SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifiersProduct name : Methyl Eugenol

CAS-No. : 93-15-21.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses : Laboratory chemicals, Industrial & for professional use only.

1.3 Details of the supplier of the safety data sheetCompany : Central Drug House (P) Ltd

7/28 Vardaan HouseNew Delhi-10002INDIA

Telephone : +91 11 49404040Email : care@cdhfinechemical.com

1.4 Emergency telephone numberEmergency Phone # : +91 11 49404040 (9:00am - 6:00 pm) [Office hours]

SECTION 2: Hazards identification

2.1 Classification of the substance or mixtureClassification according to Regulation (EC) No 1272/2008Acute toxicity, Oral (Category 4), H302Skin irritation (Category 2), H315Eye irritation (Category 2), H319Carcinogenicity (Category 2), H351Specific target organ toxicity - single exposure (Category 3), H335

For the full text of the H-Statements mentioned in this Section, see Section 16.

Classification according to EU Directives 67/548/EEC or 1999/45/ECXn Harmful R22, R40, R36/37/38

For the full text of the R-phrases mentioned in this Section, see Section 16.

2.2 Label elementsLabelling according Regulation (EC) No 1272/2008Pictogram

Signal word WarningHazard statement(s)H302 Harmful if swallowed.

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Methyl EugenolCAS No 93-15-2

MATERIAL SAFETY DATA SHEETSDS/MSDS

H315 Causes skin irritation.H319 Causes serious eye irritation.H335 May cause respiratory irritation.H351 Suspected of causing cancer.

Precautionary statement(s)P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.P281 Use personal protective equipment as required.P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

Supplemental Hazard noneStatements

2.3 Other hazards - none

SECTION 3: Composition/information on ingredients3.1 Substances

Synonyms : Eugenol methyl ether4-Allyl-1,2-dimethoxybenzeneEugenyl methyl ether

Formula : C11H14O2Molecular Weight : 178,23 g/molCAS-No. : 93-15-2EC-No. : 202-223-0

Hazardous ingredients according to Regulation (EC) No 1272/2008Component Classification Concentration

4-AllylveratroleCAS-No. 93-15-2 Acute Tox. 4; Skin Irrit. 2; Eye <= 100 %EC-No. 202-223-0 Irrit. 2; Carc. 2; STOT SE 3;

H302, H315, H319, H335,H351

Hazardous ingredients according to Directive 1999/45/ECComponent Classification Concentration

4-AllylveratroleCAS-No. 93-15-2 Xn, R22 - R40 - R36/37/38 <= 100 %EC-No. 202-223-0

For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

SECTION 4: First aid measures4.1 Description of first aid measures

General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.

If inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contactWash off with soap and plenty of water. Consult a physician.

In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowedNever give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

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4.2 Most important symptoms and effects, both acute and delayedThe most important known symptoms and effects are described in the labelling (see section 2.2) and/or insection 11

4.3 Indication of any immediate medical attention and special treatment neededno data available

SECTION 5: Firefighting measures

5.1 Extinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixtureCarbon oxides

5.3 Advice for firefightersWear self contained breathing apparatus for fire fighting if necessary.

5.4 Further informationno data available

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.Evacuate personnel to safe areas.For personal protection see section 8.

6.2 Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into theenvironment must be avoided.

6.3 Methods and materials for containment and cleaning upSoak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closedcontainers for disposal.

6.4 Reference to other sectionsFor disposal see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handlingAvoid contact with skin and eyes. Avoid inhalation of vapour or mist.Normal measures for preventive fire protection.For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilitiesStore in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which areopened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

8.1 Control parametersComponents with workplace control parameters

8.2 Exposure controlsAppropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands before breaks andat the end of workday.

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Personal protective equipment

Eye/face protectionFace shield and safety glasses Use equipment for eye protection tested and approved underappropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protectionHandle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose ofcontaminated gloves after use in accordance with applicable laws and good laboratory practices.Wash and dry hands.Body ProtectionComplete suit protecting against chemicals, The type of protective equipment must be selectedaccording to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protectionWhere risk assessment shows air-purifying respirators are appropriate use a full-face respirator withmulti-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup toengineering controls. If the respirator is the sole means of protection, use a full-face supplied airrespirator. Use respirators and components tested and approved under appropriate governmentstandards such as NIOSH (US) or CEN (EU).

