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Honeywell Specialty Chemicals

Seelze GmbH

Wunstorfer Strasse 40

30926 Seelze, Germany

T. +49 5137 999 214

F. +49 5137 999 867

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Honeywell Building

17 Changi Business Park Central 1 # 01-01

Singapore 486073

T. +65 6580 3811

F. +65 6783 6054

www.honeywell-lifescience.com

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www.burdickandjackson.com

North America

Burdick & Jackson

1953 S. Harvey Street

Muskegon, MI 49442 USA

T. 1 800 368 0050

T. 1 231 726 3171

F. 1 231 728 8226


101 Columbia Road

Morristown, NJ 07962 USA

T. 1 973 455 3366 T. 1 973 455 4205

F. 1 973 455 6394 F. 1 973 455 3198

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B&J Solvent Specifications Quick-Reference Guide

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B&J Brand® 76–77

ACS/HPLC Certified 77

GC2® 78

Purified Plus® 78

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B&J Brand 79–81

BioSyn® 82

Anhydrous 83


Purified Plus 84

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B&J Brand 84

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B&J Brand 85

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B&J Brand 85

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B&J Brand 86

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B&J Brand 86–87

Anhydrous 88


GC2 89

Purified Plus 89

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B&J Brand 90

Anhydrous 90

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B&J Brand 91

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B&J Brand 91

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B&J Brand 92–94

BioSyn 95

Anhydrous 96


GC2 97

Purified Plus 97

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B&J Brand 98

Anhydrous 99

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B&J Brand 99–100

BioSyn 100–101

Anhydrous 101

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B&J Brand 102

BioSyn 103

Anhydrous 103

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B&J Brand 104

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B&J Brand 104–105

Anhydrous 106


GC2 107

Purified Plus 107

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B&J Brand 108–109


Purified Plus 110

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B&J Brand 111

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B&J Brand 111–112

Anhydrous 112

Purified Plus 113

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B&J Brand 113–115

Anhydrous 116


GC2 117

Purified Plus 117

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B&J Brand 118

Purified Plus 118

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B&J Brand 119

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B&J Brand 119–120

Anhydrous 121


Purified Plus 122

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B&J Brand 122

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B&J Brand 123–124

BioSyn 124–125

Anhydrous 125


GC2 126

Purified Plus 127

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B&J Brand 127

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B&J Brand 128

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B&J Brand 128

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See Dichloromethane 92–97

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B&J Brand 129

BioSyn 130

Anhydrous 131

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B&J Brand 131–132

Anhydrous 132

GC2 133

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B&J Brand 133–134

Anhydrous 135

GC2 135

Purified Plus 136

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B&J Brand 136–137

Purified Plus 137

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B&J Brand 138

Anhydrous 139

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B&J Brand 139–140

BioSyn 140–141

Anhydrous 141


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B&J Brand 142–144

BioSyn 144–145

Anhydrous 145–146


Purified Plus 147

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B&J Brand 147–148

BioSyn 148

Anhydrous 149


Purified Plus 150

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B&J Brand 150

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BioSyn 151

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BioSyn 151

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B&J Brand 152

HPLC Certified 152

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B&J Brand 153

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B&J Distributors Reference

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1310 Goshen Parkway

West Chester, PA 19380

T. 1 800 932 5000

F. 1 610 431 9174

www.vwrsp.com

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8500 107 Street

Pleasant Prairie, Wl 53158

T. 1 800 343 8338

F. 1 262 947 7007

www.mgscientific.com

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377 Research Parkway

Meriden, CT 06450

T. 1 203 235 7989

F. 1 203 235 7163

www.brandnu.com

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Division of Asia Pacific

Specialty Chemicals Ltd

PO Box 232, Seven Hills, NSW 1730

15 Park Road, Seven Hills, NSW 2147

Australia

T. +61 2 9839 4000

F. +61 2 9674 6225

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PO Box 98485

Sloan Park, 2152 Gauteng

13 Languwa Street, Steijdon Park

Randburg, South Africa

T. +27 11 792 3300

F. +27 11 792 3363

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PO Box 6924

2da Avenida Santa Eduvigis

Res. Edison

Planta Baja Caracas 1010, Venezuela

T. +58 212 285 5811

F. +58 212 283 4253

+58 212 283 6335

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948-1 Daechi-3-Dong, Gangnam-Gu

Seoul, Korea 135-283

T. +82 2 2008 2008

F. +82 2 2008 2009

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Felipe Villanueva #3-7

Colonia Guadalupe Inn

Mexico 01020 DF

T. +525 55 651 5180

F. +525 55 664 0766

The trademarks listed below are used throughout the Burdick & Jackson™ Solvent Guide

and, to the best of our knowledge, are accurate at the time of publication.

TTTTrrrraaaaddddeeeemmmmaaaarrrrkkkkssss ooooffff HHHHoooonnnneeeeyyyywwwweeeellllllll IIIInnnntttteeeerrrrnnnnaaaattttiiiioooonnnnaaaallll

Burdick & Jackson™

B&J Brand®

B&J BioSyn®

B&J GC2®

B&J Purified Plus®

HandleLock® SolView B-Jacket®

TTTTrrrraaaaddddeeeemmmmaaaarrrrkkkkssss ffffrrrroooommmm OOOOtttthhhheeeerrrr CCCCoooommmmppppaaaannnniiiieeeessss

Expedite® Applied Biosystems

Florisil® U.S. Silica Co.

Justrite® Justrite Manufacturing

Company, L.L.C.

©2003 Honeywell International, Inc. Printed in Japan.

µBondapak® Waters Inc.

NOWPak® ATMI Inc.

OligoPilot™ Amersham Biosciences

Teflon® DuPont

Pioneers in Purity

Burdick & Jackson™ is a leading manufacturerof solvents and DNA reagents, havingpioneered the technology to purify solventsover 40 years ago. By implementing itshighly developed purification technology ina quality-assured facility, Burdick & Jacksonproduces exceptionally uniform productsproviding the purity, consistency andreliability you value.

Proprietary packaging techniques ensurethat quality is maintained to customer use.As part of Honeywell’s Life Science business,Burdick & Jackson offers customers thefurther reassurance of extensive globalresources and support.

CH3CN

About Burdick & Jackson

2 Burdick & Jackson Solvent Guide Preface | About Burdick & Jackson

Over 40 years ago, Burdick & Jackson™ pioneered the technology and began developing

equipment to produce high-purity solvents. This continually evolved to today’s process of

purification, which delivers extremely uniform solvents and DNA reagent formulations.

With new applications and techniques continually emerging, Burdick & Jackson continues

to focus on developing products that meet the most demanding requirements.

Burdick & Jackson develops and manufactures a full range of high-purity solvents and

DNA reagents at its Muskegon facility in Michigan, USA. This technically advanced facility

is ISO 9001 certified and thereby meets international quality management standards.

Honeywell’s Six Sigma Plus is also fully implemented at Burdick & Jackson.

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Preface | About Burdick & Jackson Burdick & Jackson Solvent Guide 3

Burdick & Jackson™ values every customer relationship, some of which date back to

its origins over four decades ago. Customers appreciate Burdick & Jackson’s consistent

delivery of safe, high-quality products, as well as attentive and supportive customer

service. Experts are available to assist with solvent selection, delivery and usage of

solvents, DNA reagents and chromatography products.

This updated, comprehensive solvent guide further highlights Burdick & Jackson’s

commitment to customer service. You should be able to find all the information you

need and the latest products in the pages of this guide.

You can also visit Burdick & Jackson on the web at www.burdickandjackson.com for

information on our company’s history, packaging options, solvent grades, health and

safety information and additional technical data, and to obtain Material Safety Data

Sheets (MSDS) and Certificates of Analysis.

PURE FACTS

Spring water is a natural flow

of water from the ground; its

original source is rain or snow that

has percolated through overlying

rock. During underground passage

and percolation, organisms and

particles may be filtered out

and mineral deposits dissolved,

resulting in pure mineral water

precipitating from the spring.

