Conforms to Regulation (EC) Ma. 1907120D6 (REACH), Annex II - Ireland

LEVAGARD PP

008 5497

TCPP Flmihle foam SUO3 (Induslrial] su12

PC32

TCPP Formulation (Industrial)

SUO3 SU10

PC32

PCFP. Foam granules SUO3 and rebound PUR foam [Industrial)

TCPP. Rigib foam (Industrial)

SUO3 SUI2

PC32

PC32

Enviraiimental Release Coteson, ERCM ERC03 ERCOS

ERC02 ERCOB ERCOS

I.? Product identifier Product name : LEVAGARDPP BEACH Substattce Name : TCPP_Tris(2-ciiloro-l-methylethyl)phasphate_multiconstituent

REACH Registration number : 01-21 19486772-26-0000

Suitable uses : Flame-retarding agent. Identified uses Sector of Use Chemical process Article

substance

1.2 Relevant identified uses of the substance or mixtirre and uses advised against

Product Cateooty Catesorv Cateslory

TCPP CASE - (Coatings, SUO3 w a i PROCQI Adhesivss, Sealank, SUI2 PCOSa PROCOZ Elastomers) (Indusirial) PC21 PROC03

PC32 PROCO4 PROCOS PROCOS PROC07 PROCOBa PROCDBb PROCO9 PROCI 0 PRQC13 PROCI4 PROCO I PRQC02 PROC03 PRQC04 PROC05 PROCOBa PROCOGb PROCOS PROCl4 PROC2I PROCOl PROCOZ PROCOB ?ROC04 PROCOS PROCOBa PROC08b PROGO9

PROCOS PROC03 PROC0.I PROC05 PROCOBa PROCOBb PROCOS FROG14 PAOC21 PRQCOI PRDC02 PROC03 PROC04 PROCOS

PRoca I

ERG02 ERG03

ERCO2 ERCO3 E X 0 4

ERCO:! ERC03 ERCOS

1 Date of issue : 2012-03-07 Page: 114s I

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I LEVAGARD PP 0081 5497 1 5

TCPP. CASE - ProfesslGnal appftcatlons, including service Ilfe (Professional)

su22

TCPP. Labaratury reagent SU22 (Professionai) TCPP One-Componenl SU22 faam, including Service Life (Professional) TCPP. Rigid faam 5u22 (Professlonai)

TCPP. Flexibie foam - SU2l Service Life (Consumer) TCPP. Om-component SU21 faaro, including service life (Consumer) TCPP. Rigid foam - SU2t Service Llfe (Consumer)

PCOl PCD9a PC32

PC21

PC32

PROCOT PROCOEa PROCOBb PROCOS PROCl9 PROCZT PROC05 PROCOBa PROCOBb PROCIO PROG11 PROC13 PROC15

PROClO PROCl1 PRQCZI PROCOS PRDCOBa PROClO PROC11 PROCZI

ACOl AC04

ACOl AGO2 AC13

ACO 1 AC05

ACOl ACD2 ACQ7 ACI 1 AC13

ERCOBa ERCDBb ERClOa ERCl la

ERCUBc ERCOBF

ERCIla

ERCl Qa ERCl la

ERClOa ERCl la

1.3 Details of the supplier of the safety data sheet Supplier : LANXESS Deutschland GrnbH, Industrial 13 Environmental Affairs

51 369 Leverkusen, Germany, Telephone: +49 21 4 30 651 09 E-mail: infosds@lanxess.com

: +49 214 30 99300 (Sict7erheitszentrale CHEMPARK Leverkusen) 1.4 Emergency telephone number

SECTION 2: ~azarcis identification 2.1 Ctassification of the substance or mixture Cfassification accordina to Resulatian /ECi No. 127212008 [CLPIGHSI Classification : Acute TCJX. 4, W302

Ciassificatlon accordina to Directive 6715481EEC rDSD1 Classification : Xn; R22 Human health hazards : Harmful if swallowed.

2.2 Label elements Hazard pictograms

Signal word : Warning Reaction mas5 of: propylene oxide and phosphorus oxychloride. 11 244733-77*4]

Hazard statements : Harmful if swallowed. Preca utionarv statements

I Date of issue : 2012-03-07

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LEVAGARD PP 0081549715

Prevention

Response

Storage Disposal

2.3 Other liazards

: Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.

: IF SWALLOWED: Call a POISON CENTER or physicIan if you feel unwell. Rinse mouth.

: Not applicable. : Not applicable.

Substance meets the : No. criteria for PBT according to Regulation (EC) No. 190712006, Annex XI11

: No. Substance meets ihe criteria for VPVB according to Regulation (EC) M a ‘I 907’12006, Annex XIll Other hazards which do not : Not available. result in classification

Product definition (REACH) : Multi-constituent substance

Productlingreclient name

Reaction mass of: propylene oxide and phosphorus oxychloride.

