sicherheitsdatenblatt_zvei_gb03.2013

8/13/2019 Sicherheitsdatenblatt_ZVEI_GB03.2013

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BETTER SAFE THAN SORRY! LEAD BATTERY KNOW HOW

AND ACCIDENT PREVENTION. ALL Banner STARTER BATTERIES ARE DECLARED

AS ACID FILLED WET BATTERIES UN 2794 .


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This leaflet was prepared by the Working Group on Environment and Occupational Health of theZVEI German Electrical and Electronic Manufacturers Association

CAS-No. Description Content R-phrases

7439-92-1 blue lead

7439-92-1 lead alloys with

traces of As,Sb

34Weight%

lead-containingBattery paste

31Weight % R61-20/22-33-62-52/53

7664-93-9 sulphuric acid 34Weight% R35

ZVEI information leaflet No. 1eEditionSeptember 2012

Instructions for the safe handling oflead-acid accumulators (lead-acid batteries)

The REACH-regulation (1907/2006/EC) has replaced thedirective on safety data sheets(91/155/EC). REACHdescribes the setting up andupdating of safety data sheetsfor substances andpreparations. For articles like lead-acid batteries safetydata sheets are not required.

This leaflet addressesmanufacturers of batteriesand is meant to applyvoluntarily.

The notes are meant to helpto comply with legal require-ments but do not replacethem.

1. Substances / formulationand company name

Data on the productTrade name

Lead-acid batteryfilled withdiluted sulphuric acid

Data on the manufacturer:

Telephone:Facsimile:

2. Hazardous subs tances

3. Potential hazards

No hazards in case of an intactbattery and observation of theinstructions for use.

Lead-acid batteries havesignificant characteristics:

- They contain dilutedsulphuric acid, which maycause servere acid burns.

- During the Charging processthey develop hydrogen gasand oxygen, which untercertain circumstances mayturn into an explosive

mixture.

- They have an internalvoltage, which dependingon their level can bedangerous to the humanbody when touched.

- Standard EN 50272-2includes safety requirementsfor batteries and batteryinstallations and describesthe basic precautions toprotect against dangersderiving from electriccurrents, leaking gases orelectrolytes.


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Batteries are marked with the followin g hazard symb ols:

The meaning of the hazard symbols is:

No smoking, no open flames, no sparks.

Wear safety goggles.

Sulphuric acid.

Observe operating instructions.

Explosive gas mixture.

4. First-aid measures

5. Fire-fight ing measures

6. Measures to be taken incase of unintentionalrelease

Cleaning / take-up procedures

Use a bonding agent, such as

sand, to absorb split acid;Use lime / sodium carbonate forneutralisation; dispose with dueregard to the official localregulations, do not permitpenetration into the sewagesystem, the earth or waterbodies.

7. Handling and stor age

Store frost-free under roof;

prevent short circuits.

Protect plastic housings againstexposition to direct sunradiation.

Seek agreement with local waterauthorities in case of largerquantities.

If batteries have to be stored instorage rooms, it is imperativethat the instructions for use areobserved.

General Inform ation:

Sulphuric acid acts corrosive and damagestissue

after contact with skin rinse with water, remove and wash wetted clothing

after inhalation of acid inhale fresh airmist*)

after contact with the rinse under running water foreyes*) serveral minutes

after swallowing*) drink a lot of water immediately,and swallow activated carbon

Lead-containing classified as toxic for reproductionbattery paste

after contact with skin clean with water and soap

*) seek the advic e of a doctor.

Suitable extingui shing agentsWhen electrical devices are set in fire in general water is the suitable extinguishingagent. For incipient fires CO 2 is the most effective agent. Fire brigades are trainedto keep a distance of 1 m when extinguishing an electrical fire (up to 1 kV) withspray jet and a distance of 5 m with full jet. For electrical fires in electricalinstallations with voltages > 1 kV other distances are applicable depending on therespective voltage. Forfires in photovoltaicinstallationsotherrulesapply.

Unsuitable extingui shing agentsPowder fire extinguishers are not suitable, amongst others because of only minorefficiency, possible risks or collateral damages.

Special protective equipmentFor larger stationary battery installations orlarger stored quantities: protectivegoggles, respiratory and acid protective equipment, acid-proof clothing.


