高分子学报 2020 年 2 月

第 51 卷 第 2 期

(GAOFENZI XUEBAO)

目 次

专论

高分子纳微球在工程疫苗中的新应用 ··········································································· 岳 华 马光辉 (125)

综述

多相聚合物微观结构和分子间相互作用的固体NMR研究 ······························································ 张荣纯 (136)

论文

基于引达省并二噻吩吡喃的稠环受体材料的设计合成及其在有机太阳能电池中的应用研究 ···························

························································ 柯 鑫 孟令贤 万相见 张 昕 常美佳 李晨曦 陈永胜 (148)

基于氢键和Diels-Alder键双重网络自修复弹性体的合成与性能 ································································

························································ 彭 燕 侯雨佳 申巧巧 王 辉 李 刚 黄光速 吴锦荣 (158)

同步交联对高乙丙橡胶含量聚丙烯多相共聚物的粒子形态控制作用 ·························································

················································································ 张孟佳 王 莉 洪柳婷 秦亚伟 董金勇 (166)

三齿β-酮亚胺钒(III)配合物的合成及其催化乙烯(共)聚合行为研究 ·············· 卢令攀 王凯悌 刘 翼 吴佳骏 (174)

静电纺丝交联凝胶聚合物电解质的制备与表征 ······································· 陈云妮 肖 琴 李青音 任世杰 (183)

基于聚丙烯酸二维光子晶体水凝胶的阳离子表面活性剂传感器 ·······························································

························································ 秦夏彤 刘根起 刘晨辉 刘建勋 李欢欢 曹云雷 范晓东 (191)

可变形微区增强丁苯橡胶及其机理 ·········································· 张丽洁 黄 晶 吴思武 唐征海 郭宝春 (198)

含硫/硒动态共价键强弱的测定 ······································································· 夏嘉豪 李宏斌 许华平 (205)

基于分子模拟对多糖类衍生物手性识别机理的探索 ····················· 邓恩停 毕婉莹 刘 博 张丽丽 沈 军 (214)

Acta Polymerica Sinica Vol. 51 No. 2 February 2020

Contents

Feature Articles

Applications of Polymeric Micro/Nanoparticles in Engineered Vaccines ······························ Hua Yue, Guang-hui Ma (125)

Reviews

The Microstructures and Molecular Interactions in Multiphase Polymers: Insights from Solid-State NMR Spectroscopy

····················································································································· Rong-chun Zhang (136)

Articles

Synthesis and Properties of a Conjugated Acceptor Material for Organic Solar Cells Based on Indaceno-

bis(dithieno[3,2-b:2ꞌ,3ꞌ-d]pyran) ·····································································································

···················· Xin Ke, Ling-xian Meng, Xiang-jian Wan, Xin Zhang, Mei-jia Chang, Chen-xi Li, Yong-sheng Chen (148)

Synthesis and Performance of a Double Network Self-healing Elastomer Based on Hydrogen Bonds and Diels-Alder

Crosslinks ················ Yan Peng, Yu-jia Hou, Qiao-qiao Shen, Hui Wang, Gang Li, Guang-su Huang, Jin-rong Wu (158)

Particle Morphology Control of Polypropylene Heterophasic Copolymer at Increased EPR Content by Simultaneous

Cross-linking ······································· Meng-jia Zhang, Li Wang, Liu-ting Hong, Ya-wei Qin, Jin-yong Dong (166)

Systheisis of Vanadium Complexes Bearing Tridentate β -Ketoimine Ligands and Their Catalytic Capabilities towards

Ethylene (Co)polymerization ·················································· Ling-pan Lu, Kai-ti Wang, Yi Liu, Jia-jun Wu (174)

Preparation and Characterization of Electrospinning Crosslinked Gel Polymer Electrolytes ·····································

·················································································· Yun-ni Chen, Qin Xiao, Qing-yin Li, Shi-jie Ren (183)

Cationic Surfactant Sensor Based on Poly(acrylic acid) Two-dimensional Photonic Crystal Hydrogel ·························

····················· Xia-tong Qin, Gen-qi Liu, Chen-hui Liu, Jian-xun Liu, Huan-huan Li, Yun-lei Cao, Xiao-dong Fan (191)

Reinforcing Styrene-Butadiene Rubber with Deformable Domains and Related Mechanisms ··········································

························································ Li-jie Zhang, Jing Huang, Si-wu Wu, Zheng-hai Tang, Bao-chun Guo (198)

Measuring the Strength of S/Se Based Dynamic Covalent Bonds ···················· Jia-hao Xia, Hong-bin Li, Hua-ping Xu (205)

Investigation of Chiral Recognition Mechanism of Polysaccharide Derivatives Based on Molecular Simulation ·············

····································································· En-ting Deng, Wan-ying Bi, Bo Liu, Li-li Zhang, Jun Shen (214)

《高分子学报》编辑委员会

顾 问：曹 镛 程正迪 蹇锡高 李永舫 王佛松 吴 奇 杨玉良

张俐娜 周其凤

主 编：张 希

副 主 编：(以下以姓氏汉语拼音为序)