Reaction mass o t propyiene oxide and phosphorus oxychloride. main component: Tris(2-chloro-l -methylethyl) phosphate

Classification 1 identifiers

-- REACH #: 01- 21 18486772-26 EC: 871-8154 CAS: 1244’733-77-4

6715481EEC

Xn; R22

See section 16 for the

phrases declared above full text of the R-

Regulation (EC) No. 127212008 [CLPI

---. Acute Tox. 4, H302

See Section 16 far the full text of the H statements declared above.

Occupational exposure limits, if waifable, are listed in Section 8.

4.1 Description of first aid measures

in Ita lation : Move exposed perron to fresh air. Keep person warm and at rest, If not breathing, iF breathing is irregular or if respiratory arrest occurs, provide artificial iesptration or axygen by trained personnel. it may h e dangerous to the person providing aid io give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. I f unconscious, place in recovery position and get medical attention immediately. Matnlain an open airway Loosen tight clothing such as a collar, tie, belt or waistband.

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LEVA GARD PP 0081549715

Ingestion

Skin contact

Eye contact

: Wash out mouth with water. Move exposed person to Fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop jf the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

: Wash skin immediately with plenty of water and soap. Remove contaminated clothing and shoes. Get medical attention if irritation develops. Wash clothing before reuse. Clean shoes thoroughly before reuse.

: Immediately flush eyes with plenty of water. occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.

4.2 Most important symptoms and effects, both acute and delayed See Section I 1 for more detailed information on health effects and symptoms.

4.3 Indication of any immediate medical attention and special treatment needed See Section 11 For more detailed information on health effects and symptoms.

5.1 Extinguisliing media Suitable extinguishing media

: In case of fire, use water spray (fog)? foam, dry chemical or COZ.

Unsuitable extinguishing : None known. media

Hazards from the substance or mixture may burst.

5 2 Special hazards arising from the substance or mixture : In a fire or if heated, a pressure increase will occur and the container

Hazardous combustion products

9

"i

*I 0 5

- - e Y L,

5.3 Advice for firefighters Special precautions for fire-

- m fighters

7 Special protective c, n equipment far fire-fighters

n .I Remark

w I - * ?

,.I

-

CI - g U1 z3

7

: Decomposition products may indude the following materials: carbon oxides phosphorus oxides halogenated compounds

: Promptly isolate the scene by removing all persons from the vicinity of Ihe incident if there is a ire. No action shall be taken involving any personal risk or w'thout suitable training.

: Fire-fighters should wear appropriate protective equipment and self- contained breathing apparatus (SCSA) with a full face-piece operated in positive pressure mode.

: Cool closed containers exposed to fire with water.

Date of issue 2012-03-07 Page: 4144

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LEVAGARD FP 00815497/5

ECTBON 6: Accidental reaease measures 6.1 Personal precautions, protective equipment and emergency procedures

: No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appraprjate personal protective equipment j52e Section 8).

: Avoid dispersal of spilt material and runoff atid contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, wateways, soil or air).

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with

wafer and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spiSi : Stop leak i i without risk. Move containers from spill area. Prevsnt entry into sewers, water courses, basements or coniined areas. Contain and colkect spillage with non-corn bustibls, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see section I for emergency contact information and section 13 for waste disposal.

6.4 Reference to other sections

: See Section 1 for emergency cantact information. See Section 8 for information an appropriate personal protective equipment. See Section 13 for additional waste treatment information.

7.2 Conditions for safe storage, including any incompatibilities

The information in this section contains generic advice and guidance. The list of Identified Uses in Section I should be consulted far any available use-specific information provided in the Exposure Scenario(s).

7.1 Precautions for safe handling

: Put on appropriate pawonal protective equipment (see Seclion 8). Eating. drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not breathe vapour or mist. Do not ingest. Avoid contact wiih eyes, skin and clathing. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous.

: Do not store above the following ternperatur accordance with local regulations. Store in protected from direct sunlight in a dry, cool and well-ventilated area, sway from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must bf! carefully resealed and kept upright to prevent leakage. Do not stare in unlabelled containers. Use appropriate cantainment to avoid environmental contamination m- 2012-03-07 Page: 5/44

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LEVAGARD PP aoBi 5497 I 5

7.3 Specific end use(s) Recommendations Industrial sector specific solutions

: Not available. : Not available.

SECTION 8: Exposure controlslpersonal protection The information in this sectton contains generic advice and guidance. The list of Identified Uses in Section I should be consulted for any available use-specific information provided in the Exposure Scenario(s). 8.1 Control parameters ExDosure limit values : Not availabk lerived effect levels

ngredient name Type Exposure Value Population Effects Remarks 3eaction mass of: DNEL Short term 22 $4 Workers Systemic iropyleoe oxide Inhalation mg/rn3 md phosphorus mychloride,

DNEL tong term Inhalation 582 Workers Systemic rnglrn3

DNEL Short term Dermal 8 mglkg Workers Systemic

DNEL Long term Dermal 2,08 rngikg Workers Systemic bwlday

bwiday

:onclusion/Summary : Not available

'redicted effect concentrations

ngreclient name Type Compartment Value Method Detail Re marks

Xeaction mass of: PNEC soil 1,7 rnglkg Assessment Factors vopylene oxide dwi md phosphorus mychloride.

