パターン形成・自己組織化の物理¤‡雑系科学...å b Ø ö @$ ^ >&scientific...
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1
Self-organization Self-assembly
( )H. Haken : Synagetics, ( )Santa Fe group : Complex systems, ( )I. Prigogine : Dissipative structures
pattern formation
i)
ii)
iii
No 1-1.
-----
-----
----- -----
2
BZ
CSTR
BZ
CSTR BZ
BZ
CSTR BZ
3
( )NADH NADH NAD
--- ON OFFBZ D3
BZ
NHK TV
4
OR-NOT OR-NOT
OR OR
(circummutation)
20 1H
circadian rhythms 23
5
SCN
A+B A: B:
S.Yamaguchi, et al., Science 302(2003)1408
Per-I-luc mouse Lucifarase-transgenic SCN suprachiasmatic nucleus
Turing
A,B
CIMA system BZ
Q. Quyang & H. L. Swinney, Nature, 352, 610(1991)
6
Fig. 2. Rearrangement of the stripe pattern of Pomacanthus imperator (horizontal movement of branching points) and its computer simulation. a, An adult P. imperator ( ~ 10 months old ). b, Close-up of region I in a. c, d, Photographs of region I of the same fish taken two (c) and three (d) months later. e, Starting stripe conformation for the simulation (region I). f, g, Results of the calculation after 30,000 (f) and 50,000 (g) iterations. h, Close-up of region II in a. i-l, Photographs of region II of the same fish taken 30 (i), 50 (j), 75 (k) and 90 (l) days later, respectively. m, Stating stripe conformation for the simulation (region II). n-q, Results of the calculation after 20,000 (n), 30,000 (o), 40,000 (p) and 50,000 (q) iterations, respectively. Fish (Fish World Co. Ltd (Osaka)) were maintained in artificial sea water (Martin Art, Senju). Skin patterns were recorded with a Canon video camera and printed by a Polaroid Slide Printer. In the simulated patterns, darker color represents higher concentrations of the activator molecule. Equations and the values of the constants used, as Fig. 1.
7
39 -0.01 /min 39s
.
PbI2 PbNO3+2KI PbI2+K2NO3
8
Scientific American 279,No.4(1998)
DLA DLA Df=1.706
H.Fujikawa, Physica A189(1992)15
(20g/l ) (7g/l) (1g/l) (15g/l: ) DLA
9
Benard-Rayleigh
R-B
10
GP GP
11
Karman Reynolds Re
1.2.
12
(1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11) (12) (13)
1
13
2 2-1.
N0
E0
�
0
000
�
�����N
Nor
EE ��
�
(1)
energy
�� 0
00
��N
N��
T1 T2
.
energy E0 N0
14
(2) flow
�E1 �E2 , �N1 �2
�E1��E2 , �N1��2
�����00 N
Nor
EE ��
�
�� flow �
||
15
2-2.
�(S)�
�(S) = (flux ) ( ) =
J��: � X� : �
( : Fick’s law )
(1)
J� X�
Fick’s law
( )
Fourier’s law
�, = 1,2, ,n L� : L���: etc.
0�� ��
� XJ
xnDJ��
���
0)( �� � � dVXJSP ��
�
xnDJ��
�� �� �
� Jxt
n��
����
���
�
���
����
����
��
�
���
TgradLJ.etc
xT
J TT
1�
� � XLJ ��
16
i j
(i) .
J = LX
L X .
L=L0 + L1X .
L L0Xi + L1XiXj 2
Onsager
L� �= L � (��� )
detailed balance . cyclic balance .
2fluxflow .
JT , JN (1) T1>T2, 1
0<� 20
I II t = 0 .
