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Remote sensing of atmospheric composition (with a focus on tropospheric and stratospheric trace gases)
Michel Van Roozendael Royal Belgian Institute for Space Aeronomy (BIRA-IASB)
SCIAMACHY book
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Content • Basics of remote-sensing of atmospheric gases
• Observations platforms
• Spectral ranges
• Radiative transport and retrieval methods
• Limb and occultation techniques
• Nadir sensing of the tropospheric composition using UV-Vis and TIR observations (GOME and IASI)
• Future missions
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Basics of (atmospheric) remote sensing • Location of measurement is different from that of the instrument
⇒ Information from atmosphere must be propagated to instrument by means of electromagnetic radiation
⇒ Remote sensing requires ‘retrieval’ = derivation from the atmospheric information from the radiation characteristics measured by the instrument
⇒ Most common instruments: spectrometers
• Radiation comes from a natural source (sun, moon, stars, earth/atmosphere emission, …) directly, after reflection, or scatttering ⇔ passive remote sensing
or
• Radiation comes from an artificial light source (lamp, laser, …) ⇔ active remote sensing
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Basics of remote sensing (2)
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Basics of remote sensing (3)
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UV-VIS-NIR sounders TIR sounders
sun Earth
4 µm
2500 cm-1
Abso
rban
ce
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Wavelength ranges in remote sensing
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• UV some absorptions + profile information, aerosols • VIS surface information (vegetation) some absorptions aerosol information • IR temperature information cloud information water / ice distinction many absorptions / emissions + profile information
• MW clouds are transparent ice / water contrast surfaces
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Remote-sensing platforms
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Ground, aircraft, balloon, rocket, satellite
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• (Near) Polar Orbit: → orbits cross close to the pole → global measurements are possible → low earth orbit LEO (several 100 km) → ascending and descending branch
• Special case: sun-synchronous orbit: – overpass over given latitude always at the same local time,
providing similar illumination – for sun-synchronous orbits: day and night branches
• Geostationary Orbit: → satellite has fixed position relative to the Earth → parallel measurements in a limited area from low to
middle latitudes → 36 000 km flight altitude, equatorial orbit
Satellite Orbits
8 http://marine.rutgers.edu/mrs/education/class/paul/orbits2.html
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Satellite observation geometries Nadir:
Backscattered solar radiation and/or emission measurements (also nighttime)
Good spatial coverage and resolution Low vertical resolution
Solar occultation:
Direct solar absorption High vertical resolution Low spatial resolution; low spatial coverage
Limb: Scattered light at the limb (UV-Vis) Limb emission (IR) ⇒ also nighttime High vertical resolution Low spatial resolution; high spatial coverage
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Atmospheric radiative transfer
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Atmosphere
Earth surface
Scattered direct radiation
Diffuse reflected radiation
Scattered reflected radiation
Multiple scattered direct radiation
Emitted radiation
Scattered emitted radiation absorption
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Radiative transfer equation
11
Express the variation of the diffuse radiation in height z at one wavelength:
)()(
),,,,()(
),,,,()(
),,(),,,,()(
),,())()((),,(
/))((/
/)(
