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References
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Index
A
alloys 31-33, 150, 175
- applications 174-175
- corrosion resistance 170-171
- modulus of elasticity 14-17
- precipitation hardening 35, 160
- processing 151-157
- properties 150, 163, 165, 213-216
- solid solution hardening 35, 160
- strengthening mechanisms 160
alloys and grades 32, 149-150, 175
-case 48, 135
colony size 30, 178-181, 185
colony size/property correlations 191-192
colony structure 30-31, 178-179, 182
grain size
- CP titanium 154-156, 162-163
- fully equiaxed structure ( + alloys) 186-
188, 191, 208, 212, 242
lamellae 30-31, 178, 185
lamellae width 179, 182-183
layer 30, 39-40, 178-180, 185, 193-194,
247-275, 279-280
nucleation and growth 30-31
phase
- anisotropy 14-15
- CRSS 19
- crystal structure 13
- modulus of elasticity 14-17
- precipitation hardening 35
- shear modulus 15-16
- slip modes 17-19
- solid solution hardening 35
- twinning modes 20-21
- unit cell 14
platelets ( alloys) 38-39, 248-255, 260-
261, 275-276
plates ( alloys) 39, 252-256, 260, 275, 277
stabilizing elements 21-22
p (see primary )
2 alloys
- alloying elements 293-294
- 2 phase 294-295
- microstructures 294-296, 301-302
- properties 301-306
- Super 2 alloy 294-296
2 phase (Ti3Al)
- anti-phase boundaries 297, 299
- cleavage fracture 291-292
- crystal structure 290
- deformation modes 290
- ordered lattice 290-291
- planar slip 291-292
- prism shear 290-291
- slip systems 290
2 plates 294
2 precipitates 35-36, 160, 175, 180, 191,
212-216, 233, 242-243
' martensite (hexagonal) 27
'' martensite (orthorhombic) 27
'/ '' boundary 27, 29
+ alloys 32-33
- applications 224-232
- corrosion resistance 45-47
- crystallographic texture 184, 220
- modulus of elasticity 16-17, 221
- processing 177-190
- properties 190-224
ABAQUS 79
acicular martensite 27
acid leaching 54
aero-engine applications
- blisk 245-246
- cast fan frame 85, 229
- cast LPT blades 308-309
- cast transmission adapter case 229
- compressor casing 121-122, 228
- compressor rotor 110-111, 132-133, 286
- compressor spool 227-228, 244
- exhaust structure 284-285
- fan blades 225-226
- fan casing 81-82
- fan disk 80, 227, 286
- GE-90 9
- impeller 120-121, 245
- integrally bladed rotor 111-112, 227
370 Index
- manifold 101-102, 228-229
- TMC rings for rotating parts 325-327
- TMC shaft 326-327
aging ( + alloys) 180, 191, 212-216, 233,
242-243
aging ( alloys) 248-250, 253, 256-257, 261-
262, 274-278
aggressive environments 166-167
aircraft applications
- bulkhead forging 78, 81, 224
- cargo handling fittings 283
cast brake torque tube 285
- cast exhaust nozzle flap 310-311
- helicopter rotor head 286-287
- landing gear beam forging 79-80, 224, 281-
282
- nacelle structure 284-285
- nut clips 283
- springs 284
- TMC augmentor actuater links 327-328
- wing attach fitting 225-226
- wingbox 100, 109
airframe application 8
airplane SR-71 3
Al equivalent content 23
allotropic transformation temperature 13-14
alloy classification 31-34
alloy element partitioning 35, 185, 202-203,
240-241
alloy refining 65
alloying elements 21-26, 293, 299
ammonium bifluoride etching (ABF) 130-131
anisotropic behavior ( processed condition)
264-274
anisotropy ( phase) 15
anodizing colors 355-356
annealing/aging temperature 180, 209
anti-phase boundaries 290, 297, 299
applications
- aero-engine (see aero-engine)
- aerospace 174
- aircraft (see aircraft)
- architecture 9-10, 354
- armor components 230
- automotive 11, 92-93, 311, 349-351
- biomedical materials 11, 343-349
- Boeing airframes 8
- coal burning power generation plants 174
- consumer goods 9, 355
- decorative arts 355-356
- downhole service 287