(2) T1 , T2 . (3) 1
!< 2!��
I II JN t JN 0 . 1
!> 10�"� 2
!< 20�
XT : #T �XN $� /T �
��� �
17
DT 0 (t !) JN =0 JT
�(S) = JTXT + JNXN > 0 JT = L11XT + L12XN JN = L21XT + L22XN
t !"���JN 0 L21XT + L22XN = 0
Onsager L21 = L12 �(S) = L11XT2 + 2L21XTXN + L22XN2
X�
% &
% &0
2
22
2221
2221
�
'�
'���
�
NT
NTconstTXN
XLXL
XLXLSX
�
dVXJdVSP ��
��� � ��� )(
dVJdXdt
Pd
dVXdJdt
Pddt
Pddt
PddtdP
tJ
tx
Jx
��
�
��
�
� ��
� ��
'�
���
����
��
���
����
��
dtdJ
Jd
dtdX
Xd
t
t
��
��
0(dt
Pdx
18
Onsager
Soret
Soret
J1, J2 Jq
(1)
% &
dtPddVJdX
dVXLdX
dVXdXLdVXdJdt
Pd
Jt
t
ttx
�� ��
� ��
� �����
�
� ��
� �
� ��
�
dtPd
dtPd Jx �
02 (�'�dt
Pddt
Pddt
PddtdP xJx
)*
)+
,
''�
''�
''�
qqqqqq
XLXLXLJXLXLXLJ
XLXLXLJ
2211
22221212
12121111
19
Soret X1=0 X20�� �
J1=L12 - X2
Soret Doufor
Onsager
L12 = L21, L1q = Lq1 = -L2q = -Lq2 (2)
(3)
L1q (thermodiffusion Soret ) Lq1 Dufour (diffusion thermoeffect)
J1
(4)
L1q Lq1
)))
*
)))
+
,
�#���
��
�#���
T)(
LT
TLJ
JJT
)(L
TT
LJ
Tqqqq
Tq
2112
12
2111211
�
�
- .extbaropSoret CCCCDJ #'#'#'#�� /1
20
% &
% &
!�#
���
��� #�
���
��� �#��
#��
tTTTs
TTJ
TTJs
q
q
,0
2
2
2
��
0��
�
�T : �P :
D12 :
Soret entropy production
t ! , J1 = 0
( 0 : )
extB
Pbarop
TSoret
Uk
C
PP
C
TT
C
#12
�#
#�#
#�#
exp
�
�
1�
1��
���
����
�#'#��
logddC
logddC
TT
CDJ
T
T
21
121
�
�/
% & % &
20
03
1
TTJ
dttJJVTk
D
q
mqB
T
0�� �#��
� �!
% & % & dttJJVTk qq
B�!
�0
2 03
1�
12DDS TT �
% &dVsV� �
% & % & % &% &
% &% &t,rT
t,rJ
t,rT
t,rTt,rJs T
q �
�
�
��
�#
�#
�� 12
21
entropy production
1.Onsager
( ) #1� ( )
2.
Jm 0, Jq = const. (0)
3. 4. (1) Soret
Soret
Soret
0
t1 P
P = 0 � (s) = 0
P 0 � (s) 0
X P
22
(Onsager )
X1 X2
P X1 X2
X X+3X�
3P�
3P ��0
(3) L
L 4=JX=LX2
X X + 3X flux J(t)
J(t)=L0 X(t) L0 Onsager
flux
J(t)=L X(t) + R(t)
R(t)
LL0
L
Onsager
q(t)
% & % & % & dseqsqk
LL si
B
55 �!
�'�00 01
% & % & % & si
B
eRsRdsk
L 55 �!
��0
01
23
1 Onsager 2
EHD
G.Gallavoti PRL, 77 (1996), pp.4334-7, “Extension of Onsager’s Reciprocity.” W. I. Goldburg et al. PRL, 87(2001), pp.245502-1-4, “Fluctuation and Dissipation in Liquid Crystal
Convection.”
No
!
Nu = S :
= S0 + q(t) + 6(t)
q(t) 6(t)
( )
24
q(t) 1 2
Nu
2 (1) Onsager (2)
2 (1) (short time scale)
( ) (2) (long time scale) ( )
( )
2-3.