TBz
eAzPddeFz
eFzPz
zIzPddz
zIzzzIdzd
zsol
zsol
ε
ϕµϕµµϕπ
ς
ϕµϕµπ
ς
ϕµϕµϕµµϕπ
ς
ϕµςεϕµµ
µττπ
µτ
µτ
π
+
′′′′+
−+
′′′′′′+
+−=
′−−−
−
−
∫ ∫
∫ ∫
000
0
2
0
1
0
00
2
0
1
1
4
4
4
Fsol flux from the sun P weighted phase function for scattering A surface albedo B Planck radiation τ optical depth
loss by extinction
gain by multiple scattering
gain by single scattering of solar radiation
gain by reflection of light from the surface
gain by emission
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Retrieval: principle
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Output Fitted spectrum
Continua H2O, CO2
CKD, MT_CKD
X-Sections (Hitran)
Synthetic spectrum Instrumental Line Shape
Lines list (Hitran, Geisa) Forward RT Model
Nadir,Limb Ground
Model
P,T profiles xa a priori vmr
Fit e.g. OPTIMAL ESTIMATION
Spectra Measurement y
Sa
a priori covariance matrix
Se
Measurement error covariance matrix
Laboratory spectroscopy
Inversions
Atmospheric chemistry
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O3 H2O NO2 SO2 H2CO, C2H2O2 IO BrO
H2O CO2 CH4 N2O O3 CO HNO3 NH3 CFC11, CFC12, … CH3OH, HCOOH, C2H2, C2H6,… + isotopologues
O2 H2O, OH, HO2 HNO3 HCl, BrO, ClO, HOCl O3 CO HCN, CH3CN
GOME, GOME-2, SCIAMACHY, OMI at nadir SCIAMACHY, OSIRIS at limb
TES, AIRS, IASI, MOPITT at nadir MIPAS, ACE at limb
DMR, MLS at limb
4400 4200 2500 20000.0
0.5
1.0
Wavenumber (cm-1)
Tra
nsm
itta
nce
CO
2-0
1-0
CO2 CH4 CO
SCIAMACHY, GOSAT, OCO at nadir
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Principle of limb/occultation profiling
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Ideal technique for the study of stratospheric composition
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Ozone profiles from 6 limb sensors
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Monthly zonal mean profiles of ozone mixing ratio (ppmv), for January 2008
Stellar occultation
Thermal IR UV-Vis limb scattering
UV-Vis limb scattering
Microwave Solar occult.
V. Sofieva, FMI
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Sampling of limb sensors
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Sofieva et al., Earth Syst. Sci. Data, 5, 349–363, 2013
Global coverage in few months
Global coverage in few days
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Data records from Limb-sounding satellite instruments between 1978 and 2010
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Still
in o
pera
tion
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Altius: new limb imaging concept
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Limb scanning 2D limb imaging
Recently approved as an ESA Earth Watch mission
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https://www.imk-asf.kit.edu/english/1189.php
The very cold conditions in Arctic winter 2010/2011 led to the first Northern Hemisphere ‘ozone hole’
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Polar Stratospheric Clouds (PSC) and Polar Mesospheric Clouds (NLC)
Mesospheric ozone loss due to solar proton event (Oct 2003)
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Limb TIR UPPER-TROPOSPHERIC SOUNDINGS
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Ethane (C2H6) from MIPAS
Anthropogenic emissions
ppbv
Courtesy of G.Stiller, KIT
Ethene (C2H4) from ACE-FTS
Herbin et al., GRL, 2009
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Nadir geometry
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Gas layer
Surface
Z
0
CO2 CH4 CO
Near infrared range
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Nadir geometry
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Gas layer
Surface
Z
0
Scattering reduces sensitivity close to the surface
O3 NO2 SO2 H2CO BrO …
UV and visible range
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Nadir geometry
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Gas layer
Surface
Z
0
Sensitivity near the surface depends on thermal contrast
Thermal infrared range