- GE-90 aero-engine 9
- heat exchangers 158-159, 172-173
- high performance vehicles 11
- jewelry 355
- offshore structures 9-10, 230, 232
- pressure vessels 103, 174
- pulp and paper production 174-175
- sports equipment 10, 351-353
- steam turbine blades 230-231
applications of CP titanium 167
armor components 230
artifacts (LM) 34, 136
artifacts (TEM) 140-143
athermal phase 28-29
autogeneous welding 108
B
alloys 32-34
- applications 281-287
- corrosion resistance 46
- modulus of elasticity 15-17
- precipitation hardening 36-40
- processing 247-261
- properties 261-281
- solid solution hardening 36
annealed structure ( + alloys)
- microstructure 178-179
- processing route 177-180
- properties 191-207, 213-214, 217-219, 238-
244
annealed structure (heavy stabilized al-
loys)
- microstructure 249-251
- processing route 248-251
- properties 262, 277-278
annealed structure (high strength alloys)
262
- fatigue crack propagation 269-271, 277,
279-281
- fracture toughness 272-276, 279-280
- HCF strength 266, 268, 279-280
- microstructure 252-253, 275-277
- processing route 252-253, 275
- tensile ductility 263-264, 275-276, 279
- yield stress 263-264, 275-276
eutectoid forming elements 22
grain size ( + alloys) 177, 183, 185, 194
grain size ( alloys) 249, 252, 259, 262,
279-280
isomorphous elements 22
phase
- crystal structure 14
- modulus of elasticity 15-17
- precipitation hardening 36-40
- slip modes 19
Index 371
- solid solution hardening 36
- unit cell 14
processed structure ( + alloys)
- microstructure 180-182
- processing route 180-181
processed structure (high strength alloys)
262
- fatigue crack propagation 269-271
- fracture toughness 272-274
- HCF strength 266-269
- microstructure 254-256
- processing route 254-255
- tensile ductility 264-265
- yield stress 264
stabilizing elements 22
transus temperature 32, 249-252
2 phase 294-295, 299
' particles 37-38, 249
bar 71-73
basket weave structure 31
bcc unit cell 14
bend factor 96
beta flecks 57-59, 67, 69
biaxial deformation 158, 161
bicycle applications 10, 352-353
bi-lamellar structure 191, 217-219, 242-243,
348
billet 71-73
bi-modal structure ( + alloys)
- crystallographic texture 184
- formation mechanism 185
- interconnecting p grains 209-212
- microstructure 183
- processing route 182-185
- properties 191, 194, 201-207, 209-212,
235-243
bi-modal structure (high strength alloys)
262
- fatigue crack propagation 270-271
- fracture toughness 272-273
- HCF strength 266, 268
- microstructure 259-260
- processing route 259-261
- tensile ductility 263-264
- yield stress 263-264
biomedical alloys 11, 345-346, 349
biomedical applications 11, 343-349
blended elemental powder route 91-93
blisk (bladed disk) 9, 245-246
blocker 78
blooming mill 151, 153
blue etch anodizing (BEA) 130-131
bone plate 346
brittle fracture 165-166, 168, 291-292
bulk head forging 78, 81, 224
Burger relationship 27, 30-31, 39, 184, 294
Burgers vector 17-19
burn resistant titanium alloys 336-337
“buy to fly” ratio 79
C
ac slip 18-19, 290
cargo handling fittings 283
cast aero-engine fan frame 85, 229
cast aero-engine transmission adapter case
229
cast brake torque tube 285
cast turbocharger rotor 350-351
cast golf club heads 10-11, 352-353
cast hip joint stem 348
cast porosity 86
cast pump impeller 86-87, 151
cast wing attach fitting 225-226
casting 85-89
casting electrode 71, 73
casting furnace 86, 88
ceramic shell 86-87
charpy impact energy 165
chemical milled compressor casing 121-122
chemical milling 121-122
- HNO3/HF ratio 122
- hydrogen pickup 122
chlorination 51-53
chlorinator 52
classification of alloys 31-34
cleavage fracture 165-166, 291-292
closed die forging 77
coatings 50
coherent 2 precipitates 35-36
