1

060-0812 12 6 011-706-3236 Fax 011-706-4981

E-mail smatsuna@pharm.hokudai.ac.jp

1994 3

1994 4 I

1996 4

1998 3

1998 4

2000 3

2000 4

2001 3

2003 11

2000 4 DC1

2001 4

2007 4

2008 4

2011 4 ( )

2011 10 2015 3

ERATO,

2012 10

(ACT-C)

2015 4

2

2001

2004 6 Thieme Verlag Award (Best Presentation Award at BOS-2004)

2007 3

2008 Thieme Journals Award

2009 3 Mitsui Chemicals Catalysis Science Award of Encouragement

2009 12 Banyu Chemist Award

2010 2

2011 1 Emerging Investigator ( Chem. Comm.)

2011 5 Merck-Banyu Lectureship Award (MBLA 2010)

2013 8 Asian Rising Stars (15th Asian Chemical Congress, Singapore)

2015 11 Asian Core Program Lectureship Award (Korea)

2015 11 Asian Core Program Lectureship Award (Thailand)

2016 7

3

Publication List

1. Takehiko Iida, Noriyoshi Yamamoto, Shigeki Matsunaga, Hee-Gweon Woo, Masakatsu Shibasaki Enantioselective Ring Opening of Epoxides with 4-Methoxyphenol Catalyzed by Gallium Hetereobimetallic Complexes: An Efficient Method for the Synthesis of Optically Active 1,2-Diol Monoethers Angew. Chem. Int. Ed. 337, 2223-2226 (1998). 2. Erasmus M. Vogl, Shigeki Matsunaga, Motomu Kanai, Takehiko Iida, Masakatsu Shibasaki Linking BINOL: C2-Symmetric Ligands for Investigations on Asymmetric Catalysis Tetrahedron Lett. 339, 7917-7920 (1998). 3. Shigeki Matsunaga, Jagattaran Das, Jochen. Roels, Erasmus M. Vogl, Noriyoshi Yamamoto, Takehiko Iida, Kentaro Yamaguchi, Masakatsu Shibasaki Catalytic Enantioselective meso-Epoxide Ring Opening Reaction with Phenolic Oxygen Nucleophile Promoted by Gallium Heterobimetallic Multifunctional Complexes J. Am. Chem. Soc. 1122, 2252-2260 (2000). 4. Yun Sik Kim, Shigeki Matsunaga, Jagattaran Das, Akihiro Sekine, Takashi Ohshima, Masakatsu Shibasaki Stable, Storable, and Reusable Asymmetric Catalyst: A Novel La-linked-BINOL Complex for the Catalytic Asymmetric Michael Reaction. J. Am. Chem. Soc. 122 , 6506–6507 (2000). 5. Shigeki Matsunaga, Takashi Ohshima, Masakatsu Shibasaki Immobilization of asymmetric multifunctional catalysts on an insoluble polymer. Tetrahedron Lett. 441, 8473-8478 (2000). 6. Hiroyuki Nogami, Shigeki Matsunaga, Motomu Kanai, Masakatsu Shibasaki Enantioselective Strecker-type reaction promoted by polymer-supported bifunctional catalyst Tetrahedron Lett. 442, 279-283 (2001). 7. Naoki Yoshikawa, Naoya Kumagai, Shigeki Matsunaga, Guido Moll, Takashi Ohshima, Takeyuki Suzuki, Masakatsu Shibasaki Direct Catalytic Asymmetric Aldol Reaction: Synthesis of Either syn- or anti-α,β-Dihydroxy Ketones. J. Am. Chem. Soc. 1123, 2466-2467 (2001). 8. Naoya Kumagai, Shigeki Matsunaga, Naoki Yoshikawa, Takashi Ohshima, Masakatsu Shibasaki Direct Catalytic Enantio- and Diastereoselective Aldol Reaction Using a Zn-Zn-linked-BINOL Complex: A Practical Synthesis of syn-1,2-Diols. Org. Lett. 33, 1539-1542 (2001). 9. Naoya Kumagai, Shigeki Matsunaga, Masakatsu Shibasaki Enantioselective 1,4-Addition of Unmodified Ketone Catalyzed by a Bimetallic Zn-Zn-linked-BINOL Complex Org. Lett. 33, 4251-4254 (2001). 10. Shigeki Matsunaga, Takashi Ohshima, Masakatsu Shibasaki Linked-BINOL — an Approach towards Practical Asymmetric Multifunctional Catalysis— Adv. Synth. Catal. 3344, 3-15 (2002). 11. Jun Tian, Noriyuki Yamagiwa, Shigeki Matsunaga, Masakatsu Shibasaki An Asymmetric Cyanation Reaction and Sequential Asymmetric Cyanation-Nitroaldol Reaction Using a [YLi3{tris(binaphthoxide)}] Single Catalyst Component: Catalyst Tuning with Achiral Additives

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Angew. Chem. Int. Ed. 441, 3636-3638 (2002). 12. Naoya Kumagai, Shigeki Matsunaga, Tomofumi Kinoshita, Shinji Harada, Shigemitu Okada, Shigeru Sakamoto, Kentaro Yamaguchi, Masakatsu Shibasaki Direct Catalytic Asymmetric Aldol Reaction of Hydroxyketones: Asymmetric Zinc Catalysis with Et2Zn/Linked-BINOL Complex J. Am. Chem. Soc. 1125, 2169-2178 (2003). 13. Shinji Harada, Naoya Kumagai, Tomofumi Kinoshita, Shigeki Matsunaga, Masakatsu Shibasaki Direct Catalytic Asymmetric Michael Reaction of Hydroxyketones: Asymmetric Zinc Catalysis with Et2Zn/Linked-BINOL Complex J. Am. Chem. Soc. 1125, 2582-2590 (2003). 14. Shigeki Matsunaga, Naoya Kumagai, Shinji Harada, Masakatsu Shibasaki Anti-Selective Direct Catalytic Asymmetric Mannich-type Reaction of Hydroxyketone Providing anti-β-Amino Alcohols J. Am. Chem. Soc. 1125, 4712-4713 (2003). 15. Jun Tian, Noriyuki Yamagiwa, Shigeki Matsunaga, Masakatsu Shibasaki Efficient Two-step Conversion of α,β-Unsaturated Aldehyde to Optically Active γ-Oxy-α,β-Unsaturated Nitriles and its Application to Total Synthesis of (+)-Patulolide C Org. Lett. 55, 3021-3024 (2003). 16. Yutaka Suto, Naoya Kumagai, Shigeki Matsunaga, Motomu Kanai, Masakatsu Shibasaki Direct Ctalytic Aldol-type Reactions Using RCH2CN Org. Lett. 55, 3147-3150 (2003). 17. Tomofumi Kinoshita, Shigemitsu Okada, Sun-Ryung, Park, Shigeki Matsunaga, Masakatsu Shibasaki Sequential Wittig-Catalytic Asymmetric Epoxidation Reaction Reusing Waste Ph3P(O): Application of α,β-Unsaturated N-Acylpyrrole as Ester Surrogate Angew. Chem. Int. Ed. 442, 4680-4684 (2003). 18. Noriyuki Yamagiwa, Shigeki Matsunaga, Masakatsu Shibasaki Heterobimetallic Catalysis in Asymmetric 1,4-Addition of O-Alkylhydroxylamine to Enones J. Am. Chem. Soc. 1125, 16178-16179 (2003). 19. Naoya Kumagai, Shigeki Matsunaga, Masakatsu Shibasaki An Efficient Synthesis of Bicyclic Amidines via Intramolecular Cyclization of Azide to Lactam Angew. Chem. Int. Ed. 443, 478-482 (2004). 20. Noriyuki Yamagiwa, Shigeki Matsunaga, Masakatsu Shibasaki Mechanistic Studies of a Reaction Promoted by the YLi3tris(binaphthoxide) Complex: Are Three 1,1’-Bi-2-naphthol Units in a Rare Earth-Alkali Metal Heterobimetallic Complex Necessary? Angew. Chem. Int. Ed. 443, 4493-4497 (2004). 21. Shigeki Matsunaga, Tomofumi Kinoshita, Shigemitsu Okada, Shinji Harada, Masakatsu Shibasaki Catalytic Asymmetric 1,4-Addition Reactions Using α, β-Unsaturated N-Acylpyrrole as a Highly Reactive Monodentate α,β-Unsaturated Ester Surrogate J. Am. Chem. Soc. 1126, 7559-7570 (2004). 22. Shigeki Matsunaga, Takamasa Yoshida, Hiroyuki Morimoto, Naoya Kumagai, Masakatsu Shibasaki Direct Catalytic Asymmetric Mannich-type Reaction of Hydroxyketone Using a Et2Zn/linked-BINOL