O

HCN(CH3)2

4 Burdick & Jackson Solvent Guide Preface | About Burdick & Jackson

CH3

CH2Cl

2

Preface | Table of Contents Burdick & Jackson Solvent Guide 5

Application and Packaging Option Guides

B&J Product Lines Application Guide 9

B&J Solvents Packaging Option Guide 10

Product Lines

Solvent Product Lines 18

B&J Brand® Solvents 18

B&J BioSyn® DNA Reagents 20

B&J BioSyn Solvents 22

B&J ACS/HPLC Certified Solvents 23

B&J Anhydrous Solvents 24

B&J GC2®

and Environmental Solvents 25

B&J Purified Plus® Certified Solvents 27

Chromatography Product Lines 28

B&J Inert II Solid Phase Extraction (SPE) 28

Columns and Accessories

B&J Solid Phase Extraction (SPE) 30

Columns and Cartridges

B&J Gel Permeation Chromatography (GPC) 34


B&J HPLC Columns and Accessories 36

B&J Narrowbore HPLC Columns 38

Solvent Packaging

Traditional Packaging Options 42

Anhydrous Solvent Packaging 43

Packaging Alternatives 44

B&J NOWPak® and 46

NOWPak II Containers

B&J NOWPak and 50

NOWPak II Dispensing Options

Other B&J NOWPak Accessories 56

B&J Stainless Steel Pressure 57

Dispense System (SSPDS)

B&J SSPDS Dispensing and Accessories 62

B&J SSPDS Installation and Operation 68

B&J SSPDS Round-Trip Program 69

B&J SSPDS Support 70

B&J HandleLock® SolView B-Jacket® 71

Solvent Specifications

B&J Solvent Specification inside

Quick-Reference Guide front cover

Cross-References for Solvent Names 74

Solvent Specifications 76

Solvent Properties

B&J Solvent Properties Table 156

B&J Solvent Miscibility Table 157

B&J Product Labels

Product Information 160

Health, Safety and Regulatory Information 161

Contents

O

CH3CCH3

PURE FACTS

Polar icecaps contain around 70%of the world’s fresh water, as theyaccumulate centuries of extremelypure water in snowfall. They haveconsequently been considered forharvesting fresh water. In 1977, a study showed that a smallerdetached iceberg holds enoughfresh water to supply a major cityfor thousands of years.

Application andPackaging Option Guides

B&J Product Lines Application Guide 9

B&J Solvents Packaging Option Guide 10

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Application and Packaging Option Guides | B&J Product Lines Application Guide Burdick & Jackson Solvent Guide 9

B&J Product Lines Application Guide

Multi-Purpose Biotech Organic ACS/HPLC Environmental Environmental Environmental Cans andApplication Synthesis Analysis Analysis Analysis Drums

B&J Brand® BioSyn® Anhydrous ACS/HPLC B&J Brand B&J Brand GC2® PurifiedSolvent Low Water Low Water Certified Solvent Purge & Trap Solvent Plus®

Product Line Content Content Solvent Methanol Solvent

HPLC ° ° °LC-Mass Spectrometry ° °Spectrophotometry ° ° °Gel Permeation Chromatography ° °Size Exclusion Chromatography ° °Natural Product Extractions ° ° °Fat Extractions ° ° °Biotech/Pharmaceutical ° ° °ManufacturingChemical Synthesis ° ° ° °Chemical Purification ° ° ° °DNA Synthesis °Peptide Synthesis ° °DNA Sequencing ° °DNA Purification ° ° ° °Protein Purification ° ° ° °Atomic Absorption Spectroscopy ° °GC-Mass Spectrometry °Capillary GC Chromatography °GC-ECD Chromatography ° ° °GC-FID Chromatography ° °Pesticide Residue Analysis ° °Drinking Water Analysis ° ° °Volatile Organic Compound Analysis ° °Semi-Volatile Compound Analysis ° °Glassware Cleaning ° °Medical Device Manufacturing ° ° °ACS Certified ° °Aldehyde Testing °Combinatorial Chemistry ° °Ultra-Low Water Content °Organic Synthesis °

B&J Solvents Packaging Option Guide

10 Burdick & Jackson Solvent Guide Application and Packaging Option Guides | B&J Solvents Packaging Option Guide

APPLICATION Multi-Purpose

12 x 1L 4 x 4L 2 x 10L 20L 20L 56L CASE QUANTITY Glass Glass B&J NOWPak® B&J NOWPak B&J NOWPak II B&J SSPDS AND PACKAGE TYPE Bottles Bottles Containers* Container* Container** Container

Acetone 010-1 010-4 NP010-10 NP010-20 CS010-56Acetonitrile UV 015-1 015-4 NP015-10 NP015-20 NS015-20 CS015-56Acetonitrile (Non-Spectrophotometric Grade) 016-4Acetonitrile 017-4 NP017-10 NP017-20 CS017-56(Low Water Content, Meets UV Specifications)Acetonitrile 018-1 018-4(Carbonyl-Free, Meets UV Specifications)n-Butyl Acetate 030-4n-Butyl Alcohol 024-1 024-4n-Butyl Chloride 034-1 034-4Chlorobenzene 043-4Chloroform (Contains Amylene and 048-1 048-4 NP048-101% Ethanol Preservative)Chloroform (Contains Amylene Preservative) 049-1 049-4 NP049-10 NP049-20 CS049-56Cyclohexane 053-1 053-4Cyclopentane 057-4o-Dichlorobenzene 061-4Dichloromethane 300-1 300-4 NS300-20 CS300-56(Contains Cyclohexene Preservative)Dichloromethane (Low Water Content, CS301-56Contains Cyclohexene Preservative)Dichloromethane 299-4 CS299-56(Contains Amylene Preservative)Dimethyl Acetamide 071-4 NP071-10 NP071-20 CS071-56N,N-Dimethylformamide 076-1 076-4 NP076-10 NP076-20 CS076-56N,N-Dimethylformamide (Low Water Content)Dimethyl Sulfoxide 081-1 081-4 CS081-56Dimethyl Sulfoxide (Low Water Content)1,4-Dioxane 087-1 087-4Ethyl Acetate 100-1 100-4 NP100-10 NP100-20 NS100-20 CS100-56Ethyl Acetate Carbonyl-Free 099-4Ethyl Alcohol Anhydrous ReagentEthyl Ether (Contains 2% Ethanol Preservative) 106-1 106-4 NS106-20Ethyl Ether (Contains No Preservative) 107-1 107-4 NS107-20 CS107-56Ethyl Ether (Contains BHT Preservative)Ethylene Dichloride 200-4Heptane 207-1 207-4 NP207-10 NP207-20 CS207-56

* HDPE overpack** Stainless steel overpack

B&J Brand Solvents

Application and Packaging Option Guides | B&J Solvents Packaging Option Guide Burdick & Jackson Solvent Guide 12Application and Packaging Option Guides | B&J Solvents Packaging Option Guide Burdick & Jackson Solvent Guide 11

Biotech Organic Synthesis ACS/HPLC Environmental Analysis Cans and Drums

200L 4 x 4L 20L 56L 200L 6 x 100mL 6 x 1L 4 x 4L 4 x 4L 12 x 1L 4 x 4L 56L 200L 4 x 4L 5-Gallon 54-Gallon B&J SSPDS Glass B&J NOWPak II B&J SSPDS B&J SSPDS Septum-Sealed Septum-Sealed Glass PVC-Coated Glass Glass B&J SSPDS B&J SSPDS Glass Metal Metal Container Bottles Container** Container Container Glass Bottles Glass Bottles Bottles Glass Bottles Bottles Bottles Container Container Bottles Can Drum

CS010-200 AH010-4 AH010-4PC 010-1 010-4 CS011-56 CS011-200 GC010-4 PP010-19 PP010-204CS015-200 AH015-4 AH015-4PC 015-1 015-4

016-4 PP016TC19 PP016-204CS017-200 BB017-4 BN017-20 BC017-56 BC017-200 AS017-0100 AS017-1

018-1 018-4

048-1 048-4

CS049-200 AS049-0100 AS049-1 AH049-4 AH049-4PC 049-1 049-4 GC049-4 PP049TC19 PP049-204AS053-0100 AS053-1 053-1 053-4

057-4

CS300-200 AH300-4 AH300-4PC 300-1 300-4 CS298-56 CS298-200 PP300-19 PP300-204

CS301-200 BB301-4 BN301-20 BC301-56 BC301-200

CS299-200 AS299-0100 AS299-1 299-4 CS299-56 CS299-200 GC299-4

CS071-200 AS071-0100 AS071-1CS076-200

BB075-4 BN075-20 BC075-56 BC075-200 AS076-0100 AS076-1CS081-200

BB082-4 AS081-0100 AS081-1

CS100-200 AS100-0100 AS100-1 AH100-4 AH100-4PC 100-1 100-4 GC100-4 PP100-19 PP100-204

AH090-4 AH090-4PCAH106-4 AH106-4PC 106-1 106-4

CS107-200 107-1 107-4PP108-19

PP108-204

CS207-200 AS206-0100 AS206-1 207-1 207-4 PP206-19 PP206-204


13 Burdick & Jackson Solvent Guide Application and Packaging Option Guides | B&J Solvents Packaging Option Guide 14 Burdick & Jackson Solvent Guide Application and Packaging Option Guides | B&J Solvents Packaging Option Guide