coherent particles 37-38
coherent particles 37-38
coil 76, 152-153, 161
cold hearth furnace 63-64
cold hearth melted slab 65, 151, 153
cold hearth melting (CHM) 62-65
cold isostatic pressing (CIP) 91
cold rolling 76, 152-153
colony structure 30-31, 178-179
color of titanium 355-356
color wheel 144-145
commercially pure titanium (see CP titanium)
compression twins 20-21
compressive residual stress 114-115, 119-120
compressor casing 121-122, 228
compressor disk microstructure 182-183
compressor rotor 110-111, 133, 286
372 Index
compressor spool 227-228, 244
condenser 173
conditioning 71
connecting rod 92-93
consumer goods 9, 355
continuous layer 30, 39-40, 178-180, 185,
193-194, 247-275, 279-280
conventional machining 83-84
conventional sheet forming 95-96
coolant fed drills 84
coolants 83
cooling rate effects
- + alloys 178-183, 186, 188-189, 192-
197, 200, 235-236, 238-240
- alloys 254-255, 259-261
- Super 2 alloy 301-303
corrosion behavior 45-48
corrosion resistance 45-46, 166-167, 287
corrosive environments 166-167
cost elements for sponge 55-56
cost of titanium 5-6
cost sensitivity 11, 166-167
CP titanium
- annealing temperature 154, 156
- applications 167, 172-175
- castings 87, 151
- charpy impact energy 165
- corrosion resistance 45-47, 166-167
- crystallographic texture 161
- forgings 151
- grain size 154-156, 162-163
- HCF strength 160, 162
- iron content 150, 154-156
- microstructural features 151-152
- modulus of elasticity 16, 160
- oxygen content 31-32, 35, 150, 160-162
- processing route 151-154
- rolled products 152-153
- slip modes 17-19, 162
- strengthening mechanisms 160
- tensile ductility 160
- tubes 107, 157-158
- twinning modes 20-21
- yield stress 150, 160, 162-163
CP titanium grades 31-32, 149-150
crack closure 192, 199-200, 215
crack front geometry 192, 197-200, 206-207,
211-212, 218, 271-274, 276, 280
creep flattening 74
creep resistance ( + alloys) 191
- grain size (fully equiaxed structure) 242
- 2 precipitates (aging) 242-243
- annealed structure 238-241
- bi-lamellar structure 242-244
- bi-modal structure 238-241
- crystallographic texture 243
creep resistance ( alloys) 262, 278
creep resistance ( alloys) 307
creep resistance (Super 2 alloy) 302
creep resistance (TMCs) 323-324
crevice corrosion 46-47, 167-168, 170-171
crevice corrosion test 170-171
CRSS 19
crystal structure 14, 290-293, 296-297
crystallographic relationship 27, 31, 192, 297-
298
crystallographic texture 75-76, 157-158, 161,
184, 191, 220-224, 243
crystallographic texture investigation 137-
138, 144-145
cutting tool life 83
cutting tool materials 83
D
deep drawing 158
definition of alloys 33, 149
definition of + alloys 33
definition of alloys 33-34
definition of heavily stabilized alloys 247
definition of high strength alloys 247
DEFORM 79
deformation modes 17-21, 290-293
deformation twinning 20-21, 154-155, 160
density 13, 42
die forging 77-78
diffusion 43-44
diffusion bonded joint 99
diffusion bonding (DB) 98-101
diffusivity data 44
disks 80, 227, 286
distillation process 52-53
dovetail slots inspection 132
ductile fracture 164, 193-194
ductile inclusions 294-295
ductility loss 168
duplex structure (see bi-modal structure)
dye penetrant inspection 124, 133-134
E
eddy current inspection 124, 132
elastic properties 14-17, 221
electrical resistivity 41-42
electrochemical machining (ECM) 123
electro-deoxidation process (EDO) 56-57
electrolytic polishing 136-137, 139-144, 147-
148
Index 373
electrolytic refining 56
electromagnetic probe 132
electron beam welding (EBW) 108
electrowinning 56
ELI grades 32, 150, 213, 230
environmental effects 47-48, 222-223, 237,
305-306
equiaxed structure (see fully equiaxed struc-
ture
equivalent Al content 23