(1)
25
i) i) kB1 �kB17
ii) ii)
iii) 1 iii)
F=U-TS 1 S=0
F=U S F=U-TS 0 S
U TS
US
26
8 (1) U (2) S
i) (1),(2) (U S ) : S U
ii) S U
(1),(2) (U S ) (2)
Rayleigh-Benard
�T qc
27
RB
1)
2.7.1
(2.7.3)
2)
3Ekinetic = ( ) +( (z )) < 0
% & % &% &
% &- . 0
1
2 ��#�
�
���
�
���
�#'9�##�
�
�
dVw
C
dVpuCTwSP
v
v
: :�
/0�
3/
:::��
0)( ���� dVXJSP ��
�
% & % &%& &
% &- . 02& ��#%%�
�
��������
��������
#'#%#%
�
�
dVw
C
dVppuC
wS%%P
vCC
vCC
: :�--/0�
3/
:w::�
% & 00
2 ����
��� �#� � dzw
d: :�
0 ���0
28
< >
; (3/ ~ �: ) thermal expansion
3)RB
w w u, v, w
shear dissipation shear rate �xw , �zu
�xw qxw qx
qx �zu �zu
- . 00
2, <'�� dzwgu
d
ji :�;
wgwgxuu
j
iji /3:� �
��
�,
% &w,v,uu ��
du
dw
29
shear dissipation shear velocity
qx
shear velocity energy dissipation rate =�d
(qx )
ns equation
0��'� wu zx
wu zx ��
dqw
udw
uqx
x �8
2dqw
du
ux
z�
% &223
2
2
1xx
z
qqd
wuud �� /;=
vvvvvv
vv
vvv21
2
2
2
9#9��
��
�8
#���
���
����
���
���
;//
;
ttme
t
tm
dtdeme
�
30
qx shear dissipation rate qx ��zu �xw
shear velocity =d /;�(��x2w)w
w = qx d u) /;�(qx
4 d2 u2 ) qx
4
qx ��zu ( shear) qx ��xw ( shear)
=d qx qx-2 qx
qx4
Rayleigh
w
:� :� heat flux
= 0
TTtT 2v #�#9'�� �
�
wt
d :�:'#�
�2
wd
wq
�
�
:22�� 22
31
4)Rayleigh Ra Prandle Prqx d
energy rate =b
=b g3/w = g/�:w
energy rate =;
22
2
2 0
wdg
wd
wt
b �
/�=
�
:
:�:
9
�'#���
% &2
2
2
ud
uuz
/;/;=; ��
22
22
ud
wdgb
/;=
�
/�=
; �
� w z g
u
32
qx d -1 w u
Rayleigh
=
Prandle Pr
Pr
Pr
etc
2
24
u
wdgb
�;
� ==
;
�
�;� 4dg
�8
TdgRa ���;� 4
2
2
2
2
;>?
>�?
�;
??
;
�
;
�
d
d
Pr
�
�
��
33
2-4. 2-4-1.
L I a rod with the diameter L. 5 cm
1 R = 140
A.2
@LU
R9
�
� 140
34
U : L : ; :
U = 10 m/s, L 104 – 105 m ; 10-5 m2/s
Re 1010 !!
: reduction ( )
;U
Re �
3
22
10
10
e
T
R
smA
� ;;
sunshine U T
T+ T
35
Intermission
1750
40 30
2-4-2. (1)
F = m� = mv (4.1) �
U
F = -grad U
t -t
(4.2) : ( )
(2) i)
A + B C (4.3) [A] = CA
[B] = CB
(4.4) ii)
(4.5) t -t
(4.6)
Ugraddt
xd��2
2
Ugraddt
xd��2
2
)( ttCCkdt
dCCCkdt
dCBA
ABA
A ���B��
.)'(02 eqsFickDCDtC
C#���
)(02 C#���� DCD
tC
36
iii)
(4.7) (4.8)
t -t
k, D, �
D��
2-4-3.
Brown
:Langevin eq. (4.9)
: Newton
: (4.10)
t -t v -v f(t) f(-t)
2
i) f(t) ( 2 ) ii) v(t) ( 1 )
i) 2
ii) 1
Stoke s law (4.11) a : � :
i),ii) m M (
)
)(
.)'(0
2
2
1#���1�
��
C1#��1�
�
��
t
tt
eqsFouriert
FtfFext
�''E�� )(vv�
)(vv tf'E���
)(vv tf'E��
Ma�>6
�E
37
(M )
(m )
?M ?m
i) t ?M f (t) (4.12)
(4.13) : f(t) v(t) (M m ( ) ( ))
v(0) Langevin eq. (4.14)
(4.15)
Langevin eq.
(4.16) mpp( )
E�
1M?
'� Om?