APPLICATION Multi-Purpose Biotech Organic Synthesis ACS/HPLC

12 x 1L 4 x 4L 2 x 10L 20L 20L 56L 200L 4 x 4L 20L 56L 200L 6 X 100mL 6 X 1L 4 x 4L 4 x 4L CASE QUANTITY Glass Glass B&J NOWPak® B&J NOWPak B&J NOWPak II B&J SSPDS B&J SSPDS Glass B&J NOWPak II B&J SSPDS B&J SSPDS Septum-Sealed Septum-Sealed Glass PVC-CoatedAND PACKAGE TYPE Bottles Bottles Containers* Container* Container** Container Container Bottles Container** Container Container Glass Bottles Glass Bottles Bottles Glass Bottles

Hexane UV 216-1 216-4 NP216-10 NP216-20 NS216-20 CS216-56 CS216-200 AH216-4 AH216-4PCHexane 217-1 217-4 NP217-20 CS217-56 CS217-200 AS217-0100 AS217-1(Non-Spectrophotometric Grade)Iso-Octane 362-1 362-4 NP362-10 NP362-20 NS362-20Isobutyl Alcohol 220-4Isopropyl Alcohol 323-1 323-4 NP323-10 NP323-20 NS323-20 CS323-56 CS323-200 AH323-4 AH323-4PCIsopropyl Alcohol (Low Water Content) 324-4 AS323-0100 AS323-1Isopropyl Myristate 225-4Methanol 230-1 230-4 NP230-10 NP230-20 NS230-20 CS230-56 CS230-200 AH230-4 AH230-4PCMethanol (For Purge & Trap Analysis)Methanol (Low Water Content) BB233-4 BN233-20 BC233-56 BC233-200 AS230-0100 AS230-1Methyl t-Butyl Ether 242-1 242-4Methyl Ethyl Ketone 247-4 NP247-10 NP247-20Methyl Isobutyl Ketone 253-4 NP253-10 NP253-20N-Methylpyrrolidone 304-1 304-4 NP304-10 NP304-20 NS304-20 CS304-56 CS304-200N-Methylpyrrolidone (Low Water Content) BB305-4 BN305-20 BC305-56 BC305-200 AS304-0100 AS304-1Pentane 312-1 312-4 NS312-20 CS312-56 CS312-200 AS312-0100 AS312-1Petroleum Ether 317-1 317-4 NS317-20 CS317-56 CS317-200 AS317-0100 AS317-1n-Propyl Alcohol 322-1 322-4 CS322-56 CS322-200Propylene Carbonate 327-1 327-4 NP327-10 NP327-20 CS327-56 CS327-200 AS327-0100 AS327-1Pyridine AH332-4 AH332-4PCPyridine (Low Water Content) 332-1 332-4 CS332-56 CS332-200 BB333-4 BN333-20 BC333-56 BC333-200 AS332-0100 AS332-1Tetrahydrofuran UV 340-1 340-4 NP340-20 NS340-20 CS340-56 CS340-200 AS340-0100 AS340-1 AH340-4 AH340-4PC(Contains No Preservative)Tetrahydrofuran (Non-Spectrophotometric 341-1 341-4 NP341-10 NP341-20 NS341-20 CS341-200 AS341-0100 AS341-1Grade, Contains BHT Pres.)Tetrahydrofuran BB343-4 BN343-20 BC343-56 BC343-200(Low Water Content, Contains BHT Pres.)Toluene 347-1 347-4 NP347-10 NP347-20 NS347-20 CS347-56 CS347-200 BN346-20 BC346-56 BC346-200 AS347-0100 AS347-1 AH347-4 AH347-4PC1,2,4-Trichlorobenzene 348-4Triethylamine BB359P100 BB359-1(12 x 100mL and 6 x 1L Glass Bottles)Trifluoroacetic Acid BB360P050 BB360P500(12 x 50mL and 6 x 500mL Glass Bottles)Water 365-4 NP365-10 NP365-20 AH365-4o-Xylene 370-1 370-4 NP370-20


B&J Brand Solvents

Application and Packaging Option Guides | B&J Solvents Packaging Option Guide Burdick & Jackson Solvent Guide 15

Environmental Analysis Cans and Drums

12 x 235mL 12 x 1L 4 x 4L 56L 200L 4 x 4L 5 Gallon 54 Gallon Glass Glass Glass B&J SSPDS B&J SSPDS Glass Metal Metal Bottles Bottles Bottles Container Container Bottles Can Drum

217-1 217-4 CS218-56 CS218-200 GC217-4 PP217-19 PP217-204

362-1 362-4 PP362TC19 PP362-204

323-1 323-4 PP323-19 PP323-204

230-1 230-4 GC230-4 PP230-19 PP230-204232-235 232-1

242-1 242-4

312-1 312-4 GC312-4317-1 317-4 CS318-56 CS318-200 GC317-4 PP317-19 PP317-204

PP322-19 PP322-204

341-1 341-4 PP341-19 PP341-204

347-1 347-4 PP347-19 PP347-204

365-4370-1 370-4


Biotech Organic Synthesis ACS/HPLC

200L 4 x 4L 20L 56L 200L 6 x 100mL 6 x 1L 4 x 4L B&J SSPDS Glass B&J NOWPak II B&J SSPDS B&J SSPDS Septum-Sealed Septum-Sealed Glass Container Bottles Container** Container Container Glass Bottles Glass Bottles Bottles

CS010-200 AH010-4CS015-200 AH015-4

CS017-200 BB017-4 BN017-20 BC017-56 BC017-200 AS017-0100 AS017-1

CS049-200 AS049-0100 AS049-1 AH049-4AS053-0100 AS053-1

CS300-200 AH300-4

CS301-200 BB301-4 BN301-20 BC301-56 BC301-200

CS299-200 AS299-0100 AS299-1

CS071-200 AS071-0100 AS071-1CS076-200

BB075-4 BN075-20 BC075-56 BC075-200 AS076-0100 AS076-1CS081-200

BB082-4 AS081-0100 AS081-1

CS100-200 AS100-0100 AS100-1 AH100-4

AH090-4AH106-4

CS107-200

CS207-200 AS206-0100 AS206-1

B&J Brand Solvents


Environmental Analysis Cans and Drums

4 x 4L 12 x 1L 4 x 4L 56L 200L 4 x 4L 5-Gallon 54-Gallon PVC-Coated Glass Glass B&J SSPDS B&J SSPDS Glass Metal Metal Glass Bottles Bottles Bottles Container Container Bottles Can Drum

AH010-4PC 010-1 010-4 CS011-56 CS011-200 GC010-4 PP010-19 PP010-204AH015-4PC 015-1 015-4

016-4 PP016TC19 PP016-204

018-1 018-4

048-1 048-4

AH049-4PC 049-1 049-4 GC049-4 PP049TC19 PP049-204053-1 053-4

057-4

AH300-4PC 300-1 300-4 CS298-56 CS298-200 PP300-19 PP300-204

299-4 CS299-56 CS299-200 GC299-4

AH100-4PC 100-1 100-4 GC100-4 PP100-19 PP100-204

AH090-4PCAH106-4PC 106-1 106-4

107-1 107-4PP108-19 PP108-204

207-1 207-4 PP206-19 PP206-204



APPLICATION Multi-Purpose

12 x 1L 4 x 4L 2 x 10L 20L 20L 56L CASE QUANTITY Glass Glass B&J NOWPak® B&J NOWPak B&J NOWPak II B&J SSPDS AND PACKAGE TYPE Bottles Bottles Containers* Container* Container** Container