equivalent Mo content 28
etching 136-138
exhaust system for motorcycles 352
extra low interstitials (ELI) 32, 150, 213, 230
eyeglass frames 343
F
fan blades 225-226
fan casing 81-82
fan disk 80, 227, 286
fast diffusing elements 43-44
fatigue crack nucleation
- + alloys 195-196, 202-203, 205, 209
- alloys 268-269
fatigue crack propagation ( + alloys) 191
- 2 precipitation (aging) 213-215
- annealed structure 196-200
- bi-lamellar structure 218-219
- bi-modal structure 205-207, 237
- crystallographic texture 222-223
- fully equiaxed structure 210-211
- oxygen 214-215
fatigue crack propagation ( alloys) 262, 269-
271, 276-277, 279-281
fatigue crack propagation (TMCs) 321-322
fatigue life calculation 227
fatigue specimen preparation 147-148
Fe content 150, 154-156
Fe diffusivity 43-44
Fe stabilized phase 154-155
filler wire 107-108
first melt electrode 59-60
flame cut 59
fluidized bed 51
fluorescent dye 134
fluorescent penetrant inspection 133-134
focused ion beam device (FIB) 140
forging 77-81
forging press 77-78
forging process modeling 79
forgings 78, 80-81, 282-283, 287
formability index 96
Formula-One racing cars 11
fracture mode
- brittle 168
- ductile 164, 193-194
fracture surface examination 143-144
fracture toughness ( + alloys) 191
- 2 precipitates (aging) 215-216
- annealed structure 200, 206
- bi-lamellar structure 218
- bi-modal structure 206
- crystallographic texture 223
- fully equiaxed structure 212
- oxygen 215-216
fracture toughness ( alloys) 262, 272-276,
279-280
frame type heat exchanger 172-173
freezing segregation 61
friction stir welding 112-113
friction welding 109-112
Fukuoka Dome 9-10, 354
fully equiaxed structure ( + alloys)
- crystallographic texture 184, 220
- formation mechanism 186-187
- microstructure 186, 188
- processing route 186-188
- properties 191, 208-212, 221-222, 242
fusion weld 104-105
fusion welded pressure vessel 103
fusion welding 102-109
G
alloys
- 2+ lath structure 297-298
- alloying elements 293, 297, 299-300
- applications 308-312
- 2 phase 299
- boron additions 306
- microstructures 297-298
- oxidation behavior 300
- processing 306-307
- properties 307
- product forms 306
phase (TiAl)
- crystal structure 292
- ordered lattice 293
- slip systems 292
gas atomization process 89
gas atomized powder 90
gas metal arc welding (GMAW) 107
gas tungsten arc welding (GTAW) 106
gates 88
general corrosion 45-46
GFM 72
globular particles ( alloys) 256-257
374 Index
globular structure (see fully equiaxed struc-
ture)
globularization mechanism 185, 187
golf club heads 10-11, 352-353
grade designations 149
grade numbers 150
grain boundary (see layer)
grain shape 181-182, 255-257, 263-274
grain size (see grain size, grain size)
“grain switching” mechanism 97
gravity separation 63
Gregor 2
growth of plates 30
H
Hall-Petch relationship 154, 163
hard alpha 58, 67, 127-128
hardening mechanisms 34-40
hardening of phase 35-36
hardening of phase 36-40
HCF strength ( + alloys) 191
- 2 precipitates (aging) 213
- annealed structure 195
- bi-lamellar structure 218
- bi-modal structure 202-204
- crystallographic texture 222
- fully equiaxed structure 208-209
- oxygen 213
HCF strength ( alloys) 262, 266-269, 277-
279
HCF strength (CP titanium) 160, 162
HCF strength ( alloys) 307
HCF strength (Super 2 alloy) 304
HCF strength (TMCs) 321-322
HCF strength/yield stress ratio 160, 162, 195,
278-279
HDH process 22, 91
“hearth only” process 66
heat affected zone (HAZ) 104-105
heat exchanger 158-159, 167, 172-173
heating rate 249-250
helicopter rotor head 286-287
hexagonal martensite ( ') 27
hexagonal unit cell 14
HF/HNO3 etching 130-131
high density inclusions (HDIs) 57-59, 63, 65-
66, 70
high interstitial defects (HIDs) 57