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8. Exposure limits andpersonal protectiveequipments

9. Physical and chemicalproperties

Lead Appearance:form: solidcolour: greyodour: odourless

Safety-related data

Solidification point: 327

CBoiling point: 1740

CSolubility in water (25

C):low (0,15 mg/l)

density(20

C): 11,35 g/cmvapour pressure (20

C)

Sulphuric acid (30 38,5 %)form: liquidcolour: colourlessodour: odourless

Solidification point: 35 bis 60

CBoiling point: ca. 108 114

CSolubility in water (25

C):complete

density (20

C): 1,2 1,3 g/cmvapour pressure (20

C)

10. Stability and reactivity ofsulphuric acid(30 to 38,5%)

Corrosive, inflammableliquid.

Thermal decomposition at338

C.

Destroys organic materialssuch as cardboard, wood,textiles.

Reacts with metalsproducing hydrogen.

Vigorous reactions with lyesand alkalis.

11. Data on t oxicolo gy of theconstituents

Sulphuric acidacts intensely corrosive on skinand mucous membranes. Theinhalations of mists may cause

damage to the respiratory tract.Lead and lead-containingbattery pastemay cause damage to the blood,nerves, and kidneys when takenin. Lead-containing battery pasteis classified as toxic forreproduction.

12. Data on the ecology of theconstituents

Preliminary remark:Relevant only if release iscaused by destruction of thebattery

Sulphuric acidWater-polluting liquid within themeaning of the German Water-Resources Act (WHG) Waterpollution class: 1 (mildly waterpolluting).

As described in section 6 use abonding agent, such as sand, toabsorb spilled acid or neutraliseusing lime / sodium carbonate.Dispose of under the locallyapplicable provisions.

Dispose with due regard toofficial local regulations,

Do not allowprogression into thesewage system, soil or bodies ofwater.

Lead and lead-containingbattery pastearehardly soluble in water.

Lead can be dissolved in anacidic or alkaline environment.Chemical and physical treatmentis required for elimination fromwater. Waste water containinglead must not be disposed of inuntreated condition.

8.1 No exposure caused by lead and lead-containing batterypaste.

8.2 Possible exposure caused by sulphuric acid and acid mist

during filling and charging.CAS-Nr. 7664-93-9

R-phrases R35 Causes severe burns.

S-phrases S 1/2 Keep looked up and out ofreach of children.

S 26 In case of contact with eyesrinse immediately with plentywater and seek medicaladvice.

S 30 Never add water to thisproduct (applies forconcentrated acid only

S 45 In case of accident or if youfeel unwell seek medicaladvice immediately (show thelabel where possible)

Threshold value on workplace 0,1 mg/m 3 *)

Hazard symbol C, corrosive

Personal protective equipment: Rubber, PVC gloves, acid-proof goggles, acid-proof clothing, safety boots.3) 0,5 mg/m3 at the lead battery production.


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13. Recyc The pointmanufactbatteries,dealers tabatteries,

secondar processin Spent leasubject toGermanOrdinancwith the r and withcontainer"Marking" Spent leaallowed tobatteries icomplian By no meelectrolytacid, be emanner.carried oucompanie 14. Trans 14.1 Batt

filled Land tranto ADR/R Special

transpgoods are notrequirethey meaccordi598)

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Hazard UN-no.: Naming

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Packing Hazard

ling informa

of sale, therers and imp

respectively tke back deadand render th

lead smelter .

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ns may the, the dilutedmptied in an ihis process it by the procs.

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sportation aID

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Hazard label

ir transport IATA-DGR

Class: 8

UN-no.: 279


Hazardclass

Packaging I

4.3 Batteriesand transpo ADR/RID

Hazardclass

UN-no.: 279


Packinggrou

Packing Insttransport agoods (pacboxes)or Special Ptransport agoods (in b

Hazardlabel:

ADR TunnelE

Note: theseapplied by tr Lead-acid b2800 aswell.

5. Marking

accordancew governing

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: 8

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Editor:ZVEI Zentralverband Elektrotechnik- und Elektronikindustrie e. V.Fachverband BatterienLyoner Strae 960528 Frankfurt

Fon.: +49 69 6302-283Fax: +49 69 6302-362Mail: [email protected]

ZVEI 2012In spite of all due care, however, we cannot accept any liabilitythat the information is complete or correct or up to date.


