patel f13 che 1110 ch4 (part 1) .ppt
TRANSCRIPT
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Chapter 3:The Mole: Relating the Microscopic
World of Atoms to Laboratory
Measurements
Brady & Senese 5th
d!
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Mole concept!
"ompare:
# g of $ to # g of %
Which ill ha'e more atoms((Why(() o*ygen b+c it has a higher
atomic number! ach atom of $ eighs ))) 1u
ach atom of % eighs )))) 16u
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What Is a Mole?
Mole: %ne mole is de,ned as the numberof atoms in e*actly #- grams of #-"carbons! !g:
# mole of $ .
# mole of % . # mole /a .
here atomic eight gi'en in Gram AtomicUnits
# mole of element 0 . gram atomic mass of0
1!# The mole con'eniently lin2smass to number of atoms ormolecules
1
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Relationships
1!# The mole con'eniently lin2smass to number of atoms ormolecules
3
# Mole of 0 . 4!--1 6 #-1units of 0
This is a con'ersion factor to con'ertbeteen uand g
23
1 g
6.0223 10 u
236.0223 10 u
1 g
atomic mass units (u) grams (g)
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Avogaros "um#er
Avogaros num#er7 ":%ne mole of anysubstance contains the same number ofunits
# mole of 0 . 4!-- 0 #-1units of 0
# mole $ . # mol /a"l .
# mole things .
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Moles: Atoms
5! g Si is ho many moles Si($o many Si atoms(
# mole of Si . -8! gms of Si
0 moles of Si . 5! gms of Si
0 . 9# 5!;+-8!
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Masses Atomic Mass: Weight of an atom in grams
!g! $7 "7 %
Molecular Mass: Weight of a molecule ingrams
!g! $-7 %-7 $-% $ormula Mass: Weight of an ionic compound
in grams! !g! /a"l7 "a9%$;-
Molar Mass: Weight of any substance in
grams
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$ormula Mass %$M& anMolecular Mass%MM&
"alculation of =ram Molecular Mass of'()
MW .
"alculation of =ram >ormula Mass of"aCl
MW .
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Relationships
1 mole
MM g
1!# The mole con'eniently lin2smass to number of atoms ormolecules
?
Molar Mass 9MM; g . # mole
@se this as a con'ersion factor tocon'ert beteen these uantities
mole1
gMM
Mass (g) mole
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Converting *et+een Mass anMoles
=i'en that the molar mass of "%-is 33!#g+mol
What mass of "%-is found in #!55 moles(
$o many moles of "%-
are there in # g(
#+33. 5+--
1!# The mole con'eniently lin2smass to number of atoms ormolecules
#
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,our -urn!
What is the molar mass of "a19%3;- ing+mol(
"a: 3!8
: 1!?C
%:#4!
A! -C?!-
B! -#5!-#"! 1#!#8
D! /one of these
1!# The mole con'eniently lin2smass to number of atoms ormolecules
##
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Mole conversion
What mass in g7 of "a19%3;- 9MM .
1#!#8 g+mol; ould a 1!- molesample ha'e(
A! #! 6 #)1 g
B! ?!? 6 #- g
"! 4! 6 #-4gD! #!4 6 #)-#g
! /one of these
1!# The mole con'eniently lin2smass to number of atoms ormolecules
#-
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.earning Chec/: MoleConversions
What is the a'erage mass of one molecule ofcarbon tetrachloride( 9MM of ""l3 is #51!8
g+mol;
#51!8+ 4!--1 6 #-1.-!55*#E-3
1!# The mole con'eniently lin2smass to number of atoms ormolecules
#1
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30( Chemical $ormula stoichiometr2
To relate components of a compound to thecompound uantity e loo2 at the chemicalformula
Fn /a-"%1there are 1 relationships:
- mol /a: # mol /a-"%1
# mol ": # mol /a-"%1
1 mol %: # mol /a-"%1
1!- "hemical formulas relateamounts of substances in acompound
#3
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.earning Chec/
"alculate the number of moles of sodium in
-!51 moles of sodium carbonate!
"alculate the number of atoms of sodium in-!51 moles of sodium carbonate!
1!- "hemical formulas relateamounts of substances in acompound
#5
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,our -urn
"alcium hosphate is idely found in nature
in the form of natural minerals! Fn one case asample is found to contain !843 moles ofphosphorus! $o many moles of "a19%3;-
are in that sample(!31-
1!- "hemical formulas relateamounts of substances in acompound
#4
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,our -urn!
$o many atoms of iron are in a #5!g sample of iron9FFF; o*ide 9MM #5?!Cg+mol;(
A! #!#1 6 #-1
B! ?!1? 6 #)-
"! 5!44 6 #--
D! #!88 6 #)#
! /one of these
1!- "hemical formulas relateamounts of substances in acompound
#C
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stimation o4 Mass Ratio
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,our -urn
"hlorophyll the green pigment in lea'es7 has
the formula "55$C-Mg/3%5! Ff !## g of Mg
is a'ailable to plant for chlorophyllsynthesis7 ho many grams of " ill be
reuired to completely use up the Mg(
.!1 g
1!- "hemical formulas relateamounts of substances in acompound
#?
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5ercent Composition
ercent composition is a list of the masspercent of each element in a compound
/a-"%1is
31!18G /a . total eight of /a+total mass of
compound! 34+#4 * # ##!11G " #-+#4 * #
35!-?G % 38+#4 * #
What is the sum of the percentcomposition of a compound( #G
1!1 "hemical formulas can be determined frome*perimental mass measurements
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5ercent Composition:Calculation? What is the G " in "%-( .-C!1 mass o4 element
7 %Mass o4 element8mass o4 +hole sample&9 1
1!1 "hemical formulas can bedetermined from e*perimentalmass measurements
-#
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.earning Chec/
A sample contained !#3#C g nitrogenand !335 g o*ygen! What is thepercentage composition of this
compound(
/ . -5G
%. C5G
1!1 "hemical formulas can bedetermined from e*perimentalmass measurements
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,our -urn!
A 15!5 g sample is found to contain-1!5G Si! What is the mass of Sipresent(
A! 4!4- 6 #)#g
B! 8!88 6 ##g
"! #!5# 6 #-g
D! 8!13 g
! /one of these
1!1 "hemical formulas can bedetermined from e*perimentalmass measurements
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Ienti42ing a compoun #aseon composition
"alculate theoretical G composition of /-%3!
1!1 "hemical formulas can bedetermined from e*perimental -3