Hexane UV 216-1 216-4 NP216-10 NP216-20 NS216-20 CS216-56Hexane 217-1 217-4 NP217-20 CS217-56(Non-Spectrophotometric Grade)Iso-Octane 362-1 362-4 NP362-10 NP362-20 NS362-20Isobutyl Alcohol 220-4Isopropyl Alcohol 323-1 323-4 NP323-10 NP323-20 NS323-20 CS323-56Isopropyl Alcohol (Low Water Content) 324-4Isopropyl Myristate 225-4Methanol 230-1 230-4 NP230-10 NP230-20 NS230-20 CS230-56Methanol (For Purge & Trap Analysis)Methanol (Low Water Content)Methyl t-Butyl Ether 242-1 242-4Methyl Ethyl Ketone 247-4 NP247-10 NP247-20Methyl Isobutyl Ketone 253-4 NP253-10 NP253-20N-Methylpyrrolidone 304-1 304-4 NP304-10 NP304-20 NS304-20 CS304-56N-Methylpyrrolidone (Low Water Content)Pentane 312-1 312-4 NS312-20 CS312-56Petroleum Ether 317-1 317-4 NS317-20 CS317-56n-Propyl Alcohol 322-1 322-4 CS322-56Propylene Carbonate 327-1 327-4 NP327-10 NP327-20 CS327-56PyridinePyridine (Low Water Content) 332-1 332-4 CS332-56Tetrahydrofuran UV 340-1 340-4 NP340-20 NS340-20 CS340-56(Contains No Preservative)Tetrahydrofuran (Non-Spectrophotometric 341-1 341-4 NP341-10 NP341-20 NS341-20Grade, Contains BHT Pres.)Tetrahydrofuran (Low Water Content, Contains BHT Pres.)Toluene 347-1 347-4 NP347-10 NP347-20 NS347-20 CS347-561,2,4-Trichlorobenzene 348-4Triethylamine (12 x 100mL and 6 x 1L Glass Bottles)Trifluoroacetic Acid (12 x 50mL and 6 x 500mL Glass Bottles)Water 365-4 NP365-10 NP365-20o-Xylene 370-1 370-4 NP370-20



Biotech Organic Synthesis ACS/HPLC

200L 4 x 4L 20L 56L 200L 6 X 100mL 6 X 1L 4 x 4L 4 x 4L B&J SSPDS Glass B&J NOWPak II B&J SSPDS B&J SSPDS Septum-Sealed Septum-Sealed Glass PVC-CoatedContainer Bottles Container** Container Container Glass Bottles Glass Bottles Bottles Glass Bottles

CS216-200 AH216-4 AH216-4PCCS217-200 AS217-0100 AS217-1

CS323-200 AH323-4 AH323-4PCAS323-0100 AS323-1

CS230-200 AH230-4 AH230-4PC

BB233-4 BN233-20 BC233-56 BC233-200 AS230-0100 AS230-1

CS304-200BB305-4 BN305-20 BC305-56 BC305-200 AS304-0100 AS304-1

CS312-200 AS312-0100 AS312-1CS317-200 AS317-0100 AS317-1CS322-200CS327-200 AS327-0100 AS327-1

AH332-4 AH332-4PCCS332-200 BB333-4 BN333-20 BC333-56 BC333-200 AS332-0100 AS332-1CS340-200 AS340-0100 AS340-1 AH340-4 AH340-4PC

CS341-200 AS341-0100 AS341-1

BB343-4 BN343-20 BC343-56 BC343-200

CS347-200 BN346-20 BC346-56 BC346-200 AS347-0100 AS347-1 AH347-4 AH347-4PC

BB359P100 BB359-1

BB360P050 BB360P500

AH365-4

Cl

Cl

PURE FACTS

Fog occurs when the moisture

content of air increases beyond

saturation point. There are several

causes, but one of the most common

is advection — when warm water

evaporates into cold air. Frequent

fog banks along the coast of

Newfoundland often persist for

days at a time.

Product Lines

Solvent Product Lines 18

B&J Brand® Solvents 18

B&J BioSyn® DNA Reagents 20

B&J BioSyn Solvents 22

B&J ACS/HPLC Certified Solvents 23

B&J Anhydrous Solvents 24

B&J GC2® and Environmental Solvents 25

B&J Purified Plus® Certified Solvents 27

Chromatography Product Lines 28

B&J Inert II Solid Phase Extraction (SPE) 28Columns and Accessories

B&J Solid Phase Extraction (SPE) 30Columns and Cartridges

B&J Gel Permeation Chromatography 34(GPC) Columns and Accessories

B&J HPLC Columns and Accessories 36

B&J Narrowbore HPLC Columns 38

B&J Brand®Solvents

18 Burdick & Jackson Solvent Guide Product Lines | B&J Brand Solvents

The B&J Brand features a wide range of high-purity solvents for applications includingliquid and gas chromatography (LC & GC), spectrophotometry, pesticide residueanalysis, organic synthesis and combinatorial chemistry.

The B&J Brand was the first commercially available solvent line to meet the extreme-purity demands of sensitive HPLC and GC applications. This is further supported byongoing manufacturing, packaging and R&D efforts. Unmatched lot-to-lot consistencymeans that standardized HPLC and GC methods do not have to be continuallyrecalibrated or adjusted when solvent lots are changed. Low trace impurities, low watercontent and low particulate levels also help protect expensive HPLC and GC columnsand system components. This industry-leading consistency results in lower costs for our customers.

FEATURES

Minimal UV contaminants

High GC purity

Low water content

Outstanding lot-to-lot consistency

PACKAGING OPTIONS

1L and 4L glass bottles

10L and 20L HDPE NOWPak® containers

20L stainless steel NOWPak II containers

56L, 200L and 1250L Stainless Steel Pressure Dispense

Systems (SSPDS)

Product Lines | B&J Brand Solvents Burdick & Jackson Solvent Guide 19

B&J Brand® Solvents for High-Purity ApplicationsFor HPLC, liquid and gas chromatography, pesticide residue analysis, spectrophotometry, organic synthesis and combinatorial chemistry.

12 x 235 mL 12 x 1L 4 x 4L 2 x 10L B&J 20L B&J 20L B&J 56L B&J 200L B&JGlass Glass Glass NOWPak® NOWPak NOWPak II SSPDS SSPDS

Description Bottles Bottles Bottles Containers* Container* Container† Container ContainerAcetone 010-1 010-4 NP010-10 NP010-20 CS010-56 CS010-200Acetone (For Pesicide Residue Analysis) CS011-56 CS011-200Acetonitrile UV 015-1 015-4 NP015-10 NP015-20 NS015-20 CS015-56 CS015-200Acetonitrile (Non-Spectrophotometric Grade) 016-4Acetonitrile (Low Water Content, Meets UV Specifications) 017-4 NP017-10 NP017-20 CS017-56 CS017-200Acetonitrile (Carbonyl-Free, Meets UV Specifications) 018-1 018-4n-Butyl Acetate 030-4n-Butyl Alcohol 024-1 024-4n-Butyl Chloride 034-1 034-4Chlorobenzene 043-4Chloroform (Contains Amylene and 1% Ethanol Preservatives) 048-1 048-4 NP048-10Chloroform (Contains Amylene Preservative) 049-1 049-4 NP049-10 NP049-20 CS049-56 CS049-200Cyclohexane 053-1 053-4Cyclopentane 057-4o-Dichlorobenzene 061-4Dichloromethane (Contains Cyclohexene Preservative) 300-1 300-4 NS300-20 CS300-56 CS300-200Dichloromethane (Contains Amylene Preservative) 299-4 CS299-56 CS299-200Dichloromethane (Contains Cyclohexene Preservative, CS298-56 CS298-200For Pesticide Residue Analysis)Dichloromethane (Contains Cyclohexene Preservative, CS301-56 CS301-200Low Water Content)Dimethyl Acetamide 071-4 NP071-10 NP071-20 CS071-56 CS071-200N,N-Dimethylformamide 076-1 076-4 NP076-10 NP076-20 CS076-56 CS076-200Dimethyl Sulfoxide 081-1 081-4 CS081-56 CS081-2001,4-Dioxane 087-1 087-4Ethyl Acetate 100-1 100-4 NP100-10 NP100-20 NS100-20 CS100-56 CS100-200Ethyl Acetate (Carbonyl-Free) 099-4Ethyl Ether (Contains 2% Ethanol Preservative) 106-1 106-4 NS106-20Ethyl Ether (Contains No Preservative) 107-1 107-4 NS107-20 CS107-56 CS107-200Ethylene Dichloride 200-4Heptane 207-1 207-4 NP207-10 NP207-20 CS207-56 CS207-200Hexane UV 216-1 216-4 NP216-10 NP216-20 NS216-20 CS216-56 CS216-200Hexane (Non-Spectrophotometric Grade) 217-1 217-4 NP217-20 CS217-56 CS217-200Hexane (For Pesticide Residue Analysis) CS218-56 CS218-200Iso-Octane 362-1 362-4 NP362-10 NP362-20 NS362-20Isobutyl Alcohol 220-4Isopropyl Alcohol 323-1 323-4 NP323-10 NP323-20 NS323-20 CS323-56 CS323-200Isopropyl Alcohol (Low Water Content) 324-4Isopropyl Myristate 225-4Methanol 230-1 230-4 NP230-10 NP230-20 NS230-20 CS230-56 CS230-200Methanol (For Purge and Trap Analysis) 232-235 232-1Methyl t-Butyl Ether 242-1 242-4Methyl Ethyl Ketone 247-4 NP247-10 NP247-20Methyl Isobutyl Ketone 253-4 NP253-10 NP253-20N-Methylpyrrolidone 304-1 304-4 NP304-10 NP304-20 NS304-20 CS304-56 CS304-200Pentane 312-1 312-4 NS312-20 CS312-56 CS312-200Petroleum Ether 317-1 317-4 NS317-20 CS317-56 CS317-200Petroleum Ether (For Pesticide Residue Analysis) CS318-56 CS318-200n-Propyl Alcohol 322-1 322-4 CS322-56 CS322-200Propylene Carbonate 327-1 327-4 NP327-10 NP327-20 CS327-56 CS327-200Pyridine (Low Water Content) 332-1 332-4 CS332-56 CS332-200Tetrahydrofuran UV (Contains No Preservative) 340-1 340-4 NP340-20 NS340-20 CS340-56 CS340-200Tetrahydrofuran (Non-Spectrophotometric Grade, 341-1 341-4 NP341-10 NP341-20 NS341-20 CS341-200Contains BHT Preservative)Toluene 347-1 347-4 NP347-10 NP347-20 NS347-20 CS347-56 CS347-2001,2,4-Trichlorobenzene 348-4Water 365-4 NP365-10 NP365-20o-Xylene 370-1 370-4 NP370-20