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Complex: Synthesis of either anti- or syn-β-Amino Alcohols J. Am. Chem. Soc. 1126, 8777-8785 (2004). 23. Yumi Abiko, Noriyuki Yamagiwa, Mari Sugita, Jun Tian, Shigeki Matsunaga, Masakatsu Shibasaki* Catalytic Asymmetric Cyano-phosphorylation of Aldehydes Promoted by Heterobimetallic YLi3tris(binaphthoxide) (YLB) Complex Synlett 2434-2436 (2004). 24. Naoya Kumagai, Shigeki Matsunaga, Masakatsu Shibasaki* Cooperative Catalysis of a Cationic Ruthenium, Amine Base, and Na Salt: Catalytic Activation of Acetonitrile as a Nucleophile J. Am. Chem. Soc. 1126, 13632-13633 (2004). *25. Noriyuki Yamagiwa, Jun Tian, Shigeki Matsunaga*, Masakatsu Shibasaki* Catalytic Asymmetric Cyano-ethoxycarbonylation Reaction of Aldehydes Using a YLi3tris(binaphthoxide) (YLB) Complex: Mechanism and Roles of Achiral Additives J. Am. Chem. Soc. 1127, 3413-3422 (2005). *26. Takamasa Yoshida, Hiroyuki Morimoto, Naoya Kumagai, Shigeki Matsunaga*, Masakatsu Shibasaki* Non-C2-Symmetric, Chirally Economical, and Readily Tunable Linked-BINOLs: Design and Application in Direct Catalytic Asymmetric Mannich-type Reaction Angew. Chem. Int. Ed. 444, 3470-3474 (2005). *27. Shinji Harada, Shinya Handa, Shigeki Matsunaga* and Masakatsu Shibasaki* Direct Catalytic Asymmetric Mannich-type Reaction of N-(2-Hydroxyacetyl)pyrrole as an Ester Equivalent Donor Angew. Chem. Int. Ed. 444, 4365-4368 (2005). 28. Naoya Kumagai, Shigeki Matsunaga, Masakatsu Shibasaki* Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination Chem. Commun. 3600-3602 (2005) *29. Noriyuki Yamagiwa, Hongbo Qin, Shigeki Matsunaga,* and Masakatsu Shibasaki* Lewis Acid-Lewis Acid Heterobimetallic Cooperative Catalysis: Mechanistic Studies and Application in Enantioselective Aza-Michael Reaction J. Am. Chem. Soc. 1127, 13419-13427 (2005). *30. Mari Sugita, Akitake Yamaguchi, Noriyuki Yamagiwa, Shinya Handa, Shigeki Matsunaga,* and Masakatsu Shibasaki* Syn-Selective Direct Catalytic Asymmetric Mannich-type Reactions of Hydroxyketones Using Y{N(SiMe3)2}3/linked-BINOL Complexes Org. Lett. 77, 5339-5342 (2005). *31. Hongbo Qin, Noriyuki Yamagiwa, Shigeki Matsunaga,* and Masakatsu Shibasaki* Bismuth-Catalyzed Intermolecular Hydroamination of 1,3-Dienes with Carbamates, Sulfonamides, and Carboxamides J. Am. Chem. Soc. 1128, 1611-1614 (2006). *32. Masakatsu Shibasaki,* and Shigeki Matsunaga* Metal/linked-BINOL complexes: Applications in direct catalytic asymmetric Mannich-type reactions J. Organomet. Chem. 691, 2089-2100 (2006).

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*33. Masakatsu Shibasaki,* Motomu Kanai, and Shigeki Matsunaga Chiral Poly-Rare Earth Metal Complexes in Asymmetric Catalysis Aldrichimica Acta. 31-39 (2006) *34. Shigeki Matsunaga*, Hongbo Qin, Mari Sugita, Shigemitsu Okada, Tomofumi Kinoshita, Noriyuki Yamagiwa, and Masakatsu Shibasaki* Catalytic Asymmetric Epoxidation of α,β-Unsaturated N-Acylpyrroles as Monodentate and Activated Ester Equivalent Acceptors Tetrahedron, 662, 6630-6639 (2006) *35. Noriyuki Yamagiwa, Yumi Abiko, Mari Sugita, Jun Tian, Shigeki Matsunaga,* Masakatsu Shibasaki* Catalytic Asymmetric Cyano-phosphorylation of Aldehydes Using a YLi3tris(binaphthoxide) Complex (YLB) Tetrahedron: Asymmetry, 17, 566-573 (2006)

