en portland cement og y . ir hno l

53
EN197- 1 1 - EN197 EN197 27 . 27 5 . CEM I Portland cement CEM II Portland-composite cements including: -Portland-fly ash cement (CEM II/A-V, CEM II/B-V) -Portland-slag cement (CEM II/A-S, CEM II/B-S) -Portland-limestone cement (CEM II/A-L (LL), CEM II/B-L (LL) CEM III Blastfurnace cements (CEM III/A, CEM III/B) CEM IV Pozzolanic cements (CEM IV/A, CEM IV/B) CEM V Composite cements . S blastfurnace slag D silica fume P natural pozzolana Q natural calcined pozzolana V siliceous fly ash (e.g. pfa); W calcareous fly ash (e.g. high-lime fly ash L and LL limestone T burnt shale M two or more of the above. 2 3 PDF created with FinePrint pdfFactory Pro trial version http://www.pdffactory.com www.cementechnology.ir cement technology magazine: 021-22883306, 22861343 www.cementechnology.ir

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Page 1: EN Portland cement og y . ir hno l

EN197-

1

1-EN197

EN19727.275

.

CEM IPortland cement

CEM IIPortland-composite cements including:-Portland-fly ash cement (CEM II/A-V, CEM II/B-V)

-Portland-slag cement (CEM II/A-S, CEM II/B-S)-Portland-limestone cement (CEM II/A-L (LL),

CEM II/B-L (LL)CEM IIIBlastfurnace cements (CEM III/A, CEM III/B)

CEM IVPozzolanic cements (CEM IV/A, CEM IV/B)

CEM VComposite cements

.

Sblastfurnace slag

Dsilica fumePnatural pozzolanaQnatural calcined pozzolanaVsiliceous fly ash (e.g. pfa);Wcalcareous fly ash (e.g. high-lime fly ash

L and LL

limestone

Tburnt shaleMtwo or more of the above.23

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Page 2: EN Portland cement og y . ir hno l

EN197-

2

27.

5-0%.

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Page 3: EN Portland cement og y . ir hno l

EN197-

3

.

3N/mm2325 4255253N , R

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Page 4: EN Portland cement og y . ir hno l

EN197-

4

.1-2-3-4-5-6-7--8-9-

10-

.

2004EN197.

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Page 5: EN Portland cement og y . ir hno l

EN197-

5

2004.

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Page 6: EN Portland cement og y . ir hno l

EN197-

6

..

Applicable cements acc. to EN -Country

with cement

EN - CEM ICEM I, CEM II/A-D, CEM II-S, CEM II-V, CEM II/A-W, CEM II/A-L, (CEM II/B-L, CEM II/B-M,

CEM III/A, CEM III/B) )AustriaCEM I, CEM II/A-D, CEM II-S, CEM II-V, CEM

II/A-W, CEM II/A-L, (CEM II/B-L, CEM II/B-M) )

Denmark CEM I, CEM II/A-V, CEM II/B-V, CEM II/ALL, CEM II/A-L

CEM I, CEM II/A-D, CEM II-S,CEM II-P/Q, CEM II-V, CEM II-T, CEM II/ALL,

CEM II/A-L,CEM II/A-M (S-D, S-T, S-LL, D-T, D-LL, T-LL, S-

P, S-V, D-P, D-V, P-V, P-T, P-LL, V-T, V-LL),CEM II/B-M (S-D, S-T, D-T, S-P, D-P, P-T, S-V, D-

V, P-V, V-T)CEM III/A, CEM III/B,

CEM IV/B-P, CEM V (S-P)Germany

CEM I, CEM II/A-D, CEM II-S,CEM II/A-P, CEM II/A-V, CEM II-T, CEM II/ALL,CEM II/A-M (S-D, S-T, S-LL, D-T, D-LL, T-LL, S-

P, S-V, D-P, D-V, P-V, P-T, P-LL, V-T, V-LL),CEM II/B-M (S-D, S-T, D-T)

CEM III/A, CEM III/B ),

UKCEM I, CEM II/A-D, CEM II-S,

CEM II-Q, CEM II-V, CEM II/A-LL, CEM II/A-L,CEM III/A, CEM III/B,

Swiss

CEM I,CEM II/A-S, CEM II/A-LL, CEM II/A-D, CEM

II/B-LL )CEM II/A-M (D-LL),

CEM III/A, CEM III/B,

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Page 7: EN Portland cement og y . ir hno l

EN197-

7

2-

2-1-

.