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Banner GmbHBanner Strae 1, A-4021 Linz

Tel. ++43/(0)732/3888-0, Fax ++43/(0)732/3888-21399E-Mail: office@ banner batterien.com

BULGARIEN Banner Baterii Bulgaria EOOD / - Ul. Ljublana 46, J&L Center, 1. Stock / . 46, J&LCenter, . 1., BG-1618 Soa / Telefon: / . +359/2/889 01 20Fax: / : +359/2/889 01 21E-Mail: [email protected]

DNEMARK Banner Batterier Danmark ApSSilovej 14, Solrd, DK-2690 KarlslundeTelefon: +45/70 20 60 61Fax: +45/70 20 60 69E-Mail: [email protected]

DEUTSCHLANDBanner Batterien Deutschland GmbHKesselbodenstrae 3, D-85391 Allershausen (Mnchen)Telefon: +49/(0)6441/30 73-23000Fax: +49/(0)6441/30 73-23099E-Mail: [email protected]

Banner Batterien Deutschland GmbH -VerkaufsniederlassungLise-Meitner-Str. 5, D-41515 Grevenbroich (Dsseldorf)Telefon: +49/(0)6441/30 73-23500Fax: +49/(0)6441/30 73-23599E-Mail: [email protected]

Banner Batterien Deutschland GmbH -VerkaufsniederlassungAm Schwingbach 14-16D-35625 Httenberg/Rechtenbach (Frankfurt)Telefon: +49/(0)6441/30 73-23100Fax: +49/(0)6441/30 73-23199E-Mail: [email protected]

Banner Batterien Deutschland GmbH -Verkaufsniederlassung MutzschenZum Storchennest 3, D-04668 Grimma (Leipzig)Telefon: +49/(0)6441/30 73-23200Fax: +49/(0)6441/30 73-23299E-Mail: [email protected]

Banner Batterien Deutschland GmbH -Verkaufsniederlassung PforzheimSdweg 6, D-75245 Neulingen-Gbrichen (Pforzheim) -Telefon: +49/(0)6441/30 73-23300Fax: +49/(0)6441/30 73-23399E-Mail: [email protected]

Banner Batterien Deutschland GmbH -VerkaufsniederlassungFriedrich-Bckling-Str. 21, D-16816 Neuruppin (Berlin)Telefon: +49/(0)6441/30 73-23400Fax: +49/(0)6441/30 73-23499E-Mail: [email protected]

FRANKREICH Banner France SASZone Industrielle No. 2, 5, Rue Vauban, F-68170 RixheimTelefon: +33/(0)389/44 28 38Fax: +33/(0)389/54 13 28E-Mail: [email protected]

Banner Toulouse - Succursale80 Rue de Fenouillet, F-31200 TOULOUSETelefon: 05/61 32 72 11Fax: 05/61 32 88 94

Banner Ile de France - SuccursaleParc GVIO - Hall 1 - Batiment D , 86/114,avenue Louis Roche, F-92230 GennevilliersTelefon: 01/47 94 32 75Fax: 01/47 98 05 19

E-Mail: [email protected]

GROSSBRITANNIEN Banner Batteries (GB) Ltd.Units 5-8 Canal View Business Park,Wheelhouse Road, Rugeley, UK-WS15 1UY StaffordshireTelefon: +44/(0)1889/57 11 00Fax: +44/(0)1889/57 73 42E-Mail: [email protected]

STERREICH Banner GmbHBanner Strae 1, A-4021 LinzTelefon: +43/(0)732/38 88-0Fax: +43/(0)732/38 88-21399E-Mail: [email protected]

Banner Batterien sterreich GmbHBanner Strae 1, A-4021 LinzTelefon: +43/(0)732/38 88-0Fax: +43/(0)732/38 88-21399E-Mail: [email protected]

Banner/EAST PENN Battery Services GmbHBanner Strae 1, A-4021 Linz

Telefon: +43/(0)732/38 88-0Fax: +43/(0)732/38 88-21399E-Mail: [email protected]