*36. Masakatsu Shibasaki,* and Shigeki Matsunaga* Design and Application of Linked-BINOL Chiral Ligands in Bifunctional Asymmetric Catalysis Chem. Soc. Rev. 335, 269-279 (2006) *37. Hiroyuki Morimoto, Sean H. Wiedemann, Akitake Yamaguchi, Shinji Harada, Zhihua Chen, Shigeki Matsunaga*, and Masakatsu Shibasaki* Trichloromethyl Ketones as Synthetically Versatile Donors: Application in Direct Catalytic Mannich-type Reactions and Stereoselective Synthesis of Azetidines Angew. Chem. Int. Ed. 445, 3146-3150 (2006). *38. Shigeki Matsunaga Recent Progress in Catalytic Intermolecular Hydroamination J. Synth. Org. Chem. Jpn. 664, 778-779 (2006). *39. Akitake Yamaguchi, Shigeki Matsunaga*, and Masakatsu Shibasaki* Direct catalytic asymmetric Mannich-type reaction of isomerizable aliphatic imines: chemoselective enolate formation from a hydroxyketone by a Zn catalyst Tetrahedron Lett. 447, 3985-3989 (2006). *40. Shigeki Matsunaga,* Mari Sugita, Noriyuki Yamagiwa, Shinya Handa, Akitake Yamaguchi, and Masakatsu Shibasaki* Syn-Selective Direct Catalytic Asymmetric Mannich-type Reactions of Aromatic and Heteroaromatic Hydroxyketones Promoted by Y[N(SiMe3)2]3/linked-BINOL Complexes Bull. Chem. Soc. Jpn. 779, 1906-1912 (2006). *41. Shin-ya Tosaki, Keiichi Hara, Vijay Gnanadesikan, Hiroyuki Morimoto, Shinji Harada, Mari Sugita, Noriyuki Yamagiwa, Shigeki Matsunaga,* and Masakatsu Shibasaki* Mixed La-Li Heterobimetallic Complexes for Tertiary Nitroaldol Resolution J. Am. Chem. Soc. 1128, 11776-11777 (2006). *42. Zhihua Chen, Hiroyuki Morimoto, Shigeki Matsunaga,* and Masakatsu Shibasaki* Catalytic Asymmetric Epoxidation of α-Methyl α,β-Unsaturated Anilides as Ester Surrogates Synlett 3529-3532 (2006). *43. Hongbo Qin, Noriyuki Yamagiwa, Shigeki Matsunaga,* and Masakatsu Shibasaki* Bismuth-Catalyzed Direct Substitution of the Hydroxyl Group in Alcohols with Sulfonamides, Carbamates, and Carboxamides Angew. Chem. Int. Ed. 446, 409-413 (2007).

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*44. Hongbo Qin, Noriyuki Yamagiwa, Shigeki Matsunaga,* and Masakatsu Shibasaki* Bismuth- and Hafnium-catalyzed Hydroamination of Vinyl Arenes with Sulfonamides, Carbamates, and Carboxamides Chem. Asian, J. 22, 150-154 (2007). 45. Hiroyuki Kakei, Riichiro Tsuji, Takashi Ohshima, Hiroyuki Morimoto, Shigeki Matsunaga, and Masakatsu Shibasaki* Catalytic Asymmetric Epoxidation of α,β-Unsaturated Esters Using Chiral Yttrium-Biaryldiol Complexes Chem. Asian, J. 22, 257-264 (2007). 46. Shinji Harada, Ryo Takita, Takashi Ohshima, Shigeki Matsunaga and Masakatsu Shibasaki* Ligand Accelerated Indium(III)-Catalyzed Asymmetric Alkynylation of Aldehydes with 2-Methyl-3-butyn-2-ol as an Ethyne Equivalent Donor Chem. Commun. 948-950 (2007) *47. Shinya Handa, Vijay Gnanadesikan, Shigeki Matsunaga*, and Masakatsu Shibasaki* syn-Selective Catalytic Asymmetric Nitro-Mannich Reactions Using a Heterobimetallic Cu-Sm-Schiff Base Complex J. Am. Chem. Soc. 1129, 4900-4901 (2007). *48. So-Young Park, Hiroyuki Morimoto, Shigeki Matsunaga*, and Masakatsu Shibasaki* Catalytic Asymmetric Michael Reactions of Malonate to α,β-Unsaturated N-Acylpyrroles Using a La(O-iPr)3/Ph-linked-BINOL Complex Tetrahedron Lett. 448, 2815-2818 (2007). 49. Naoya Kumagai, Shigeki Matsunaga, Masakatsu Shibasaki* Catalytic nucleophilic activation of acetonitrile via a cooperative catalysis of cationic Ru complex, DBU, and Na salt Tetrahedron, 663, 8598-8608 (2007) *50. Hiroyuki Morimoto, Gang Lu, Naohiro Aoyama, Shigeki Matsunaga*, and Masakatsu Shibasaki* Lanthanum Aryloxide/Pybox-Catalyzed Direct Asymmetric Mannich-Type Reactions Using a Trichloromethyl Ketone as a Propionate Equivalent Donor J. Am. Chem. Soc. 1129, 9588-9589 (2007). *51. Akitake Yamaguchi, Naohiro Aoyama, Shigeki Matsunaga*, and Masakatsu Shibasaki* Ba-catalyzed Direct Mannich-type Reactions of a β,γ-Unsaturated Ester Providing β-Methyl aza-Morita-Baylis-Hillman-type Products Org. Lett. 99, 3387-3390 (2007). *52. Hiroyuki Kakei, Toshihiko Sone, Yoshihiro Sohtome, Shigeki Matsunaga* and Masakatsu Shibasaki* Catalytic Asymmetric Cyclopropanation of Enones With Dimethyloxosulfonium Methylide Promoted by a La-Li3-(Biphenyldiolate)3 + NaI Complex J. Am. Chem. Soc. 1129, 13410-13411 (2007). *53. Shigeki Matsunaga* and Masakatsu Shibasaki* Multimetallic Bifunctional Asymmetric Catalysis Based on Proximity-Effect-Control Bull. Chem. Soc. Jpn. 881, 60-75 (2008). 54. Ryo Takita, Shinji Harada, Takashi Ohshima, Shigeki Matsunaga and Masakatsu Shibasaki* Catalytic Enantioselective Addition of Terminal Alkynes to Aldehydes: Preparation of (S)-(–)-1,3-Diphenyl-2-Propyn-1-ol and (S)-(–)-4-Methyl-1-Phenyl-2-Pentyn-1,4-Diol

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Org. Synth. 85, 118-130 (2008) *55. Hisashi Mihara, Yoshihiro Sohtome, Shigeki Matsunaga*, Masakatsu Shibasaki* Chiral Catalyst-based Convergent Synthesis of HIV Protease Inhibitor GRL-06579A Chem. Asian, J. 33, 359-366 (2008). 56. Masataka Morita, Toshihiko Sone, Kenzo Yamatsugu, Yoshihiro Sohtome, Shigeki Matsunaga, Motomu Kanai,* Yasuyoshi Watanabe, and Masakatsu Shibasaki* A method for the synthesis of an oseltamivir PET tracer Bioorg. Med. Chem. Lett. 118, 600-602 (2008). *57. Zhihua Chen, Hiroyuki Morimoto, Shigeki Matsunaga*, and Masakatsu Shibasaki* A Bench-stable Homodinuclear Ni2-Schiff Base Complex for Catalytic Asymmetric Synthesis of α-Tetrasubstituted anti-α,β-Diamino Acid Surrogates J. Am. Chem. Soc. 1130, 2170-2171 (2008). *58. Shinya Handa, Keita Nagawa, Yoshihiro Sohtome, Shigeki Matsunaga*, and Masakatsu Shibasaki* A Heterobimetallic Pd-La-Schiff Base Complex for anti-Selective Catalytic Asymmetric Nitroaldol

