kvalitet vazduha u r srbiji, 2011

55
Република Србија Министарство енергетике, развоја и заштите животне средине Агенција за заштиту животне средине Годишњи извештај о стању квалитета ваздуха у Републици Србији 2011. године

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Kvalitet Vazduha u Republici Srbiji, 2011 godine

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  • ,

    2011.

  • ,

    2011.

    , 2012.

  • :

    , :

    , ..

    2011. : .............................................. , . . :

    ................................................. , ..; -, ..; , ..; , ..

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    : ........................................................... (: . ) ; (: . )

    :

    : 300

  • 2011.

    3

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    () ..................................................................................................................................... 6

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    2011. .. 9

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    SAQI_11 .............................................................................................................................................. 15

    2011. ....................................................................................................................................................... 17

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    .................................................................................................................................................................................... 20

    10 .......................................................................................................................................................... 23

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    ....................................................................................................................................................................... 30

    2011. ............................................................................................................................................. 31

    : CO, SO2, O3, NO2 PM10 ........................................................................................................ 34

    .............................................................. 36

    .............................................................................................................................................................................. 40

    2011. ............................................................................... 42

    ........................................................................................................................................................................................... 46

    :

    ...................................................................... 47

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    .................................................................................................................................................................................... 50

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  • 2011.

    4

    (. . .36/09) 2008/50, (DIRECTIVE 2008/50/EC on ambient air quality and cleaner air for Europe), , . . : (. . .11/10 75/10), (. . . 58/11), (. . . 58/11)...

    (. . .36/09) II , VII VIII (. . .72/12).

    67. . . , , , .

    , . , . , , .

    (. . 135/04, 36/09, 36/09) a , , (. . . 91/10) e (. . . 71/10).

  • 2011.

    5

    , , , . o , , 2011. 408.8 kt. 7% . , , .

    2012. , 2011., , , , , - , , .

    2011. 25 x 25 km /, 1.

    1. , t/ , , 2011. ; 25 25 () ()

    e, , , .

    jzHighlight

    jzHighlight

  • 2011.

    6

    , 2011. 67.7 kt 15% . , , .

    , , , , , , Lafarge, U.S. Steel Serbia, -, - .

    2011. 2.

    2. , t/, , 2011. ; 25 25 () ()

    ()

    , , , , . , , 2011. 24.9 kt. : , , , , , -, .

    2011. 3.

    jzHighlight

  • 2011.

    7

    3. , t/, 2011. ; 25 25 () ()

    A . 2010. . 2011. .

    , 2006. (, ) 2007. . .

    . 353-5228/2007-1 30.08.2008 . CARDS SUPPLY OF EQUIPMENT FOR AIR QUALITY MONITORING STATIONS, SERBIA (EUROPEAID/ 124394/D/SUP/YU) . 28 , , , . 2008-2010, 2011.

  • 2011.

    8

    . e . , . . : , _, _, _, . , _, _ , _., _., _, _, _ , , ,_. , _, _, _, _, , , _, _ , _ , , , _. , , , , , , _.. . , _ , .

    , , 2012, , 4.

    4.

  • 2011.

    9

    , . 12. , . 10 , .

    2011.

    . 11. , " ".

    " " . .

    " ", . .

    2011. . : - SO2, - CO, - Nx - O3, , . . , , ISO/IEC 17025.

    . , _ , 10 2.5 . TECORA LECKEL. . 10 2.5 , GRIMM, - . 5. 7.

  • 2011.

    10

    5. 2011.

    o , , a " " , , , .

    .

    , , .

    , / .

    2011 . .

    - . AERMOD, .

    : , , . a a (, ). AERMOD- .

    , 6.

  • 2011.

    11

    6. ()

    . .

    , , (. . . 58/11).

    . .

    . , , " ". , , , .

    , , , , 10 .

  • 2011.

    12

    SO2 TELEDYNE API Model 100E. a , ( SRPS EN 14212).

    NO/NO2/NOx TELEDYNE API Model 200A. , ( SRPS EN 14211).

    CO TELEDYNE API Model 300A. , ( SRPS EN 14626).

    O3 TELEDYNE API Model 400A. , ( SRPS EN 14625).

    Syntech Spectras GC955 400/600 800 /. , a , ( SRPS EN 14662-3).

    PM10

    PM10 GRIMM EDM 180 Aerosol Spectrometer. . N 12341 PM10. PM10 5 ( ) (-).

    je , . , 7.

  • 2011.

    13

    7. 10

    2011. 2012. 10 ( ) TECORA Skypost HV PM10 , . (, , , ). 2012. .

    . 5. , (. . 58/11) . :

    , , , ;

    , ;

    , .

    :

    1. , ;

    2. , ;

    3. , ;

    4. , .

  • 2011.

    14

    , , , 1.

