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ESCUELA MILITAR DE INGENIERAMCAL. ANTONIO JOS DE SUCRE BOLIVIA

EMPRESA MILITAR DE REFINACIN (EMR)

Gerene! ING. C"RISTIAN FERNANDO CULLAR MONTA#O

D$re%&r! ING. JUAN PABLO ESTI'LE PE#A

Jee e &*er+%$&ne,! ING. MANSOORE" ALABAI'I NAINI

S+!ING. SUBT. JAVIER "CTOR GME-ING. 'AT"IA DVILA FERNNDE-

ING. TAMARA SERRATE ARA/-ING. MILTON "O0OS LPE-

ING. 'EVIN DE LA -ERDA A0ALAING. MANUEL ALEJANDRO LINO RODRGUE-

D&%ene! ING. ORLANDO MELGAR

SANTA CRU-1 2345

GERENCIA "IDROTERMINADO

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Pgina 2de 46

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ESCUELA MILITAR DE INGENIERA M%+6. An&n$& J&,7 e S8%re Un$+ A%+79$%+ S+n+ Cr8:

"OJA DE REVISION

FEC"AOBSERVACION AUTORIDAD FIRMA

D M A

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NDICE

4. INTRODUCCIN2. "IDROTERMINADO

;. "IDROTRATAMIENTO3.1 PRINCIPIOS BSICOS3.2 FINALIDAD DEL HIDROTRATAMIENTO3.3 OBJETIVOS Y APLICACIONES3.4 IMPORTANCIA DEL PROCESO DE

HIDROTRATAMIENTO3.5 RANGO CARACTERSTICO DE LAS VARIABLES DEL

PROCESO3.6 HIDROTRATAMIRNTO DE NAFTAS3.7 HIDROCRAING3.! REACCIONES PROD"CIDAS D"RANTE EL

HIDROTRATAMIENTO3.!.1 H#$%&$'()*+)%,-#/3.!.2 H#$%&$'(/#0%&'/,-#/3.!.3 H#$%&$'('0,*,-#/3.!.4 H#$%&'/,-#/ $' ,%&0#-&(3.!.5 H#$%&$'('/,-#/3.!.6 H#$%&'/,-#/ $' &*'&+#/,(3.!.7 H#$%&-%,)'&

3. VARIABLES DEL PROCESO DE

HIDROTRATAMIENTO3..1 C&/$#-#/ $' &'%,-#/3..2 T''%,0)%,3..3 P%'(#/ ,%-#,* $' 8#$%'/&3..4 V'*&-#$,$ '(,-#,*3..5 R'*,-#/ 829-,%,3..6 T#& $' -,0,*#:,$&%'( )0#*#:,$&( '/ '* %&-'(&3..7 F&%, $' *&( -,0,*#:,$&%'(3..! A-0#;,-#/ $'* -,0,*#:,$&%3.. D'(,-0#;,-#/ $'* -,0,*#:,$&%

3.1< IMPACTO AMBIENTAL3.11 N"EVAS TECNOLOGAS

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BIBLIOGRAFIA

4. INTRODUCCIN

E* '0%*'& ,$'( $' ('% )/, ':-*, -&*'=, $' 8#$%&-,%>)%&(?

-&/0#'/' )/, %,/ ;,%#'$,$ $' -&/0,#/,/0'( & '*''/0&( #/&%/#-&(

-&& ,:)+%'? /#0%'/&? &@'/&? ;,/,$#&? /@)'*? &-,(#&/,*'/0'?

8#'%%&. E(0&( '*''/0&( )/#$&( , *, ,*0, ;#(-&(#$,$ $' *&( '0%*'&(

'(,$&(? 8,-'/ /'-'(,%#& () '=&%,#'/0&? &0#;& &% '* -),* (' )0#*#:,

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)/ %)& $' %&-'(&( $'(,%%&**,$&( ,%, *, $'* '0%*'& )' 8,/ (#$&

,*#,'/0' '*',$&( ,%, (,0#(+,-'% *,( $',/$,( ,>#'/0,*'(

-,$, ;': ( '(0%#-0,(.