Detail

PNEC Sewage Treatment 7,84 mgll Assessment Factors

PNEC Sediment 13,4 mglkg Equilibrium dwt Partitioning

PNEC Marine water 1,34 mglkg Equilibrium sediment dwt Partitioning

PNEC Marlne 0,064 mgll Assessment Factors PNEC Fresh water 0,64 mg/l Assessment Factors

Plant

:onclusionlSummary : Not available.

Recommended monitoring procedures

: lf this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures andlor the necessity lo use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determinalion of hazardous substances.

8.2 Exposure cantrols

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LEVAGARD PP 0081549715

Risk manaaernent measures Uecupational ewosure controls Technical measures

personal D rotection meas ureq Respiratory protection

Hand protection

Eye protection

Skin protection

U vi

a c1 f

Hygiene measures

If this product contains ingredients with exposure limjts, use process E Y I C ~ O S U F ~ S , local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits.

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: Full mask with type ABEK filter if product forms vapours ,

Chemical-resistant, impervious glovss complying with an approved standard shoLtld be worn at all times when handling chemical products if a risk assessment indicates this is necessary. After contarninatkm with product changi? the gloves immediately and dispose of them according to relevant national and local regulations Recommended: 1 hour) PVC gloves

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid expostire to liquid splashes, mists, gases or dusts. Recommended: Tightly fitting safety goggles.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: Wear protective clothing. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques shoutd be used to remove potentially contaminated clothing. Wash contaminated olofhing before reusing. Ensure that eyewash stations and safety showsrs are close to the workstation location.

Environmental exposure controls

Tech n ica I measures : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduct; emissions to acceprable levels.

9.1 Information on basic physical and chemical properties

General infwmation Apaearance

Physical state : Liquid, Colour : Colourless. Odour : Odourless

lmaorkant health, safe& and environmental information Boiling point : Decomposes. Melting point : C-2O"C (e-4T)

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1 LEVAGARD PP 0081 5497 I 5

Flash point : Closed cup: ~245°C p473"F) Vapour pressure : cO.ODOi hPa(25"C) Density : t,29 kglL (20 "C)

Solubility : 1,08 gll (water) Viscosity : Dynamic: 85 rnPa-s Auto-Ignition temperature : >4OO0C (>752"F)

tem peratu re

Na additional information.

Decomposition ; 288°C

9.2 Other information

(SECTION IO: Stability and reactivity 90.1 Reactivity : No specific teat data related to reactivity available for this product or

its ingredients. 10.2 Chemical stability : The product is stable. 10.3 Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions reactions will not occur. 10.4 Conditions to avoid : No specific data. 10.5 Incompatible materials : No speciFic data. 10.6 Hazardous decomposition products

: Under normal conditions af storage and use, hazardous decomposition products should not be produced.

Exposure

1 SECTION 14 : Toxicological information I I I .? Information on toxicological effects

Potential acute health effects

Acute toxicity Ingestion : Harmful if swallowed.

Productlingreclient Result Species Dose name

Reaction mass of: La50 - Ra t - 632mg/kg - propylene oxide and Oral Female phosphorus oxychloride.

LD50 - Rat-Male 500 to2000 -

Reaction mass of: LD50 - Rat - Male >2000 mgllcg - propylene oxide and Dermal phosphorus oxychloride.

Oral mglkg

t

Reaction mass of: LC50 - Rat propylene oxjde and Inhalation phosphorus oxychloride. Dusts and

mists

Test

>7 mgil

OECD 402 Acute Dermal Toxicity I EU Method B.3 (Acute Toxicity (Dermal))

4 hours OECD 403 Acute Inhalation Toxicity I 4 3 3 Acute Inhalation Toxicity-Fixed Dose Procedure

IrrltatianlCorrosion ProducVingredient name Result Species Score Exposure Test

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Reaction mass of; Skin - Rabbit 0.2 propylene oxide and ErythernalEschar phosphorus oxychloride.

Skin ~ Oedema Rabbit 0

Skin Eyes

Eyes - Cornea Rabbit 0 opacity

lesion

Redness of the conjunctivae

Eyes - Iris Rabbit 0

Eyes - Rabbit 0

: Non-irritating (Rabbit) : Non-Irritating (Rabbit)

Potential chronic: health effects Chronic toxicitv Prod uctl ing redien t n arne Result

OECD 404 Acute Dermal Irritation/Carrosion OECD 404 Acute Dermal IrritationlCarrosian OECD 405 Acute Eye IrritatianlCorrosion OECD 405 Acute Eye IrritationlCorrosion OECD 405 Acute Eye Irritation/Corrosion

Species Dose Exposure Rat - Female 170 rnglkg 13 weeks

daily Reaction mass of: propylene Sub-chronic oxide and phosphorus NOAEL Oral oxych I oride.