胡文兵 黄 飞 李子臣(常务) 刘冬生 宛新华 王笃金 王献红

委 员：薄志山 陈尔强 陈国颂 陈 红 陈 全 陈学思 陈永明

董 侠 杜建忠 傅 强 甘志华 胡 晓 黄飞鹤 黄 维

江东林 蒋锡群 李光宪 李宏斌 李悦生 李志波 林嘉平

刘明杰 刘世勇 吕小兵 马於光 牛 嘉 乔金樑 史林启

孙俊奇 唐本忠 唐传兵 王健君 王利祥 王玉忠 解孝林

徐志康 杨 柏 杨万泰 杨小牛 杨振忠 尤 为 余 龙

张 军 张先正 章明秋 赵 江 赵 彤 郑 强 周永丰

朱美芳 祝 磊

编辑部主任：黄英娟

编辑部成员： 郭舒月 孟令艳 孙一依 赵 华 郑佳之

GAOFENZI XUEBAO （月刊，1957 年创刊）

第 51 卷 第 2 期 2020 年 2 月 20 日

ACTA POLYMERICA SINICA (Monthly, Started in 1957)

Vol. 51 No. 2 February 20, 2020

编 辑 《高分子学报》编委会 Edited by Editorial Board of Acta Polymerica Sinica 地址：北京市海淀区中关村北一街 2 号 Add: Zhongguancun North First Street 2, 邮政编码：100190 Beijing 100190, China 电话：010-62588927 Tel: 010-62588927 http://www.gfzxb.org http://www.gfzxb.org E-mail: gfzxb@iccas.ac.cn E-mail: gfzxb@iccas.ac.cn

主 编 张 希 Editor-in-Chief Xi Zhang 主 管 中国科学院 Administrated by Chinese Academy of Sciences 主 办 中国科学院化学研究所 Sponsored by Institute of Chemistry

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i

Acta Polymerica Sinica Vol. 51 No. 2 February 2020 Cover Image

Synthesis and Properties of a Conjugated Acceptor Material for Organic Solar Cells Based on Indacenobis(dithieno[3,2-b:2ꞌ,3ꞌ-d]pyran) Xin Ke, Ling-xian Meng, Xiang-jian Wan, Xin Zhang, Mei-jia Chang, Chen-xi Li, Yong-sheng Chen

This article introduces a new non fullerene acceptor we designed and synthesized, named IDTO2HT-2F. With the electron-donating capability

of the unit improved, the new acceptor has a narrow bang gap. The organic solar cell based on the acceptor IDTO2HT-2F exhibits a PCE of

10.85% with a high short circuit current density. It provides an effective method for designing new non fullerene acceptors.

Acta Polymerica Sinica, 2020, 51(2), 148 − 157

doi: 10.11777/j.issn1000-3304.2019.19131

Acta Polymerica Sinica Vol. 51 No. 2 February 2020 Contents

Feature Articles

Applications of Polymeric Micro/Nanoparticles in Engineered Vaccines Hua Yue, Guang-hui Ma

This feature article is to summarize the application of using polymeric

micron/nanoparticles as the chassises in engineered vaccines, including the on-

demand design concept, relative mechanism and development prospects in the

field of biomedicine.

Acta Polymerica Sinica, 2020, 51(2), 125 − 135

doi: 10.11777/j.issn1000-3304.2019.19143

Vol. 51, No. 2 ACTA POLYMERICA SINICA 2020

ii

Reviews

The Microstructures and Molecular Interactions in Multiphase Polymers: Insights from Solid-State NMR Spectroscopy Rong-chun Zhang

This review article is aimed to summarize some research progresses and

discuss the perspective of using cutting-edge solid-state NMR approaches

for characterizing the microstructures and inter-/intra-molecular interactions

of various multiphase polymeric materials.

Acta Polymerica Sinica, 2020, 51(2), 136 − 147

doi: 10.11777/j.issn1000-3304.2019.19175

Articles

Synthesis and Properties of a Conjugated Acceptor Material for Organic Solar Cells Based on Indacenobis(dithieno[3,2-b:2ꞌ,3ꞌ-d]pyran) Xin Ke, Ling-xian Meng, Xiang-jian Wan, Xin Zhang, Mei-jia Chang, Chen-xi Li, Yong-sheng Chen

We designed and synthesized a new non fullerene acceptor for organic solar

cells based on indacenobis(dithieno[3,2-b:2',3'-d]pyran). The acceptor has a

narrow band gap of 1.30 eV with the absorption edge extended to 956 nm.

The organic solar cell device based on the acceptor and the polymer PM6

exhibits a power conversion efficiency (PCE) of 10.85% with a high short

circuit current density (Jsc) of 20.61 mA cm−2.

Acta Polymerica Sinica, 2020, 51(2), 148 − 157

doi: 10.11777/j.issn1000-3304.2019.19131

Synthesis and Performance of a Double Network Self-healing Elastomer Based on Hydrogen Bonds and Diels-Alder Crosslinks Yan Peng, Yu-jia Hou, Qiao-qiao Shen, Hui Wang, Gang Li, Guang-su Huang, Jin-rong Wu

A self-healing elastomer with high mechanical properties was fabricated by

introducing two reversible networks of hydrogen bond and DA crosslinks.