* HDPE overpack† Stainless steel overpack

B&J BioSyn® DNA Reagents

FEATURES

Developed using Burdick & Jackson’s

in-house synthesis capabilities

Manufactured to the same qualitystandards as B&J Brand® solvents

Products and packages designed to facilitate direct connection to

popular DNA synthesizers

PACKAGING OPTIONS

45mL, 200mL, 450mL, 900mL, 2L and 4L glass bottles

20L stainless steel NOWPak® II containers

56L and 200L Stainless Steel Pressure Dispense

Systems (SSPDS)

175L Entegris containers

Using in-house synthesis capabilities, Burdick & Jackson™ developedBioSyn DNA Reagents, which are processed and purified for scientistsperforming oligonucleotide synthesis. These reagents are packaged to facilitate direct connection to popular DNA synthesizers.

All Burdick & Jackson DNA reagents are processed to exactingspecifications, ensuring the highest synthesis efficiency. They are also passed through a 0.2-micron filter during packaging to eliminateparticulate contamination.

Burdick & Jackson continually expands its DNA reagent line toaccommodate new instruments and chemistries. Customers can discussspecial requirements or custom reagent formulations that do not appear in product listings with Burdick & Jackson experts.

20 Burdick & Jackson Solvent Guide Product Lines | B&J BioSyn DNA Reagents

Product Lines | B&J BioSyn DNA Reagents Burdick & Jackson Solvent Guide 21

B&J BioSyn® DNA Reagents

Reagents Used with ABI 392, 394 and 3900 DNA Synthesizers

20 x 45mL 12 x 200mL 12 x 450mL 12 x 900mL 4 x 2LDescription Glass Bottles Glass Bottles Glass Bottles Glass Bottles Glass BottlesActivator ETT * 0.25M Ethylthiotetrazole/Acetonitrile BR721-0450 BR721-2Activator Solution † 0.45M Tetrazole/Acetonitrile BR632-0045 BR632-0200 BR632-0450 BR632-0900 BR632-2A Cap 10% Acetic Anhydride/10% Pyridine/ BR641-0200 BR641-0450 BR641-2

80% Tetrahydrofuran (v/v/v)B Cap 10% N-Methylimidazole/90% Tetrahydrofuran (v/v) BR651-0200 BR651-0450 BR651-2Deblock-T ‡ 3% Trichloroacetic acid/Dichloromethane (w/v) BR605-0200 BR605-0450 BR605-0900 BR605-2Diluent Acetonitrile BR017-0045Oxidation-T 0.02M Iodine/2% Water/20% Pyridine/ BR663-0200 BR663-0450 BR663-2

78% Tetrahydrofuran (v/v/v)

Reagents Used with OligoPilot™ II and ÄKTAoligopilot 10 and 100 DNA Synthesizers

20 x 45mL 4 x 4L 20L 175L 200LGlass Glass B&J NOWPak® II Entegris B&J SSPDS

Description Bottles Bottles Container Container ContainerActivator 0.4M Tetrazole/Acetonitrile SR633-20 BR633-175Capping A 20% N-Methylimidazole/80% Acetonitrile (v/v) SR654-20 BC654-200Capping B 20% Acetic Anhydride/30% 2,6-Lutidine/ SR644-20 BC644-200

50% Acetonitrile (v/v/v)Detritylation 3% Dichloroacetic Acid/97% Dichloromethane (v/v) SR622-4 SR622-20 CS622-200Diluent Acetonitrile BR017-0045Oxidation Solution 0.05M Iodine/10% Water/90% Pyridine (v/v) SR664-20 BC664-200

Reagents Used with ABI Expedite® 8905, 8909 DNA Synthesizers

20 x 45mL 4 x 4L 20L 200LGlass Glass B&J NOWPak II B&J SSPDS

Description Bottles Bottles Container ContainerActivator ETT 0.25M Ethylthiotetrazole/Acetonitrile BR721-20 BC721-200Capping A 90% Tetrahydrofuran/10% Acetic Anhydride (v/v) SR639-4Capping B 10% N-Methylimidazole/10% Pyridine/ SR653-4

80% Tetrahydrofuran (v/v/v)Diluent Acetonitrile BR017-0045Oxidation-C 0.02M Iodine/10% Water/0.4% Pyridine/ BR665-4 BR665-20

89.6% Tetrahydrofuran

Custom Blend Reagents for DNA Synthesis 20 x 45mL 4 x 2L 4 x 4L 20LGlass Glass Glass B&J NOWPak II

Description Bottles Bottles Bottles ContainerCap A 10% Acetic Anhydride/10% 2,6-Lutidine/ BR640-2

80% Tetrahydrofuran (v/v/v)Cap B 16% N-Methylimidazole/84% Tetrahydrofuran (v/v) BR650-2Diluent Acetonitrile BR017-0045Oxidation A 0.02M Iodine/10% Water/20% Pyridine/ BR666-2 SR666-4 SR666-20

70% Tetrahydrofuran

* Also available in 200L SSPDS, Cat. No. BC721-200; 20L NOWPak container, Cat. No. BR721NP20; and 20L NOWPak II container, Cat. No. BR721-20.† Also available in 175L pressurized Entegris container, Cat. No. BR632EP175; 20L NOWPak container, Cat. No. BR632NP20; and 20L NOWPak II container,

Cat. No. BR632-20.‡ Also available in 4L glass bottles, Cat. No. BR605-4; and 20L NOWPak II container, Cat. No. BR605-20.

22 Burdick & Jackson Solvent Guide Product Lines | B&J BioSyn Solvents

B&J BioSyn® Solvents

FEATURES

Ultra-low water specifications

Low amine specifications

Low particulate levels

High solvent purity

PACKAGING OPTIONS

1L and 4L glass bottles

20L stainless steel NOWPak® II containers

56L, 200L and 1250L Stainless Steel Pressure Dispense

Systems (SSPDS)

Production of synthetic DNA and RNA has evolved over the past decade into a highlysophisticated science, resulting in an ever-increasing demand for high-purity, low-water-content solvents. Burdick & Jackson™ BioSyn solvents are specifically processed andtested for these challenging applications.

Large quantities of solvents are used in DNA synthesis, making it critical to reduceimpurities to extremely low levels. Burdick & Jackson analyzes and characterizes theseimpurities to enhance the purification process and eliminate them from its BioSyn low-water-content solvents.

For customers, this is highly valuable, as solvents critically affect overall yields, despiteconstituting only a small portion of total synthesis cost.