Reactions and Applications to Short Syntheses of β-Adrenoceptor Agonists Angew. Chem. Int. Ed. 447, 3230-3233 (2008) *59. Keiichi Hara, So-Young Park, Noriyuki Yamagiwa, Shigeki Matsunaga*, Masakatsu Shibasaki* Catalytic Asymmetric Epoxidation of α,β-Unsaturated Phosphine Oxides with a Y(O-iPr)3/Biphenyldiol Complex Chem. Asian, J. 33, 1500-1504 (2008). *60. Sean H. Wiedemann, Hidetoshi Noda, Shinji Harada, Shigeki Matsunaga,* and Masakatsu Shibasaki* Sc3+-Catalyzed Aldol-type Additions of N-Benzoylcyclopropanecarboxamides via Iodide-Mediated Ring-Opening: Stereoselective Synthesis of γ-Lactams Org. Lett. 110, 1661-1664 (2008). 61. Masakatsu Shibasaki,* Shigeki Matsunaga, Naoya Kumagai Strategies for Constructing Diverse Chiral Environments in Multimetallic Bifunctional Asymmetric Catalysis Synlett 1583-1602 (2008). 62. Yoshihiro Sohtome, Yuko Kato, Shinya Handa, Naohiro Aoyama, Keita Nagawa, Shigeki Matsunaga, and Masakatsu Shibasaki* Stereodivergent Catalytic Doubly Diastereoselective Nitroaldol Reactions Using Heterobimetallic Complexes Org. Lett. 110, 2231-2234 (2008). *63. Akitake Yamaguchi, Shigeki Matsunaga,* and Masakatsu Shibasaki*

Direct Catalytic Asymmetric Mannich-type Reactions of γ-Butenolides: Effectiveness of Brønsted Acid in Chiral Metal Catalysis Org. Lett. 110, 2319-2322 (2008). *64. Gang Lu, Hiroyuki Morimoto, Shigeki Matsunaga*, and Masakatsu Shibasaki* Chiral γ-Amino Amide Synthesis via Heterobimetallic La/Li/pybox-Catalyzed Direct Asymmetric Mannich-type Reactions of α-Keto Anilides Angew. Chem. Int. Ed. 447, 6847-6850 (2008) *65. Zhihua Chen, Kenichiro Yakura, Shigeki Matsunaga*, and Masakatsu Shibasaki*

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Direct Catalytic Asymmetric Mannich-type Reaction of β-Keto Phosphonate Using a Dinuclear Ni2-Schiff Base Complex Org. Lett. 110, 3239-3242 (2008). *66. Toshihiko Sone, Akitake Yamaguchi, Shigeki Matsunaga* and Masakatsu Shibasaki* Catalytic Asymmetric Synthesis of 2,2-Disubstituted Terminal Epoxides via Dimethyloxosulfonium Methylide Addition to Ketones J. Am. Chem. Soc. 1130, 10078-10079 (2008). *67. Hiroyuki Morimoto, Tatsuhiko Yoshino, Takafumi Yukawa, Gang Lu, Shigeki Matsunaga* and Masakatsu Shibasaki* Lewis Base-Assisted-Brønsted Base Catalysis: Bidentate Phosphine Oxides as Activators and Modulators of Brønsted Basic Lanthanum-Aryloxide Angew. Chem. Int. Ed. 447, 9125-9129 (2008) *68. Hidetoshi Noda, Sean H. Wiedemann, Shigeki Matsunaga,* and Masakatsu Shibasaki* A DyI3-Catalyzed Mannich-type Reaction of α-Methylcyclopropanecarboxylate-type Donors for the Stereoselective Synthesis of Pyrrolidines with Quaternary Stereocenters Chem. Lett. 337, 1180-1181 (2008) *69. Zhihua Chen, Makoto Furutachi, Yuko Kato, Shigeki Matsunaga* and Masakatsu Shibasaki* A Stable Homodinuclear Biscobalt(III)-Schiff Base Complex for Catalytic Asymmetric 1,4-Additions of β-Keto Esters to Alkynones Angew. Chem. Int. Ed. 448, 2218-2220 (2009) *70. Toshihiko Sone, Gang Lu, Shigeki Matsunaga* and Masakatsu Shibasaki* Catalytic Asymmetric Synthesis of 2,2-Disubstituted Oxetanes from Ketones via One-pot Sequential Addition of Sulfur Ylide Angew. Chem. Int. Ed. 448, 1677-1680 (2009) *71. Keiichi Hara, Shin-ya Tosaki, Vijay Gnanadesikan, Hiroyuki Morimoto, Shinji Harada, Mari Sugita, Noriyuki Yamagiwa, Shigeki Matsunaga,* and Masakatsu Shibasaki* Mixed La-Li Heterobimetallic Complexes for Tertiary Nitroaldol Resolution Tetrahedron, 665, 5030-5036 (2009) 72. Masakatsu Shibasaki,* Motomu Kanai, Shigeki Matsunaga, Naoya Kumagai Recent Progress in Asymmetric Bifunctional Catalysis Using a Multimetallic System Acc. Chem. Res. 442, 1117-1127 (2009) *73. Yuko Kato, Zhihua Chen, Shigeki Matsunaga* and Masakatsu Shibasaki* Catalytic Asymmetric Synthesis of Nitrogen-containing gem-Bisphosphonates Using a Dinuclear Ni2-Schiff Base Complex Synlett 1635-1638 (2009) *74. Yingjie Xu, Gang Lu, Shigeki Matsunaga*, and Masakatsu Shibasaki* Direct anti-Selective Catalytic Asymmetric Mannich-type Reactions of α-Ketoanilides for γ-Amino Amides and Azetidine-2-amides Synthesis Angew. Chem. Int. Ed. 448, 3353-3356 (2009)

*75. Hisashi Mihara, Yingjie Xu, Nicholas E. Shepherd, Shigeki Matsunaga*, and Masakatsu Shibasaki* A Heterobimetallic Ga/Yb-Schiff Base Complex for Catalytic Asymmetric α-Addition of Isocyanides to Aldehydes

