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    GII CHI TIT S 202

    Cu 1.Cc ion c cu hnh electron ca kh him l cc ion:+ Ca cc nguyn t nhm A+ in tch ion c tr s bng s th t ca nhm cha nguyn t

    p n ng l CCu 2.Cc ion cng cu hnh electron c cng s lp electron. Do c in tch nh hn (in

    tch ht nhn nh hn) th c bn knh ln hnVy bn knh ca O2- > F- > Na+

    p n ng l DCu 3.

    - phn cc ca lin kt ph thuc vo hiu m in ca 2 nguyn t tham gia lin kt- Cc phn t ang xt u c nguyn t hiro trong phn t (chn H lm mc)- Da vo quy lut bin thin m in ca nguyn t cc nguyn t trong chu k, trong

    nhm bit c hiu m in tng i ca cc nguyn t nguyn t vi hiro.

    *Ch : Khng tnh c gi tr chnh xc hiu m in nhng c lng c hiu m intng i gia 2 nguyn t tham gia lin kt, lm c s sp xp phn ccp n ng l A

    Cu 4.Da vo s thay i s oxi ha ca cc nguyn t cc cht trong PTHH, ta xc nh c cc

    phn ng oxi ha kh l:-1 -1 -3 -1

    1. CH CH + H2O CH3 - CHO

    2. CH2=CH2 + H2ot CH3 - CH3

    3. CH4 + 2O2oe

    ot CO2-2 + 2H2O

    +7 +4

    4. 3C2H4 + 2KMnO4 + 4H2O 3C2H4(OH)2 + 2MnO2 + 2KOHp n ng l D

    Cu 5.Trong phng th nghim, ngi ta thng iu ch kh clo bng cch cho cht oxi ha mnh

    (MnO2, KClO3, KMnO4, CaOCl2) tc dng vi axit clohiric c:

    4HCl + MnO2ot Cl2 + MnCl2 + 2H2O

    6HCl + KClO3 3Cl2 + KCl + 3H2O

    16HCl + 2KMnO4 5Cl2 + 2KCl + 2MnCl2 + 8H2O

    2HCl + CaOCl2 Cl2 + CaCl2 + H2O*Ch : Nu cht oxi ha l MnO2 th cn phi un nng, cn cht oxi ha l KMnO4, KClO3 hocCaOCl2 phn ng xy ra nhit thng.

    p n ng l ACu 6.

    - CO2 v SO2 l hai oxit axit nn u phn ng vi dung dch kim (NaOH, Ba(OH) 2,Ca(OH)2). Do khng th dng cc dung dch ny lm sch kh CO2 c.

    - CO2 ch c tnh oxi ha (nguyn t cacbon c s oxi ha +4, cao nht), SO2 c tnh kh(nguyn t lu hunh c s oxi ha +4, trung gian) nn CO2 khng phn ng vi nc

    brom, cn SO2 phn ng (b gi li)SO2 + Br2 + 2H2O H2SO4 + 2HBr

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    CO2 + Br2 + H2O khng phn ng (thot ra)

    p n ng l ACu 7.Khi tng p sut ca h ln 2 ln th tch gim 2 ln (gi nguyn nhit ) nng ca cccht tng ln 2 ln. Do :

    v = K ([A].2).([B].2)2 = 8K[A].[B]2 = 8.vVy tc phn ng tng 8 ln

    p n ng l CCu 8.Xt cc phng n:

    A.sai, th d dung dch Na2CO3:Na2CO3 2Na

    + + CO32

    CO32 + H2O HCO3

    - + OH- Mi trng kim pH 7,0.

    B.sai, th d dung dch NaHS:NaHS Na+ + HS-

    HS- + H2O H2S + OH-

    Mi trng kim pH > 7,0C.sai, v ch 25oC: [H+] = [OH-] = 10-7 (M) pH = 7

    Chng hn, 37oC: [H+] = [OH-] = 10-6,8 (M) pH = 6,8D.ng, v dung dch axit nn c pH < 7Ch : Trong dung dch HCl c 10 -8, phi k n s in li ca H2O:

    H2O H+ + OH-

    x(M) x(M)HCl H+ + Cl-10-8 (M) 10-8 (M)

    Ta c:2

    + - -8 -14 2 -8 -14H OK = [H ][OH ] = (x + 10 ).x = 10 x +10 .x - 10 = 0

    x =-8 -16 -14 -8-10 + 10 + 4.1.10 = 9,5125.10

    2.1

    Vy [H+] = x + 1.10-8 = 10,5125.10-8 (M) pH = -lg (10,5125.10-8) = 6,9783. p n ng l D