0)0(v)(
)(2
)()(2
0
�
F��F
tf
ttM
Lktftf B 3
)0(v)()0(v)(v)0(v)(v tfttdtd
'E��
)(v)0(v)(v
)0(v)(v)0(v)(v
20 M
t tet
ttdtd
?��8
E��
E�
�t
tdt
0
��E��E� '�
t
t
sttt dssfetet0
)(0
)0( )()(v)(v
38
t0
(4.A1)
t 0
(4.A2)
v(0) v(0) <v(0)v(0)> = <v02>
(4.A3) (4.12)
(4.A4)
(4.A5) (4.A6) (4.A7)
(4.A8)
0)()0( ��� �!!'E��E� eee ttt
dssfet st )()v(t
-
)(�!�E��8
dssfe s )()0v(0
-�!E��
)()()0v(0
-
0
-
2 sfsfesdds ss FF� � �!
FE'E
!
2
0020
)(0 0
0
0
2
)(2
)(2)()(
M
LkedsLk
ssesddsLk
ssLksfsf
BsB
ssB
B
E��
F�F�
F��F
�� �
!�
E
F'E
!� !�3
3
T
Tv
Tv
T21
v21
0
2
020
20
20
ML
Mk
M
LkM
k
kME
BB
B
B
�E8
�E
�
�
��
2
0
02
2
)(2
)()()()(
M
Lk
dtttLM
ksdsfsftdtftf
B
B
�
F��FF�FF ���!
!�
!
!�
!
!�3
39
(4.A9)
L0 (4.A7)
(4.A10)
(4.A11)
E� f(s)
(4.16) v(t) 1
(4.17)
(4.18) 2
(4.19)
(4.20)
(4.21)
sdsfsfk
M
sdsfsfk
ML
B
B
FF�
FF�
�
�!
!
!�
0
2
20
)()(
)()(2
sdsfsfkM
sdsfsfk
MMM
L
B
B
FF�
FF91
�1
�E
�
�!
!
0
0
20
)()(T
)()(1
% & - .% & - .�
���E�E�
�E�E�
E'�
E��
E'�
E'��
tstt
tstt
t
dssfextx
dssfextxdtt
0
)(00
0
)(0
00
)(e-11
1v
)(
)(e-11
1v
)()(v
% & % &
���
����
��CC9�
���
����
��'�'��
��
����
��� ���
E?
E1
EEEE1
EEEE
12
14321
v 222
020
MB
ttBt
ttMk
eetMk
ex)t(x
% &t
xtxD
t 2
)(lim
20�
�!�
E�
E
1�
E
19�
!�
20v
221
limMk
tMk
tD BB
t
40
4.2
(4.A12)
: (4.22)
: (4.23)
t s ?M
!!
D kBT E� kBT T 0 : D 0 but E 0 ii) ?M t ?m Langevin eq.
tet E�� 20v)0(v)(v
E���
���� �
E��
���
���
E��
!E�
!
�202
0
0
20
0
vv0
1
v1
)0(v)(v tedtt
�!
�80
)0)v(v( dttD
�!
FF1
�E0
)()( sdsfsfkM
B
Ma
tfdtd
ak
DCDtC B
�>�>
6)(v
v6
2
�E�'E��
1��#�
�
�
)()v()(v
0tfstsds
dtd t
'��� � G
41
4.3 :
0 ( ?M t ?m )
t -t
s = -?�
? s �
1) 2)
( )
!
Onsager : Lij = Lji
Lij = Lij
0 + 3Lij
)(v
)0()()(
20
tftf
s �DD GG
)()(
vvv
v-v
tftf
dtd
dtd
dtd
��
���
����
�
�
���
�
GG
)(v)(
)(v)(
)(v)()(v)(
0
0
00
stsds
std
stsdsstsds
t
t
tt
��
��
'���
�
�
��
G
?G?
GG
42
4 Navier-Stokes random force
t -t v -v
Lagrangian picture r1 r2
r1 (Euler picture)
)(1
)(vvvv 2
0 tfPtFt
'#''#�#9'�
� ������
/;
)(vvvv 2
0 tft
'#�#9'�
� �����
;
vv���
9#9
DtDv�
t��v�
rd� v�d
vvvvvv
�����
���
gradgradtr
t
gradrdd
9�9��
���
8
9�
43
Fig. 11. Comparison of the trajectories of a Brownian or subdiffusive random walk (left) and a Lvy walk with index = 1.5 (right). Whereas both trajectories are statistically self-similar, the Lvy walk trajectory possesses a fractal dimension, characterising the island structure of clusters of smaller steps, connected by a long step. Both walks are drawn for the same number of steps (approx. 7000).
