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= = /291 acminSSci,".maxTT.O,3/291@ 4 niac1= /211 a0,bR-mRT#m"#n0mRT"H33/211' $eun%lic&!' 3 9" PB''= +B3'BlnQ,.a%s- =,.a%s- (E" 0 10 20 30-4.2-4.0-3.8-3.6-3.4ln (Qads)Qads(kJ/mol) ! +A. O' ln Q,.a%s- B .a%s 188 a @ ' (E, ' 2N Q,.a%s- .a%s ' 3 93B ''= /9 2L1"$! 14. ? B ''= R "31 d "2!3"3 d "L"3( d "1"9999( p''= 9 "3(Z)|/!"31.a%s- 'I = B, @USYJ@ $eun%lic&!' "_9 ' 9 /1 /{1 (K"0.0 0.2 0.4 0.6 0.8 1.04812160.0 0.2 0.4 0.6 0.8 1.0-200204060G()(kJ/mol)S()(J/mol K)(a)(b) ! +B. O' 9 /1 /{1 189 GIBAA' " a'',= 'nx@=A3/2LE1"_9'nx ' 9 2("$! 1+. P n x Z Tnx USY S-m2 C qrr ( E 2 !"1E !"21 !"1( '''3' ' 9 3 9 3 '9 ,,9'',9 ' ' " &' @'='B B3C'9C'9 B3C '9C ' "21 W ' 9C 'A JS-m29A C qrr ' =4 &1J3C 3'9B'"&9'I e'U'3'9 B'"G''9 B''='9B' 9,9 99B'"R ''9CB'3 " ? BA ' , ''A93'9 '9'"9 BC'C'=,'=9 /1 /9A1 "217 5. USY298K,11K22K!"# USY$ %Freundlich&'% Freundlich&()K*n! + ( , Gibbs&'!"#( ,Gibbs& ' !,-+'USY '(./!7,+ ' 0 , 1/!7++ 2')' !3#+ USY456298K,11K22K%, 7 45 6 298 K, /9 K 1 K% ( 45 6 29: K, /9 K 1: K%!"#++ +'! USY#'00+;42# 218 '00+)42# 2/ EFGHIJ!"#USY+ ,S=>2 ( ?@@ + 7 ! K S=>2 ( ?@@, ' ' + ' ) ' )!L; ', S=>2 ( ?@@ D # ! "#+';0+( '! M ## 0 ( '!3#+ 'S=>245688K,:/K:29K%'#0 ( ?@@ 45 6299 K, / K, /9 K, 1: K 18 K%!219 "#S=>2 '#0(;+ 00+)42+ ,'#0(?@@ +7!L '#0(?@@7#, ,' ! C # + -+ S=>2'#0(?@@; 70000 )!3#+ S=>2 4N 6 9, 1/ 2/ KGH=O%! "# 7S=>2#' 00 + ) 42, 700 00 )! 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