Sub-acute NQAEL Rat Oral

100 mglkg 28 days

Mutaclenicifly Productlingredient name Test Experiment Result Reaction mass of propylene OECD 482 Genetic Experiment: In vitro Negative oxide and phosphorus Toxicology DNA Subject oxych I o rid e. Damage and Repair, Mammalian-Animal

Unscheduled DNA Cell: Somatic Synthesis in Mammalian Cells in vitro

Teratocrenicihr

Productlingredient name ResuIt Species Reaction mass of; propylene Negative - Oral Rat oxide and phosphorus oxychloride.

Experiment: In vivo Nagative Subject: Mam malian-Animal

peprodwtive foxicitv Productlingredient Maternal Fertility name toxicity Reaction mass of: propylene oxide and phosphorus oxychloride.

Remarks

Dose 99 mgllrg LOAEL

Exposure

Developmental Species Dose Exposure toxin

: ' Dosage caused no mortality

Rat- Male, Oral: 89 - Female rngikg

daily LOAEL

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LEVAGARD PP 0081 5497 I5

lSECT!ON 112: Ecological information 12.1 Toxicity

Prod uctl ing red ient name Test

Reaction mass of: propylene oxide and phosphorus axychloride.

IS0 81 92

ConclusionlSummary

14 Yo 28 days

Exposure

3 hours

Result Specks

Acute EC50 - Bacteria 784 mg/l Fresh water Acute EC50 - Daphnia - 48 hours 131 mgll fresh Daphnia water magna

OECD Acute IC50 82 - Algae - 72 hours 201 Alga, mgll Fresh Growth water subcapitata Inhibition Teat (growth rate)

Pseudokirchnenella

AcuteLC5051 - Fish- mgll Fresh Firnephales water promelas

OECD Acute NOEC - Algae- 72 hours 201 Alga, Growth water subcapitata Inhibition Test (growth rate)

13 mgll Fresh Pseudokrrchneriell a

Acute NOEC - Fish - 96 hours 9.8 mg/l Fresh Pimephales water pro me la s

OECD 202 Chronic EC50 - Daphnia - 21 days Daphnia s p 40 mgll Fresh Daphnia Acute water magna Immobilization Test OECD 202 Chronic NOEC - Daphnia - 21 days Daphnia sp. 32 mg/1 fresh Daphnia Acute water magna Immobilization Test

ConclusionlSummary : Nat available. 12.2 Persistence and degradability

Prod ucff ina redien t name

Reaction mass of OX& and phosphorus oxyc h I oride.

Productlinaredient name Rate of Period (days1 iest

Aquatic half-life

des rad ationl elimination Pid

Reaction mass of: propylene 95 70 64 days OECD 302A Inherent oxjde and phosphorus oxychloride. Test

8iodegradabitity: Modified SCAS

€U C.4-0 (Determination of the “Ready” Eiadeg ra da bil i ty - Manometric Respirometry Test)

: Not readily blodegradable. Inherently biodegradable, not fulfilling criteria

96 hours

Biodes rada bility

Not readily

I Date of issue 2012-03-07

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0081549715 I

Rate of period (daw1 "fest dearadationl elimination 1%)

42.3 Bioaccumulative potential

Biaaccu rn U lative Dorential

Reaction mass of: propylene oxide and - phosphorus oxychloride.

'82.4 Mobility in soil Soillwater partition coefficient (Koc)

Prod ucvtling redient name L0gp.W

: Not available.

BCF 0.8 to I 4

Potential low

Mobility : Not availabte. W . 5 Results of PET and vFvB assessment PBT : No. vPvB : No.

42.6 Other adverse effects Other adverse effects AUX

: Not available. : The product contains organically bound halogens and can contribute

to the AOX value in waste water.

9 3: Disposal considerations ~.

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario( s).

13.1 Waste treatment methods Product

Methods of disposal : Examine possib ES for re-utilisation. Product residues and uncleaned empty containers should be packaged, sealed, labelled, and disposed of or recycled according to relevant national and local regulations. Where large quantities are concerned. consult the suppliar. When uncleaned empty containers are passed on, the recipient must be warned of any possible hazard that may be caused by residues. For disposal within the EC, the appropriate code according to the European Waste List (EWL) should be used. It is among the tasks of the polluter to assign the waste to waste codes specific to industrial sectors and processes according io the European Waste List (EWL)

Hazardous waste

Packasinq Methods of disposal

Special precautions

: The classification of the product may meet khe criteria for a hazardous wzste

: The generation of waste should be avoided or minimised wherever passible. Waste packaging should be recyclad. IncineratIan or landfill should only be considered when recycling is not feasible.