.

:

.

25-18 .

.]1[

.

..]2[

.

.

:

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Page 8: EN Portland cement og y . ir hno l

EN197-

8

.

.

20.

.

.]3[

13001400

.1450.

.1450

.

)MnO(

.C2S)(

)1(

(CaO))(C3S. C2S

C3S

.)1(.]4[

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Page 9: EN Portland cement og y . ir hno l

EN197-

9

)(

75 % .25 %.]5[.

EN197..]6[

.

CEMIII/B)80(CEM I4000KJ/kg2000KJ/Kg..]7[

5-020-694-80CEM II/A-SCEM II

5-035-2179-65CEM II/B-SSleg Cement

5-065-3664-35CEM III/A5-080-6634-20CEM III/BCEM III5-095-8119-5CEM III/CBlast Furnace slag

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Page 10: EN Portland cement og y . ir hno l

EN197-

10

.]8[

.]91[

-––––-

:J K CEMENT-

Grasim Industries and ultra tech -

India cement Ltd-

Gujarat Ambuja cement Ltd

19962006

.]11[

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Page 11: EN Portland cement og y . ir hno l

EN197-

11

Product -Year Growth( - )

Annual Compound Growth ( - )

Slag CementPortland Cement

2005

.]12[

-3,1

-315BTU72000

-3,5

)(2800 lane-mile of inch) (

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Page 12: EN Portland cement og y . ir hno l

EN197-

12

.

..]13[

CaO414043424334404178/55SiO2353735353433353438/26

Al2O311812121616168/062/8MgO8108751461146/4Fe2O38/02/10/23/05/07/18/08/004/2

SO3229/06/19/017/13/176/1Mn2O33/07/05/08/06/05/06/05/0

Na2O36/034/0K2O32/067/0

.]14[

ASTMC595PBFSC

(SM)1S1S

25<257070>

1164DINEPZHOZSHZ

30<318575>

15-NFPCFCMNCHFCLK

302050<657580>

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Page 13: EN Portland cement og y . ir hno l

EN197-

13

-65<CF

CHFCPMCMS

30<307070>85>

JIS R5211

ABC

---

53030606070

5210KSL

-2565

.]15[

%Uk(P)Uk(G)SpainJapanIndia

SiO23/2235/41/356/384/327/34Al2O38/53/136/134/85/161/21Fe2O38/25/03/05/04/05/1CaO8/651/39389/418/4137

MgO3/19/89/83/99/51/4Mn2O33/04/05/03/02/1-

Na2O5/02/03/03/0-6/0K2O3/05/07/05/0--

S4/09/0113/1-TiO23/05/05/11/1--L.O.I5/00/1-1-

:

..]16[

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Page 14: EN Portland cement og y . ir hno l

EN197-

14

CEM III45050050

25070050

Properties of Portland slag cement discussed aboveProperties Values Setting time (minute)Initial 15Final 450Compressive strength (MPa)1 day 53 day 147 day 1828 day 38 Autoclave expansion (%) 0,3

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Page 15: EN Portland cement og y . ir hno l

EN197-

15

15080050

Properties of Portland slag cement discussed aboveProperties Values

Setting time (minute)Initial 40Final 625

Compressive strength (MPa) 1 day 103 day 207 day 2528 day 49

Autoclave expansion (%) 0,02

3095020

: Properties of Portland slag cement discussed aboveProperties ValuesSetting time (minute)Initial 35Final 610

Compressive strength (MPa) 1 day 73 day 157 day 2228 day 43

Autoclave expansion (%) 0,2

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Page 16: EN Portland cement og y . ir hno l

EN197-

16

Properties of Portland slag cement discussed aboveProperties Values

Setting time (minute)Initial 55Final 750

Compressive strength (MPa) 1 day 33 day 127 day 1528 day 33

Autoclave expansion (%) 0,03

.S-A/CEM IIS-B/CEM III

20 %70 %70 %228

20 %CEM II/A-S70 %CEM III/B-S.

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Page 17: EN Portland cement og y . ir hno l

EN197-

17PDF created with FinePrint pdfFactory Pro trial version http://www.pdffactory.com

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Page 18: EN Portland cement og y . ir hno l

EN197-

18

slagstar85-79% .10-20 %1-4 %

)..

slagstar19872003.]26[

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Page 19: EN Portland cement og y . ir hno l

EN197-

19

slagstarCEMIII/ACEMIII/B.