Banner Kunststoffwerk GmbHTraunauweg 22, A-4030 LinzTelefon: +43/(0)732/38 88-21800Fax: +43/(0)732/38 88-21850E-Mail: [email protected]

Banner Batterien sterreich GmbH -VerkaufsniederlassungKrntner Str. 168, A-8053 GrazTelefon: 0316/27 21 52-22100Fax: 0316/27 21 52-22199E-Mail: [email protected]

Banner Batterien sterreich GmbH -

VerkaufsniederlassungBundesstr. 4, A-6063 Innsbruck/RumTelefon: +43/(0)512/26 20 70-22200Fax: +43/(0)512/26 20 70-22299E-Mail: [email protected]

Banner Batterien sterreich GmbH -VerkaufsniederlassungBanner Str. 1, A-4021 LinzTelefon: +43/(0)732/38 88-21601, 21602Fax: +43/(0)732/38 88-21699E-Mail: [email protected]

Banner Batterien sterreich GmbH -VerkaufsniederlassungLehenweg 6, A-6830 RankweilTelefon: +43/(0)5522/44 2 58-22300Fax: +43/(0)5522/45 3 57E-Mail: [email protected]

Banner Batterien sterreich GmbH -VerkaufsniederlassungLamezanstr. 5, A-1232 WienTelefon: 01/616 51 81-22000Fax: 01/616 21 90E-Mail: [email protected]

Banner Batterien sterreich GmbH -VerkaufsniederlassungSteingasse 207, A-9020 KlagenfurtTelefon: 0463/33 7 22-22400Fax: 0463/33 6 19-22499E-Mail: [email protected]

POLEN Banner Polska Sp. z o.o.ul. Gliwicka 234, PL-40861 KatowiceTelefon: +48/(0)32/203 72 45Fax: +48/(0)32/203 72 46E-Mail: [email protected]

Banner Polska Sp. z o.o. - Filiaul. Krta 2, PL-05850 Ozarw Mazowiecki (Warszawa)Telefon: +48/(0)22/721 14 47Fax: +48/(0)22/721 14 48E-Mail: [email protected]

RUMNIEN Banner Baterii Romania s.r.l.B-dul Biruinei nr. 67, RO-077145 Pantelimon, jud. llfovTelefon: +4/021/3000 627, +4/021/310 11 49Fax: +4/021/3000 637E-Mail: [email protected]

RUSSLANDOOO Banner Batterien / Krasnogorskij rajon, Promzona-37, pos.Archangelskoe /

-37, ., RUS-143420 Moskovskaja Oblast / Telefon: / : +7/(499)504 98 69Fax: / : +7/(499)504 98 69E-Mail: [email protected]

SCHWEIZ Banner Batterien Schweiz AG / Batteries Banner Suisse SA

Banner Strae 1, CH-5746 WalterswilTelefon: +41/(0)840 Banner (226637)Gratisfax: +41/(0)800 Banner (226637)E-Mail: [email protected]

Banner Batterien Schweiz AG - VerkaufsniederlassungBanner Strae 1, CH-5746 WalterswilTelefon: 0840 Banner (226637)Fax: 0800 Banner (226637)E-Mail: [email protected]

SLOWAKEI Banner Baterie SR, s.r.o.Za Stanicou 1, Nr. 1537, SK-83104 Bratislava 3Telefon: +421/(0)2/43 63 43 44Fax: +421/(0)2/43 42 18 74E-Mail: [email protected]

TSCHECHIEN Banner Baterie R, s.r.o.Uhnves, Ptelstv 1011, CZ-10400 Praha 10Telefon: +420/267 090-510Fax: +420/267 090-522E-Mail: [email protected]

TRKEI Banner Ak San. ve Tic. Ltd. ti.Beylikdz Mermerciler Sanayi Sit., 7. Cad. No:4(Hellmann Logistik binas), TR-34520 Beylikdz - stanbulTelefon: +90/212/877 85 10Fax: +90/212/879 29 72E-Mail: [email protected]

UNGARN Banner Batterien Hungria KftIpari park, Jedlik nyos u. 6, H-2330 DunaharasztiTelefon: +36/24/49 18 91Fax: +36/24/49 18 92E-Mail: [email protected]

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