B&J BioSyn Solvents

Low Water Content4 x 4L 20L B&J 56L B&J 200L B&JGlass NOWPak II SSPDS SSPDS

Description Bottles Container Container ContainerAcetonitrile BB017-4 BN017-20 BC017-56 BC017-200 (Meets UV Specifications)Dichloromethane BB301-4 BN301-20 BC301-56 BC301-200(Contains Cyclohexene Preservative)N,N-Dimethylformamide BB075-4 BN075-20 BC075-56 BC075-200Dimethyl Sulfoxide BB082-4Methanol BB233-4 BN233-20 BC233-56 BC233-200N-Methylpyrrolidone BB305-4 BN305-20 BC305-56 BC305-200Pyridine BB333-4 BN333-20 BC333-56 BC333-200Tetrahydrofuran BB343-4 BN343-20 BC343-56 BC343-200(Contains BHT Preservative)Toluene BN346-20 BC346-56 BC346-200

B&J BioSyn Mobile Phase Modifiers

12 x 50mL 12 x 100mL 6 x 500mL 6 x 1LDescription Glass Bottles Glass Bottles Glass Bottles Glass BottlesTriethylamine BB359P100 BB359-1Trifluoroacetic Acid BB360P050 BB360P500

Product Lines | B&J ACS/HPLC Certified Solvents Burdick & Jackson Solvent Guide 23

B&J ACS/HPLC Certified Solvents

FEATURES

ACS certified

Lot-to-lot consistency

HPLC grade — controlled for UV absorbance, GC assay, water content and non-volatile residue

PACKAGING OPTIONS

4L glass bottles

4L PVC-coated glass bottles

Burdick & Jackson’s™ ACS/HPLC Certified Solvents are ideal for HPLCanalysis, organic synthesis and spectrophotometry applications. This lineoffers unmatched lot-to-lot consistency and product certification that meetsACS standards.

Certified solvent specifications are achieved through careful materialselection and processing. To ensure the highest-quality end product,Burdick & Jackson supplements standard ACS analysis with its own stringent internal quality control.

B&J ACS/HPLC Certified Solvents4 x 4L 4 x 4L Glass PVC-Coated

Description Bottles Glass BottlesAcetone AH010-4 AH010-4PCAcetonitrile AH015-4 AH015-4PCChloroform (Contains Amylene Preservative) AH049-4 AH049-4PCDichloromethane AH300-4 AH300-4PCEthyl Acetate AH100-4 AH100-4PCEthyl Alcohol, Anhydrous Reagent AH090-4 AH090-4PCEthyl Ether (Contains 2% Ethanol Preservative) AH106-4 AH106-4PCHexane AH216-4 AH216-4PCIsopropyl Alcohol AH323-4 AH323-4PCMethanol AH230-4 AH230-4PCPyridine AH332-4 AH332-4PCTetrahydrofuran AH340-4 AH340-4PCToluene AH347-4 AH347-4PCWater (HPLC Grade, Not ACS Certified) AH365-4

24 Burdick & Jackson Solvent Guide Product Lines | B&J Anhydrous Solvents

B&J Anhydrous Solvents6 x 100mL 6 x 1L Septum-Sealed Septum-Sealed

Description Glass Bottles Glass BottlesAcetonitrile AS017-0100 AS017-1Chloroform (Contains Amylene Preservative) AS049-0100 AS049-1Cyclohexane AS053-0100 AS053-1Dichloromethane AS299-0100 AS299-1Dimethyl Acetamide AS071-0100 AS071-1N,N-Dimethylformamide AS076-0100 AS076-1Dimethyl Sulfoxide AS081-0100 AS081-1Ethyl Acetate AS100-0100 AS100-1Heptane AS206-0100 AS206-1Hexane AS217-0100 AS217-1Isopropyl Alcohol AS323-0100 AS323-1Methanol AS230-0100 AS230-1N-Methylpyrrolidone AS304-0100 AS304-1Pentane AS312-0100 AS312-1Petroleum Ether AS317-0100 AS317-1Propylene Carbonate AS327-0100 AS327-1Pyridine AS332-0100 AS332-1Tetrahydrofuran (Contains No Preservative) AS340-0100 AS340-1Tetrahydrofuran (Contains BHT Preservative) AS341-0100 AS341-1Toluene AS347-0100 AS347-1

FEATURES

Water content ranging from<10 ppm to <50 ppm

Low residue

Convenient and effectivepackaging ensures product quality

Certificate of Analysis printed on the label

PACKAGING OPTIONS

100mL Septum-sealed glass bottles

1L Septum-sealed glass bottles

Burdick & Jackson’s™ Anhydrous Solvents are specificallymanufactured for moisture-sensitive applications including organicsynthesis and organometallic, oligonucleotide and combinatorialchemistry. Their water content ranges from less than 10 ppm to less than 50 ppm, with low residue eliminating the need for extrapurification and drying steps in your labs.

This line is packaged in specially designed septum-sealed bottles tomaintain low water content and ensure product integrity. Convenientpackaging features a double closure, which includes an easy-slip-onvinyl cap with PTFE liner and screw-on phenolic cap with an 18mmhole. The large septum surface allows for easy access as well asenough space for repeated punctures.

B&J Anhydrous Solvents

FOR MORE INFORMATION

See page 43 for the anhydrous septum-sealed bottle assembly.

Product Lines | B&J GC2 and Environmental Solvents Burdick & Jackson Solvent Guide 25

FEATURES

Less than 1 ppb tracecontamination for semi-volatileswith a molecular weight greater

than toluene (92)

Ideal for EPA protocols

Actual lot chromatogramsavailable upon request

PACKAGING OPTIONS

235mL, 1L and 4L glass bottles

56L and 200L Stainless SteelPressure Dispense Systems

(SSPDS)

Burdick & Jackson™ was the first manufacturer to produce high-purity solvents forpesticide residue analysis. As more sensitive gas and liquid chromatographic methodswere introduced, B&J continuously improved these solvents. In 1986, B&J was again thefirst to develop a new ultra-high-purity solvent line for capillary GC analysis, called B&JGC2. Today Burdick & Jackson offers an extensive solvent selection for all yourenvironmental needs.

B&J’s Purge & Trap Methanol is guaranteed to be free from any detectable amount of thevolatile organic contaminants found on the US EPA Contract Laboratory Program (CLP)Target Compound List for sample sizes up to 100 µL. It is also suitable for use in all USEPA 500 series (drinking water), 600 series (waste water) and SW-846 (solid waste) testmethods for volatile analytes.

B&J GC2 Solvents are developed for trace analysis at or below the part-per-billion level,using capillary gas chromatography. Each lot is performance tested to meet demandingGC specifications.

Samples of every B&J GC2 solvent are concentrated 1000-fold and tested by temperature-programmed capillary GC-FID. This analysis detects both low-boiling and high-boilingmolecules, anything eluting from toluene through diesel fuel and other semi-volatilecompounds of environmental interest.

B&J GC2® and Environmental Solvents

B&J Solvents for Environmental Analysis

B&J Brand® Purge & Trap MethanolFor analysis of trace volatile organic compounds using purge and trap methods

12 x 235mL 12 x 1LDescription Glass Bottles Glass BottlesMethanol for Purge 232-235 232-1and Trap Analysis

B&J GC2 SolventsFor trace analysis at or below the part-per-billion level

4 x 4LDescription Glass Bottles Acetone GC010-4Chloroform (Contains Amylene Preservative) GC049-4Dichloromethane (Contains Amylene Preservative) GC299-4Ethyl Acetate GC100-4Hexane GC217-4Methanol GC230-4Pentane GC312-4Petroleum Ether GC317-4

26 Burdick & Jackson Solvent Guide Product Lines | B&J GC2 and Environmental Solvents

B&J Solvents for Environmental Analysis (continued)

B&J Brand® Solvents for Environmental Analysis12 x 1L 4 x 4L 56L 200LGlass Glass B&J SSPDS B&J SSPDS

Description Bottles Bottles Container ContainerAcetone 010-1 010-4 CS011-56 CS011-200Acetonitrile (UV) 015-1 015-4Acetonitrile (Non-Spectrophotometric Grade) 016-4Acetonitrile (Carbonyl-Free, Meets UV Specifications) 018-1 018-4Chloroform (Contains Amylene and 1% Ethanol Preservatives) 048-1 048-4Chloroform (Contains Amylene Preservative) 049-1 049-4Cyclohexane 053-1 053-4Cyclopentane 057-4Dichloromethane (Contains Cyclohexene Preservative) 300-1 300-4 CS298-56 CS298-200Dichloromethane (Contains Amylene Preservative) 299-4 CS299-56 CS299-200Ethyl Acetate 100-1 100-4Ethyl Ether (Contains 2% Ethanol Preservative) 106-1 106-4Ethyl Ether (Contains No Preservative) 107-1 107-4Heptane 207-1 207-4Hexane (Non-Spectrophotometric Grade) 217-1 217-4 CS218-56 CS218-200Iso-Octane 362-1 362-4Isopropyl Alcohol 323-1 323-4Methanol 230-1 230-4Methyl t-Butyl Ether 242-1 242-4Pentane 312-1 312-4Petroleum Ether 317-1 317-4 CS318-56 CS318-200Tetrahydrofuran (Non-Spectrophotometric Grade, Contains BHT Preservative) 341-1 341-4Toluene 347-1 347-4Water 365-4o-Xylene 370-1 370-4

Product Lines | B&J Purified Plus Certified Solvents Burdick & Jackson Solvent Guide 27

B&J Purified Plus®Certified Solvents

Simply screening commercial solvents and repackaging batches thathappen to meet ACS specifications frequently causes wide fluctuations insolvent quality. For this reason, Burdick & Jackson™ carefully processesevery B&J Purified Plus Certified Solvent.