    1. , ( ". . ", 11/10 75/10 )

    ,

    g/m3

    (

    )

    ,

    (

    +

    )

    (SO2)

    1 h 350 24 x 500 - -

    24 h 125 3 x 125 50 75

    50 - 50 - -

    (NO2)

    1 h 150 18 x 225 75 105

    24 h 85 - 125 - -

    40 - 60 26 32

    PM10

    24 h 50 35 x 75 25 35

    40 - 48 20 28

    PM2.5

    25 - 30 12.5 17.5

    (O3)

    8 h max 120 25 h

    3

    - -

    (CO)

    8 h max 10000 - 16000 5000 7000

    24 h 5000 - 10000 - -

    3000 - - - -

    (Pb)

    24 h 1 - 1 - -

    0.5 - 1 0.25 0.35

    (C6H6)

    5 - 8 2 3.5

  • 2011.

    15

    . 21 , , , :

    1. - ;

    2. - , ;

    3. - .

    , .

    .

    SAQI_11

    , , , . , , . , , . .

    , , . . .

    , , . . , , AQI, SAQI_11. SAQI_11, "AQI" , "S" , , , "_11" .

    SAQI_11 5

  • 2011.

    16

    :

    - ,

    - ,

    , , - ,

    , , - ,

    - ,

    SAQI_11 , , . SAQI_11, "", "" "" - . "" " " . . , . , , , _. , , . SAQI_11 ; , "" "".

    , gm3, 24

    , SAQI_11 2.

    2. SAQI_11

    ,

    g/m3

    .

    T,

    g/m3

    .

    SO2 125 0.0 50.0 50.1 75.0 75.1 125.0 125.1 187.5 > 187.5

    NO2 85 125 0.0 42.5 42.6 60.0 60.1 85.0 85.1 125.0 > 125.0

    PM10 50 75 0.0 25.0 25.1 35.0 35.1 50.0 50.1 75.0 > 75.0

    CO 5000 10000 0.0 2500 2501 3500 3501 5000 5001 10000 > 10000

    O3-8h max. 120 0.0 60.0 60.1 85.0 85.1 120.0 120.1 180.0 > 180.0

    50 0.0 25.0 25.1 35.0 35.1 50.0 50.1 75.0 > 75.0

    SO2 50 0.0 30.0 30.1 40.0 40.1 50.0 50.1 75.0 > 75.0

    NO2 40 60 0.0 26.0 26.1 32.0 32.1 40.0 40.1 60.0 > 60.0

    PM10 40 48 0.0 20.0 20.1 28.0 28.1 40.0 40.1 48.0 > 48.0

    CO 3000 0.0 1500 1501 2100 2101 3000 3001 4500 > 4500

    50 0.0 25.0 25.1 35.0 35.1 50.0 50.1 75.0 > 75.1

    24

    h

  • 2011.

    17

    . , . , .

    SAQI_11 . , , SAQI_11. , , .

    SAQI_11 . . .

    2011.

    2011. . . , .

    (gm3), , (gm3), X ` (gm3), (%) SAQI_11 (%) 2011. .

    , gm3, a. . .

    .

    .

    X ` X`` , , . , . , , , 3 24 . , , , . ,

  • 2011.

    18

    .

    ( %) SAQI_11 , . . . .

    2011. . . .

    , 2011., , 3. 90%, 75%. , , 90% .

    2011. , 50 g/m3, ; 193 g/m3 - , 79 g/m3 - 72 g/m3 _, 3.

    , 125 g/m3, 2011. , , 162 - , 77 - , - 65 19 .

    125 g/m3, 2011. , 3, , _, _. _, _, . 1, .

    350 g/m3, 2011. , 3, , , , _ _ . , , , 500 g/m3, . 3, 2011. , _ , _, _ .

    , SAQI_11, , , . SAQI_11. , g/m3, .

    3. SO2 (gm3), ,

  • 2011.

    19

    (gm3), 4 ` , 25` ` (gm3), (%) SAQI_11 (%) 2011.

    2011. je 8. SO2 (gm3) 2011. .