: This material and its container must be disposed af in a safe way Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runof-; and contact with soil, waterways, drains and sewers.

.- I Date of issus : 2012-03-07 Page: 91/44 I

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ILEVAGARD PP O Q 8 I 5497 I 5

Jot regulated.

(SECTION 14: Transport information

Not regulated. Not regulated.

~

14.1 UN number

14.2 UN proper shipping Dame

14.3 Transport hazard ctass(es)/Marks

14.4 Packing I P U P

14.6 Special precautions for userlAdditianal information

ADRRlD I ADNlADNR I IMDG

l- l- I-

I- INa. VO .

14.7 Transport in hulk according to Annex I1 of MARPOL 73/78 and the IBC Code

Hazard notes: Not dangerous cargo. Keep dry. Keep separated from foodstuffs.

: Not available.

IATA

No

Not regulated.

(SECTION 45: Regulatory information I 15.1 Safety, health and environmental regulationsllegislation specific for the substance or mixture EU Reaulattion lECI No. f907/2006 (REACH1

Annex XVll- Restrictions : Not applicable on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

15.2 Chemical Safety Assessment

: This product contains substances for which Chemical Safety Assessments are still required.

Date of issue : 2012-03-07 Page: 12/44

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E: . .

LEVAGARL? PP 0081 5497 I5

Abbreviations and acronyms ;

FulI text of abbreviated H statements Full text of R-phrases referred to in sections 2 and 3

Wording of the instructions For use according to Use Descriptor Systsrn, to which reference is made in paragraph 1:

:

ATE =Acute Toxlcity Estlmats CLP = Glassification, Labelting and Packaging Regulation [Regulation (EC) No. 1272/2008] DNEL = Derived No Effect Level EUH ststemen! = CLP-specific Hazard statement

RRN = REACH Rsgistration Number

H302 Harmful if swallowed.

PNEC = PrEdictd NQ €Tf& CoilC2tlli%tUl

R22- Harmful i f swallowed.

m a 1 AC02

ACO4 ACO5 AC07 ACZ 1 AC13 ERC02 ERC03 me04

ERCOS ERCOBa

ERCOBb

ERCO3c

ERCON

ERClOa

ERG1 1 a

PCOI PCOga PC21 PC32 PROCOI PROGO2

PROC03 PROC04

PROC05

PROCOG PROC07 P R 0 c 0 €la

PROCOBb

PROCOS

PROCiO PROCI 1 PROCl3 PROClJ

Vehlcles Machinery, mechanical appliances, electricallelectronic 3i . t ICkS

Stone, plaster, cement. glass and ceramic articles Fabrics, textiks and apparel Metal artlcles Wood arbcles Plastic articles Formulation of prqaratbns" Formulation in rnatenals lnduslrial use of procssing aids in processes and prcducts, not becoming part of articles lndustnal use :esUiitng in inclusion into 01 onto a matrix Wide dispersive indoor use of processing aids in open systems Wide dispersive indoor LISP af reactive subsli;nces in open systems Wide dispersive indoor use resulting in inclusion into OT onto a matrix Wide dispersive outdoor use resulting in inclusion Into or onfa a matrix Wide dispersw outdoor USE of long-fife articles and rnakmk with low release Wide dtspetme indoor use of lang-life articles and inaterials with low reisase Adhesivss. seatar~!~ Coatings and paints. thinners. paint removers Laboratory chemicals Polymer preparations and compounds Use in ctmEd procss, no llkdihod of exposure Use in clcsd, continuous process with occasional controllEd aposure Use in closed baich process {synthesis ur formulsticn) Use in batch and other process (synthesis) wliefe opporhinity for exposure arises Mixing cr blending in batch prccesse5 for fcirnulatm of prqmrations' and articles (niullistage andlor significant conlazt) Calendering opm-ations lndustrlal spraying Transfer of substance or preparation (chargingldischarging) iromllo vesselsr'large coritainen at non-dzdicated facilitias Transfsr of substance or prqaration (chargingldischarging) fromlto vesselsllarge containers at dadicatd facilitiEs Transfer of substance or preparation into m a l l containers (dedicaied filling line, including welghing] Roller application or brushing Non induetnal spraying Trealmnt of arlicles by dipping and pouring Production of preparatiws' or articles by tabletting, cornprsssian. extrusion, pelletisation

PROCIS Use as laboratory reagent

Date d issue : 2012-03-07 Page: 13/44

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EPA Export 13-02-2018:03:31:31

