industrial use of electron beam in the area of ... · the area of environmental protection,...
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Industrial Use of Electron Beam in
the Area of Environmental Protection,
Material Modification and Food
Processing
Sylwester Bulka, Yongxia Sun, Andrzej G. Chmielewski
Institute of Nuclear Chemistry and Technology,
Warsaw, Poland
naphtalene acenaphtene anthracene fluoranthene
pyrene benzo(a)pyrene dibenzo(a,h) anthracene
PAH treatment
Fig.19. Dioxin removal by EB from waste incinerator
150 t
solid
waste
produce
40,000
m3/h flue
gas
(Hakoda T. et al.)
Self-shielded type and Curtain
beams
300 keV max. and 40 mA max.
Electron accelerator &
Irradiation vessel
Fig.20 Dioxins removal
(MUNICIPAL WASTE INCINERATION JAERI, Takasaki, Japan)
House for test
Stack
VOCs removal by EB
EB, EB + catalyst
Most are lab-based experiments, pilot
test was performed by Prof. Kim from
Konkuk Uni. , ROK.
EB/Catalyst Konkuk , ROK
Acceleration of
Electron
Irradiation of
Electron
Activation of Catalyst
& Oxidation of
by-Products
VOC Removal by
Radical Reaction
N2, O2, H2O, etc.
e-
OH , N , H , HO2 , O
radicals VOC
CO2 , O3 , By-
products
VOC Decomposition by EB
e-
Oxidation by Catalyst
radical
Surface Activation
Surface Reforming
Oxidation of by-products
& VOC
Catalyst O3
Oil fuel combustion off-gases
Electron beam flue gas treatment (EBFGT)
technology for simultaneous removal of SO2
and NOx from combustion of liquid fuels
Ahmed A. Basfar , Osama I. Fageeha , Noushad Kunnummal ,
Seraj Al-Ghamdi ,Andrzej G. Chmielewski , Janusz Licki ,
Andrzej Pawelec , Bogdan Tyminski , Zbigniew Zimek, FUEL,
2007
Fig.26. Saudi Arabia pilot plant process units
1. Ammonia addition, 2. EB-TECH mobile unit, 3. cyclone,
4. cartridge filter 5. ID fan 6. stack
Cl- 0.0012 0.0068 0.0032
NO3- 0.35 0.44 0.34
SO42- 78.19 79.24 79.63
NH4+ 21.16 20.28 20.00
Na+ 0.258 0.025 0.015
Mg2+ 0.0047 0.0045 0.0012
Ca2+ 0.027 0.014 0.012
Element Concentration, mg/kg
Arsenic <0.02 <0.02 <0.02
Cadmium <0.003 <0.003 0.023
Chromium 0.27 0.13 0.90
Cobalt 0.02 0.02 0.04
Lead 1.03 0.45 1.56
Mercury <0.03 <0.03 <0.03
Nickel 29.8 58.5 102.3
Zinc 12.9 28.4 13.6
Table 3. By-Products
Fulfilled heavy metal requirement for fertilizer
EBFGT for NOx removal from flue gas
emitted from diesel engine
Cargo ships
SO2 emission NOx emission
Fig. 33 SO2 and NOx emission from cargo ship
Summary
EB can be applied for mutilple pollutants
treatment (SOx, NOx, VOCs, PAHs and
dioxins) from flue gas.
EB + catalyst is better effective for VOC
removal than EB or catalyst.
Industrial Use of Electron
Beam in the Area
of Environmental Protection
Material modification
Food processing
Modification of biodegradable polymers for practical
applications (as Green products)
•Crosslinking to improve thermal deformation of Dummy Lens
•Crosslinking to synthesize hydrogel for Washi improvement and
Soil Conditioner
•Degradation to synthesize Plant Growth Promoter
Environmentally-friendly products
Products for environmental remediation
Production of metal adsorbents using Graft polymerization
Development of Radiation Processed
Environment-friendly Products
•Crosslinking of Poly-lactic acid with 3 wt %
Triallyl isocyanurate to (TAIC) at 20-50 kGy to
improve thermal deformation of Dummy Lens (>
60C, deformation)
Ref.: M. Tamada,
TARRI, Japan
Obtained hydrogel
1. Swell hundreds times in water without dissolving
2. Water is not released by pressure
3. Biodegradability is maintained after crosslinking
Crosslinking of Cellulose Derivatives
30-70% Carboxymethyl cellulose(CMC) at 50 kGy
dose
Development of Radiation Processed
Environment-friendly Products
•super water absorbent (SWA) (Carboxymethyl
cellulose gel) can be applied for soil conditioner in
arid area, addition 3 % dry SWA to sandy soil in
arid area, available soil water content increased 2
times
3% SWA, 31 tons/ha
0% SWA, 19 tons/ha
Ref.: M. Tamada,
TARRI, Japan
Development of Radiation Processed Environment-
friendly Products
•Decomposed marine polysaccharides such as
chitosan from crab and shrimp shells play role of the
plant growth promoter (PGP) in shoot elongation and
harvesting yield. 30-60% increase of harvesting yield
of rice, chili, potato, carrot etc. In Asian country.
Industrial Use of Electron
Beam in the Area
of Environmental Protection
Material modification
Food processing
Industrial Use of Electron Beam in the
area of food processing
Purpose of food irradiation
Prevention of foodborne illness
Preservation - to destroy or inactivate organisms that
cause spoilage
Delay of sprounting and ripening of fruits and
vegetables to increase longevity
Sterilization- for hosptial patients
Ref.:U.Gryczka et al., „Application of electron beam accelerators for food
irradiation”, p.50-58, in „the industrial and Environmental application of electron
beams”, ISBN: 978-83-933935-7-2.
Facility Location
BGS Beta-Gamma-Service
GmbH & Co, KG
Bruchsal, Germany
BGS Beta-Gamma-Service
GmbH & Co, KG
Wiehl, Germany
Ionmed Esterilización SA Tarancón, Spain
Ionison SA Chaumesnil, France
Ionison SA Dagneux, France
INCT Warsaw, Poland
Electron beam facilities approved for
food irradiation in the EU