high loading rates 165
high temperature alloys ( + alloys)
- 2 precipitates 233
- alloy element partitioning 240-241
- applications 244-246
- cooling rate 235-236, 238-241
- intermediate annealing treatment (bi-modal
structure) 240-241
- intermediate annealing treatment (lamellar
structure) 242-243
- processing 234-235
- silicides 233-235, 243
- volume fraction of primary 240
high temperature properties ( + alloys)
- creep resistance 238-243
- fatigue crack propagation 237
- HCF strength 202, 204
- LCF strength 236-237
- tensile ductility 202, 236
- yield stress 202, 235-236
high temperature properties (orthorhombic
alloys) 303-305
high temperature properties (Super 2 alloy)
301-302, 304, 306
hip joint implant 374-348
history of titanium 2
homogeneous distribution of platelets 39-
40, 250-251
homogenization annealing 70
homogenization time 152
hot band 76, 152-153
hot isostatic pressing (HIP) 85, 88-89,91
hot rolling 74, 151-152
hot working 71
Hunter process 53
hybride vehicle 338
hydraulic fluid resistance 285
hydride precipitation 168-169
hydrides (TEM artifacts) 140-142
hydrogen content 22
hydrogen diffusivity 44
hydrogen effects on properties 48, 222-223,
237
hydrogen embrittlement 48, 168
hydrogen pickup 47-48, 122, 156, 168
hydrogen powered vehicles 338
hydrogen removal 122
hydrogen storage materials 338-339
hydrogen tolerance 48, 156
hydrostatic tensile stress 169
I
ignition tests 336-337
ilmenite 2, 51
impeller 121, 244-245
incoherent platelets 39, 253
incoherent plates 30, 253
inert gas shield 106
Index 375
inert gas sweep 54
inertia weld macrostructure 110
inertia welded fan disk 80, 286
inertia welded compressor rotor 110-111, 133,
286
inertia welded compressor spool 227-228, 244
inertia welding 109-111
inertia welding modeling 109-110
ingot
- non-axisymmetric 63, 65, 151, 153
- round 59-60
ingot conditioning 71
inhomogeneous distribution of platelets 40,
250
inspection methods 123-134
inspection of DB joints 100
integrally bladed rotor 111-112, 227
intercrystalline fracture 193
interface phase (TEM artifact) 140-141
interference microscopy 137-138
intermediate annealing treatment (bi-modal
structure) 203-204, 240-241
intermediate annealing treatment (high
strength alloys) 253
intermediate annealing treatment (lamellar
structure) 217, 242
internal fatigue crack nucleation 115, 224
internal hydrogen 48
internal porosity 85
internal stress measurement 146-147
International Conferences on Titanium 1
interstitial stabilized defects 55
investment cast aero-engine frame 85, 229
investment casting 85-89
ion milling 139-142
iron content 150, 154-156
iron diffusivity 43-44
iron stabilized phase 154-155
isothermal particles 37-38
J
jet polishing 139
joining methods 102-113
K
Klaproth 2
Kroll 2
Kroll process 2, 51, 53
Kroll’s etch 136-137
L
lamellar microstructure 30-31, 177-180
landing gear beam forging 79-80, 224, 281-
282
laser deposition 93-94
laser deposition apparatus 95
laser shock processed impeller 121
laser shock processing 118-120
- intensity 119
- laser coupling 119-120
- residual stresses 120
lath structure ( 2+ ) 297-298
LCF strength ( + alloys)
- 2 precipitates (aging) 214
- annealed structure 199, 205
- bi-lamellar structure 218
- bi-modal structure 205, 236
- oxygen 214 light microscopy (LM) 135-138
limiting draw ratio (LDR) 158
linear friction weld microstructure 112-113,
227
linear friction welding 9, 111-112, 227
liquid hydrogen fuel system 174
LM artifacts 34, 136
low cost titanium parts 11
M
m value 97, 101
machined blisk 245-246
machined fan disk 80
machining 79-80, 83-84
macrostructure of inertia weld 110
manifold 101-102, 228-229
market shares (alloy type) 7
market shares (application) 5-8
martensite
- microstructure 27-28, 178-179