Purified Plus Certified Solvents allow lab process scale-up withoutencountering lot-to-lot variations and decrease issues traceable to solventcontamination. Greater lot-to-lot consistency also saves significant time andexpense by reducing the need for method modifications when changingsolvent lots.

FEATURES

Low residue

Purified solvent

ACS General Use certified

PACKAGING OPTIONS

Specially lined 5-gallon can

Specially lined 54-gallon drum

B&J Purified Plus Certified SolventsDescription 5-Gallon Can 54-Gallon DrumAcetone PP010-19 PP010-204Acetonitrile PP016TC19 PP016-204Chloroform (Contains Amylene Preservative) PP049TC19 PP049-204Dichloromethane PP300-19 PP300-204Ethyl Acetate PP100-19 PP100-204Ethyl Ether PP108-19 PP108-204Heptane PP206-19 PP206-204Hexane PP217-19 PP217-204Iso-Octane PP362TC19 PP362-204Isopropyl Alcohol PP323-19 PP323-204Methanol PP230-19 PP230-204Petroleum Ether PP317-19 PP317-204n-Propyl Alcohol PP322-19 PP322-204Tetrahydrofuran PP341-19 PP341-204Toluene PP347-19 PP347-204

28 Burdick & Jackson Solvent Guide Product Lines | B&J Inert II Solid Phase Extraction (SPE) Columns and Accessories

B&J Inert II Solid Phase Extraction (SPE)


Burdick & Jackson’s™ new Inert II SPE columns are a significant improvement over glasscolumns; they are inert to solvents yet have the added safety and lower cost of plastic.Inert II SPE columns are specially treated to be inert to solvents and include PTFE inletand outlet meshes. This means no extractable phthalates, no residual production oil andno extraneous peaks.

B&J’s new inert plastic columns, like the original inert glass columns, are manufacturedwith stringently selected packing materials to ensure maximum recovery and reproducibility.No need to change methods when switching from Inert SPE to Inert II SPE columns;you’re getting the same quality packing material in a variety of bonded phases. B&J’s InertII SPE Columns are available with Florisil®, C8 (both suitable for the CLP Quick TurnaroundMethods), C18, cyclohexyl, diol, silica, and alumina packing materials. B&J’s Octadecyl(C18) Column (Cat. Nos. 5011 and 5013) is optimized to meet all the requirements for EPAMethod 525.

For applications that require no trace amounts of extractables from plastic found inconventional SPE columns, try B&J’s new Inert II SPE columns for improved performanceand better results.

ADVANTAGES

Provides significant gains in detectioncapabilities because of reduced

background contamination

Decreases downtime for GC/MSsource cleaning

Eliminates extraneous peaks

Responsive technical support

Every stationary phase batch tested toensure lot-to-lot reproducibility

B&J Inert II SPE AccessoriesCat. No. Description Pkg. of5430 Empty 8 mL column, no frits 305435 Empty 8 mL column, bulk 10005440 Empty 8 mL column, with frits 309470A Inert II SPE Sampling Adapter 19472A Inert II SPE Sampling Adapter 69474A Phenolic Delivery Caps 1L 69475A PTFE Cap Adapters 1L 69476A Phenolic Delivery Caps 4L 69477A PTFE Cap Adapters 4L 69478A Tubing, 1/8" PTFE (5 feet) 19479A 1L Cap Adapter Assemblies 6

(1 each of 9474A, 9475A and 6 each of 9478A)9480A 4L Cap Adapter Assemblies 6

(1 each of 9476A, 9477A and 6 each of 9478A)9480AS 4L Cap Adapter for HPLC Reservoir 6

Product Lines | B&J Inert II Solid Phase Extraction (SPE) Columns and Accessories Burdick & Jackson Solvent Guide 29

B&J Inert II SPE ColumnsColumns consist of inert plastic housing with PTFE frits.

Element Cat. No. Description Size Particle Size Pore Size Surface Area Analysis %C End Capped Pkg. of5004 Octadecyl (C18) 500 mg/8 mL 40 – 60� 60 Å 525 – 575 m2/g 21 – 22 Yes, Trimethylsilyl 30

(for organic sample matrices)5008 Octadecyl (C18) 1000 mg/8 mL 40 – 60� 60 Å 525 – 575 m2/g 21 – 22 Yes, Trimethylsilyl 30



(for water sample matrices)5013 Octadecyl (C18) 1000 mg/8 mL 40 – 60� 60 Å 525 – 575 m2/g 20 – 21 Yes, Trimethylsilyl 30

(for water sample matrices)5014 Octyl (C8) 500 mg/8 mL 40 – 60� 60 Å 525 – 575 m2/g 11 – 12.5 Yes, Trimethylsilyl 305018 Octyl (C8) 1000 mg/8 mL 40 – 60� 60 Å 525 – 575 m2/g 11 – 12.5 Yes, Trimethylsilyl 305024 Cyclohexyl 500 mg/8 mL 40 – 60� 60 Å 525 – 575 m2/g 10 – 11 Yes, Trimethylsilyl 305028 Cyclohexyl 1000 mg/8 mL 40 – 60� 60 Å 525 – 575 m2/g 10 – 11 Yes, Trimethylsilyl 305044 Diol (20H) 500 mg/8 mL 40 – 60� 60 Å 525 – 575 m2/g NA Yes, Trimethylsilyl 305048 Diol (20H) 1000 mg/8 mL 40 – 60� 60 Å 525 – 575 m2/g NA Yes, Trimethylsilyl 305054 Silica (Si) 500 mg/8 mL 40 – 60� 60 Å 525 – 575 m2/g NA NA 305058 Silica (Si) 1000 mg/8 mL 40 – 60� 60 Å 525 – 575 m2/g NA NA 305059 Silica (Si) 2000 mg/8 mL 40 – 60� 60 Å 525 – 575 m2/g NA NA 305104 Florisil® 500 mg/8 mL 150 – 250� 90 Å 300 m2/g NA NA 305108 Florisil 1000 mg/8 mL 150 – 250� 90 Å 300 m2/g NA NA 305109 Florisil 2000 mg/8 mL 150 – 250� 90 Å 300 m2/g NA NA 305133 Alumina, Neutral Activity III 3000 mg/8 mL 50 – 200� 200 m2/g NA NA 30

B&J Inert II SPE Vacuum Manifold and AccessoriesCat. No. Description Pkg. of7406 Gasket 17414 12-Port Rack Plate Only 17416 Replacement Rack Leg 17418 Replacement Rack Leg Pad 17420 Replacement Cover Leg 17422 Replacement Spring Clip 17424 Vacuum Gauge 17426 Stainless Steel Male Tee 17428 Stainless Steel Hose Connector 17430 Stainless Steel Elbow 17432 Stainless Steel Valve 17436 Stainless Steel Street Tee 17438 Stainless Steel Check Valve 17440 PTFE Drain Tube 17442 Stainless Steel Male Branch Tee 17446 Hex Plug, PTFE 19427T Tapered Port, PTFE (for 12 or 24 port vacuum manifold) 19429T Turn Valve, PTFE (for 12 or 24 port vacuum manifold) 19431T Tapered Ports, PTFE (for 12 or 24 port vacuum manifold) 69433T Turn Valves, PTFE (for 12 or 24 port vacuum manifold) 6

30 Burdick & Jackson Solvent Guide Product Lines | B&J Solid Phase Extraction (SPE) Columns and Cartridges

B&J Solid Phase Extraction (SPE)

Columns and Cartridges

The Burdick & Jackson™ SPE system features columns and cartridges as well as vacuummanifolds and accessories. Combined with an expanded line of analytical HPLC columnsand B&J Brand® high-purity solvents, the B&J SPE system allows you to order the highest-quality chromatography products from a single source.