G. M. Viswanathan, H. E. Stanley, Nature, 381(1996)413
Fig.4. a, Possible flight path of a bird constructed from the longest time series, as described in the text. The time resolution of the data prevents us from considering changes in fright directions which occur more frequently than once per hour. b, Possible flight path given by the Lvy-walk model discussed in the text. Both flight paths have scale-invariant 'fractal' properties which may indicate that the distribution of food on the ocean surface is spatially scale invariant. FIG. 1 The longest of the 19 time series, with a length of 416 h. Each point in the time series gives the number of 15-s intervals in each hour for which the animal was wet for 9s or more.
44
=�= 0.1
correlation time
? 10s
total time for ex.
500 ?�
= =
Navier – Stokes equation Reynolds Re ;0#2v
;0#2v 0 Navier-Stokes equation
DtDv�
vvv ���
gradt
9'��
0vvv�#'
�� ����
t vv ���#
45
( :0.2cm 100m) 105
life time ?e ?e ?1?1�
Analogy ?m ?e E�7 ?1�
;eff = ;0 + 3; HI I �
EHD �eff = �0 + 34�������( ) BZ keff = k0 + 3k ( )
(1)
(2) (3) ( )
vv ���#
kdkver rki���� ��
)()(v � 9�
% &
% &� �
� �
��
�F��FF
FFFF�#
�9
FFF9FF'F
11
11
11vv
,
vvvv
kkdkei
kkkkk
kdkdkei
kkkrki
kkrkki
�����
�����
�������
�����
���
11vv kkk
�����
�
46
2 (1) Onsager (2)
2 (1) (short time scale)
( ) (2) (long time scale) ( )
( )
N
47
3 3-1.
d :�
-��(d ):
:
:�:: : sin2 gdMMd '��� ���
:��2Md : : ��� <<2Md
0�:�
���
����
�����
gMD
Ddd
gM �::�
: sinsin
% &Dd
dd
DDd
c
c
�
�J�
�
�*+,
KIL
'���
��� �
��
6
,0
0611
61sin
2
3
:
:
::
:::
48
49
3-2.
(1)
% &
% & % &
% & 42
3
41
21
xxxU
xUxd
d,xf
xx,xftdxd
'��
��
'���
=
=
==
=�� f (x, =�) = 0
=J�� Jss x,x 00
xsJ = = 0 xs0
(pitch-fork bifurcation) ( supercritical bifurcation)
'��'�� �� 202
2 xxdtdx
J��'� Jxx,x 02
50
�<0 xs (subcritical)
(2)
�= 0
x1 ��M�
(=�= 0, x2 = N2 , 0 )
N2 N2 > 0 transcritical pitchfork N2 < 0 hysterisis pitchfork
32
2 xxxdtdx
�'�� �=
032
2 ��'�� � xxxdtdx =
���
��� �J� �� =4
21
22
22x
51
(3)
(a)��N�> 0, ��> 0, A0 = 0 (normal bifurcation)
(b)��N�< 0, ��> 0, A0 = 0 (inverted bifurcation)
(c)��N�> 0, ��> 0, A0 0
( A0 < 0 )
( A0 > 0 )
(d)� �� � O�� 0 �� � ��� �O� 0
growth rate
O'�
'���� �i
Axxxdtdx
=�
� 053
=EEOE� 9�F'F� i
52
(4) a) Type I
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73
E. Simonotto et al., Phys. Rev. Lett., Vol.78, No.6, pp.1186-1189(1997)
3-5-2.