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J. Am. Chem. Soc. 1131, 8384-8385 (2009). *76. Yuko Kato, Makoto Furutachi, Zhihua Chen, Harunobu Mistunuma, Shigeki Matsunaga*, and Masakatsu Shibasaki* A Homodinuclear Mn(III)2-Schiff Base Complex for Catalytic Asymmetric 1,4-Additions of Oxindoles to Nitroalkenes J. Am. Chem. Soc. 1131, 9168-9169 (2009). *77. Akitake Yamaguchi, Shigeki Matsunaga*, and Masakatsu Shibasaki* Catalytic Asymmetric Synthesis of α-Alkylidene-β-hydroxy Esters via Dynamic Kinetic Asymmetric Transformation Involving Ba-Catalyzed Direct Aldol Reaction J. Am. Chem. Soc. 1131, 10842-10843 (2009). *78. Shinsuke Mouri, Zhihua Chen, Shigeki Matsunaga*, and Masakatsu Shibasaki*

Direct Catalytic Asymmetric Aldol Reaction of β-Keto Esters with Formaldehyde Promoted by a Dinuclear Ni2-Schiff Base Complex Chem. Commun. 5138-5140 (2009). *79. Tatsuhiko Yoshino, Hiroyuki Morimoto, Gang Lu, Shigeki Matsunaga*, and Masakatsu Shibasaki* Construction of Contiguous Tetrasubstituted Chiral Carbon Stereocenters via Direct Catalytic Asymmetric Aldol Reaction of α-Isothiocyanato Esters to Ketones J. Am. Chem. Soc. 1131, 17068-17069 (2009). *80. Shinsuke Mouri, Zhihua Chen, Harunobu Mitsunuma, Makoto Furutachi, Shigeki Matsunaga*, and Masakatsu Shibasaki* Catalytic Asymmetric Synthesis of 3-Aminooxindoles: Enantiofacial Selectivity Switch in Bimetallic vs Monometallic Schiff Base Catalysis J. Am. Chem. Soc. 1132, 1255-1257 (2010). *81. Makoto Furutachi, Zhihua Chen, Shigeki Matsunaga* and Masakatsu Shibasaki* Catalytic Asymmetric 1,4-Additions of β-Keto Esters to Nitroalkenes Promoted by a Bifunctional Homobimetallic Co2-Schiff Base Complex Molecules 115, 532-544 (2010). *82. Nicholas E. Shepherd, Hirooki Tanabe, Yingjie Xu, Shigeki Matsunaga* and Masakatsu Shibasaki* Direct Catalytic Asymmetric Vinylogous Mannich-type and Michael Reactions of an α,β-Unsaturated γ-Butyrolactam Under Dinuclear Nickel Catalysis J. Am. Chem. Soc. 1132, 3666-3667 (2010). *83. Shinya Handa, Vijay Gnanadesikan, Shigeki Matsunaga*, and Masakatsu Shibasaki* Heterobimetallic Transition Metal/Rare Earth Metal Bifunctional Catalysis: a Cu-Sm-Schiff Base Complex for syn-Selective Catalytic Asymmetric Nitro-Mannich Reaction J. Am. Chem. Soc. 1132, 4925-4934 (2010). *84. Takafumi Yukawa, Bianca Seelig, Hiroyuki Morimoto, Shigeki Matsunaga,* Albrecht Berkessel,* and Masakatsu Shibasaki* Catalytic Asymmetric aza-Morita-Baylis-Hillman Reaction of Methyl Acrylate Promoted by a La-linked-BINOL Complex Combined with DABCO J. Am. Chem. Soc. 1132, 11988-11992 (2010). *85. Yingjie Xu, Shigeki Matsunaga*, and Masakatsu Shibasaki*

syn-Selective Catalytic Asymmetric 1,4-Addition of α-Ketoanilides to Nitroalkenes under Dinuclear Nickel Catalysis

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Org. Lett. 112, 3246-3249 (2010). *86. Makoto Furutachi, Shinsuke Mouri, Shigeki Matsunaga*, and Masakatsu Shibasaki* A Heterobimetallic Ni/La-salan Complex for Catalytic Asymmetric Decarboxylative 1,4-Addition of Malonic Acid Half-Thioester Chem. Asian J. 55, 2351-2354 (2010). *87. Masakatsu Shibasaki* and Shigeki Matsunaga* Bifunctional Asymmetric Catalysis Based on Dinuclear Schiff Base Complexes J. Synth. Org. Chem. Jpn. 668, 1142-1149 (2010). *88. Harunobu Mitsunuma and Shigeki Matsunaga* Dinuclear Ni2-Schiff base complex-catalyzed asymmetric 1,4-addition of β-keto esters to

nitroethylene toward γ2,2-amino acid synthesis Chem. Commun. 447, 469-471 (2011). [Emerging Investigator Special Issue] *89. Gang Lu, Tatsuhiko Yoshino, Hiroyuki Morimoto, Shigeki Matsunaga,* and Masakatsu Shibasaki* Stereodivergent Direct Catalytic Asymmetric Mannich-type Reaction of α-Isothiocyanato Ester with Ketimines Angew. Chem. Int. Ed. 550, 4382-4385 (2011) *90. Hirotomo Komai, Tatsuhiko Yoshino, Shigeki Matsunaga,* and Motomu Kanai* Lewis acid-catalyzed Benzylic C-H Bond Functionalization of Azaarenes: Addition to Enones Org. Lett. 113, 1706-1709 (2011). *91. Yingjie Xu, Luqing Lin, Motomu Kanai, Shigeki Matsunaga*, and Masakatsu Shibasaki* Catalytic Asymmetric Ring-Opening of meso-Aziridines with Malonates Under Heterodinuclear Rare Earth Metal Schiff Base Catalysis J. Am. Chem. Soc. 1133, 5791-5793 (2011).

*92. Shigeki Matsunaga,* and Tatsuhiko Yoshino

Construction of Contiguous Tetrasubstituted Chiral Carbon Stereocenters via Direct Catalytic

Asymmetric Aldol and Mannich-type Reactions

the Chemical Record, 111, 260-268 (2011).

*93. Shinsuke Mouri, Zhihua Chen, Shigeki Matsunaga*, and Masakatsu Shibasaki*

Catalytic Asymmetric Amination of Oxindoles Under Dinuclear Nickel Schiff Base Catalysis

Heterocycles 884, 879-892 (2012). DOI: 10.3987/COM-11-S(P)66

*94. Toshihiko Sone, Akitake Yamaguchi, Shigeki Matsunaga*, and Masakatsu Shibasaki*

Enantioselective Synthesis of 2,2-Disubstituted Terminal Epoxides via Catalytic Asymmetric

Corey-Chaykovsky Epoxidation of Ketones

Molecules 117, 1617-1634 (2012). doi:10.3390/molecules17021617

*95. Harunobu Mitsunuma, Masakatsu Shibasaki, Motomu Kanai*, and Shigeki Matsunaga*

Catalytic Asymmetric Total Synthesis of Chimonanthine, Folicanthine, and Calycanthine via Double

12

Michael Reaction of Bisoxindole

Angew. Chem. Int. Ed. 551, 5217-5221(2012) [DOI: 10.1002/anie.201201132].