    0 - 50 50.1-75 75.1-125 125.1-187.5 >187.5

    _ 193 162 1331 994.9 3153.8 36.6 6.7 11.5 12.0 33.2 98

    _ 79 77 571 430.7 1561.4 55.3 9.0 14.5 9.6 11.5 100

    _ 72 65 938 637.3 1917.6 67.9 5.8 8.5 6.0 11.8 100

    39 19 253 177.6 417.0 74.2 10.4 10.1 4.7 0.5 100

    __ 31 2 230 117.6 207.3 84.3 11.2 3.9 0.3 0.3 98

    _ 30 3 174 121.5 204.2 84.4 9.2 5.6 0.8 0.0 98

    29 10 284 171.0 557.5 84.8 8.9 3.4 2.0 0.9 96

    _ 29 2 154 112.1 231.2 81.9 12.3 5.2 0.5 0.0 100

    _ 27 1 132 82.5 190.6 88.5 9.3 1.9 0.3 0.0 88

    _ 26 2 190 119.6 202.1 87.1 9.6 2.7 0.3 0.3 100

    26 0 94 84.2 174.9 88.8 8.9 2.3 0.0 0.0 95

    _ 25 1 190 91.4 203.5 89.3 8.2 2.2 0.0 0.3 100

    24 3 298 117.2 287.0 91.8 6.3 1.1 0.3 0.5 100

    _ 22 5 351 154.4 397.7 95.5 2.0 1.1 0.8 0.6 98

    22 2 182 123.3 212.8 89.3 4.7 5.5 0.5 0.0 100

    _ 21 6 200 152.3 200.5 97.1 0.9 0.3 1.4 0.3 95

    20 0 97 75.8 152.7 92.3 6.4 1.3 0.0 0.0 82

    _ 19 1 155 45.8 145.3 95.6 3.8 0.3 0.3 0.0 100

    19 0 119 109.1 257.8 91.8 5.5 2.7 0.0 0.0 100

    _. 18 1 213 67.1 154.0 95.9 3.3 0.5 0.0 0.3 100

    _ .. 3 18 5 172 130.7 325.0 95.1 2.2 1.2 1.5 0.0 89

    _ 18 0 73 62.2 150.0 98.1 1.9 0.0 0.0 0.0 100

    _ 17 0 66 57.7 128.6 98.1 1.9 0.0 0.0 0.0 99

    _ 17 0 77 48.0 94.5 99.5 0.3 0.3 0.0 0.0 100

    _. 16 2 508 90.9 366.8 97.5 0.8 1.1 0.3 0.3 100

    16 0 103 64.7 137.4 98.4 0.8 0.8 0.0 0.0 100

    _.. . 13 0 57 47.9 87.5 99.5 0.5 0.0 0.0 0.0 100

    13 0 56 44.2 116.5 99.7 0.3 0.0 0.0 0.0 90

    12 0 59 30.3 88.3 99.7 0.3 0.0 0.0 0.0 100

    - 12 0 78 61.5 114.8 98.3 1.4 0.3 0.0 0.0 99

    12 0 90 45.8 94.2 99.2 0.5 0.3 0.0 0.0 100

    _ 11 0 63 33.3 81.8 99.7 0.3 0.0 0.0 0.0 100

    11 0 87 45.4 133.0 99.5 0.3 0.3 0.0 0.0 100

    9 0 51 35.6 76.1 99.7 0.3 0.0 0.0 0.0 100

    9 0 45 31.3 61.7 100.0 0.0 0.0 0.0 0.0 100

    _ 8 0 38 31.7 67.6 100.0 0.0 0.0 0.0 0.0 99

    7 0 29 23.4 40.2 100.0 0.0 0.0 0.0 0.0 97

    , %,

    ,

    %

    2011

    .

    SO2

    > 1

    25

    gm

    3

    4 '

    25

    '

  • 2011.

    20

    , , III .

    8. SO2 (gm3) 2011. ( )

    , 2011. , , 4. 90%, 75%. , , 90%.

    2011. NO2 40g/m3 je _ _ 62g/m3, _ 62g/m3, __ 55g/m3, _ 54g/m3, __._ 43g/m3, 43g/m3 _ 41g/m3. , 60g/m3,

    0 50 100 150 200 250

    _

    -

    _.. .

    _

    _

    _

    _.

    _

    _

    _

    _

    _

    __

    _ ._

    _

    _

    _

    _

    > 125 gm3

  • 2011.

    21

    _ _ _.

    4. NO2 (gm3), , (gm3), 19 ` (gm3), (%) SAQI_11 (%) 2011.

    , 85g/m3, 2011.