"/& $' *&( %&-'(&( )' 8, ;'/#$& -&>%,/$& ,&% #&%0,/-#, $'/0%&

$' *&( %&-'(&( #/$)(0%#,*'( '( '* %&-'(& $' H#$%&$'()*+)%,-#&/? '* -),*

-&/(#(0' '/ %'$)-#% *, -,/0#$,$ $' ,:)+%' )/, #)%':, -&/0,#/,/0'

)' (' '/-)'/0%, '/ '* '0%*'& $'($' () +&%,-#/ '/ '* ()>()'*&.

E(0' ,:)+%' (' '/-)'/0%, -&>#/,$& -&/ &0%&( -&)'(0&( )@#-&(?

)' (# /& (' '*##/,/? ,* '(0,% %'('/0'( '/ *, -&>)(0#/ $' *&(

,)0&;#*'( & ,%0'+,-0&( )' )0#*#-'/ ,(&*#/, & $#('*? -,)(,%@, )/,

-&%%&(#/ '/ *&( &0&%'( & '/;'/'/,#'/0& $'* #(& ,* #(&0#'& -&/0,#/,%@, ,* ,>#'/0'.

A-0),*'/0' )/, $' *,( %#/-#,*'( %'&-),-#&/'( , /#;'* )/$#,* '( '*

-%'-#'/0' @/$#-' $' -&/0,#/,-#/ '/ 0&$&( *&( >#0&( $' *, /,0)%,*':,

,#%'? ,),? 0#'%%, *, -),* '(0 $#%'-0,'/0' ;#/-)*,$, -&/ *,(

,-0#;#$,$'( #/$)(0%#,*'( 0'/$#'/0'( , (,0#(+,-'% *,( /'-'(#$,$'( $' *,

(&-#'$,$. E( #&%0,/0' $'(0,-,% )' , '$#$, )' '* -%)$& '( (

'(,$& '* -&/0'/#$& $' -&/0,#/,/0'( -&& '* ,:)+%' '( ,&%? &% *&)' (' 8,/ '/'%,$& $#;'%(&( '(0)$#&( ,%, $#(#/)#% () -&/0'/#$&

)(,/$& -,0,*#:,$&%'( -&'%-#,*'( , >,(' $' M& M&*#>$'/& '/ '*

%&-'(& $' HDS. A$'( $' () #&%0,/-#, ,>#'/0,*? '(0&(

-,0,*#:,$&%'( 0#'/'/ *, -,,-#$,$ $' %'$)-#% *, -&%%&(#/ $' *&( ')#&(

&0&%'( $&/$' (' )(,/ '(0&( 8#$%&-,%>)%&(.

2. "IDROTERMINADOE* 8#$%&0'%#/,$& '( )/ %&-'(& $' ,-,>,$& )' (' $#;#$' '/ 2

%&-'(&( '* 8#$%&0%,0,#'/0& '* '/$)*:,#'/0&.

;. "IDROTRATAMIENTO

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;.4 Pr$n%$*$&, B)%&( -&/ (,0)%,-#/ *##0,$, $'

,%&0#-&(. A(@? ,)/)' *, %#/-#,* +)/-#/ $'* 8#$%&0%,0,#'/0&

'( *, $'()*+)%,-#/ $'* -%)$&? (' )'$'/ **',% , -,>& 0,>#/

$'(/#0%&'/,-#&/'(? $'($,-#&/'(? 8#$%&'/,-#&/'( -%,)'&(

$' 8#$%&-,%>)%&(. "/, ;': $'0'/#$, *, %',--#/? *&( '0,*'(

'%,/'-'/ '/ *, ()'%+#-#' $'* -,0,*#:,$&% #'/0%,( )' '* %'(0&$' %&$)-0&( (&/ '0%,@$&( $'* %',-0&%. E(0' '+*)'/0' '( '/+%#,$&