Acta Polymerica Sinica, 2020, 51(2), 158 − 165

doi: 10.11777/j.issn1000-3304.2019.19140

Vol. 51, No. 2 ACTA POLYMERICA SINICA 2020

iii

Particle Morphology Control of Polypropylene Heterophasic Copolymer at Increased EPR Content by Simultaneous Cross-linking Meng-jia Zhang, Li Wang, Liu-ting Hong, Ya-wei Qin, Jin-yong Dong

Particle morphology control in heterophasic copolymerization of propylene to increased EPR contents was realized by simultaneous cross-linking

in the formation of EPR. Simultaneous cross-linking drastically altered the EPR’s viscoelastic properties, making it much less prone to flow under

polymerization conditions and thus leading to a controllable morphology development.

Acta Polymerica Sinica, 2020, 51(2), 166 − 173

doi: 10.11777/j.issn1000-3304.2019.19115

Systheisis of Vanadium Complexes Bearing Tridentate β-Ketoimine Ligands and Their Catalytic Capabilities towards Ethylene (Co)polymerization Ling-pan Lu, Kai-ti Wang, Yi Liu, Jia-jun Wu

A series of vanadium complexes with promising stabilities and high activities were

synthesized and employed as effective catalysts in ethylene (co)polymerization.

Cyclic olefin copolymers with high comonomer incorporations, high molecular

weights and high glass transition temperatures were obtained in high yields.

Acta Polymerica Sinica, 2020, 51(2), 174− 182

doi: 10.11777/j.issn1000-3304.2019.19128

Preparation and Characterization of Electrospinning Crosslinked Gel Polymer Electrolytes Yun-ni Chen, Qin Xiao, Qing-yin Li, Shi-jie Ren

A series of crosslinked gel polymer electrolytes (e-CGPEs) were prepared by electrospinning technique and Friedel-Crafts alkylation reaction. The

introduction of crosslinked network improves high-temperature dimensional stability of the nanofiber membranes. In addition, the e-CGPEs exhibit

excellent electrochemical properties.

Acta Polymerica Sinica, 2020, 51(2), 183 − 190

doi: 10.11777/j.issn1000-3304.2019.19149

Vol. 51, No. 2 ACTA POLYMERICA SINICA 2020

iv

Cationic Surfactant Sensor Based on Poly(acrylic acid) Two-dimensional Photonic Crystal Hydrogel Xia-tong Qin, Gen-qi Liu, Chen-hui Liu, Jian-xun Liu, Huan-huan Li, Yun-lei Cao, Xiao-dong Fan

A cationic surfactant-responsive poly(acrylic acid) two-

dimensional photonic crystal hydrogel was prepared. It is easy to

operate and has the characteristics of reusability and visualization,

which is expected to be used for the determination of cationic

surfactants in water.

Acta Polymerica Sinica, 2020, 51(2), 191 − 197

doi: 10.11777/j.issn1000-3304.2019.19170

Reinforcing Styrene-Butadiene Rubber with Deformable Domains and Related Mechanisms Li-jie Zhang, Jing Huang, Si-wu Wu, Zheng-hai Tang, Bao-chun Guo

By introducing a small amount of coordination cross-linked nitrile rubber into

styrene-butadiene rubber, the strength and fracture toughness of styrene-

butadiene rubber were significantly increased.

Acta Polymerica Sinica, 2020, 51(2), 198 − 204

doi: 10.11777/j.issn1000-3304.2019.19135

Measuring the Strength of S/Se Based Dynamic Covalent Bonds Jia-hao Xia, Hong-bin Li, Hua-ping Xu

We prepared poly(ethylene glycol) attached substrates linked by a single bond of either

SS, SeS, or SeSe. Atomic force microscope-based single molecule force spectroscopy

measurements of the three bonds indicated their strengths decreased as SS > SeS > SeSe.

Acta Polymerica Sinica, 2020, 51(2), 205 − 213

doi: 10.11777/j.issn1000-3304.2019.19166

Vol. 51, No. 2 ACTA POLYMERICA SINICA 2020

v

Investigation of Chiral Recognition Mechanism of Polysaccharide Derivatives Based on Molecular Simulation En-ting Deng, Wan-ying Bi, Bo Liu, Li-li Zhang, Jun Shen

Chiral recognition mechanism of cellulose tris(phenylcarbamate) and amylose tris(phenylcarbamate) is investigated by molecular simulation of

interactions between derivatives and enantiomers based on molecular mechanics and molecular dynamics. The results indicated that chiral

recognition was significantly dependent on the synergistic interactions between polysaccharide derivatives and enantiomers at the chiral grooves

formed by the carbamates and aromatic rings of the derivatives with different stabilities.

Acta Polymerica Sinica, 2020, 51(2), 214 − 220

doi: 10.11777/j.issn1000-3304.2019.19116