    Cu 9.Gi x, y ln lt l s mol N2, H2 trong hn hp X

    Ta c:28.x + 2.y

    = 4,25.2 = 8,5x + y

    28x + 2y = 8,5.x + 8,5.y = 19,5x = 6,5y 3x = yPTHH: N2(k) + 3H2(k) 2NH3(k)

    Ban u: x 3x (mol)Phn ng a 3a 2a (mol)Cn li: (x a) 3(x a) 2a (mol)

    Theo bi ra, ta c:28.(x - a) + 3(x - a).2 + 2.a.17

    = 6,8.2 = 13,6(x - a) + (3x - 3a) + 2a

    34.x = 54,4x 27,2a 20,4x = 7,2a a 20,4

    = = 0,75x 27,2

    Vy H% =a

    .100% = 75%x

    p n D ng

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    Cu 10.

    X l CaCO3, Y l NaHCO3

    CaCO3ot CaO + CO2

    (X) (X1)CaO + H2O Ca(OH)2(X1) (X2)Ca(OH)

    2+ NaHCO

    3 CaCO

    3+ NaOH + H

    2O

    (X2) (Y) (X) (Y1)Ca(OH)2 + 2NaHCO3 CaCO3 + Na2CO3 + 2H2O

    (X2) (Y) (X) (Y2)p n ng l C

    Cu 11:Ta c s :

    2C2H5OH

    C6H10O5ln men81% CaCO3 Tinh bt 5,5 mol

    2CO2 2+ Ca(OH) Ca(HCO3)2 CaCO3

    1 mol 1 molV nguyn t cacbon c bo ton, nn:

    2 3 3 2CO CaCO Ca(HCO )n = n + 2.n = 5,5 + 2,1 = 7,5 (mol)

    6 10 5 2C H O CO

    1 7,5n = .n = = 3,75 (mol)

    2 2

    V H = 81%, nn:6 10 5C H O (thct)

    3,75.100n = = 4,63 (mol)

    81

    Vy m = 4,63.162 = 750 (gam)

    p n ng l C*Ch : Cc PTHH xy ra:

    (C6H10O5)n + nH2O o

    +

    t

    HnC6H12O6

    Tinh bt glucozC6H12O6men r-u 2C2H5OH + 2CO2Glucoz ancol etylicCO2 + Ca(OH)2 CaCO3 + H2O2CO2 + Ca(OH)2 Ca(HCO3)2

    Ca(HCO3)2ot CaCO3 + CO2 + H2O

    Cu 12.Theo bi ra:

    2 2CO H O

    30,8 12,6n = = 0,7 mol; n = = 0,7 mol

    44 18

    Ta thy:2 2CO H O

    n = n

    X thuc dy ng ng anken hoc monoxicloankanV X khng lm mt mu dung dch thuc tm iu kin thng X thuc dy ng ng monoxicloankanp n ng l D

    *Ch : Cc monoxicloankan (mt vng no trong phn t) khng tc dng vi dung dch thuc tm.Cu 13.

    Gi cng thc ca hirocacbon ny dng: CnH2n+2-2k

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    - V hirocacbon th kh nn n 4- V hirocacbon nng hn khng kh nn:

    14n + 2 2k > 29 n 2 (0 k n)- V hirocacbon lm mt mu nc brom hirocacbon khng no

    k > 0 n > 2Do : n = 3 hoc n = 4

    Theo bi ra:2 2CO Br

    7,04 25,6n = = 0,16 (mol); n = = 0,16 (mol)

    44 160

    Ta c: 2 2Br CO

    = n = nn

    Do : 2Br

    = n = k.xn (x l s mol ca CnH2n+2-2k)

    2CO

    n = n.x n = k CTPT dng CnH2

    Suy ra: CTPT ca hirocacbon c th l:- C3H2: khng c cu to no tha mn- C4H2: HC C-C CH (v mch cacbon h) x = 0,16/4 = 0,04 (mol) m = 0,04.50 = 2 (gam)p n ng l A

    Cu 14:

    Xt cc phng n:A.Sai, v benzen khng lm mt mu dung dch Br2B.Sai, v benzen (C6H6) CnH2n-6 (n 6)

