 60min,

post cure is unnecessary.

Lamination of TSC200 on SUS Stiffener

• Treatment using an iron, heat press, or heated rollers at 100~120℃ for over 5 seconds is recommended.

*If lamination is insufficient, crimples may be caused during the removal of the release film.

Flow chart

SUS Stiffener

Page 20: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

How to use

CONFIDENTIAL

Press Condition Post Cure

Temperature Pressure Time Temperature Time

Quick Press & Post Cure

170±10℃ 1~3MPa Over 5min 160±10℃ Over 60min

Press Only 170±10℃ 1~3MPa Over 60min - -

Press condition

StorageTSC200 should be stored under 10℃ / 70%RH

*Storage at room temperature may cause the adhesive layer to stiffen, thusleading to the loss of conductivity.

Page 21: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

23℃50%RH

Initial 7days 14days 21days

Peeling strength① 12 N/cm 12 N/cm 13N/cm 14N/cm

Peeling strength② 12 N/cm 12 N/cm 13 N/cm 11 N/cm

Solder float260℃①More than 60sec

OKMore than 60sec

OKMore than 60sec

OKMore than 60sec

OK

260SolderFloat℃②More than 60sec

OKMore than 60sec

OKMore than 60sec

OKMore than 60sec

OK

Solder reflow①5PassOK

5PassOK

5PassOK

5PassOK

Solder reflow②5PassOK

5PassOK

5PassOK

5PassOK

①,② on the above shows the following structure.①;PI/TSC/SUS②;Cu/TSC/SUS

Laminating condition ; 170℃-2MPa-5min.press + 160℃1hr oven curing

Excellent performance 21days after

23℃50%RH / Adhesive and Solder resistance

CONFIDENTIAL

Page 22: Conductive Adhesive sheet TSC200 - 欣于實業有限公司€¦ · This electrical conductive adhesive sheet for FPC has excellent humidity resistance / ... Toyo original Urethane

Copyright © 2011 TOYO CHEM CO., LTD. All Rights Reserved.

CONFIDENTIAL

[Ground connected resistance]

Cu:18um

Surface: Ni/Gold Plate

Cover-lay : PI25um,Adhesive 35um(total:60um)

Cover-lay Land diameter : 1.2mmφ

Distance of pole : 4mm

Width of Adhesive sheet : 10mm

Press conditions

170℃-2MPa-5min press and 160℃-1hr baking

23℃50%RH / Conductivity

0

10

20

30

40

50

60

70

80

90

100

0 7 14 21

23℃50%RH(Day)

Res

ista

nce(

XY

Z