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8/18/2019 ESBO Nanya

1/12

H

H

E

HPI# ng{'n'€ FRaIE-l

NAN YA PLASTICS CORPG'RATION


2/12

Epoxidized

Soybean

Oil

ESO

132,ESO

-

132D

Introduction

Physical

& Chemical

Properties

Characters

Applications

& Description n PVC

Processing

Packing

& Operation

Material

SafetyData

Sheet

MSDS)

Appendix

. JHPA

CertihcateFor ESO

-

132,ESO-I32D


3/12

Epoxidizedoybean

il

ESO-132,aproductafter

oxidation f soybeanil

,

is widely

sed

snon-toxic

stabilizernd

plasticizer

n

PVCprocessing.

The

production

echnology

is based n hecooperation

between anYa and

Nippon

Sanwa osei.

ESO-132D

Deodorized

Epoxidized

oybean

il),

madeof SO-132bya

series f deodorization

purifications

s

produced

o

meethespecialequestsn

some pplications.


4/12

Chemical

Name

Eooxidized

ovbean il

I{,C

-

O

-

C

-

C

-(CHr)x -

CH

-

CH

-

R

| \ / /

Hl

-

o

-

c

-

c

-(cH,)x

cH cH R'

I lC-O-C-C-(CH,)x-CH

_CH

o

MolecularWeisht

MeltedPoint

>

150i5mmHg

oiling Point

3r5.6

SpecificGravity

0.982 1.002

25'C

400

a

50 cps

25t

)

Weight

Loss after Heating

Refractive ndex

t.470 0.0022st )

Color

Number

200

APHA)

6.4-6.8o/oxiraneOxygen

Iodine Value


5/12

l. Non-toxic

BesidesheapprovalromJHPA,PL specification.7,

tem (Approval

o.

J-7885), lso

meet

trict

FDA equirement,ccordingo thestipulationsnFoodAdditives18 .27 nd175.300).

ESO 132andESO 132D canbeusedn association

ith

stabilizers.or

example,hecombination

between a-ZnandCa-Zn eries tabilizers

ith ESO, s in

non-toxic pplications.hisnon-toxic

combination ill

be

hemainstreamn PVC

processing.

2. Heat stability and Weather

-

resistance

Thesynergisticffect anbeexpectedn case fthe combination ith metal

eries tabilizers.

hanks

to the

capability fthe active poxy

ing o catchHCI and ts antioxidation

ffect gainst egradation.

After heating nd ight exposure,hecross-linkingmong VCmolecules

anbeminimized.

Namely,hebig-scale nhancementn both

heat tability nd

weatheresistanceor PVC

products

an

beexoected.

3.

Low

volatility and High molecule

plasticizer

Much

ower n volatility han

DOP

about

0%of DOP), t

provides

etter tabilityn PVC lexibility.

With aboutM.W. 1000,ESO 132canbe egardedsa

good

plasticizer

n

PVC

processing.

4. Low I.V., Good in non-migration

esistance

nd extraction esistance

Low

I.V.,

good

ompatibility ith PVC

Plasticizers,t therefore rovides oodperformance

n non-

migration nd

extraction

esistance.

5. Water

-

resistance,Oil

-

resistance nd

Low

loss n transparency.


6/12

ApplicationsFormulas

PVCLeather'.llm.

Coatingnd

Ertmsion

Fi lnrsbl

packing

\on-tor ic

Description

.