- modulus of elasticity 16-17
- MS temperature 28-29
- transformation 27
martensite (LM artifact) 34, 136
martensite (TEM artifact) 142-143
massive martensite 27
mean stress effect on HCF strength 224
mechanical polishing 135, 147
mechanical polishing artifacts 136
mechanical testing 147-148
melt related defects 57-58, 66-70
metal inert gas welding (MIG) 107
metallic titanium production
- processes 56-57
- sponge 51-55
melting 57-66
melting temperature 13
376 Index
metastable phase diagram 37
metastable phases ( , ') 36-38
Mg reduction 2, 53-55
microstructural features
- + alloys 177-190, 233-234
- alloys 248-261
- CP titanium 151-152
microstructure of colonies 30-31, 143-144,
178-179
microstructure of compressor disk 182-183
microstructure of DB joint 99
microstructure of fusion weld 104-105
microstructure of HAZ 104-105
microstructure of linear friction weld 112-113
microstructure of martensite 27-28, 178-179
microtexture investigation 137-138, 144-145
mill products 71-73
mill-annealed condition 74, 189-190
mill-annealed structure ( + alloys)
- crystallographic texture 184, 220
- microstructure 106, 190
- processing route 189-190
Mo equivalent content 28
modeling of forging process 79
modeling of inertia welding 109-110
modulated structure 28, 35-36
modulus of elasticity 14-17, 160, 221, 319
MS temperature 28
multistage compressor rotor 110-111
multi-zone ultrasonic inspection 127
N
“95-99” curves 114
Na reduction 2, 53
“near ” alloys 33
“necklace” microstructure 256-257
noble metals addition 45, 47, 150, 166-167,
170-171
non-aerospace applications 9-11
nonuniform platelets distribution 39-40,
250-251
nonuniform recrystallization 250
Normaski interference microscopy 137-138
nucleation of plates 30
nut clips 283
O
off-road racing trucks 11
offshore applications 9-10, 230
omega phase
- athermal transformation 28-29
- modulus of elasticity 16-17
- precipitation 37-38, 249
open die forging 77
ordered 2 phase 289, 294-295
ordered lattice 289, 291, 293, 297
orientation image microscopy (OIM) 144-145
orientation polyhedron 145
Orowan mechanism 274
orthorhombic alloys 303
orthorhombic martensite ( '') 27, 35-36
orthorhombic phase 296-270
overpeening 117-118
oxalic acid stain etch 136, 138
oxidation 48-50
oxidation resistant alloys 49, 284-285, 300
oxide layer 49, 135, 300
oxide layer thickness 355-356
oxide surface film passivation 45, 170
oxidizing environments 45, 166
oxygen content 31-32, 35, 150, 161-162, 191,
212-216
P
pack rolling 75, 152
paint 2
particulate reinforcement 92-93
passive oxide film 45, 170
permanent mold casting 89
PGM additions 45, 47, 150, 166-167, 170-171
phase diagrams 21-26
- Ti-Al 23
- Ti-Al-V (isothermal sections) 26
- Ti-Cr 25
- Ti-Fe 68
- Ti-Mo 24
phase transformations 27-31
pickling 121
pile-ups 35, 38, 263, 291
pitting corrosion 46
planar slip 35, 38, 162, 223, 292
plasma arc welding (PAW) 108-109
plate 71, 73-75
plate heat exchanger 172-173
plateau etching 143-144
platinum group metals (PGM) addition 45, 47,
150, 166-167, 170-171
polarized light microscopy 137-138, 156
pole figure determination 146
pole figures 161, 184, 220
polishing artifacts 136
porosity 85
powder metallurgy 89-92
powder size 90-91
pre-aging 40, 250-251
precipitate-free-zone 248
Index 377
precipitation hardening 35-40, 160, 175, 191,
212-216, 223, 233, 242, 262, 274-278
precipitation of platelets 38-39, 248-250,
253
precipitation of 2 35-36, 160, 175, 191, 212-
216, 223, 233, 242
precursors 38, 40, 249-250
PREP powder 90
pressure vessel 103, 174
primary ( p) size 182, 184, 204-206
primary ( p) volume fraction 184, 202, 209-
211, 240, 260
primary processing 70-76
processing control 254, 256-258
processing modeling 79
processing route