    0 - 42.5 42.6-60 60.1-8585.1-125 >125

    _ ._ 62 51 250 360.4 24.6 35.6 25.5 9.5 4.8 98

    _ 62 59 361 595.7 56.2 19.5 8.2 3.6 12.6 100

    __ 55 37 659 803.4 43.9 24.4 20.9 6.4 4.4 94

    _ 54 21 142 192.1 26.6 40.9 26.6 5.2 0.5 100

    __._ 43 34 405 507.6 71.1 12.4 6.6 4.3 5.5 95

    43 7 110 153.9 58.4 28.5 11.2 1.9 0.0 100

    _ 41 13 155 203.4 63.3 24.9 8.2 1.9 1.6 100

    _ 39 4 102 149.2 67.9 25.9 5.1 1.1 0.0 97

    _ 34 4 116 147.6 74.2 17.5 7.1 1.1 0.0 100

    _. 34 2 120 156.8 78.6 15.1 5.8 0.5 0.0 100

    . 30 0 84 133.3 87.9 10.7 1.4 0.0 0.0 100

    27 0 75 134.8 89.0 9.3 1.6 0.0 0.0 100

    27 1 86 127.6 88.5 9.6 1.6 0.3 0.0 100

    _ 26 0 63 116.9 93.3 6.1 0.6 0.0 0.0 98

    _ 24 0 66 113.5 90.4 8.5 1.1 0.0 0.0 100

    24 0 73 98.9 90.3 8.5 1.2 0.0 0.0 90

    24 0 76 89.4 96.4 2.7 0.8 0.0 0.0 100

    _.. . 23 0 72 125.5 92.3 5.5 2.2 0.0 0.0 100

    _ 23 0 54 90.3 95.4 4.6 0.0 0.0 0.0 90

    23 22 128 167.6 89.6 3.0 1.4 5.2 0.8 100

    21 0 60 112.7 95.3 4.4 0.3 0.0 0.0 100

    _ 21 0 59 100.1 94.8 5.2 0.0 0.0 0.0 100

    _ 21 0 62 90.3 95.3 4.1 0.5 0.0 0.0 100

    19 0 69 101.6 96.8 2.3 0.9 0.0 0.0 95

    _ 19 0 65 83.3 97.5 2.2 0.3 0.0 0.0 100

    16 0 51 86.1 99.7 0.3 0.0 0.0 0.0 100

    _ 15 0 53 80.9 99.2 0.8 0.0 0.0 0.0 98

    _ .. 3 14 0 52 71.6 99.0 1.0 0.0 0.0 0.0 82

    14 0 65 92.8 97.8 1.9 0.3 0.0 0.0 100

    14 0 55 85.0 99.2 0.8 0.0 0.0 0.0 100

    13 0 39 71.2 100.0 0.0 0.0 0.0 0.0 100

    _. 7 0 58 58.3 99.7 0.3 0.0 0.0 0.0 100

    - 5 0 44 62.8 99.7 0.3 0.0 0.0 0.0 100

    4 0 20 39.0 100.0 0.0 0.0 0.0 0.0 100

    ,

    %,

    2011

    .

    NO2

    > 8

    5

    gm

    3

    19

    '

    ,

    %,

  • 2011.

    22

    _ 59 , _ _ 51 , __ 37 , __._ 34 , _ 21 , 22 , .

    2011. __ 659g/m3, __._ 405g/m3 _ 361g/m3.

    , 18 . , , 225 g/m3, . 2011. : __ 803g/m3, _ 596g/m3, __._ 508g/m3 _ _ 360g/m3.

    9. NO2 (gm3) 2011. ( )

  • 2011.

    23

    2011. 9. NO2 (gm3) 2010. .

    , , III .

    10

    10 2011. 5. 10. 90%, 75%. , , 90%.

    2011. PM10 (48 g/m3), _ _.. , 90% .

    5. 10 (gm3), (50 gm3), (gm3), 36 ` (gm3), (%) SAQI_11 (%) 2011.

    0 - 25 25.1-35 35.1-50 50.1-75 >75

    _ 85 258 355 154.8 3.1 9.4 14.2 26.7 46.6 96

    _ ._ 79 181 536 158.9 11.8 13.6 19.7 21.2 33.6 90

    _ .. 3 75 164 473 143.0 17.4 13.6 17.4 17.0 34.7 87

    _ 69 186 278 131.7 6.6 18.1 24.4 20.8 30.1 100

    _ 69 208 251 116.8 1.7 13.4 25.4 24.9 34.6 96

    __._ 69 175 344 115.3 8.6 12.6 20.9 28.1 29.8 83

    _ 67 167 255 137.2 6.0 20.0 28.2 15.9 29.9 100

    63 159 270 133.9 19.2 19.2 18.1 9.6 34.0 100

    _ 53 134 293 106.0 20.7 24.2 16.4 16.4 22.2 95

    _ 52 132 250 101.4 20.2 21.0 21.3 19.9 17.6 96

    _ 51 129 224 102.3 19.5 27.1 18.1 17.3 18.1 100

    _ 48 107 311 88.3 22.5 21.9 25.8 16.4 13.3 99

    _ 45 102 147 78.7 20.7 24.6 24.0 18.6 12.0 91

    _. 41 94 216 84.5 38.4 21.0 14.3 14.8 11.5 98

    ,

    %,

    2

    011.

    PM10

    > 5

    0

    gm

    3

    36

    '

    ,

    %,

  • 2011.

    24

    , 10, , 10 _ (73.3%), __._ (57.9%),_. (51.7%), _ (59.5%), (43.6%) .

    , 10 _ (46.6%), _. (34.7%), _ (34.6%), (34.0%) ., 5.

    10 2011. 10. 10 (gm3) 2011. .

    10 . 10 (gm3) 2011.

    0 20 40 60 80 100 120 140 160 180 200 220 240 260 280

    _.

    _

    _

    _

    _

    _

    _ .. 3

    _

    __._

    _ ._

    _

    _

    _

    > 50 gm3

  • 2011.

    25

    . .

    6. (mgm3), 8- (mgm3), (%) SAQI_11 (%) 2011.