Better

cat-r'csislanccn conrbinrtiour th nletrl stiibilizcrs .

a

Irrpro\

ng transfatcnc)'.

e Suguestcdosagc .5 - 1.0 PHR.

o

I'rrpcrlr tblrrLrlatirg r th DO.\

or

DINA.

uscdasanti-

l l r ' .z i r ' l r l . r ' t iz,

'

i r P\

(

|

'

'

.

o

Srrggestct llosauc(1.( l 10.0PHR.

r

Appl icrblc n

combinat ion

\

lh Bl-Zn. Ca-Znslabi l izcrs.

o

Suggestecilosage

o

PVC Lel ther . l lnr : . ( l l . ( l PHR.

oToys

ancl nject ion roducts:

1.( l 5.0

PHR.

r

Good o bc pplicd in non toric

PfodLlct\-

Lrchs to]-s.

glo\

c etc.

r

(irxxlrrc(ing

to color

urrtlcr.

o nhanceonrl)alibilil

\ ith

I ' \ ' ( poir

lcr

l icr

blcnding

i th DOP.DI\P

and

DIDP.

o

Rcducing onrpouncl in{iscosi tv t icrmir ing $ i th

inolgunic

ignrcnts.

r

Suggcstccloslgc:

i .0

6.0 ' l lR.

o

Appl icrble o iorking i th Br Zn sel ies tabi l izels.

r

SLrggcsledosrge:1.0 1.0PI R.

o

Widclv

uscdascor clrgc lil nr in ugricullure ndcxterior

hydrolvsis-rcsisliinc.

lolh.

o

, \ppl icablen corrbinat ioni th stabi l izcls.o rnake

rp

thc stabilitv n illc leturilrtion irr

Sb,O,

ancl lrO,.

. Suggcslcdosagc: .0

-s.0

l lR.

r

In

pair

ith

poli"estef-tlle hsticizeN

o enhanceon nrigntiol.

o Suggcstcdlosage ccordingo diftcfent

prodrrcts:

o

Non-nigrat ion able ncl i re

5.0

I0.0 PHR.

eGasket f le i i igelator :

bout 0 PHR.

r

,\pplicablc n pair r

th TOT1\'1o l s 1o nhrncc inli-

firi.rrintpr.oducts.

o

\Lr ' - r . :c. tcJ

l , r . : r : t - . :

t t .

0 { l

PHR

o

\Vi ld l l 'appl icd

n crr

prncl products.

r

Couplingu'ith polyester ) \\ 'ork s a plasticizcrbr

solr.ent ndoil resistantbrmLrlas.

.

Suggestedosage: .0 5.0PHR.

o

Wildlv

uscd n l lexible ubcs.

&

Toncr&

\'iastcr atch

Anti-weathel'

Non-nr israt ion

F re-retuldat ion

.,\nti fbgging

Low cxtractior'l

tbrrnLrlas


7/12

Packing

and Notices

,F

a

In

use

l .

Fol ' \ ' (

lcr th ' r .

l lnr . . .c lc.

hc

LLtgcstcd

osage

o nr() fc

l l rn

1.0

pHR.

i f

crceedcd.

einupr ro

blcedin-r :.

L I ior

' \

(

packinr

i l r l .

lhc nar inrunr

oslgc

hould

cbelorr

0.0

pHR

Il.

erccct lecl

bcculc l i r l

v i th

leeding.

-1.

\ 'hcn

r int inu

s rccl r rcstcd

lhe

nlrxintunr

osaqehould

cbelos

.0

Pll l l

.

i i ' crcccdcd.

hc cak

cohc'sion

cl r lccn

r int inu

nk

and

pVC

prodlrc ls

l 'nt \

entefgc.

-1.With

consicleration

l

thc

poor

n i t ia l

olor.to

\rC.

in

tcr .n ts

l ' those

ruppl ical ions

bal

n i t ia l

olor.arc

sscnt i l l

theESO

losauc

s ota l l1 , .

depcndcnt

n he

dosl lc

ol 'stabi l izer..

he ugsested

osasc

s 1.0

.0 pHR

.

5. 1.0PIIR

dosasc'\

l l

br ins h '

o i ipoint

f ' I , \ rC lorvnboLrt

'C

l :spcciu l lv.

bl r ig idP\ i t

appl ications

thc

closagehoult l

c

Lrnclerropcr.

con ro

Storage

and Transportation

l . ESO

hould

e

propcr lv

lored

t h '

crnpcrrture

clou.-15

.