H2O N2O
O3 CO
HNO3 NH3 SO2
CFC11, CFC12, …
CH3OH, HCOOH,
C2H2, C2H6,…
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Solar Backscatter UV (SBUV)
• Retrieval of ozone profile information from measurements at several wavelengths
• 12 wavelengths (250 – 340 nm) • spectral band with of the channels : 1.1 nm • horizontal resolution : 200 x 200 km2 • vertical resolution : approx. 8 km
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SBUV measurement principle
• Because of the large ozone absorption the penetration depth depends on the wavelength
• Comparison of measurements at different wavelengths provides profile information
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Total Ozone Mapping Spectrometer (TOMS) • Global total ozone mapper • 6 wavelengths in the UV • good spatial resolution (50x50 km2) • global coverage in 1 day • Additional products (SO2, aerosols)
The TOMS programme: Satellite Period Nimbus 7 Oct 78 – May 93 Meteor3 Aug 91 – Dec 94 Adeos Aug 96 – Jun 97 Earth Probe Jul 96 – Dec 97 Dec 97 – Dec 2006
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Global Ozone Monitoring Experiment (GOME) • First simultaneous measurements of complete spectrum
from the UV to the near IR • good spectral resolution (0.2 – 0.4 nm) • use of DOAS to retrieve columns of a number of species
(O3, NO2, OClO, BrO, HCHO, SO2, H2O) • use of UV wavelengths to retrieve ozone profiles (BUV
technique) • global coverage in 3 days
Operation on ERS-2: From April 1995 until July 2011 Successors: SCIAMACHY ENVISAT (2002-2012) GOME-2 METOP (2006-now) OMI AURA (2004-now) …
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Beer-lambert law applied to light transmission through a slab in the atmosphere
𝐼𝐼 𝜆𝜆 = 𝑰𝑰𝟎𝟎(𝜆𝜆) ∙ 𝑒𝑒− ∑ 𝝈𝝈𝒊𝒊 𝜆𝜆 ∙𝑐𝑐𝑖𝑖∙𝐿𝐿 + 𝜺𝜺𝑹𝑹𝑹𝑹𝑹𝑹 𝜆𝜆 +𝜺𝜺𝑴𝑴𝒊𝒊𝑴𝑴 𝜆𝜆 ∙𝐿𝐿
Rayleigh scattering ~ λ-4 Mie Scattering ~ λ-(1…3) Trace gases
Remove by high-pass filtering High frequency Broadband band extinction
𝐼𝐼 𝜆𝜆 = 𝑰𝑰𝟎𝟎(𝜆𝜆) ∙ 𝑒𝑒− ∑ 𝝈𝝈′𝑖𝑖 𝜆𝜆 ∙𝑐𝑐𝑖𝑖∙𝐿𝐿 + 𝝈𝝈𝒃𝒃𝒊𝒊 𝝀𝝀 + 𝜺𝜺𝑹𝑹𝑹𝑹𝑹𝑹 𝜆𝜆 +𝜺𝜺𝑴𝑴𝒊𝒊𝑴𝑴 𝜆𝜆 ∙𝐿𝐿
DOAS Frequency separation in the wavelength space
DOAS Differential Optical Absorption Spectroscopy
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O3 transmission
Polynomial 3rd degree
Differential spectrum
Inte
nsity
(a.u
.) Exemple of frequency separation
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• UV-Vis cross-sections are independent of pressure and weakly dependent on temperature (can be linearised)
• Molecules absorbing in UV-Vis are generally short-lived
UV-Vis absorption cross-sections
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Nadir geometry
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Gas layer
Surface
Z
0
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Air Mass Factor (AMF) The AMF is defined as the ratio of the trace gas slant optical density to the vertical one in the atmosphere: The AMF expresses the sensitivity of the measurement, and depends on a variety of parameters such as: • wavelength • geometry • vertical distribution of the species • clouds • aerosol loading • surface albedo
v
sAMFτλτ ,...),( Θ
=
Because of the optically thin approximation, the AMF depends weakly on the vertical column the idea is that if all other dependences are known, the measured signal is proportional to the VC.
𝐴𝐴𝐴𝐴𝐴𝐴 𝜆𝜆,𝜃𝜃 =−log 𝐼𝐼− 𝜆𝜆,𝜃𝜃 𝐼𝐼+ 𝜆𝜆,𝜃𝜃⁄
𝜎𝜎(𝜆𝜆) ⋅ 𝑉𝑉𝑉𝑉
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AMF(z) dependences
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Surface albedo (or reflectivity)
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440 nm
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Surface albedo climatology (MODIS)
440 nm July
440 nm Dec.
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Cloud fractions
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GOME-2 FRESCO+ (TEMIS)
Clouds detected as bright targets above dark surfaces. Their altitude can be derived from depth of O2-A band absorption in the NIR.