    0 -5000 5001-7000 7001-10000 10001-16000 >16000

    2.40 23.5 84.3 5.0 4.7 5.0 0.9 90

    2.20 11.6 91.0 7.4 1.1 0.5 0.0 100

    1.90 14.9 91.0 3.6 4.4 1.1 0.0 100

    eo__ 1.80 12.5 94.5 3.6 1.4 0.5 0.0 96

    1.70 10.4 86.7 9.0 4.0 0.3 0.0 95

    1.70 12.3 92.1 3.8 2.5 1.6 0.0 100

    1.60 12.5 94.2 3.4 1.2 1.2 0.0 93

    _.. . 1.60 11.2 94.8 3.6 1.1 0.5 0.0 100

    _. 1.50 9.4 97.0 1.9 1.1 0.0 0.0 97

    _ 1.40 5.7 98.6 1.4 0.0 0.0 0.0 99

    _ 1.4 7.8 97.1 2.3 0.6 0.0 0.0 96

    _ 1.40 10.8 95.1 4.0 0.3 0.6 0.0 95

    _ 1.30 9.6 95.6 3.3 1.1 0.0 0.0 100

    . 1.30 9.0 94.2 4.7 1.1 0.0 0.0 100

    1.20 4.8 100.0 0.0 0.0 0.0 0.0 97

    1.20 5.6 99.5 0.5 0.0 0.0 0.0 100

    _. 1.10 7.5 98.6 0.8 0.5 0.0 0.0 100

    _ 1.10 8.5 99.2 0.3 0.5 0.0 0.0 100

    1.10 8.3 96.4 3.1 0.6 0.0 0.0 98

    _. 1.0 5.2 99.5 0.5 0.0 0.0 0.0 100

    _ 0.90 5.2 99.7 0.3 0.0 0.0 0.0 100

    _ 0.90 3.1 100.0 0.0 0.0 0.0 0.0 85

    _ 0.80 4.4 100.0 0.0 0.0 0.0 0.0 100

    0.80 5.6 99.7 0.3 0.0 0.0 0.0 100

    _ 0.8 6.6 99.5 0.5 0.0 0.0 0.0 100

    0.78 7.2 95.0 4.1 0.8 0.0 0.0 99

    0.70 3.0 100.0 0.0 0.0 0.0 0.0 100

    _. 0.40 2.0 100.0 0.0 0.0 0.0 0.0 100

    _ 0.40 2.3 100.0 0.0 0.0 0.0 0.0 100

    - 0.40 5.8 99.7 0.0 0.3 0.0 0.0 100

    0.39 4.2 99.7 0.3 0.0 0.0 0.0 100

    Ko 0.30 2.1 100.0 0.0 0.0 0.0 0.0 94

    C

    .

    x

    8h

    . 8 h

    , %,

    ,

    %,

    2

    010.

  • 2011.

    26

    8 . 2011. 6. 8 . 90%.

    2011. (16mg/m3) 8 , , (23.5 mg/m3). 8 , 10 mg/m3, : (23.5mg/m3 ), (14.9mg/m3 ), __ (12.5mg/m3), (12.3mg/m3 ) .

    SAQI_11. , - . , . 2011. : 5.9% , 1.6% , 1.2 % , 1.1 % .

    11. CO (mgm3) 2011.

    0.00 0.50 1.00 1.50 2.00 2.50 3.00

    Ko

    _.

    -

    _

    _.

    _

    _

    _

    _

    eo__

    . x 8h

  • 2011.

    27

    , 2011. . , 2011. (. . , 11/2010 75/2010).

    120 g/m3 , 120 g/m3 25 .

    , .

    12. 8h 30.08.2011.

    12. . (_. , _ , _, _, _. , _, _, _), , , .

    , . , , .

    . , , , N2 . , 13.

    0

    20

    40

    60

    80

    100

    120

    0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23_. _. _

    _ _ .

    _

    h

  • 2011.

    28

    13 . 3 (gm3) 2005-2011. , _

    14 , 2011. , , 7.

    7. 8- (gm3),

    8- 120 gm3, 8- (gm

    3), 26` 8- , (%)

    SAQI_11 8- (%) 2011.

    0

    10

    20

    30

    40

    50

    60

    70

    80

    90

    100

    mg/m3

    2005 2006 2007 2008

    0 -60 60.1-85 85.1-120 120.1-180 >180

    eo_ 73 27 183 121 36.4 18.7 37.5 7.2 0.3 99

    _ 65 22 173 114 53.3 20.1 20.6 3.6 2.5 96

    _ 66 21 164 116 43.8 22.7 27.7 5.8 0.0 100

    _. 75 31 159 122 35.6 21.6 34.2 8.5 0.0 100

    - 95 54 151 128 8.5 21.9 54.8 14.8 0.0 98

    74 27 146 121 34.5 18.4 39.7 7.4 0.0 97

    95 35 144 123 1.1 19.7 69.1 10.0 0.0 95

    _ 49 4 142 92 60.8 27.1 11.0 1.1 0.0 100

    __. _67 4 135 106 39.1 25.4 34.3 1.1 0.0 95

    _ 77 13 135 111 28.2 26.6 41.9 3.3 0.0 100

    _ 65 5 131 108 41.6 26.8 30.1 1.4 0.0 100

    _ 54 0 117 93 52.3 34.7 13.0 0.0 0.0 94

    _. 47 0 105 84 67.9 25.1 7.0 0.0 0.0 94

    28 0 85 62 91.2 8.8 0.0 0.0 0.0 93

    ,

    %,

    2

    010.

    3

    .

    x

    8h

    > 1

    20

    g

    m3

    . 8 h

    26 '

    ,

  • 2011.

    29

    2011. , .