Control of environmental exposurePrevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge intothe environment must be avoided.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical propertiesa) Appearance Form: liquid

Colour: colourless

b) Odour no data availablec) Odour Threshold no data available

d) pH no data availablee) Melting point/freezing Melting point/range: -4 °C - lit.

point

f) Initial boiling point and 254 - 255 °C - lit.boiling range

g) Flash point 110 °C - closed cuph) Evapouration rate no data available

i) Flammability (solid, gas) no data availablej) Upper/lower no data available

flammability orexplosive limits

k) Vapour pressure no data availablel) Vapour density no data available

m) Relative density 1,036 g/cm3 at 25 °Cn) Water solubility no data availableo) Partition coefficient: n- no data available

octanol/water

p) Auto-ignition no data availabletemperature

q) Decomposition no data availabletemperature

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r) Viscosity no data availables) Explosive properties no data availablet) Oxidizing properties no data available

9.2 Other safety informationno data available

SECTION 10: Stability and reactivity10.1 Reactivity

no data available10.2 Chemical stability

Stable under recommended storage conditions.10.3 Possibility of hazardous reactions

no data available10.4 Conditions to avoid

no data available10.5 Incompatible materials

Strong oxidizing agents10.6 Hazardous decomposition products

Other decomposition products - no data availableIn the event of fire: see section 5

SECTION 11: Toxicological information

11.1 Information on toxicological effectsAcute toxicityLD50 Oral - rat - 810 mg/kg

Inhalation: no data available

Skin corrosion/irritationSkin - rabbitSerious eye damage/eye irritationno data availableRespiratory or skin sensitisationno data availableGerm cell mutagenicityno data availableCarcinogenicity

Limited evidence of carcinogenicity in animal studies

IARC: No component of this product present at levels greater than or equal to 0.1% is identified asprobable, possible or confirmed human carcinogen by IARC.

Reproductive toxicityno data available

Specific target organ toxicity - single exposureInhalation - May cause respiratory irritation.

Specific target organ toxicity - repeated exposureno data available

Aspiration hazardno data available

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Additional InformationRTECS: CY2450000

To the best of our knowledge, the chemical, physical, and toxicological properties have not beenthoroughly investigated.

SECTION 12: Ecological information

12.1 ToxicityToxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 6 mg/l - 96 h

LC50 - Oncorhynchus mykiss (rainbow trout) - 6 mg/l - 96 h

12.2 Persistence and degradabilityno data available

12.3 Bioaccumulative potentialno data available

12.4 Mobility in soilno data available

12.5 Results of PBT and vPvB assessmentPBT/vPvB assessment not available as chemical safety assessment not required/not conducted

12.6 Other adverse effectsToxic to aquatic life.no data available

SECTION 13: Disposal considerations

13.1 Waste treatment methodsProductOffer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensedprofessional waste disposal service to dispose of this material.Contaminated packagingDispose of as unused product.

SECTION 14: Transport information14.1 UN number

ADR/RID: -

14.2 UN proper shipping nameADR/RID: Not dangerous goodsIMDG: Not dangerous goodsIATA: Not dangerous goods

14.3 Transport hazard class(es)ADR/RID: -

14.4 Packaging groupADR/RID: -

14.5 Environmental hazardsADR/RID: no

14.6 Special precautions for userno data available

SECTION 15: Regulatory information

IMDG: - IATA: -

IMDG: - IATA: -

IMDG: - IATA: -

IMDG Marine pollutant: no IATA: no

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

no data available15.2 Chemical Safety Assessment

For this product a chemical safety assessment was not carried out

SECTION 16: Other informationFull text of H-Statements referred to under sections 2 and 3.

Acute Tox. Acute toxicityCarc. CarcinogenicityEye Irrit. Eye irritationH302 Harmful if swallowed.H315 Causes skin irritation.H319 Causes serious eye irritation.H335 May cause respiratory irritation.H351 Suspected of causing cancer.Skin Irrit. Skin irritation

Full text of R-phrases referred to under sections 2 and 3Xn HarmfulR22 Harmful if swallowed.R36/37/38 Irritating to eyes, respiratory system and skin.R40 Limited evidence of a carcinogenic effect.

Further informationThe above information is believed to be correct but does not purport to be all inclusive and shall beused only as a guide. The information in this document is based on the present state of ourknowledge and is applicable to the product with regard to appropriate safety precautions. It does notrepresent any guarantee of the properties of the product. Central Drug House (P) Ltd and its Affiliatesshall not be held liable for any damage resulting from handling or from contact with the aboveproduct. See www.cdhfinechemical.com for additional terms and conditions of sale.

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