eco-friendly anaphoretic e-coating for corrosion

1
CONTACT: [email protected] (Project Coordinator) Parque Científico y Tecnológico de Gipuzkoa · Pº Miramón, 196 20014· Donostia-San Sebastián (Gipuzkoa), Spain www.cidetec.es 80 V and 60 s (20 cm 2 ) were the best electrical conditions to obtain 20 μm, in which was obtained better corrosion resistance (NSS test). Curing conditions were evaluated., obtaining that 120°C and 140°C during 60 min were the best conditions to obtain a compact and homogeneous layers. Few microns of anodizing can improve corrosion resistance Next Steps: E-coat system is under comparison with CAA (Cr-VI), leading a complete analysis of their behaviour against corrosion. Introduction A development of an alternative treatment to chromic anodising based on anaphoresis that meets REACH standards is the main goal of ECOLAND project. Anaphoresis (e-coating) consists of applying an organic coating by immersion using electric current. It has the advantage of enabling painting without the need for preliminary priming. The e-coating technology is based on reduction of application time while replacing with a single coat two layers that usually contain Cr(VI) (substances with this element will be prohibited starting in 2024 to meet European REACH regulations). It is expected to lengthen the useful life of the components treated by e-coating in comparison with traditional anodised and painted systems. Copyright of Liebherr Copyright of CIDETEC Pilot plant of e-coat system M. Rosalina Pérez-García 1 , Marian Musgo 1 , Jorge Rodríguez 1 , M. Belén García-Blanco 1 , Peter Hope 2 & Janet Hope 2 1 CIDETEC. Parque Tecnológico de San Sebastián Pº Miramón 196, 20014 Donostia (Gipuzkoa), Spain. 2 LVH Coatings Ltd., Station Road, Coleshill, Birmingham B46 1HT, UK. ECO-friendly anaphoretic e-coating for corrosion resistance in aeronautic applications - + e - e - Al alloy Cathode Anode (workpiece) + - - - - - + + - - - - - - - + + + + + + + + Stainless Steel - e-coating + water - - - - - - - - - Test e-coat Thickness (μm) 10 20 30 Dry-adhesion test (ISO 2409:2013) Grade 0 Grade 0 Grade 0 Solvent Resistance Rub-test (ASTM D4752) Pass Pass Pass NSS (ISO 9227) > 200 h > 1200 h > 1000 h Results & Discussion Effect of e-coat thickness Effect of temperature Test Anodizing & e-coat Thickness of anodizing (μm) 3 6 9 E-coat (μm) 10 Dry-adhesion test (ISO 2409:2013) Grade 0 Grade 0 Grade 0 Solvent Resistance Rub-test (ASTM D4752) Pass Pass Pass NSS (ISO 9227) > 2000 h > 2000 h > 2000 h Effect of anodizing & e-coat system Excess of thickness = non uniform e-coatings Thickness 10-30 μm = homogeneous e-coatings WE: Al 7075 alloy CE: SS or Al alloy 10 μm 20 μm 30 μm Intrinsic anodic e-coat layer = 400 nm Zoom 100 °C 60 min 120 °C 60 min 140 °C 60 min It seems like not completely consolidated Test e-coat Curing conditions 100 °C 60 min 120 °C 60 min 140 °C 60 min Solvent Resistance Rub-test (ASTM D4752) No-OK Pass Pass NSS (ISO 9227) 700 h > 1200 h > 1200 h 3.7 μm 8.2 μm 14.1 μm Anodizing conditions: 2.2 M H 2 SO 4 , 16 V, 6, 12 and 21 min respectively Find out more!: www.cidetec.es/en/projects/surface-engineering-6/ecoland-4 Topic Manager: Project Coordinator: Partners: This project has received funding from the Clean Sky 2 Joint Undertaking under the European Union’s Horizon 2020 research and innovation programme under grant agreement No 785412. Conclusions

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CONTACT: [email protected] (Project Coordinator)

Parque Científico y Tecnológico de Gipuzkoa · Pº Miramón, 196 20014· Donostia-San Sebastián (Gipuzkoa), Spain

www.cidetec.es

• 80 V and 60 s (20 cm2) were the best electrical conditions to obtain 20 µm, in which was obtained better corrosion resistance (NSS test).