Ifcxceeded.

polvmcrization

i l l rake lace

L Conti ln l inrt ionlom Lrst nd and...elci l l lead o thcpolvnrer ization.t

is suggcsted

o pu1

rct i l l

creen

28

mcsh

min.)

n the ents

f

arrsroragc

tanks.

he egular

lcaninrr

f the

ntcta l

creen

hould

cclonc.

i . Bclorr

0

.C.

the

iscosi t l

f EsO

sour .s

p. f lor ierthan

5

,C.

i t is

n thc

paslc

irm

(l ike

arul) .

l is

eas),to ct

hard

n pipe

ranspoftation.

eatins

t

up o.l5

nta\ .can

ase

ff theproblcm.

Safety

L Skin

contact ral

carrse

rr i tat ion.

spccial ly

o thosc

skjn- l l lcrgic

peoplc.

l l

conl i tcted.rash

ol l 'contuninat ion

\ ' i th

soup

and \ , r ter .

cck

ntedical

l l lcnt ion

i f

i t r i tat i r rn crsisrs.

L

l l 'cvc

cont i rcteci .insc

ir l l5

nt inutcs

nininrunt

i th

a

gcnt lc

water

strei lnt .

obl l in nrcdical

t tenl ion f the

syntptonls

crsist .

Packing

L Loldcd

n 53-gallon

ror

dr.um.

00ku

ncrpcr

drum.

2. SO

ank

vai lable.lMT

per

et

raccording

ontnct .


8/12

L lvlanufacturer/

Manufacturer

Supplier

Name HP Plant Plastics th Division NanYa Plastics

orporation

ManufacturerSupplierAddress20l,Tung

waN. Rd.,Taipei, aiwan,

.O.C.

Consultants ameandPhoneNo. :

(02

2712221|xt .

Emergencyontact hone o.

(02)

27122211xt. FaxNo.:

02)

27178530

Appearance

Clear

iquid

Vapor

ressureNA

-Er--

Specificnvity

tlo:

l) :0.982

-

1.002

Product ame Eooxidized ovbean il

Short-term

Exposure

Limit

(STEL)

Evaporationate(Ethyl cetate: ) :NA

Solubilityn

Water

0.01%

(

20t

)


9/12

Flash oint 600 F

TestMethod:

v)

Open up

)

Closedcup

LowerExplosion

imit LEL : No data

UpperExplosion imit

(

UEL

)

: No data

Fire Fighting

Agent

Dry

chemical

alcohol oamor carbon

ioxide.

Special ireFighting roceduresNone

Conditions

o Avoid

Hazardous ecomposition

Materialso Avoid Strone cidanddust.

(

v

)

Inhalation

v)

Skin

ontact

(

v)

Ingestion

(v

)

Eyes ontact

Skin contact

may cause rritation of the skin.

Eyescontact

will

cause

rritation

of eyes.

Inhalation

l. Removeo freshair.

2. Ifbreathing

s

difficult

,

ensure

irway s clearand

give

oxygen.

Ifnot breathinginstituteCardiopulmonaryesuscitation

CPR).

3.

Keep ffected

erson

armandat rest.

Get mmediate edical ttention.

Skin ontactIrnmediately

ash ith

plenty

f soap ndwaterwhile emoving

contaminatedlothing.

Eyes

ontact

l. Flushmmediatelyith

plenfy

fwater or at east15minutes.

Eyelids hould e

held way

rom heeyeballo ensurehoroughinsing.

2. Get mmediateedical ttention.

Ingestion I . If afiected

enon

awake,insehis(her)mouth.

2. Let

drink

plenty

fwarmwater

r

milk,

and hen nduce omiting.

3. Get mmediate edical ttention.

Emergencyesponse

&

First

Aid

Measures


10/12

7.

Measures

o

Prevent xposure

Pcrssnlrl

E1-r"'s\\ iear

chenticl l

sulctv

gogglcs.

Pfotcclivc

['-cluipntcnt

(i]or

es Use Lrtrbcr

lor

cs ol chenricul

lolccl ir

c

l loves.