    2011. 14. 3 (gm3) 2011. .

    14 . 3 (gm3)

    2011.

    2011. , , 120 gm3, _ 183 gm3, _173 gm3, _ 164 gm3 . _. 31 , _ 27 , 27 .

    (1710 m) (808 m) 8h (95 gm3) , - 54 35 . .

    2011. 25 , , : _., _ , - .

    0 20 40 60 80 100 120 140 160 180 200

    _.

    _

    __.

    _

    _

    _

    _

    _

    eo_

    _.

    -

    > 120 gm3 . 8 h

  • 2011.

    30

    , - , (ODS-zone Depleting Substances) 1990- .

    (ODS) . ODS -, , , , 1,1,1-, , , , , , , .

    , ( , .22/10).

    ODS -, .

    2010. , . " " (Essential use Exemptions). , , , , (. ).

    , , / , 2011. , .

    01.01.2010. , , HCFC . je 2011. HCFC- 12.54 .

    , 2005-2011. 15.

    15. , 2005-2011. ODP

    0

    5

    10

    15

    20

    2005 2006 2007 2008 2009 2010 2011

    HCFC (ODP )

  • 2011.

    31

    2011.

    2011. , e 8. 8. , 2011. , SO2, NO2, PM10, CO O3 ,

    (

    )

    SO2

    g/m

    3

    >125

    g/m

    3

    NO2

    g/m

    3

    >85

    g/m

    3

    PM10

    g/m

    3

    >50

    g/m

    3

    CO

    mg/m

    3

    >5

    g/m

    3

    O3

    g/m

    3

    >120

    g/m

    3

    1 1 8,7 0 12,7 0

    0,4 0

    2 _ 3 11,1 0 61,7 59 45,0 102 0,5 0 66,1 21

    3 _ 1 16,8 0 21,2 0

    0,3 0

    4 . 1

    30,3 0

    0,7 0

    5 _ 1 18,3 0 21,4 0

    0,7 0

    6 _ 3

    48,2 107

    7 _ 3 19,1 1 34,4 4 52,0 132 0,4 0 73,4 27

    8 _. 2 18,5 1 33,7 2 41,0 94 0,7 0 74,5 31

    9 _ 3 24,9 1 53,7 21 51,0 129 0,8 0 48,6 4

    10 _ 2 26,0 2 41,4 13

    0,7 0 65,1 5

    11 _ 3

    53,2 134 0,6 0

    12 _._ 3 29,7 3 62,2 51 79,0 181 1,0 0

    13 __ 2 31,0 2 54,9 37

    1,2 2

    14 __._ 2

    42,9 34

    67,1 4

    15 1 24,2 3 26,6 1

    0,8 3

    16 1 29,5 10 13,7 0

    0,5 0

    17 _ 3 22,4 5 25,8 0 69,0 186 0,9 0 65,5 22

    18 _. 1 16,2 2 7,3 0

    0,3 0

    19 _ 1 29,3 2 18,7 0

    0,5 0

    20 _ 3

    15,5 0 85,5 258

    21 _ 3

    22,8 0 69,0 208

    22 1 20,0 0 23,9 0

    0,7 0

    23 1 25,5 0 18,9 0

    0,9 4

    24 _ 3 71,5 65

    25 _ 3 193,4 162

    26 _ 3 78,9 77 24,1 0

    0,4 0 77,1 13

    27 1 11,1 0

    0,8 0

    28 3 12,2 0 16,4 0 63,0 159 0,5 0 74,6 27

    29 1 38,5 19

    0,9 4

    30 _. 1 9,2 0 14,4 0

    0,7 1

    31 1 11,7 0 26,7 0

    0,8 0

    32 2 19,0 0 42,9 7

    1,4 3 28,3 0

    33 1 15,9 0 21,4 0

    0,7 1

    34 1 21,9 2 22,6 22

    0,9 1

    35 - 1 11,7 0 4,9 0

    0,3 0 95,4 54

    36 _.. . 1 13,5 0 23,2 0

    0,9 1

    37 _ 3 20,7 6 39,3 4 67,0 167 0,8 0 54,1 0

    38 1 7,5 0 4,2 0

    0,3 0 94,9 35

    39 1 12,6 0 24,0 0

    1,2 18

  • 2011.

    32

    8 . .

    . .21 , 90%. 2011. :

    I , ( ) 2011. : , , _ . ., , , _, , , , _, _ , , , , , , _.. . , .

    II , ( , , , ) 2011. () ;

    III , ( , , ) 2011. : ( 10, ), (), (), ( 10),

    2011. III , , ( 10), _ _ ( 10).

    2011. III , , _ ( 10).

    2011. , .21. 16.

    , , , , 2011. III - ( , , ).

    2011. III , _ _; II , I , , _ , , _, , , _ , , , , , , _.. , .

    , , 2011. III - .

  • 2011.

    33

    16. 2011. . 21

    2011. III _. I , _.

    2011. III - .

    22 ( 124). 10 12 , 54% , NO2 7 , 32% , SO2 3 , 14% .

    10 .

    , , .

  • 2011.