*96. Yudai Suzuki, Motomu Kanai*, and Shigeki Matsunaga*

Mg-catalyzed Enantioselective Benzylic C-H Bond Functionalization of Isoindolinones: Addition to

Imines

Chem. Eur. J. 118, 7654-7657 (2012) DOI: 10.1002/chem.201200821

*97. Hirotomo Komai, Tatsuhiko Yoshino, Shigeki Matsunaga,* and Motomu Kanai*

Lewis acid-catalyzed Benzylic C-H Bond Functionalization of Azaarenes: Addition to Imines and

Enones

Synthesis, 444, 2185-2194 (2012) doi:10.1055/s-0031-1291041

*98. Shota Kato, Tatsuhiko Yoshino, Masakatsu Shibasaki, Motomu Kanai*, and Shigeki Matsunaga*

Catalytic Asymmetric Synthesis of Spirooxindoles via Mannich-type Reaction of Isothiocyanato

Oxindoles

Angew. Chem. Int. Ed. 551, 7007-7010 (2012) [DOI: 10.1002/anie.201203005].

*99. Hirooki Tanabe, Yingjie Xu, Bo Sun, Shigeki Matsunaga*, and Masakatsu Shibasaki*

Direct Catalytic Asymmetric Vinylogous Michael Reaction of α,β-unsaturated γ-butyrolactam under

dinuclear nickel Schiff base catalysis

Heterocycles 86, 611-622 (2012). DOI: 10.3987/COM-12-S(N)58

*100. Luqing Lin, Kumiko Yamamoto, Shigeki Matsunaga*, and Motomu Kanai *

Rh-Catalyzed Cross-Aldol Reaction via in situ Aldehyde-Enolate Formation from Allyloxy-Boranes

and Primary Allylic Alcohols

Angew. Chem. Int. Ed. 551, 10275-10279 (2012) [DOI: 10.1002/anie.201205680]

*101. Takashi Andou, Yutaka Saga, Hirotomo Komai, Shigeki Matsunaga*, and Motomu Kanai *

Cobalt-Catalyzed C-4 Selective Direct Alkylation of Pyridines

Angew. Chem. Int. Ed. 552, 3213-3216 (2013) DOI: 10.1002/anie.201208666 and 10.1002/ange.201208666

*102. Tatsuhiko Yoshino, Hideya Ikemoto, Shigeki Matsunaga*, and Motomu Kanai *

A Cationic High-Valent Cp*CoIII Complex for Catalytic Generation of Nucleophilic Organometallic

Species: Directed C-H Bond Activation

Angew. Chem. Int. Ed. 552, 2207-2211 (2013) DOI: 10.1002/anie.201209226 and 10.1002/ange.201209226

13

*103. Shigeki Matsunaga*, and Masakatsu Shibasaki *

Multimetallic Schiff Base Complexes as Cooperative Asymmetric Catalysts

Synthesis, 445, 421-437 (2013) DOI: 10.1055/s-0032-1316846

104. Motomu Kanai,* Shigeki Matsunaga, Kounosuke Oisaki, and Yohei Shimizu

Carbon–Carbon Bond-Formations Promoted by Redox-Active Metal Catalysts

J. Synth. Org. Chem. Jpn. 771, 433-442 (2013) doi:

*105. Shota Kato, Motomu Kanai*, and Shigeki Matsunaga*

Catalytic Asymmetric Synthesis of Spirooxindoles via Addition of Isothiocyanato Oxindoles to

Aldehydes Under Dinuclear Nickel Schiff Base Catalysis

Chem. Asian J. 88, 1768-1771 (2013) DOI: 10.1002/asia.201300251

106. Atmika Paudel, Keiichi Kaneko, Ayako Watanabe, Shigeki Matsunaga, Motomu Kanai, and

Hiroshi Hamamoto, Kazuhisa Sekimizu Structure-activity relationship study of novel iminothiadiazolo-1 pyrimidinone antimicrobial agents

J. Antibiotics 666, 663-667 (2013) doi: 10.1038/ja.2013.69

*107. Tatsuhiko Yoshino, Hideya Ikemoto, Shigeki Matsunaga*, and Motomu Kanai *

Cp*CoIII-Catalyzed C2-Selective Addition of Indoles to Imines

Chem. Eur J. 119, 9142-9146 (2013) DOI: 10.1002/chem.201301505

*108. Keiichi Kaneko, Shigeki Matsunaga*, and Motomu Kanai *

Sultam Synthesis via Cu-Catalyzed Intermolecular Carboamination of Alkenes with

N-Fluorobenzenesulfonimide

Org. Lett. 115, 2502-2505 (2013). DOI: 10.1021/ol4009848

*109. Luqing Lin, Kumiko Yamamoto, Shigeki Matsunaga*, and Motomu Kanai *

Rh-Catalyzed Aldehyde-Aldehyde Cross-Aldol Reaction under Base-free Conditions: In Situ

Aldehyde-derived Enolate Formation via Orthogonal Activation

Chem. Asian J. 88, 2974-2983 (2013) Selected as a Frontispiece

*110. Shota Kato, Motomu Kanai, and Shigeki Matsunaga*

ENANTIOSELECTIVE SYNTHESIS OF SPIROOXINDOLES VIA DIRECT CATALYTIC

ASYMMETRIC ALDOL-TYPE REACTION OF ISOTHIOCYANATO OXINDOLES

Heterocycles 88, 475-491 (2014) DOI: 10.3987/COM-13-S(S)60

14

*111. Shigeki Matsunaga* and Masakatsu Shibasaki*

Recent Advances in Cooperative Bimetallic Asymmetric Catalysis: Dinuclear Schiff Base Complexes

Chem. Commun. 550, 1044-1057 (2014).

*112. Shohei Yamamoto, Yutaka Saga, Takashi Andou, Shigeki Matsunaga* and Motomu Kanai*

Cobalt-Catalyzed C-4 Selective Alkylation of Quinolines

Adv. Synth. Catal. 3356, 401-405 (2014).

*113. Sun Bo, Tatsuhiko Yoshino, Shigeki Matsunaga*, and Motomu Kanai *

Air-Stable Cp*Co(CO)I2 Complex as a Precursor for Cationic Cp*CoIII Catalysis: Application for

Directed C2-Selective C-H Amidation of Indoles

Adv. Synth. Catal. 3356, 1491-1495 (2014).