LEVA GA RD PP DO81 5497 / 5

PROC19

PROC21

suo3

SUI0

SUI2

su2 1

su22

Hand-rnixing with intimate contact and only PPE available Low energy manipulation of substances bound in materjals andlor articles Industrial uses: Uses of s u k t a n c s as such or In preparations* at industrial sitas Forrnulatlon [muting] of preparations andlor repackaging [excluding alloys) Manufacture of plastics praducts, including compounding and conversion Consumer uses: Private households (=general public = consumers) Professionat uses: Public domain (administration, education, entertainmefit, services, craftsmen)

History Date of issue : 2012-03-07 Date of previous issue ; 2011-12-28 Version : 5

Indicates information that has changed from previously issued version. Notice to reader

The data given here is based OR current knowledge and experience. The purpose offhis Safety Data Sheet and its Annex [ifrequired according to Regulation {€Cl 7907/2006 (REACh)] is lo describe the products in terms o f their safefy requirements. The given details do not imply any guarantee concerning the composition, properfies or performance.

I Date of issue : 2012-03-07 Page: 14144 I

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Energizing Ctiemisry

ldentification of the substance or mixture Product definition : Multi-canstituent substance

Product name : LEVAGARDPP Code : o a ~ 5 m

Short title of the exposure scenario (Industrial) List of use descriptors

: TCPP. CASE L (Coatings, Adhesives, Ssalants, Elasbmers)

: identified use name: TCPP. CASE - (Coatings, Adhesives, Sealants, Elastomers) (Industrial) Process Category: PROCOI PROCO2, PROC03. PROCO4, PRUC05, PRDCO8, PROC07, PROC08a. PROCDBb, PROCOS, PROCjO, PROCI 3, PRQCl.1 Substance supplied to that use in form of: As such Sector of end use: SU03, SUI2 Subsequent service life relevant OF that use: No Environmental Release Category: ERC02, ERCO3, ERC05 Markat sector by type of chemical product: PCO?, PCOSa, PC21, PC32

Name of contributing : Sets ES rigid Foam Industry application. environmental scenario and corresponding ERC List of names of contributing worker scenarios and corresponding PRDCs

: -PROCOI, PROC02, PROCOS, PRUCO4, PROC05, PROCOS, PROCW, PROC08a, PROCOSb, PROCOS, PROC10, PROC13, PROGd4

section 2 - Exposure contrr3Is Contributing exposure scenario controlling erlviroimental exposure for ; See ES rigid foam Industry application.

- -.c Contributing exposure scenario controlling worker exposure far ; -PRQCOl, PROCOP, PROCOS, PROC04, PROC05, PROCOB, PROCO'I, PROCO8a, PROCOBb, PROCOS, PROCIO, PROC13, PROC24

Product Characteristics : Vapour pressure: .: 0,0001 hPa. (25 "C)

Concentration of : 530% substance in mixture or article Physical state 1 liquid I solid

Dust : Not applicable,

Amounts used ; Not relevant.

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LEVAGARD PP

Frequency and duration of Use Other given operational : Indooruse. conditions affecting workers exposure

TCPP. CASE 2 (Coatings, Adhesives, Sealanis, Elastomers) (industrial)

: Exposure duration per year: 230 d Exposure duration per day: 8 h (full shift).

Use at room temperature.

Technical conditions and measures to control dispersion from soiirce towards the worker

Local exhaust ventilation required. (PROC04, PROCOS, PROCOG, PROCO7, PROC08a, PROC05b, PROCOS, PROCIO, PROCI 3, PROCI 4)

Organisational measures to preventllimit reIeases, substance. dispersion and exposure

: Only properly trained and authorjsed persannel shall handle the

Substance-handling procedures shall be well documented and strictly supervised

Conditions and measures related ta personal protection, hygiene arid health evaluation Personal protection : Wear protective clothing as described in section 8.

Wear gloves as described in section 8.

Section 3 - Exposure estimation and reference to Its source Website: : Not available.

Exposure estimation and reference to its source - Environment: See ES rigid foam Industry application,

Expasure assessment (environment): Exposure estimation

: Amount has been added to ES rigid foam - industrial applications (80 Oh) and ES rigid foam - professional application (20 %)

: The predicted exposure concentrations for air, the aquatic and the terrestrial environment are below derived PNEC values;, resulting in RCRs c 1.

Exposure estimation and reference to its source -Workers: -PROCOI, PROC02, PROC03, PROC04, PROC05, PROCOG, PROC07, PRDCOSa, PR0C08b, PROCDS, PRDCI 0, PROCIS, PROCI 4

Exposure assessment : ECETOC TRA (04/2O'lO) (h U man): Exposure estimation : The calculated individual and combined (derrnat and inhalation)

exposure values are below the DNELs (RCR < I).

Section 4 - Guldance to Downstream User to evaluate if he works inside the boundaries set by the ES Environment : Not applicable. Health : Under the above listed conditions the process is deemed safe.

Other conditions should only be considered when measurements or suitable calculations show that the RCR is G 1,

Additional good practice advice beyond the REACH CSA Environment : Not available. Health : Not available.