Vcnt i l l t ion Equip ,ent i lat i r cclLl i ln ' rcnlr

l rc i l i t r . Kccp

ir l icsh.

l l lndl inq &

Slorasc

Should e

stotedundcr

{5

C.

Prccattlions

I . Placc onta niniltedlothin_l

n closcci ontaincr

irr slolagc Lnti launder.cdI dirclrrrlcLl.

l

clL,thrr.-:

is o be aundcradinlir lrn

pclson cl l i l rninu

opcralion f contaminanlhrz;rrdorrs

'rr,rper

ir

'

Pcrsonal

l . Do notcr t . d l ink.

snroke. lncl ur l r ' l rshteln rolk ing

arcas.

| |y- rcnc

J.

After handling washhands horoughl\.

,1.

Kccp he l'orking tcrts

lcan.

8. Responeo Spill andWaste

Disposal

I Isolatc

hc

cont i l r l inuted

rcus

i

i th in sund

caf ihor c lout o bui ld

enrpolulvl ikc:

I--nrc'rgcncl

in cast' l ' lc'akruc

nlir lgc.

I lcsl tonc o

Slt i l ls

l .

L.sc'c loLr t

o i rbsolb pi l l

or

r rsc. inr i lur rc lhrxl

o l fe i r t Nn( l hcn rrc inc| l tc hecLrLr l r

-1.

C can

i

it l t

sorp and llcf.

\ \ ' i rstc i :pu. l l

lnc

n

e

r r r . '

ML-thods

9.

Transportationnformation

Llni lcd

Nat ion

NLrnrbcr ' ( l . lN.No)

Hazard

( ' lassi l lcl t ion

I lazard abcls

I : l . t l t t t l r tb le

l . iquid

10. nformation

of

MSDSheparation

\anre : \ul Yu Plltstics orporation

(

)r 'ganzrt on

that

f rc lared

. \ddress Fornrosn

ldrrst l i i r l' i r lk o.

I . \ la i l i ro. \ iLn] inCountr .Tl i r ran I l .O.( .

IhC { SDS

Telephonc

(05

68l l - .1-+5\1.

Pclsnn hu

pr.p,u.r i, f ' , .

niSOS

lob Tit lc : SafiyanclSanit

ior Munrgcr

Nanrc SuYu-lVling

Dalc hcMSDS

Dav:0.1

l \ lonth: . lunc Ycur ' :1999

\\ ls

prcpaleo


11/12

HiTtrE

J 7 BB5

Aftn'r+li

|

|

+

2 ,H o El

,tJif

l 'Ll: l : ; ld,F;=ii l : t ' t ')c7"+t;EE

,=il

i +

rF

*

6i

* +

a

rr"

Y.

=

)

v

jl

B? f: iAE

7":r f,.1: iH

u

fr

*Et6

(Jllp+n

f

)

i:

i-iit

L

-aL

'.7r

u-:a

ft.if.l-:

I:

l:rlEi

4.

'Fr [

l1

1l - -

2)l

l5R

) i rv

' .Li i t i t r ' ,

2. \42

'+

HCCffi

=L U

l l r : l

(FOI{ I

3

,

lNtr".

EIt

c

=

)v#lEE#A

i

6 e*E*+

(;

F€

6 E

+*Ei*

EE

E

=aB

=r

HtrSryIfltiiE,,EilFl

{ i"}fsiftlit

t-,

.J<

rF

trt.ru

tr:v

Fq€

+*t l

q, ( [Hi l

tfiffia

(ffifi8)

LSO- 132

i lSO-1:J2D


12/12

al

t't

Printed on Nan Ya PP Synthet ic

Paper.

Pleasedo not mix

wilh other

9ene6l

paper

ecycle.

(1999.09.1000)

ffi H lE flgr # Hlfi€ [Rr*=l

NAN YA PLASTICS

CORPORATION

201, UNHWA

N. ROAD. AIPEI,AIWAN,

.OC.

TEL:

O2\

712-2211

esbo nanya

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