*114. Hideya Ikemoto, Tatsuhiko Yoshino, Ken Sakata, Shigeki Matsunaga*, and Motomu Kanai *

Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C-H

Alkenylation/Annulation Sequence

J. Am. Chem. Soc. 1136, 5424-5431 (2014). DOI: 10.1021/ja5008432

*115. Shohei Yamamoto, Shigeki Matsunaga* and Motomu Kanai*

COBALT-CATALYZED C5-SELECTIVE C-H FUNCTIONALIZATION OF 4-Me-QUINOLINES WITH

STYRENES: AN APPROACH TO 5,6-DIHYDRO-4H-BENZO[de]QUINOLINES

Heterocycles 90, 89-96(2014)

*116. Yingjie Xu, Keiichi Kaneko, Motomu Kanai, Masakatsu Shibasaki,* and Shigeki Matsunaga*

Regiodivergent Kinetic Resolution of Terminal and Internal rac-Aziridines with Malonates under

Dinuclear Schiff Base Catalysis J. Am. Chem. Soc. 1136, 9190-9194 (2014). DOI: 10.1021/ja5039165 *117. Sun, B.; Yoshino, T.; Matsunaga, S.; Kanai, M. A Cp*CoI2-dimer as A Precursor for Cationic Co(III)-catalysis: Application to C-H Phosphoramidation of Indoles Chem. Commun. 22015, 51, 4659. DOI: 10.1039/C4CC10284C *118. Suzuki, Y.; Sun, B.; Yoshino, T.; Matsunaga, S.; Kanai, M. Cp*Co(III)-catalyzed Oxidative C-H Alkenylation of Benzamides with Ethyl Acrylate Tetrahedron 22015, 71,4552. DOI: 10.1016/j.tet.2015.02.032 *119. Suzuki, Y.; Sun, B.; Sakata, K.; Yoshino, T.; Matsunaga, S.; Kanai, M. Dehydrative Direct C-H Allylation with Allylic Alcohols under [Cp*CoIII] Catalysis Angew. Chem., Int. Ed. 22015, 54, 9944. DOI: 10.1002/anie.201503704

15

*120. Sun, B.; Yoshino, T.; Kanai, M.; Matsunaga, S.

Cp*CoIII Catalyzed Site-Selective C-H Activation of Unsymmetrical O-Acyl Oximes: Synthesis of Multisubstituted Isoquinolines from Terminal and Internal Alkynes Angew. Chem., Int. Ed. 22015, 54, 12968. DOI: 10.1002/anie.201507744 *121. Lin. L.; Yamamoto, K.; Mitsunuma, H.; Kanzaki, Y.; Matsunaga, S.; Kanai, M.

Catalytic Asymmetric Iterative/Domino Aldehyde Cross-Aldol Reactions for the Rapid and Flexible Synthesis of 1,3-Polyols J. Am. Chem. Soc. 22015, 137, 15418. DOI: 10.1021/jacs.5b11192 *122. Bunno, Y.; Murakami, N.; Suzuki, Y.; Kanai, M.; Yoshino, T.; Matsunaga, S. Cp*CoIII-Catalyzed Dehydrative C–H Allylation of 6-Arylpurines and Aromatic Amides Using Allyl Alcohols in Fluorinated Alcohols" Org. Lett. 22016, 18, 2216. DOI: 10.1021/acs.orglett.6b00846 123. Miyazawa, T.; Minami, K.; Ito, M;, Anada, M.; Matsunaga, S.; Hashimoto, S. Enantio-and diastereoselective desymmetrization of α-alkyl-α-diazoesters by dirhodium(II)-catalyzed intramolecular C-H insertion Tetrahedron 22016, 72, 3939. DOI: 10.1016/j.tet.2016.05.015 *124. Tanaka, R.; Ikemoto, H.; Kanai, M.; Yoshino, T.; Matsunaga, S. Site- and Regioselective Monoalkenylation of Pyrroles with Alkynes via Cp*CoIII Catalysis Org. Lett. 22016, 18, 5732. DOI: 10.1021/acs.orglett.6b02997 125. Maeda, N.; Furukawa, A; Kakita, K.; Anada, M.; Hashimoto, S.; Matsunaga, S.; Kuroki, K.; Ose, T.; Kato, A.; Arii, J.; Kawaguchi, Y.; Arase, H.; Maenaka, K. Rapid Screening by Cell-Based Fusion Assay for Identifying Novel Antivirals of Glycoprotein B-Mediated Herpes Simplex Virus Type 1 Infection Biol. Pharm. Bull. 22016, 39, 1897. DOI: 10.1248/bpb.b16-00533 126. Miyazawa, T.; Imai, K.; Ito, M.; Takeda, K.; Anada, M.; Matsunaga, S.; Hashimoto, S. Diastereo- and Enantioselective Construction of 6,7-Dioxabicyclo[2.2.1]heptane Derivatives by a Dirhodium(II)-Catalyzed Intramolecular C-H Insertion Reaction HeteroCycles 22017, 95, 1211. DOI: 10.3987/COM-16-S(S)72 *127. Yoshino, T.; Matsunaga, S. (Pentamethylcyclopentadienyl)cobalt(III)-Catalyzed C–H Bond Functionalization: From Discovery to Unique Reactivity and Selectivity Adv. Synth. Catal. 22017, 359, 1245. DOI: 10.1002/adsc.201700042 128. Kato, S.; Saga, Y.; Kojima, M.; Fuse,H.; Matsunaga, S.; Fukatsu, A.; Kondo, M.; Masaoka, S.; Kanai, M. Hybrid Catalysis Enabling Room-Temperature Hydrogen Gas Release from N-Heterocycles and Tetrahydronaphthalenes J. Am. Chem. Soc. 22017, 139, 2204. DOI: 10.1021/jacs.7b00253 129. Paudel, A.; Hamamoto, H.; Panthee, S.; Kaneko, K.; Matsunaga, S.; Kanai, M.; Suzuki, Y.; Sekimizu, K. A Novel Spiro-heterocyclic Compound Identified by the Silkworm Infection Model Inhibits Transcription in Staphylococcus aureus Front. Microbiol. 22017, published online. DOI: 10.3389/fmicb.2017.00712 *130. Yoshida, M.; Kawai, K.; Tanaka, R.; Yoshino, T.; Matsunaga, S. Cp*CoIII-catalyzed directed C–H trifluoromethylthiolation of 2-phenylpyridines and 6-arylpurines

16

Chem. Commun. 22017, 53 5974. DOI: 10.1039/C7CC03072J *131. Ikemoto. H.; Tanaka, R.; Sakata, K.; Kanai, M.; Yoshino, T.; Matsunaga, S. Stereoselective Synthesis of Tetrasubstituted Alkenes via a Cp*CoIII-Catalyzed C−H Alkenylation/Directing Group Migration Sequence Angew. Chem., Int. Ed. 22017, 56 7156. DOI: 10.1002/anie.201703193 132. Tajiri, H.; Uruno, T.; Shirai, T.; Takaya, S.; Matsunaga, S.; Setoyama, D.; Watanabe, M.; Kukimoto-Niino, M.; Oisaki, K.; Ushijima, M.; Sanematsu, F.; Honma, T.; Terada,T.; Oki,E.; Shirasawa, S.; Maehara, Y.; Kang, D.; Côté, J.-F.; Yokoyama, S.; Kanai, M.; Fukui, Y. Targeting Ras-Driven Cancer Cell Survival and Invasion through Selective Inhibition of DOCK1 Cell Reports 22017, 19, 969. DOI: 10.1016/j.celrep.2017.04.016 *133. Fukagawa, S.; Xu, Y.; Anada, M.; Yoshino, T.; Matsunaga, S. Catalytic Enantioselective Desymmetrization of meso-Aziridines with Fluoromalonates Heterocycles 22017, 94 1337. DOI: 10.3987/COM-17-13725. 134. Sakata, K.; Eda M.; Kitaoka Y.; Yoshino T.; Matsunaga S. Cp*CoIII-Catalyzed C–H Alkenylation/Annulation Reactions of Indoles with Alkynes: A DFT Study J. Org. Chem. 22017, ASAP. DOI: 10.1021/acs.joc.7b01047 135. Abe, T.; Suzuki, T.; Anada, M.; Matsunaga, S.; Yamada, K. 2-Hydroxyindoline-3-triethylammonium Bromide: A Reagent for Formal C3-Electrophilic Reactions of Indoles Org. Lett. 22017, 19, in press.