    Stiren (C6H5CH=CH2) CnH2n-6 (n 6)C.ng, cc nguyn t trong phn t benzen (6 nguyn t C v 6 nguyn t H) nm trn mt

    mt phng (do 6 nguyn t C u c trng thi lai ha sp2)D.Sai, ng vi CTPT C6H6 c tn gi l benzen khi c cu to: (cn cc cu to khc

    s c tn gi khc)p n ng l C

    Cu 15:Xt cc phng n:

    A.Nu X l HOOC-COOH khng tha mn, vHOOC-COOH + AgNO3/NH3 khng phn ng

    B.Nu X l OHC-CHO khng tha mn, vOHC-CHO + H2O khng phn ng

    C.Nu X l OHC-COOH khng tha mn, vOHC-COOH + AgNO3/NH3 khng phn ng

    D.+ X l CH CH tha mn:CH CH + 2AgNO3 + 2NH3 AgC CAg + 2NH4NO3

    CH CH + H2Ooxt, t CH3CHO

    + Y l OHC-CHO tha mn:

    OHC-CHO + 4AgNO3 + 6NH3 + 2H2O H4NOOC-COONH4 + 4Ag + 4NH4NO3+ Z l OHC-COOH tha mn:

    OHC-COOH + 2AgNO3 + 4NH3 + H2O H4NOOC-COONH4 + 2Ag + 2NH4NO3OHC-COOH + NaOH OHC-COONa + H2O

    + T l HOOC-COOH tha mn:HOOC-COOH + 2NaOH NaOOC-COONa + 2H2O

    p n ng l DCu 16.c im khng phi ca cc axit bo thng gp. u l cc axit cacboxylic no

    + Axit bo no: Axit panmitic CH3(CH2)14COOH

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    Axit stearic CH3(CH2)16COOH

    + Axit bo khng no: Axit oleic C17H33COOHAxit linoleic C17H31COOH

    p n ng l CCu 17.Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn ng thy phn:

    (C6H10O5)n + nH2O+ oH , t nC6H12O6

    Tinh bt/xenluloz glucozC12H22O11 + H2O

    + oH , t C6H12O6 + C6H12O6Saccaroz glucoz fructoz

    C12H22O11 + H2O+ oH , t 2C6H12O6

    Glucozp n ng l C

    Cu 18. Theo bi ra:Z

    4,48n = = 0,2 (mol)

    22,4

    ng vi CTPT C2H7NO2 c cc CTCT lCH3COONH4 (amoni axetat) (x mol)

    HCOOH3NCH3 (metyl amoni fomat) (y mol)PTHH: CH3COONH4 + NaOH CH3COONa + NH3 + H2O

    x x xHCOOH3NCH3 + NaOH HCOONa + CH3NH2 + H2O

    y y y

    Theo bi ra, ta c:x + y = 0,2

    x = 0,05; y = 0,1517.x + 31.y= 13,75.2

    x + y

    Mui khan thu c gm CH3COONa (0,05 mol) v HCOONa (0,15 mol)mmui = 0,05.82 + 0,15.68 = 14,3 (gam)

    p n ng l A*Ch : Kh NH3, CH3NH2, u lm xanh giy qu tm m.Cu 19.

    * T nilon -6,6: [-HN-(CH2)6-NH-CO-(CH2)4-CO-]nKhi lng 1 mt xch: 226 vC* T capron: [-HN-(CH2)5-CO-]nKhi lng 1 mt xch: 113 vCSuy ra:

    - S mt xch trong on mch nilon -6,6: n1 =27346

    = 121226

    - S mt xch trong on mch t capron: n2 =17176

    = 152113 p n ng l C

    Cu 20.Phn ng xy ra khi pin in ha Zn - Ag hot ng

    Zn + 2Ag+ Zn2+ + 2Ag Ta thy:- Khi lng in cc Ag tng (khi lng in cc Zn gim)- Nng ion Zn2+ tng (nng ion Ag+ gim)- Trong pin Zn - Ag th anot l Ag, catot l Zn

    anot (cc Zn): Zn Zn2+ + 2e

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    catot (cc Ag): Ag+ + 1e Ag

    Do catot thiu in tch dng (do Ag+ b in phn) nn K+ (cu mui) di chuyn v (ch khng v anot)

    - Sut in ng chun + 2+o o opin(Zn-Ag) Ag /Ag Zn /ZnE = E - E o

    pin(Zn-Ag)E = 0,8 - (-0,76) = 1,56 V

    p n ng l B

    Cu 21.