.CEMIII/A )50 %

40 % (CEM I8 %CEMIII/B)40 %75 % (17 %.

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Page 20: EN Portland cement og y . ir hno l

EN197-

20

..

28CEMIII/B325CEMI325 .

.

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Page 21: EN Portland cement og y . ir hno l

EN197-

21

.]27[

.

.

.

.

.

.

.

,

.]28[

.

.

.

.

.

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Page 22: EN Portland cement og y . ir hno l

EN197-

22

.

.

20 %

..30 %

60 %28.

.

.

.

.

Ca(OH)2CaSO4C3A

(ettringite)3Ca.Al2O3,3CaSO4,32H2O.

168.

Ca(OH)2.Ca(OH)2

.

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Page 23: EN Portland cement og y . ir hno l

EN197-

23

.

.

.1892(Michaelis)

C3A.

.

.

:

1-2890

.

2-.

.

.

.

.

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Page 24: EN Portland cement og y . ir hno l

EN197-

24

..

.

.

.

.

.

.

.

.

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Page 25: EN Portland cement og y . ir hno l

EN197-

25

Ca(OH)2

.

1-2-

.

.

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Page 26: EN Portland cement og y . ir hno l

EN197-

26

.

.

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Page 27: EN Portland cement og y . ir hno l

EN197-

27

-2-2-

.1979EN197-1.][

.EN197-1.

][

.-

5-06-2080-94CEM II / A-LLCEM II

5-021-3565-79CEM II / B-LL

24 )%40 (2000.][

CEM II A-LLCEM II A-L)6 %20 % (425525325R.][

.][LL.TOC2/0 %5,0 % .

5-06-2080-94CEM II / A-LCEM II

5-021-3565-79CEM II / B-L

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Page 28: EN Portland cement og y . ir hno l

EN197-

28

.CaSO4,2H2OC3A .

.][+C3A +

OHCaSoOAlCaOOHOAlCaOOHCaSo 232,43,32,322632,3)2,4(3 →++

) ( .

, .

. ,) (C3A

.C3A +

)212,4,3224232,43,32,332,33(3 OHCaSoOOALHOHCaSOOAlCaOOAlCaOCaO ++→

C3A , .C3A

.389C3A5.

. C3A) ( . , . ,

.][

.110

5- ..

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Page 29: EN Portland cement og y . ir hno l

EN197-

29

C3SC3A. ,

,.

+C3AACCaCOOAlCaOCaCO 3,332,33 →+

,.C3ACaCO3, C3A

.10

.:][

---------) ,(

.][

20 %

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Page 30: EN Portland cement og y . ir hno l

EN197-

30

LC1-LC2020284255%

LC535 %R325

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Page 31: EN Portland cement og y . ir hno l

EN197-

31

.

w/c5/03:1100×80×80mm412×100mm

3 %NaCl25 )(

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Page 32: EN Portland cement og y . ir hno l

EN197-

32

20 %20 %w/c5/0

..

912.

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Page 33: EN Portland cement og y . ir hno l

EN197-

33

.

2-3-][.

P,QV,W

0-5 18-30 18-30 40-64 CEM/A CEM V 0-5 31-50 31-50 20-38 CEM/B

.

4 %.

.

4/25 N CEM V 5/25 R

5/25 N

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EN197-

34

..

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Page 35: EN Portland cement og y . ir hno l

EN197-

35

10 %10 % 20 %.

2-4-][EN197

CEM II/A-TCEM II/B-T.

DotternhausenRohrbach Zement

.

.

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Page 36: EN Portland cement og y . ir hno l

EN197-

36

80fluized-bed.010 fluized-bed

)t/h16 (2-5-

.]38[

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Page 37: EN Portland cement og y . ir hno l

EN197-

37

OHHOHCaCH

CHSHCHSCCHSHCHSC

22)(

23

==

+−−→++−−→+

CH .

OHCaSiOOHCaSiO 2322 )( +→+

SiO2Al2O3Fe2O3. .25

.]38[

.

.

) (.]39[

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Page 38: EN Portland cement og y . ir hno l

EN197-

38

XRD..70

. .

.SiO2,Al2O3,Fe2O3

EN197Q,P.P

Q , ,

.

EN197CEM IIAB.CEM IV) (

AB.