,/0'( $' **',% , )/ (',%,$&%? $&/$' (' (',%, '* -%)$& 0%,0,$&

$'* ,( %#-& '/ 8#$%'/&. E/ )/, -&*)/, $' %'-0#+#-,-#/ ('

,&0, '* -%)$& $' -),*)#'% ()*+)%& $' 8#$%'/& %',/'/0' $'

*,( -&*,( *#'%,(? '* ,( (' 0%,0, ,%, '*##/,% '* ()*+)%& $'

8#$%'/&. L, %#/-#,* ;'/0,=, $' '(0' 0%,0,#'/0& %,$#-, '/ ()

&-, ('*'-0#;#$,$? $' +&%, )' (' $'()*+)%, )/ ,*#& %,/& $'

0#&( $' -&)'(0&( &%/#-&( ,:)+%,$&(? '* '*';,$& %,$& $'

-&/&-##'/0& ' #*,/0,-#/ $' '(0, 0-/#-,. A-0),*'/0'? 2,%%#*'( $' -%)$& $' '0%*'& (&/ 0%,0,$&(

$#,%#,'/0' '/ '* )/$&? )(,/$& 0''%,0)%,( ()'%#&%'( , *&(

3)%&(

#/(,0)%,$&( &*'+#/,(? $' *,( +%,--#&/'( $' '0%*'& *@)#$,(?

-&& *, ,(&*#/, $' $'(0#*,-#/ $#%'-0,.

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N&%,*'/0'? '* 8#$%&0%,0,#'/0& (' %',*#:, ,/0'( )' &0%&(

%&-'(&( -&& *, %'+&%, -,0,*@0#-,? ,%, )' '* -,0,*#:,$&% /&

(' -&/0,#/' -&/ *, -,%, $' ,0'%#,* /& 0%,0,$&. E*

8#$%&0%,0,#'/0& (' )0#*#:, 0,>#/ ,/0'( $'* -%,)'& -,0,*@0#-&

,%, %'$)-#% '* ,:)+%' '=&%,% '* %'/$##'/0& $' %&$)--#/? ,(@

-&& ,%, '=&%,% *,( +%,--#&/'( #/0'%'$#,( $' '0%*'&

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,(*'&( $' -,*'+,--#/.

;.; O=>e$?&, @ +*6$%+%$&ne, e6 "$r&r++9$en&!

L&( &>='0#;&( (' )'$'/ ,%),% '/ +)/-#/ , *,( %',--#&/'(

%#/-#,*'( & $'(',$,( )' 0#'/'/ *),% R'&-#/ $' -&/0,#/,/0'( -&& ,:)+%'? /#0%'/&? &@'/&?

'0,*'(? '0-. E/ '(0, -*,(#+#-,-#/ (' #/-*)'/ *&( %&-'(&(

-), %,:/ $' '*##/,% *,( #)%':,( '( '=&%,% *, -,%, )'

*)'& ('% ,*#'/0,$, , &0%&( %&-'(&( '='*& $' '(0&( (&/

'* %'0%,0,#'/0& $' *, ,*#'/0,-#/ , %'+&%,-#/ -,0,*@0#-,?

'* %'0%,0,#'/0& , *, -,%, , 8#$%&-%,)'& -%,)'&

-,0,*@0#-&. I),*'/0'? '#(0'/ 0#&( $' %&-'(&( '/ *&( )' *,

%'&-#/ $' *&( -&/0,#/,/0'( (' **';, , -,>& , &>='0& $'

'=&%,% *, -,*#$,$ $' *&( %&$)-0&( 0'%#/,$&( -&& $#('*?