- + alloys 177-189, 234-235
- alloys 248-261
- CP titanium 152, 154
processing temperature 184, 234-235, 249
protective surface oxide film 45-46, 170
pseudo-binary phase diagram 33
purification of sponge
- acid leaching 54
- inert gas sweep 54-55
- vacuum distillation 54-55
R
R-ratio 191-192, 199, 215, 223-224
r value 158
racing bicycle 352-353
racing cars 11, 352
racing motorcycles 352
racing wheelchair 352-353
radiographic inspection 124, 129
rammed graphite casting 86
rectilinear shape 79
recrystallization 71, 154, 184-185, 187, 260
recrystallization annealing temperature 156,
184, 187, 260
recrystallization annealing time 249
reducing environments 45, 166
reduction by
- Mg 2, 53-55
- Na 2, 53
REP powder 89-90
residual compressive stress 114-115
residual tensile stress 115
revert 59, 70
ring rolled cylinder 82-83
ring rolling 81
risers 88
robotic peening 116
roller expansion 158, 172
rolling mill 74
rotating electrode process (REP) 89-91
rutile 2, 51
S
scale (oxide layer) 49, 300
scanning electron microscopy (SEM)
- fracture surface 143
- microstructure 143
- orientation image (OIM) 144-145
Schmidt factor 18
scrap 59, 70
seamless cylinder 81
secondary precipitates ( + alloys) 188,
191, 217-218
segregation 61, 67
self-diffusion of titanium 43-44
Sendzimir mill 76
shape memory alloys (TiNi)
- applications 343-344
- aging effect on MS 342-343
- crystal structure 339
- composition effect on MS 342
- “one-way” shape memory 343
- strain reversibility 341
- superelasticity 340-341, 344
- transformation sequence 340-341
- twinned martensite 329, 341
- “two-way” shape memory 344
shaped eddy current probe 132-133
shear modulus 15-16
shearing of coherent particles 35, 38, 212
sheet 71, 73, 75
sheet formability index 96
sheet formed parts 283
sheet forming 95-96
shell type heat exchanger 158, 172
shot peening
- Almen intensity 117
- fatigue life 117-118, 147-148
- machines 116
- pressure 114, 117
- residual stresses 114, 119-120
- stress relaxation 115
- time 117-118
shrinkage pores 86
side-plates 252-253, 255
silicides 233-235, 243
slip bands 35, 38, 162, 195-196, 213, 223
slip length/property correlation 192, 213
slip modes 17-19, 290-293
slip steps at the surface 48, 237
378 Index
slow diffusing elements 43-44
smeared metal 135
soft ball bats 353-354
soft zones along grain boundaries 248, 263-
280
solid solution hardening 35-36, 160
solidification 61, 67
“sonic shape” 79
specific heat capacity 41
SPF 97-99
SPF/DB 98-101
SPF/DB component 101-102
spinodal decomposition 28, 35-36
split crucible furnace 88
sponge 2
sponge cake 53
sponge cost elements 55-56
sponge crushing 55
sponge fines 91, 93
sponge fire 55
sponge particle size 55
sponge price 5-6
sponge production 51-55
sponge production (USA) 4
sponge production capacity (worldwide) 3-5
sports equipment 9-11, 351-353
“spring back” 96, 158-159
springs 284, 350-351
steam turbine blades 230-231
Steckel mill 76, 153
stent 343-344
stop-off agent 100
strain induced porosity 72-73, 127-128
strain localization 35-36, 38, 160, 162, 195-
196, 213, 223, 263-264, 275
strain rate sensitivity 97 strength to density ratio 42
stress corrosion susceptibility 175, 223
stress induced martensite (artifact) 34, 136
stress relieving treatment 180, 189, 209, 213-
214
strip 75-76
structure/property correlations
- + alloys 191
- alloys 262
subsurface fatigue crack nucleation 115, 224
Super 2 alloy 294-296, 302-304
superconducting Nb-47Ti alloy
- artificial pinning center material (APC) 333
- microstructure 332
- processing 332
- wire 332-334
superconductivity 329-331
superheat 65, 86
superplastic behavior 97
superplastic forming 97-99
superplastically formed part 99
surface damage 84, 114
surface effects on fatigue life 147-148