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D. F. Russell, L. A. Wilkens, F. Moss, Nature, Vol. 402, pp. 291-294(1999)
79
Chaos, Vol. 8, No. 3, p. 599-603(1998)
Physical Review E, Vol. 56, No. 1, p. 923-926(1997)
A.Priplata et al., Phys.Rev.Lett.89, (2002)238101-1
80
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K.Harada, S. Kai et al., IEICE trans., Vol.74, No.6, pp.1486-1491(1991)
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Fig. 2. Rearrangement of the stripe pattern of Pomacanthus imperator (horizontal movement of branching points) and its computer simulation. a, An adult P. imperator ( P�7M�months old ). b, Close-up of region I in a. c, d, Photographs of region I of the same fish taken two (c) and three (d) months later. e, Starting stripe conformation for the simulation (region I). f, g, Results of the calculation after 30,000 (f) and 50,000 (g) iterations. h, Close-up of region II in a. i-l, Photographs of region II of the same fish taken 30 (i), 50 (j), 75 (k) and 90 (l) days later, respectively. m, Stating stripe conformation for the simulation (region II). n-q, Results of the calculation after 20,000 (n), 30,000 (o), 40,000 (p) and 50,000 (q) iterations, respectively. Fish (Fish World Co. Ltd (Osaka)) were maintained in artificial sea water (Martin Art, Senju). Skin patterns were recorded with a Canon video camera and printed by a Polaroid Slide Printer. In the simulated patterns, darker colour represents higher concentrations of the activator molecule. Equations and the values of the constants used, as Fig. 1. Kondo: Nature Liesegang-Ring Formation
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Figure 17. The new phase of rhythmic activity in cardiac pacemaker cells, electrically stimulated at each old phase, replotted from unpublished data of Jalife (1975). The action potential occurs at phase 0.
148
Figure 18. The new phase of the flashing rhythm in fireflies of three species perturbed by the sight of their own flash at various old phases. The flash occurs at phase 0 on this scale. Each box is exactly on cycle by one cycle. Replotted from Hnson (1978, Figure 7)
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Figure 3. Excess mitotic delays induced by 30-min pulses of 10 g/ml cycloheximide. (abscissa) Fraction of cell cycle completed when pulses begin. Mitosis at 0 and 1.0. DNA synthesis ends around 0.3. (ordinate) Excess delay (delay in excess of pulse duration) plotted as fraction of a control cell cycle. (From Scheffey and Wille, 1978, Figure 1, with permission.)
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Fig. 4 The simultaneous representation of the traces of the alpha component. The “start” represents application of the photic stimulation.
f0 : flash : 10 Hz Fig. 1 The international 10-20 electrode system. Top view of the scalp. The upper part is the front of the head. The abbreviations are as follows : Fp; frontal pole, F; frontal, C; central, T; temporal, P; parietal, O; occipital.
Fig. 2 The alpha spectra from O2 to Fp2: (i) at rest, (ii) under 10Hz photic stimulation. K. Harada, et al. IEICE trans., 74(1991)1486
166
4 Phaseolus coccineus 15
5 Canavalia ensiformis KLEINHOONTE 1929 10 18
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Fig. 5 The “on”-responses to the stimulation ; (a) the amplitude, (b) the phase and (c) the phase difference between posterior and anterior and regions.
Fig. 6 The “off”-responses of the amplitude (a), the phase (b) and the phase difference (c). The “last stim.” presents removal of the stimulation.
167
62 Chenopodium amaranticolor KÖNTIZ
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168
circadian rhythm Fig. 2 Time course of reentrainment of circadian rectal temperature rhythm to an 8-h phase-advanced schedule of sleep and social contacts. Top trace: with bright light; bottom trace: without bright light.
169
Fig. 3 Time courses of orthodromic reentrainment of circadian melatonin rhythm to an 8-h phase-advanced schedule of sleep and social contacts (subject YA). , With bright light; , without bright light. Shaded areas indicate the rest time, and horizontal open bars represent time of bright light exposure.
Fig. 6 Time courses of antidromic reentrainment of circadian melatonin rhythm to an 8-h phase-advanced schedule of sleep and social contacts (subject KA). See Fig. 3
Fig. 5 Time courses of antidromic reentrainment of circadian melatonin rhythm to an 8-h phase-advanced schedule of sleep and social contacts (subject AI). See Fig. 3 legend.
Fig. 4 Time courses of orthodromic reentrainment of circadian melatonin rhythm to an 8-h phase-advanced schedule of sleep and social contacts (subject IS). See Fig. 3 legend.
170
Circumnutation
Circummutation
Circadian Rhythm
171
Fig. 77 8:8 Canavalia ensiformis KLEINHOONTE 1929
502 - 512
Fig. 79 6:6 Canavalia ensiformis KLEINHOONTE 1929
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Chaos, Vol. 8, No. 3, p. 599-603(1998)
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