)'%&(/? %'(#$),*'(? ,-'#0'( *)>%#-,/0'(? '/0%' &0%&(. C&/;'%(#/ $' -&)'(0&( , &0%&( '/ '* #(& #/0'%;,*& $'

0''%,0)%, $' '>)**#-#/. A*)/&( '='*&( (&/ '*

8#$%&0%,0,#'/0& $' *,( ,(&*#/,( ,%, -&/;'%0#%? &*'+#/,( '/

,%,+#/,( %'$)-#% '* /'%& $' >%&&? *, (,0)%,-#/ $'

8'0'%&,%&0#-&( $'* -&>)(0#>*' )'%&='0 ,%, '=&%,% ()

)/0& $' 8)&. C&/;'%(#/ $' +%,--#&/'( , &0%,( $' '/&% )/0& $'

'>)**#-#/. E/ '(0' 0#& $' %&-'(&( (' #/-*)' '* 8#$%&-%,)'&

$' %'(#$)&( ,%, %&$)-#% $'(0#*,$&( '$#,/&( *#;#,/&(? '*

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,(&*#/,? '* 8#$%&-%,)'& $' /,+0, ,%, &>0'/'% %&,/&

>)0,/&.

E/ '* %&-'(& $' 8#$%&0%,0,#'/0& '* +*)#$& ;, $'($' '* %',-0&%

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*&( ( *#;#,/&(? ()*+)%& $' 8#$%&'/&? )/, ')'K,

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8#$%&0%,0,$& (,*$% &% *, ,%0' #/+'%#&% $' *, 0&%%'.

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D'>#$& , *, %,/ $#;'%(#$,$ $' -&)'(0&( %'('/0'( '/ '*

'0%*'&? (' )'$'/ %'('/0,% %,/ ;,%#'$,$ $' %',--#&/'(

)@#-,( '/ *&( %&-'(&( $' 8#$%&0%,0,#'/0&. E* -&/=)/0& $'

%',--#&/'( -&*'=,( )' (' $'(#/, -&& HDT (' $'(-%#>'/

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H#$%&$'()*+)%,-#/ HDS? )' -&/(#(0' '/ '*##/,% 0&&( $'

,:)+%'. H#$%&$'(/#0%&'/,-#/ HDN? %')';' *&( 0&&( $'

/#0%'/&. H#$%&$'('0,*,-#/ HDM? -&/(#(0' '/ %'&;'% 0&$&( *&(

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#&%0,/0'( $'/0%& $' *, %'+#/,-#/ $'* '0%*'&. E* %&(#0& $'*

HDT '( ,/'=,% *,( $#+'%'/0'( +%,--#&/'( $'* '0%*'& 0,*'( -&&

/,+0,(? $#'('* ,(*'&( %&;'/#'/0'( $' *, 0&%%' $' $'(0#*,-#/

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-&/0,#/,/0'( 0,*'( -&& ,:)+%'? /#0%'/& ,*)/&( '0,*'(.

D' ,)@ *, %,/ #&%0,/-#, $'* HDT? , )' ,* %'&;'% '* ,:)+%'-&/0'/#$& '/ *&( 8#$%&-,%>)%&( (' ';#0,/ %&>*',( $' C&%%&(#/ $'* ')#& $' %&-'(&. D#(#/)-#/ $' *, -,*#$,$ $'* %&$)-0& 0'%#/,$&. E/;'/'/,#'/0& $' *&( -,0,*#:,$&%'( $'* %&-'(& $'

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C&/0,#/,-#/ ,0&(+%#-, -),/$& (' '*',/ -&&

-&>)(0#>*'( , )' )'$'/ ('% '* &%#'/ $' **);#, ,-#$, .

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E* &>='0#;& %#/-#,* $'* 8#$%&0%,0,#'/0& $' /,+0,( '(

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S&/ %&-'(&( $&/$' (' 8,-' %',--#&/,% 8#$%'/& -&/

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;. "$r&%r+%$n H I,&9+

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;.K REACCIONES PRODUCIDAS DURANTE EL

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