surface etching inspection 124, 129-131
surface oxide layer 49, 300
surface replication inspection 124, 134
surface treatment 113-123
suspension springs 350-351
symphathetic nucleation and growth 30
T
TR value 96
TEM artifacts 140-142
temperature dependence of CRSS 19
temperature dependence of E 16
temperature dependence of G 16
tensile ductility ( + alloys) 191
- 2 precipitates (aging) 213
- annealed structure 193-194, 202
- bi-lamellar structure 218-219
- bi-modal structure 194, 202, 236
- crystallographic texture 221
- fully equiaxed structure 208
- oxygen 213
tensile ductility ( alloys) 262-265, 275-276,
279
tensile ductility (CP titanium) 160
tensile ductility ( alloys) 307
tensile ductility (orthorhombic alloys) 305
tensile ductility (Super 2 alloy) 301-303
tension twins 20
texture 75-76, 157-158, 161, 184, 191, 220-
224, 243
texture investigation 137-138, 144-145
thermal conductivity 41
thermal expansion coefficient 41-42
thermo-mechanical processing 79-80
thickness of oxide layer 355-356
thin foil preparation 137, 139-140
through-transus processed structure (high
strength alloys) 262
- microstructure 257-258
- processing route 256, 258
Ti-Al phase diagram 23
Ti-Al-V (isothermal sections) 26
Ti-Cr phase diagram 25
Ti-Fe phase diagram 68
Ti-Mo phase diagram 24
TiCl4 2, 51-53, 55-56
- distillation 52-53
Index 379
- reduction by Mg 2, 53-55
- reduction by Na 2, 53
TiN 68
TiO2 2, 51-53
titanium fire (aero-engine compressor) 335-
336
titanium matrix composites (TMCs)
- applications 325-328
- carbon coating on fibres 317
- cost 325-326, 328
- cross plies 315
- cross weave wires 317
- degradation 323, 325
- fibre architecture 319-321, 323-324
- fibre/matrix interface 317
- fibre orientation 319-321, 323-324
- fibre touching 314, 316
- fibres 313-314
- microstructure 315
- monotape 315-316
- oxidation 323, 325
- processing methods 314
- properties 318-324
tool life 83
torque monitoring 84
transmission electron microscopy (TEM) 139-
142
tube welding 106-107, 157-158
tubes 157-158, 172
tungsten inert gas welding (TIG) 89, 106
turnings 59
twinning 138, 154, 161
twinning modes 20-21
twins 138, 155
type I defects 57-58, 67-68, 127
type II defects 57-59, 69
U
ultrasonic inspection 124-129
- detection capability 125
- “false positives” 126
- multi-zone method 127
- scan trace 125
- sonic shape 79, 128
- transducer 124
- ultrasonic image 127-128
undeformable platelets 39
unit cell 14, 291, 293, 297
unrecrystallized grain structure 180-181, 254-
257
upsetting 78
usage by alloy type (USA) 7
usage by market sector
- Japan 6
- USA 7-8
- USSR 6
V
vacuum arc remelting (VAR) 58-62
vacuum casting furnace 88
vacuum distillation of sponge 54
vacuum distillation process (VDP) 54-55
vapor honing 116
VAR final step 66
VAR furnace 61-62
VAR ingot 59-60, 151
void coalescence 164
void nucleation 164
voids 72, 127-128
volume fraction of phase 247, 250, 253
volume fraction of plates 253, 260
volume fraction of 2 precipitates 35, 233
W
warm forming 159, 249
wavy slip 35, 161-162
wax pattern 86
weld repair (castings) 88-89
weldability 151, 170
welding 102-113
welding of tubes 106-107, 157-158
Widmanstätten structure 31, 178
wingbox 100, 109
X
X-ray computer tomography 129
X-ray diffraction 146-147
Y
yield stress ( alloys) 150, 160, 175
yield stress ( + alloys) 191
- 2 precipitates (aging) 213, 242-243
- annealed structure 193, 202
- bi-lamellar structure 218-219
- bi-modal structure 202, 236
- crystallographic texture 221
- fully equiaxed structure 208
- oxygen 213
yield stress ( alloys) 262-264, 275-276, 279
yield stress (CP titanium) 150, 160
yield stress ( alloys) 307
yield stress (orthorhombic alloys) 304-305
yield stress (Super 2 alloy) 301-304