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Identification of the substance or mixture Product definition : Multi-constituent substance Code : 00815487 Product name : LEVAGARDPP

Short title of the exposure scenario List af use descriptors

Name of cohtributing environmental scenario and corresponding ERG List of names of contributiny worker scenarios and corresponding PROCs

: TCPP. Flexible foam (Industrial)

: Identified use name: TCPP. Fkxjble foam (Industrial) Process Category: PROCOI, PROC02, PROCQ3, PROC04, PROCOS, PROCOea. P R O C O ~ ~ , PROCOS, PROC14, PRQCZI Substance supplied to that use in form of: As such Sector of end use: S U O 3 S U I 2 Subsequent service life relevant for that use: No. Environmental Release Category: ERC02, ERCOB. ERC05 Market sector by type of chemical product: PC32

: -ERCO2, ERC03, ERC06

: -PROCO1, PROCOZ, PROCQ3, PROC04, PROC05, PROCQBa, PROCOBb, PROCOS, PROC14, PROCZI

Section 2 - Exposure controfs ~

Contributing exposure scenario controlling environmental exposure far : -ERC02, ERC03, ERCOS

Product Characteristics : Liquid.

Concentration of substance : Z 30% in mixture or articie

Vapour pressure: < 0.0001 hPa (25 "C)

Amounts used : B I ~ : 5 390 va B1 b: 1 930 Va Blc. 472% Bld: 267 tla 32 : T 640 Ua

i f receiving surface water flow is (m.'ld): I8 000. Local marine water dilution factor: 100.

Envirorimental factors not ; Local freshwater dilution factor: I O . influenced by risk management Other given operational : Indooruse. conditions affecting enviranmantal exposure Technical conditions and : Foaming process is enclosed. measures at process lavel (source) to prevent release -..-

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LEVAGARD PP

rechnical on-site conditions 3nd measures to reduce or imit discharges, air ?missions and releases to ;oil 3rganisational measures to weventllimit release from substance. site

hnditions and measures *elated to municipal sewage reatm e n t plant hndi t ions and measures +elated to external treatment If waste for disposal Zonditions and measures : Not applicable. -elated to external recovery sf waste

Zontributing exposure scenario controtling worker exposure for : -PROCOI, PROCOZ, PROCD3, 'ROC04, PROCOS, PRUCOBa, PRUC08b, PROCOS, PROCI4, PROC21

TCPP. Flexible io am (lnd us trial) ; The waste water has to be directed to a dedicated sewage treatment

plant or treated by other suitable techniques. All waste gases are treated with activated carban filters. Attach dust collectors to the blade during cutting of the foam. Floor shoutd be impervious and resistant to liquid,

: Only properly trained and authorised personnel shall handle the

Substance-handling procedures shall be well documented and strictly supervised.

: Size of sewage trealment plant (m3/d): ZOO0

: General information on waste disposal see section 13.

Concentration of substance in mixture or article Physical state

Dust

AmQlrlltS used

Frequency and duration of use Human factors not influenced by risk management Other given operational conditions affecting workers exposure Technical conditions and measures at process level (source) to prevent release Organisational measures to preventllimit reIeases, dispersion and exposure

Product Characteristics Vapouf pressure: <0,0001 hPa. (25 "C)

8 %.

liquid

Dustiness: low

Not applicable.

Exposure duration per year; 230 d Exposure duration per day' 8 h {full shift) Not available.

At the start of the process operators necessarily have close contact to the product.

Local exhaust ventilation required. (PROCU4, PROCOS, PROCBa, PROC8b, PROCOS, PROC14, PROC21)

Only properly trained and authorised personnel shall handle the substance. Substance-handling procedures shall be WE~I documented and strictly supervised.

Conditions and measures related io personal protection, hygiene and health evaluation Personal protection : Wear protective clothing as described in section 8.

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LEVAGARD PP TCPP. Flexiisle foam {lndusfrialr)

Section 3 - Exposwre estimation and reference to its source Website: : Not available.

Exposure estimation and reference to its source - Environment: -ERCOZ, ERC03, ERCOS

Exposure assessment (environment):

Exposure estimation

: EUSES (v2.q) with setting from ELI RAR (2008) ; Bla, Blb, Bld, 2 The calculations were done considering half the amount of CASE industry application ES.

: The predicted exposure concentrations for air, the aquatic and the terrestrial environment are below derived PNEC values, resulting in RCRs < 1.

Exposure estimation and reference to its source -Workers: -PRDCO4, PROC02, PROC03, PROC04, PROCOS, PROC08a, PROCOBb, PROCOS, PROCf4, PROC21

Exposirre assessment : ECETOC TRA (KI4/2010) (human):

Exposure estimation : The calculated individual and combined (dermal and inhalation) exposure values are below the DNELs (RCR c I ) ,

.--

Section 4 - Guidance to Downstream User to evalttaate if he works inside the boundaries set by the ES Environment : Under t h e above listed conditions the process is deemed saFz

Other conditions should only be considered when measurements or suitable calculations show that the RCR IS 4 1. Under the above listed conditions the process is deemed safe. Other candiiions should only be considered when measurements or suitable calculations show that the RCR is -= 1.