    34

    : CO, SO2, O3, NO2 PM10

    , , , , , , 10 , . SAQI_11 ( ". ", 11/10 75/10 ). , , 9. "" " ".

    9.

    2011. 90% . , , , , . 10.

    10. , 2011.

    , 99% , 2011. . , . 99% . 2011. 92% . 8% 8h 120g/m3.

    2011. . 10% 5%

    1 2 3 4 5

    CO 0 - 2500 2501-3500 3501-5000 5001-10000 >10000

    SO2 0 - 50 50.1-75 75.1-125 125.1-187.5 >187.5

    O3 0 - 60 60.1-85 85.1-120 120.1-180 >180

    NO2 0 - 42.5 42.6-60 60.1-85 85.1-125 >125

    PM10 0 - 25 25.1-35 35.1-50 50.1-75 >75

  • 2011.

    35

    , 15%. 10 2011. . 21% 34% . 55% 2011. .

    10 2011. . 46% , , 18%.

    . , 2011, 17% 15% . , 2011. 1%.

    45% . 2011. 12% 33% . 2011. 10. 25%.

    , , , 10 , , 17.

    17. (%) SAQI_11

    CO 93 4 2 1 0

    SO2 84 9 6 1 0

    O3 36 22 34 8 0

    NO2 25 36 25 10 5

    PM10 12 14 20 21 34

    0102030405060708090

    100

    ,

    %

    CO 100 0 0 0 0

    SO2 37 7 11 12 33

    O3 28 27 42 3 0

    NO2 90 8 1 0 0

    PM10 22 24 29 18 7

    0102030405060708090

    100

    ,

    %

  • 2011.

    36

    (: 4321, :2157, h:813m, ) (: 4447, : 2052, h:243m), 2011. ( SO42-, NO3-, NH4+, Ca2+,K+, Cl-, Na+, Mg2+, pH, Cd, Pb, Ni, Mn, Fe, Al, Zn Cu).

    ( ) .. ( ). ( ) . 2011. 11, 18 19.

    11. _ 2011.

    mg / l mg / l kg / ha mg / l mg / l kg / ha

    0.27 12.03 7.2 0.42 12.65 6.2

    0.13 4.65 0.01 4.29

    0.23 8.99 0.3 9.72

    0.09 2.34 2.1 0.07 3.77 1

    0.01 2.68 0.8 0.01 1.49 0.5

    0.15 13.01 7.2 0.1 17.48 6.5

    0.13 4.63 3.8 0.12 4.44 2.1

    0.08 4.45 1.8 0.07 3.26 0.8

    g / l g / l g / ha g / l g / l g / ha

    0,02 0.85 0.2 0.02 2.3 1

    0.05 16.4 5 0.5 29.7 8

    10 54.5 40 10 54.9 57

    10 193.7 86 10 356.9 127

    2 65.1 29 1 97.5 48

    0.5 88.3 3 0.8 27.9 13

    10.8 742.4 141 11.2 491.8 245

    10 432.6 102 10 635.9 159

    6.4 8.2

  • 2011.

    37

    18.

    19.

    : (5.6 > 5.0), 5.0 > 4.0 (4.0 ) 12. 5% , 8% .

    7.2

    8.2

    2.1

    0.8

    7.2

    3.8

    1.8

    6.26.4

    1

    0.5

    6.5

    2.1

    0.8

    0

    1

    2

    3

    4

    5

    6

    7

    8

    9

    kg

    /ha

    141

    102

    86

    4029

    5 3 0.2

    244.6

    158.7

    126.9

    57.047.9

    7.712.9

    0.70

    50

    100

    150

    200

    250

    g/h

    a

  • 2011.

    38

    12.

    1999. 2011. 446.0 l/m2 (2000. ) 923.3 l/m2 (2001. ), . ( 20).

    20.

    , , 383 (2004. .) 7178 eq/m2 (2006. .) , ( 21 ).

    21.

    ( a ), ( ) ( 22), , .

    % % % %

    91 30 33 14 46.7 15 50 1 3.3

    75 41 54.7 12 29.3 28 68.3 1 2.4

    4.0 pH < 5.0

    pH < 4.0

    5.0 pH < 5.6

    y = 0.8566x + 712.31

    0

    200

    400

    600

    800

    1000

    1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011

    Su

    ma p

    ad

    avin

    a (

    mm

    )

    Godina

    y = 106.63x + 3873.8

    0100020003000400050006000700080009000

    1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011

    Dep

    ozic

    ija H

    +jo

    na

    (meq

    /m2)

    Godina

  • 2011.

    39

    22. ,

    , . , , , ( 23).

    23. , ,

    , 1999. 2011. , , , , .

    0

    500

    1000

    1500

    2000

    2500

    1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011

    Dep

    ozic

    ija (

    mg

    /m2)

    Godina

    S N Cl

    0

    500

    1000

    1500

    2000

    2500

    1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011

    Dep

    ozic

    ija (

    mg

    /m2)

    Godina

    Na Mg Ca K

  • 2011.

    40

    , . . 14 ( ).

    , , ( , 36/09, 17; , 3, 9).