• Curing conditions were evaluated., obtaining that 120°C and 140°C during 60 min were the best conditions to obtain a compact and

homogeneous layers.

• Few microns of anodizing can improve corrosion resistance

Next Steps: E-coat system is under comparison with CAA (Cr-VI), leading a complete analysis of their behaviour against corrosion.

IntroductionA development of an alternative treatment to chromic anodising based on anaphoresis that meets REACH

standards is the main goal of ECOLAND project. Anaphoresis (e-coating) consists of applying an organic coating

by immersion using electric current. It has the advantage of enabling painting without the need for preliminary

priming. The e-coating technology is based on reduction of application time while replacing with a single coat two

layers that usually contain Cr(VI) (substances with this element will be prohibited starting in 2024 to meet

European REACH regulations). It is expected to lengthen the useful life of the components treated by e-coating

in comparison with traditional anodised and painted systems.

Co

pyrigh

t of Lieb

herr

Co

pyrigh

t of C

IDETEC

Pilot plant of e-coat system

M. Rosalina Pérez-García1, Marian Musgo1, Jorge Rodríguez1, M. Belén García-Blanco1, Peter Hope2 & Janet Hope2

1 CIDETEC. Parque Tecnológico de San Sebastián Pº Miramón 196, 20014 Donostia (Gipuzkoa), Spain.

2 LVH Coatings Ltd., Station Road, Coleshill, Birmingham B46 1HT, UK.

ECO-friendly anaphoretic e-coating

for corrosion resistance in

aeronautic applications

-+

e-e-

Al a

lloy

Ca

tho

de

An

od

e (

wo

rkp

iece

)

+

-

-

-

-

-

+

+-

-

-

-

-

-

-

+

+

++

+

+

++

Sta

inle

ss

Ste

el

- e-coating + water

-

-

-

-

-

-

- --

Test e-coat

Thickness (µm) 10 20 30

Dry-adhesion test(ISO 2409:2013) Grade 0 Grade 0 Grade 0

Solvent Resistance Rub-test (ASTM D4752) Pass Pass Pass

NSS (ISO 9227) > 200 h > 1200 h > 1000 h

Results & Discussion

Effect of e-coat thickness

Effect of temperature

Test Anodizing & e-coat

Thickness of anodizing (µm)

3 6 9

E-coat (µm) 10

Dry-adhesion test(ISO 2409:2013)

Grade 0 Grade 0 Grade 0

Solvent Resistance Rub-test (ASTM D4752)

Pass Pass Pass

NSS (ISO 9227) > 2000 h > 2000 h > 2000 h

Effect of anodizing & e-coat system

Excess of thickness = non uniform e-coatings

Thickness 10-30 µm = homogeneous e-coatings

WE: Al 7075 alloyCE: SS or Al alloy

10 µm 20 µm

30 µmIntrinsic anodic e-coat layer = 400 nm

Zoom

100 °C 60 min120 °C 60 min140 °C 60 min

It seems like not completely consolidated

Test e-coat

Curing conditions 100 °C

60 min

120 °C

60 min

140 °C

60 min

Solvent Resistance Rub-test (ASTM D4752) No-OK Pass Pass

NSS (ISO 9227) 700 h > 1200 h > 1200 h

3.7 µm 8.2 µm 14.1 µm

Anodizing conditions: 2.2 M H2SO4, 16 V,

6, 12 and 21 min respectively

Find out more!: www.cidetec.es/en/projects/surface-engineering-6/ecoland-4

Topic Manager:Project Coordinator: Partners:

This project has received funding from the Clean

Sky 2 Joint Undertaking under the European

Union’s Horizon 2020 research and innovation

programme under grant agreement No 785412.

Conclusions