    Theo bi ra:2H

    0,672n = = 0,03 (mol)

    22,4

    PTHH: 2 2M + 2HCl MCl + H 0,03 (mol) 0,03 (mol)

    Suy ra: M1,67

    M = = 55,670,03

    Suy ra, hai kim loi kim th l Ca (40) v Sr

    p n ng l BCu 22.PTHH ca phn ng xy ra khi nung Fe(NO3)2; Fe(OH)3; FeCO3 l

    2Fe(NO3)2ot Fe2O3 + 4NO2 + 2

    1O

    2

    2Fe(OH)3ot Fe2O3 + 3H2O

    2FeCO3 + 2 (kk)1

    O2

    ot Fe2O3 + 2CO2

    Tm tt bng s :

    Fe(NO3)2Fe(OH)3o

    2

    t- H O

    Fe2O3(r)

    FeCO3Vy cht rn thu c Fe2O3 (nu ).

    p n ng l DCu 23.

    PTHH ca cc dung dch mui vi KOH:- AlCl3 + 3KOH Al(OH)3 + 3KCl

    Lc u, to kt ta trng, sau kt ta b tan:Al(OH)3 + KOH (d) K[Al(OH)4] (tan)

    - Fe(NO3)3 + 3KOH Fe(OH)3 + 3KNO3 nu

    - FeSO4 + 2KOH Fe(OH)2 + K2SO4Trng xanh

    - Mg(NO3)2 + 2KOH Mg(OH)2 + 2KNO3

    Trng- NH4Cl + KOH

    ot NH3 + KCl + H2OMi khai

    C th nhn bit c tt c 5 dung dch.p n ng l D

    to

    -(NO2 + O2)

    to

    khng kh

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    Cu 24.Cc nhin liu ha thch gm:

    - Xng, du ha, kh ng hnh, kh ha lng (tch ra t du m)- Than - Kh thin nhinVy c 6 nhin liu ha thch.

    p n ng l C

    Cu 25.- Nguyn t R c 4 lp electron nguyn t R chu k 4

    - To c oxit cao nht l R2O7 nguyn t R c 7 electron ha tr nguyn t R nhm VII (A hoc B)

    - Nguyn t R c cc electron ha tr trn phn lp d R l nguyn t d nguyn t R nhm B

    Vy R chu k 4, nhm VIIB R l nguyn t Mn (Z = 25): 1s22s22p63s23p63d54s2p n ng l C

    Cu 26:Cc nguyn t cng chu k (theo th t t tri sang phi): N, O, F

    Cc nguyn t cng nhm (nhm A, theo th t t trn xung): N, PTrong cng chu k, tnh phi kim ca cc nguyn t tng dn: Trong cng mt nhm, tnh phi

    kim ca cc nguyn t gim dn.Do , dy nguyn t sp xp tnh phi kim tng dn l P, N, O, Fp n ng l C

    Cu 27.- Cc hp cht: F2O, Cl2O, Br2O, I2O (X2O) l hp cht gia halogen vi oxi.- Ch c F c m in ln hn O (F l nguyn t c m in ln nht, tip n l ca O..)

    cn cc halogen khc (Cl, Br, I) u c m in nh hn O. Do halogen c m in cngnh th hiu m in ca n vi oxi cng ln, lin kt cng phn cc. Halogen c m in nhnht l I.

    p n ng l D*Ch : Gi tr m in ca cc halogen v oxi

    Nguynt

    F O Cl Br I

    min

    3,98 3,44 3,16 2,96 2,66

    Hiu m in(X - O)

    0,54 0 0,28 0,48 0,78

    Cu 28.+ Trong cc cht, nguyn t st c cc trng thi oxi ha: 0 (n cht, thp nht); +2; +8/3; +3

    (cao nht thng gp)+ Cc hp cht cha st c trng thi oxi ha trung gian (+2; +8/3) th chng c tnh oxi ha

    (xung s oxi ha thp hn) v ng thi c tnh kh (ln s oxi ha cao hn). C th cc cht l: FeO (+2), FeCO3 (+2)

    p n ng l DCu 29.

    Gi s 2 dung dch c cng nng l 0,1M

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    HCl H+ + Cl-

    0,1M 0,1MpH(dd HCl) = x = -lg0,1 = -lg10

    -1 = 1

    CH3COOH H+ + CH3COO

    -Ban u 0,1MPhn li: 0,001M 0,001M

    Cn bng: 0,001(10

    -3

    M) 3

    3

    (ddCH COOH)pH = y = lg10 = 3 . Vy y = x + 2

    p n ng l ACu 30.