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How do we get vertical resolution in nadir UV/vis observations?
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Long-term ozone monitoring
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ESA CCI
A few highlights from GOME and successor missions
OMI ….
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GOME formaldehyde, July 1996
Wagner and Platt, Satellite mapping of enhanced BrO concentrations in the troposphere, Nature, 395, 1999, 486-490
Polar BrO « explosion events »
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SCIAMACHY mapping of carbon gases CO2 and CH4
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Infrared Atmospheric Sounding Interferometer • advanced thermal IR
sounder. • global measurements 2
times per day (at 9h30 and 21h30 local solar time)
MetOp IASI
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Vertical profile information from TIR Altitude information can be derived from: 1. Pressure broadening of absorption
lines 2. Temperature dependence of line
strengths
Vertical profile information up to ~35 km max Details of retrievable profile information depend on molecule, S/N, spectral resolution of instrument…
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Examples of averaging kernels for ozone and CO
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IASI, DOFS=3.5 Ozone CO
Averaging kernels
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Surface emissivity
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Emissivity retrieved from satellite hyperspectral imagers (IASI)
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Thermal contrast (IASI)
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Day Night
Clerbaux et al, Atmos. Chem. Phys., 9, 6041–6054, 2009
Thermal contrast is highest in the morning over land surfaces
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A few IASI highlights
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CO concentrations due to fires observed last fall over Indonesia Mediterranean tropospheric ozone summer anomaly
Safieddine et al., ACP, 14, 10119-10131, 2014 Courtesy M. George, LATMOS
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Volcanic SO2 plume detection
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La Soufrière Hills (Montserrat)
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Overview of current and future nadir missions 1995 2000 2005 2010 2015 2020 2025 2030
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ERS-2 GOME ENVISAT SCIAMACHY
METOP-A GOME-2/IASI METOP-B
METOP-C NPP OMPS
AURA OMI
JPSS-1 OMPS JPSS-2 OMPS
Sentinel-5 P S4/ MTG-S1
S5+IASI-NG/ EPS-SG S4/ MTG-S2
Copernicus
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CEOS ACC 10 | June 2014 | Slide 50
The Sentinel Missions for Copernicus Atmosphere Services
GEOstationary (GEO) – Hourly revisit time over Europe – Mainly air quality – Diurnal cycle of tropospheric composition Sentinel-4 (on MTG-S)
Low Earth Orbit (LEO) – Daily revisit time global coverage
– Climate, air quality, ozone & UV
– Tropospheric & stratospheric composition
Sentinel-5 + IASI-NG (on MetOp-SG)
Sentinel-5 Precursor (dedicated platform)
2015 2016 2017 2018 2019 2020 2021 2022 2023 2024 2025 2026 2027 2028 2029 2030Sentinel-5pSentinel-4 - 1Sentinel-5 - 1Sentinel-4 - 2Sentinel-5 - 2Sentinel-5 - 3
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Sentinel-5 Precursor - TROPOMI • TROPOspheric Monitoring Instrument on
ESA Sentinel-5 Precursor (TROPOMI) • Pushbroom imager design similar to OMI,
but with: Improved spatial resolution (7x7 km2) Improved S/N ratio More spectral channels covering UV-
VIS-NIR-SWIR Spectral bands: 270-500 nm, 675-775 nm, 2305-2385 nm
Launch: November 2016
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Summary / conclusion • Satellite observations of atmospheric composition in the UV/vis, NIR and
thermal IR provide consistent global datasets for many species distributed between the surface and the mesosphere
• The measurements are averaged horizontally and vertically which makes them difficult to interpret
• Remote sensing in an indirect method that necessitates use of a priori information in the data retrieval which has an impact on the results
• Visible and NIR measurements provide good sensitivity to the boundary layer, the thermal IR has intrinsic vertical information
• The future of nadir missions is bright, but we are facing a limb-sensor gap for the continued monitoring of the stratospheric composition
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Thank you for your attention!
Questions?
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