Health :

Additional good practice advice beyond the REACH CSA [Environment : No! applicable. Health ; Wear protective gloveslprotective clolhingkye pratectionlface

protection. Wear respiratory protection. See Section 8 for information on appropriate personal protective equipment.

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Emigiueg Chemistry

!dentification of the substance or mixture Product definition : Multi-constituent substance Code ; 00815497 Product name : LEVAGARDPP

Section 9 -Title Short title of the exposure scenario List of use descriptors

Name of contributing environmental scenario and corresponding ERC List of names of contributing worker scenarios and corresponding FROGS

: TCPP. Formulation (Industrial)

: Identified use name: TCPP. Formulation (Industrial) Process Category: PROCOI , PROCQ2, PROCOS, PROC04, PROCO5, PROCOBa, PROCOSb, PROCOS Substance supplied to that use in form of; As such Sector of end use: SU03, SUI0 Subsequent service life reievant for that use; No. Environmental Release Category; ERC02, ERC03 Market sector by type of chemical product: PC32

: -ERCOP, ERC03

: -PROCOI, PROC02, PROCOJ, PROC04, PROCOS, PROCOBa, PROCOBb, PRUC09

Section 2 - Exposure controls Contributing exposure scenario controlling environmental exposure for : -ERCD2, ERCO3

Product Characteristics : Physical slate: Liquid. Vapour pressure: < 0.0001 hPa (25 "C)

Concentration of substance in mixture or article Amounts used Frequency and duration af use Environmental factors not influenced by risk management Other given operational conditions affecting environmental exposure Technical on-site conditions and measures ta reduce or limit discharges, air emissions and releases to soil

: 100%

: 22975t/a : 300 dla

: Local freshwater dilution factor: IO. If receiving surface water flow is (m"/d): 18 000, Local marine water dilution factor: 100.

: Indoor use.

: The waste water has to be direcled to a dedicated sewage treatrnenl plant or treated by other suitable techniques. Floor should be impervious, resisting to liquid and easy to clean.

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LEVAGA RID PP Organisational me preventllimit release from substance. site

Conditions and measures related to municipal sewage treatment plant Conditions and measures related to external treatment ~f waste fur disposal Gonditions and measures related ta external recovery 3f waste

Contributing exposure scenario controlling worker exposirre for : -PROCOl, PROC92, PROCOS, PROC04, PROCOS, PROCOBa, PROC08b, PROCOS

TCPP. Formulation (lftdusfria~ res to : Only properly trained and authorised personnel shall handle the

Substance-handling procedures shall be well documented and strictly supervised.

: Size of sewage treatment plant (mYd): 2050

: General information on waste disposal see section 13.

: Not applicable.

Product Characteristics : Vapour pressure: -=O.ODOI hPa (25 “C )

Concentration of 100% substance in mixture or article Physical state : liquid

Dust : Not applicable.

Section 3 - Exwsure estiniatim and reference ta its source

Arnourrts used : Not applicable.

Frequency and duration of use Other given operational : Indoor use. conditions affecting workers exposure Technical conditions and ; Local exhaust vmtilation required. (PROC04, PROCO5, measures to control dispersion from source towards the worker

: Exposure duration per year: 230 d Exposure duration per day: 8 h (full shift).

Use at ambient tmperature.

PROC08a, PROCOBb, PROCOS)

Organisational measures to preventllimit releases, substance. dispersion and exposure

Conditions and measures related to personal protection, hygiene and health evaluation

; Only properly trained and authorised personnel shall handle the

Substance-handling procedures shall be well documented and strictly supervised.

: Wear protective clothing as described in section 8- Personal protection

Website: : Not available.

Exposure estimation and reference to its source - Environment: -ERGO2, ERCD3 I

Exposure assessment (environment): EXpOSUre estimation

; EUSES (~2.1) with setting from EU RAR (2008) Ala, A2, A3, A4

: The predicted exposure concentrations for air, the aquatic and t he terrestrial environment are below derived PNEC vzlues. resulting in RCRs c 1.

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Exposure assessment : ECETOG TRA (04/2010;) (human):

Section 4 - Guidance to Downstream User to evaluate if he works inside the boundaries set by the ES Environment : Under the above listed conditions the process is deemed safe.

Other conditions should only be considered when measurements or suitable calculations show that the RCR Is < 1.

HeafZh : Under the above listed conditions the process j5 deemed safe. Other conditions should only be considered when measurements or suitable calculations show that the RCR is 1.

Additional good practice advice beyond the REACH CSA Environment : Not applicable. Health : The use of gloves is recommended for this process.

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