    Xt cc phn ng:-1 0 0 -1

    A. H2O2 + Cl2 O2 + 2HClcht kh cht oxi ha

    loi-1 0 0 -2

    B. H2O2 + O3

    2O2 + H2Ocht kh cht oxi ha loi

    -1 -1 -1 0

    C. 2H2O2 + Ca(ClO)2 CaCl2 + 2O2 + 2H2Ocht kh cht oxi ha

    loi (H2O2 c tnh oxi ha yu hn Cl2; O3; Ca(ClO2))-1 +4 -2 +6

    D. H2O2 + Na2SO3 H2O + Na2SO4

    cht oxi ha cht kh tha mnp n ng l D

    *Ch : -H2O2 th hin tnh kh khi tc dng vi cc cht oxi ha mnh hn nh Cl2, O3, Ag2O,KMnO4 trong mi trng axit, Ca(ClO)2...

    - H2O2 th hin tnh oxi ha khi tc dng vi cc cht kh (SO2, Na2SO3, KNO2,...)Cu 31.

    p dng cng thc ca quy tc VanHop:vt = v30.3

    (t-30)/10 vt/v30 = 3

    (t-30)/10

    3(t-30)/10 = 81 = 34 (t - 30)/10 = 4 t = 40 + 30 = 70 (oC)

    p n ng l BCu 32.H2O ng vai tr l axit khi n nhng proton (H

    +) to ra OH-Ta thy cc qu trnh (2, 4, 5) to ra OH- (trong cc qu trnh ny H2O ng vai tr axit)p n ng l B

    Cu 33.Theo bi ra:

    3HNOn = 0,4.1 = 0,4 (mol)

    * Trng hp 1: HNO3 phn ng ht:Fe + 4HNO3 Fe(NO3)3 + NO + 2H2O

    0,1 0,4 mol 0,1 (mol)

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    2Fe(NO3)3 + Fe 3Fe(NO3)2

    2x x 3xTa c: (0,1 - 2x) . 242 + 3x . 180 = 26,44

    24,2 - 484x + 540x = 26,44 56x = 2,24 x = 0,04

    Suy ra Fen = 0,1 + 0,04 = 0,14 (mol) mFe = 0,14.56 = 7,84 (gam)

    p n ng l A* Trng hp 2: HNO3 d:Fe + 4HNO3 Fe(NO3)3 + NO + 2H2Ox 4x x

    Ta c: 242.x + (0,1 - 4x).63 = 26,44 242x - 252x + 6,3 = 26,44 -10x = 20,14 (loi)

    Cu 34.

    Theo bi ra:2 3CO BaCO

    2,688 15,76n = = 0,12 (mol); n = = 0,08 (mol)

    22,4 197

    PTHH: CO2 + Ba(OH)2 BaCO3 + H2Ox x x

    2CO2 + Ba(OH)2 Ba(HCO3)2

    2y y

    Ta c:

    x + 2y = 0,12 x = 0,08

    x = 0,08 y = 0,02

    Suy ra: 2Ba(OH)

    0,1n = x + y = 0,08 + 0,02 = 0,1 (mol) a = = 0,04 (M)

    2,5

    p n ng l CCu 35.

    C6H7O (dn xut ca benzen) tc dng vi dung dch NaOH

    hp cht phenolCc cht lo -CH3-C6H4-OH (o-crezol)m-CH3-C6H4-OH (m-crezol)

    p-CH3-C6H4-OH (p-crezol) (3 cht)p n ng l B

    *Ch : - Phenol l loi hp cht c nhm -OH lin kt trc tip vi vng benzenC6H5OH + NaOH C6H5ONa + H2O

    CH3-C6H4-OH + NaOH CH3C6H4-ONa + H2OCu 36.Cc hirocacbon no, mch h, c t 1 n 5 nguyn t C trong phn t khi phn ng vi kh clo

    theo t l mol 1 :1 (c as) u ch to ra mt dn xut monoclo lCH4 + Cl2 CH3Cl + HCl

    CH3-CH3 + Cl2 CH3-CH2Cl + HClCH3 CH3

    CH3-C-CH3 + Cl2 CH3-C-CH2Cl + HClCH3 CH3

    c 3 chtp n ng l CCu 37.S phn ng:

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    X (C2H2; H2) oxt, t Y (C2H4, C2H6, C2H2, H2) 2

    dd Br , d- C2H6, H2- Gi x l s mol C2H2 (cng nh H2) trong hn hp X

    mX = (26 + 2).x = 28.x (gam) (1)- Theo nh lut bo ton khi lng, ta c: mX = mY (2)- Mt khc, theo bi ra: mY = m(bnh brom tng) + m(kh thot ra)

    mY = 10,8 +4,48

    .8,2 = 14 (gam)22,4

    (3)

    T (1, 2, 3) suy ra: x = 0,5 (mol)- Theo nh lut bo ton nguyn t:V nguyn t C, H c bo ton nn th tch kh O2 t chy hon ton hn hp Y cng

    bng th tch O2 t chy hon ton hn hp X

    C2H2 + 25

    O2

    2CO2 + H2O

    0,5 1,25 (mol)

    H2 + 21

    O2

    H2O

    0,5 0,25 (mol)

    2On = 0,25 + 1,25 = 1,5 (mol)

    2O (ktc)V = 1,5.22,4 = 33,6 (lt)

    p n ng l ACu 38.Xt cc phng n:

    A. Khng ng, v benzen C6H6 CnH2n-6 (n 6)stiren C8H8 CnH2n-6 (n 6)

    B. ng: stiren cn c tn gi vinyl benzen hoc phenyl etilenC. ng: 8 nguyn t C v 8 nguyn t H trong phn t stiren u nm trn mt mt phng (v

    cc nguyn t C c trng thi lai ha sp2)D. ng: Phn t stiren c cu to bi gc phenyl (C6H5

    -, tnh cht ging benzen) v gcvinyl (CH2=CH-, tnh cht ging vi anken)

    p n ng l ACu 39.Cng thc n gin nht C2H3O2

    CTPT dng (C2H3O2)n C2nH3nO2n CnH2n(COOH)nV 2n + n 2n + 2 n 2+ Nu n = 1: C2H3O2 khng c cu to tha mn+ Nu n = 2: C4H6O4 c cu to chng hn:HOOC-CH2CH2-COOH (tha mn)Vy CTPT ca X l C4H6O4.

    p n ng l BCu 40.

    Theo bi ra:2 5C H OH

    5,75n = = 0,125 (mol)

    46

    Gi x l s mol mi axit c trong hn hp XTheo bi ra, ta c 46.x + 60.x = 5,3 106x = 5,3 x = 0,05 (mol)

    PTHH: HCOOH + C2H5OH xt

    HCOOC2H5 + H2O

    CH3COOH + C2H5OH xt

    CH3COOC2H5 + H2OTa thy nHCOOH +

    3CH COOHn = 2.x = 2.0,05 = 0,1 Cu > Au > Al > Fe.p n ng l B*Ch : Ag dn in tt nht, ri n CuCu 59.

    Theo bi ra:2 2O H

    5,04 1,8n = = 0,225 (mol); n = = 0,9 (mol)

    22,4 2

    Theo nh lut bo ton electron, ta c:24,3.n

    = 0,9 + 1,8 = 2,7M

    24,3n = 2,7M 9n = M

    Ta c bng:

    Vy M l Al. p n ng l CCu 60.

    Theo bi ra: Cu3,84

    n = = 0,06 (mol)64

    * Th nghim 1:3HNO

    n = 0,080.1 = 0,08 (mol)

    PTHH: 3Cu + 8HNO3 3Cu(NO3)2 + 2NO + 4H2OBan u: 0,06 0,08 (mol)Phn ng: 0,03 0,08 0,02 (mol)

    Suy ra: NO (1)0,08.2

    n = = 0,02 (mol)8

    * Th nghim 2:3 2 4HNO H SO

    n = 0,08 mol; n = 0,08.0,5 = 0,04 (mol)

    -3NO

    n = 0,08 mol

    +Hn = 0,08 + 0,04.2 = 0,16 (mol)

    PTHH: 3Cu + 2NO3- + 8H+ 3Cu2+ + 2NO + 4H2O

    Ban u: 0,06 0,08 0,16

    Phn ng: 0,06 0,04 0,16 0,04 (mol)Suy ra: NO (2)

    0,06.2n = = 0,04 (mol)

    3

    Do : nNO(2) = 2.nNO(1) V2 = 2V1 (i vi cht kh, trong cng iu kin, t l v s molcng bng t l v th tch)

    p n ng l B

    n 1 2 3

    M 9 (Be) 18 27 (Al)

    KL Loi Loi Tha