    : (2 ) (), () , () , (), () , () , () , (), (), (), () , () ().

    24.

    24.

    (/m3) www.sepa.gov.rs , . (EAN European Aeroallergen Network).

    , , , . , .

  • 2011.

    41

    . . 30 50 . . , , .

    , , , .

    30 , 15 .

    2011., 25.

    25. (, )

    , , .

  • 2011.

    42

    2011.

    26, , . ,- - .

    26. ,

    27, , . - , - - .

    27. ,

    28, . -,- .

    0

    200

    400

    600

    800

    1000

    1200

    1400

    1600

    1800

    PA

    ./

    m3

    0

    20

    40

    60

    80

    100

    120

    140

    160

    180

    200

    PA

  • 2011.

    43

    28.

    2011. ( , ).

    29.

    30, 31 32, : , 2003. 2011. .

    0

    2000

    4000

    6000

    8000

    10000

    12000

    14000

    PA

    ..

  • 2011.

    44

    30. 2003 2011.

    31. 2003 2011.

    32.

    2003 2011.

    , :

  • 2011.

    45

    33. 2011. .

    2011. . , . , .

    34, , , , .

    , . . .

    , . , .

    2011 14 , . - , .

    , .

    0

    400

    800

    1200

    1600

    2000

    2400

    J F M A M J J A S O N D

    /3

  • 2011.

    46

    34.

    . 11. .13 (. . .36/09) (. . .58/11) 2011. .

    ; , , , , 2011. 22 124 39 .

    , , , , 2011. III - ( , , ).

  • 2011.

    47

    :

    . , , .

    - .

    .

  • 2011.

    48

    2011. -1.

    -1. (mg /m3), S2 2011.

    SO2(mg/m3)

    >

    .

    267 156 2386

    205 164 1434

    75 68 545

    60 52 889

    39 17 192

    32 5 218

    32 5 197

    30 13 344

    26 1 131

    22 2 154

    V 22 6 207

    21 2 135

    18 0 124

    . 18 0 118

    17 5 179

    17 2 146

    17 0 82

    17 0 71

    . 16 0 100

    12 0 40

    10 0 49

    . 9 0 36

    9 0 41

    8 0 22

    8 0 25

    8 0 36

    6 0 24

    6 0 17

    6 0 27

    213 6 0 41

    3 0 24

    2 0 27

    2 0 51

    2 0 19

    2 0 12

    1 0 13

  • 2011.

    49

    2011. , 50 g/m3, - 267 g/m3, - 205 g/m3 , - 75 g/m3 - 60 g/m3.

    , 125 g/m3, 2011. - 164 , - 156 , - 68 - 52 .

    2011. - 2386 g/m3, - 1434 g/m3, - 889 g/m3 - 545 g/m3 .

    SO2 -1.

    -1. SO2 (mg/m3) 2011.

  • 2011.

    50

    2011. -2.

    -2. (mg/m3), N2 2011.

    NO2(mg/m3)

    >

    .

    70 98 177

    61 42 178

    55 16 121

    54 40 250

    51 37 659

    50 13 130

    45 12 98

    44 6 124

    43 14 149

    43 7 149

    40 7 152

    32 0 72

    . 31 4 95

    30 3 114

    27 7 108

    23 0 84

    21 0 51

    15 0 50

    15 0 80

    V 14 0 56

    14 0 44

    . 14 1 103

    14 0 83

    11 0 34

    11 0 60

    10 0 45

    10 0 34

    8 0 27

    . 4 0 16

    . 4 0 17

    3 0 7

    . 2 0 6

    . 2 0 5

  • 2011.

    51

    2011. NO2 40 g/m3 , 70 g/m3 , - 61 g/m3 , - 61 g/m3

    2011. - 659 g/m3 , - 250 g/m3 - 178 g/m3 .

    , 85 g/m3, 2011. - 98 , - 42 - 40 .

    NO2 -2.

    -2. NO2 (mg/m3) 2011.

  • 2011.

    52

    2011. -3 .

    -3. (mg/m3), . 2011.

    (mg/m3)

    >

    .

    63 171 304

    36 84 234

    33 58 264

    , 31 0 230

    29 32 174

    29 46 204

    27 55 127

    25 43 175

    25 46 137

    25 39 151

    24 22 139

    , 24 18 147

    22 32 490

    22 20 122

    22 22 126

    20 32 214

    19 6 60

    18 3 62

    17 23 281

    16 18 144

    . 16 6 139

    V 16 24 208

    16 22 137

    15 3 71

    14 1 89

    12 17 79

    10 0 49

    10 12 97

    9 1 61

    8 8 104

    7 5 116

    6 3 74

    5 6 158

    4 0 49

  • 2011.

    53

    2011. , 50 g/m3, - 63 g/m3.

    2011. , 50 g/m3, - 171 , - 84 - 58 .

    2011. - 490 g/m3 , - 304 g/m3 - 281 g/m3.

    -3.

    -3. (mg/m3) 2011.

  • ,

    27

    11160

    :+381112861080

    :+381112861077

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