Q D5-020-694-80CEM II/A-D

5-035-2179-65CEM II/B-QCEM II5-020-694-80CEM II/A-D

5-035-2179-65CEM II/B-Q

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Page 39: EN Portland cement og y . ir hno l

EN197-

39

W D,Q5-011-3565-89CEM IV/ACEM IV5-055-3645-64CEM IV/B

CEM II]41[-1-

C3A

. .

30 %40 %

-2-

30 %212815 %

3040.

3-

.

. ..

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Page 40: EN Portland cement og y . ir hno l

EN197-

40

30 % ,.

-4-

500

.

-5--

) (

.25 %–

70 %.

-6-.

§)(CaSo4-2H2O§)( C-A-H §C-H-S)(CaCO3-CaSiO3-CaSO4-15H2O

C-S-H

.20 %80 %

.

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Page 41: EN Portland cement og y . ir hno l

EN197-

41

-7-

.C3A C3A

.]42[

,

.

9.]43[ .

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Page 42: EN Portland cement og y . ir hno l

EN197-

42

..

IVV52.

.

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Page 43: EN Portland cement og y . ir hno l

EN197-

43

6/11 % 7/14 %.

.

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Page 44: EN Portland cement og y . ir hno l

EN197-

44

030.

35 %45 %55 %4500cm2/g

.]44[.

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EN197-

45

.

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Page 46: EN Portland cement og y . ir hno l

EN197-

46

.

55 %.

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Page 47: EN Portland cement og y . ir hno l

EN197-

47

ca(OH)2

.

.

.

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Page 48: EN Portland cement og y . ir hno l

EN197-

48

35%45 %55 %.

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Page 49: EN Portland cement og y . ir hno l

EN197-

49

-]45[

5-010-694-90CEM II/A-DCEM II

)Silica fume : ( .

.CH

.OHCaSiOOHCaSiO 2322 )( +→+

XRD7C-S-H12075 %90

]10[.≡−−≡ SiOSi

.

HSCOHCaOHSislowlyreactOHSiOHHSiOSi

−−→+−≡⋅−→≡−+≡−−≡

2)()(

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ASTM33

%OPC

0/9522SiO2

9/06/6Al2O3

6/08/2Fe2O3

3/01/60CaO9/03/3MgO5/01/2SO3

1/26/2LOI

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m 1/0m13)(

2038/0) m2/g(

mm45/1:27/25/1%6/276/4

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SP-) g(

) g() g() g(w/cm%

2/1-0/62525512850%OPC9/12/120/62525512850%SF51/22/230/62525512850%SF102/23/330/62525512850%SF15

)5%10%15(%*superplasticizer

OPCSFSP

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Superplasticizer* : .superplasticizer.

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.

East Bay Municipal Utility District Wastewater Treatment Plant CaliforniaAburn Dam CaliforniaPalo Verde (Nuclear) Power Generating Plant ArizonaSacramento Wastewater Treatment Plant CaliforniaSouthern Nevada Water Project NevadaTehama-Colusa Canal CaliforniaGeorge R, Moscone Convention Center CaliforniaPort of Richmond CaliforniaPacheco Pass Tunnel CaliforniaIdaho Falls Hydro Electric IdahoAmerican River Falls Power Plant IdahoCoyote Power Generating Plant N. DakotaSan Francisco Wasterwater Treatment Plant Project CaliforniaPioneer Reservoir CaliforniaChabot Dam CaliforniaDumbarton Bridge CaliforniaPeace Valley Water Project CaliforniaPyramid Lake Powerhouse CaliforniaRock Springs Wyoming Power Plant WyomingHong Kong Center CaliforniaGraduate Theological Union Building, UC Berkeley CaliforniaPacific Gas & Electric CaliforniaHelms Creek Powerhouse Pump Station CaliforniaNorth Point Seawall CaliforniaBechtel Engineering Center, UC Berkeley California

t∆

1h26m4h23m2h57m2,5220100CO0h55m4h45m3h50m2,522298B20 h45m5h20m4h35m2,522397B30h43m5h28m4h45m2,522595B5

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Redding Airport Runway California

Los Angeles Aqueduct ( - )Los Angeles Flood Control District during the 's and 'sBonneville Dam ( )Golden Gate Bridge ( )Piers of the San Francisco-Oakland Bay Bridge ( )Friant Dam ( )Nearly all of the concrete in the California State Water ProjectIncluding the California Aqueduct in the 's and the 's

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