1. Shigeki Matsunaga, Masakatsu Shibasaki Rare Earth-Alkali Metal Heterobimetallic Asymmetric Catalyses in Multimetallic Catalysts in Organic Synthesis, Wiley-VCH, 2004, Eds by M. Shibasaki, and Y. Yamamoto, chapter 5, pp121-142. 2. Shigeki Matsunaga, Masakatsu Shibasaki Gallium Trichloride (e-EROS: Encyclopedia of Reagents for Organic Synthesis) 3.

2003, 39, pp 662-663.

4. Masakatsu Shibasaki, Shigeki Matsunaga, Naoya Kumagai Direct Catalytic Asymmetric Aldol Reaction Using Chiral Metal Complexes (Modern Aldol Reactions, Wiley-VCH, Ed by Mahrwald, R., 2004, chapter 6, pp197-227 5. Masakatsu Shibasaki, Shigeki Matsunaga, Naoya Kumagai Direct Catalytic Asymmetric Aldol Reaction of α-Hydroxyketone Promoted by a Et2Zn/linked-BINOL Complex in Catalysts for the Fine Chemical Synthesis, Wiley, Eds by S. M. Roberts, J. Xiao, J. Whittall, T. E. Pickett, 2004, volume 3, pp 202-208. 6. Masakatsu Shibasaki, Shigeki Matsunaga, Naoya Kumagai Direct Catalytic Asymmetric Michael Reaction of α-Hydroxyketone Promoted by a Et2Zn/linked-BINOL Complex in Catalysts for the Fine Chemical Synthesis, Wiley, Eds by S. M. Roberts, J. Xiao, J. Whittall, T. E. Pickett, 2004, volume 3, pp 210-216. 7. Masakatsu Shibasaki, Naoki Yoshikawa, Shigeki Matsunaga

17

Direct Catalytic Asymmetric Aldol Reaction (Comprehensive Asymmetric Catalysis, Supplement I, Chapter 29.4, pp135-142. Eds by Jacobsen, E. N.; Pfaltz, A.; Yamamoto, H.)

10. Masakatsu Shibasaki, Hiroyuki Kakei and Shigeki Matsunaga Catalytic Asymmetric Epoxidation of α,β-Unsaturated Esters Promoted by an Yttrium-Biphenyldiol Complexin Catalysts for the Fine Chemical Synthesis, Wiley, Eds by S. M. Roberts, J. Xiao, J. Whittall, T. E. Pickett, 2007, volume 5, pp 239-248. 11. Masakatsu Shibasaki, Shigeki Matsunaga Metal-Catalyzed Asymmetric Synthesis in Asymmetric Synthesis–The Essentials, Wiley, Ed by S. Bräse, 2006, pp 47-51. 12.

TCI-mail 2006. 7 Number 131, pp 2 (ISSN 1349-4856) 13. Masakatsu Shibasaki, Shigeki Matsunaga, Naoya Kumagai Lanthanide Lewis Acid in Acid Catalysis in Modern Organic Synthesis, Wiley, Ed by H. Yamaoto, K. Ishihara, 2008, Chapter 13, pp 635-720. 14. Shigeki Matsunaga tris[1,1,1-trimethyl-N-(trimethylsilyl)silanaminato]-Yttrium (e-EROS: Encyclopedia of Reagents for Organic Synthesis) 15.

: in , 2008 16.

Development of Asymmetric Catalysts Based on Rare Earth Metals and their Applications to Biologically Active Compounds Synthesis in 10 2007 , pp 36-42 [780-786]

18. Shigeki Matsunaga, Masakatsu Shibasaki 500995-67-5 Lithium tris[(1S)-1,1’-binaphthyl-2,2’-diolato]yttrate (e-EROS: Encyclopedia of Reagents for Organic Synthesis) 19. Masakatsu Shibasaki , Shigeki Matsunaga, Naoya Kumagai Lanthanide Lewis Acid in Acid Catalysis in Modern Organic Synthesis, Eds. by Yamamoto, H.; Ishihara, K. Wiley-VCH, Weinheim, 22008, pp635-720.

18

21. Shigeki Matsunaga

The Catalytic Use of Lithium Compounds for Bond Formations

in Science of Synthesis (SOS), 8.1 Lithium Compounds, update 8.1.28, Knowledge Update. Georg ThiemeVerlag KG,

Rüdigerstrasse, 2011, pp 209-222.

22. Shigeki Matsunaga, Masakatsu Shibasaki

Cationic Bismuth-Catalyzed Hydroamination and Direct Substitution of the Hydroxy Group in Alcohols with Amides

in Topics in Current Organic Synthesis: Organic Synthesis Using Bismuth, Ed. by T. Ollevier, Springer, 2011, 128,

pp169. (DOI: 10.1007/128_2011_169)

23. Masakatsu Shibasaki, Shigeki Matsunaga “BINOL”

in Privileged Chiral Ligands and Catalysts, Ed. by Zhou, Q.-L. Wiley-VCH, Weinheim, 2011, pp295-322.

24. Masakatsu Shibasaki, Motomu Kanai, Shigeki Matsunaga, Naoya Kumagai

Multimetallic Multifunctional Catalysts for Asymmetric Reactions

In Topics in Organometallic Chemistry: Chemistry of Bifunctional Molecular Catalysis; Ikariya, T.; Shibasaki,

M. Eds.; Springer-Verlag: Berlin Heidelberg, 2011; vol 37, pp 1-30.

25. Shigeki Matsunaga

Direct C C Bond Formation (Michael, Aldol, and Mannich)

In: Carreira E.M. and Yamamoto H. (eds.) Comprehensive Chirality, Volume 5, pp. 243-292. Amsterdam: Elsevier,

2012

26. Shigeki Matsunaga Desymmetrization meso epoxide In: Carreira E.M. and Yamamoto H. (eds.) Comprehensive Chirality, Volume 4, pp. 534-580. Amsterdam: Elsevier,

2012