The entire line of packing materials used in the B&J SPE system columns and cartridgesundergoes careful testing. Each material must meet B&J’s stringent quality assurancerequirements to assure reproducibility, reliability and high recovery.

The B&J SPE system column consists of a retaining frit, packing material and a containingfrit in a polypropylene tube that serves as a reservoir.

Large accessory reservoirs are also available. The exit port is a Luer tip that allows thecolumns to be affixed securely to the vacuum manifold.

The product is double sealed to ensure the integrity of the columns. This packagingminimizes the possibility of contamination and maximizes convenience.

The basic support material in the colums and cartridges is small-pore silica gel. This provides a large surface area and structurally rigid support. The silica-based packingmaterials include a variety of non-polar and polar bonded phases.

Other packing materials include ion-exchange resins, aluminas and Florisil®.

ADVANTAGES

Wide selection of support materialsand multiple cartridge/column sizes

Every stationary phase batch tested to ensure lot-to-lot reproducibility

B&J’s reliable quality


Product Lines | B&J Solid Phase Extraction (SPE) Columns and Cartridges Burdick & Jackson Solvent Guide 31

B&J SPE ColumnsColumns and frits consist of medical-grade polypropylene.

B&J Non-Polar (Silica Based) SPE ColumnsElement

Cat. No. Description Size Particle Size Pore Size Surface Area Analysis %C End Capped Pkg. of9000 Octadecyl C18 100 mg/1.5 mL 30 – 70� 60 Å 400 – 500 m2/g 6 – 7 Yes, Trimethylsilyl 1009002 Octadecyl C18 200 mg/4.0 mL 30 – 70� 60 Å 400 – 500 m2/g 6 – 7 Yes, Trimethylsilyl 509004 Octadecyl C18 500 mg/4.0 mL 30 – 70� 60 Å 400 – 500 m2/g 6 – 7 Yes, Trimethylsilyl 509006 Octadecyl C18 500 mg/8.0 mL 30 – 70� 60 Å 400 – 500 m2/g 6 – 7 Yes, Trimethylsilyl 309008 Octadecyl C18 1000 mg/8.0 mL 30 – 70� 60 Å 400 – 500 m2/g 6 – 7 Yes, Trimethylsilyl 309009 Octadecyl C18 2000 mg/8.0 mL 30 – 70� 60 Å 400 – 500 m2/g 6 – 7 Yes, Trimethylsilyl 309010 Octyl C8 100 mg/1.5 mL 35 – 75� 60 Å 450 – 550 m2/g 5 – 7 Yes, Trimethylsilyl 1009012 Octyl C8 200 mg/4.0 mL 35 – 75� 60 Å 450 – 550 m2/g 5 – 7 Yes, Trimethylsilyl 509014 Octyl C8 500 mg/4.0 mL 35 – 75� 60 Å 450 – 550 m2/g 5 – 7 Yes, Trimethylsilyl 509016 Octyl C8 500 mg/8.0 mL 35 – 75� 60 Å 450 – 550 m2/g 5 – 7 Yes, Trimethylsilyl 309018 Octyl C8 1000 mg/8.0 mL 35 – 75� 60 Å 450 – 550 m2/g 5 – 7 Yes, Trimethylsilyl 309032 Ethyl C2 200 mg/4.0 mL 50� 60 Å 500 m2/g 5.5 Yes, Trimethylsilyl 509034 Ethyl C2 500 mg/4.0 mL 50� 60 Å 500 m2/g 5.5 Yes, Trimethylsilyl 50

B&J Polar (Silica Based) SPE ColumnsElement

Cat. No. Description Size Particle Size Pore Size Surface Area Analysis %C End Capped Pkg. of9050 Silica SI 100 mg/1.5 mL 50� 60 Å 500 m2/g NA NA 1009052 Silica SI 200 mg/4.0 mL 50� 60 Å 500 m2/g NA NA 509054 Silica SI 500 mg/4.0 mL 50� 60 Å 500 m2/g NA NA 509056 Silica SI 500 mg/8.0 mL 50� 60 Å 500 m2/g NA NA 309058 Silica SI 1000 mg/8.0 mL 50� 60 Å 500 m2/g NA NA 309058B Silica SI 1000 mg/8.0 mL 50� 60 Å 500 m2/g NA NA 3009059 Silica SI 2000 mg/8.0 mL 50� 60 Å 500 m2/g NA NA 309062 Cyanopropyl CN 200 mg/4.0 mL 35 – 75� 60 Å 450 – 550 m2/g 5 – 6 Yes, Trimethylsilyl 509064 Cyanopropyl CN 500 mg/4.0 mL 35 – 75� 60 Å 450 – 550 m2/g 5 – 6 Yes, Trimethylsilyl 509070 Aminopropyl NH2 100 mg/1.5 mL 35 – 75� 60 Å 400 – 500 m2/g 4.5 – 6 No 1009073 Aminopropyl NH2 300 mg/4.0 mL 35 – 75� 60 Å 400 – 500 m2/g 4.5 – 6 No 509074 Aminopropyl NH2 500 mg/4.0 mL 35 – 75� 60 Å 400 – 500 m2/g 4.5 – 6 No 50

B&J Brand Solvents

32 Burdick & Jackson Solvent Guide Product Lines | B&J Solid Phase Extraction (SPE) Columns and Cartridges

B&J SPE Columns

B&J Ion Exchange SPE ColumnsEffective Pore Size: Medium Molecular Exclusion Limit: 1000 Daltons Resin: Polystyrene Divinylbenzene

Cat. No. Description Size Counter Ion Particle Size Total Capacity Total Capacity Mesh Pkg. of9080 Strong Anion Exchange (SAX); 100 mg/ Acetate 35 – 75� 3.2 meg/dry g 1.2 – 1.5 meg/g 140 – 325 100

Trimethyl Ammonium 1.5 mL resin bed (U.S. Std)9084 Strong Anion Exchange (SAX); 500 mg/ Acetate 35 – 75� 3.2 meg/dry g 1.2 – 1.5 meg/g 140 – 325 50

Trimethyl Ammonium 4.0 mL resin bed (U.S. Std)9090 Strong Anion Exchange (SCX); 100 mg/ Hydrogen 35 – 75� 5.1 meg/dry g 2.4 meg/g 100 – 230 100

Sulfonic Acid 1.5 mL resin bed (U.S. Std)9094 Strong Anion Exchange (SCX); 500 mg/ Hydrogen 35 – 75� 5.1 meg/dry g 2.4 meg/g 100 – 230 50

Sulfonic Acid 4.0 mL resin bed (U.S. Std)

B&J Florisil® SPE Columns (Pesticide Residue Grade)

Cat. No. Description Size Particle Size Pore Size Surface Area Pkg. of9100 Florisil FL 100 mg/1.5 mL 75 – 150� 60 Å 300 m2/g 1009102 Florisil FL 200 mg/4.0 mL 75 – 150� 60 Å 300 m2/g 509104 Florisil FL 500 mg/4.0 mL 75 – 150� 60 Å 300 m2/g 509106 Florisil FL 500 mg/8.0 mL 75 – 150� 60 Å 300 m2/g 309108 Florisil FL 1000 mg/8.0 mL 75 – 150� 60 Å 300 m2/g 30

B&J Alumina SPE Columns

Cat. No. Description Size Particle Size Pore Size Surface Area Pkg. of9114 Alumina (Basic) AB 500 mg/4.0 mL 60 – 200� 100 Å 110 m2/g 509124 Alumina (Acidic) AA 500 mg/4.0 mL 60 – 200� 100 Å 110 m2/g 509128 Alumina (Acidic) AA 1000 mg/4.0 mL 60 – 200� 100 Å 110 m2/g 309130 Alumina (Neutral) AN 100 mg/1.5 mL 60 – 200� 100 Å 110 m2/g 1009134 Alumina (Neutral) AN 500 mg/4.0 mL 60 – 200� 100 Å 110 m2/g 509138 Alumina (Neutral) AN 1000 mg/8.0 mL 60 – 200� 100 Å 110 m2/g 30

B&J Specialty SPE ColumnsElement

Cat. No. Description Size Particle Size Pore Size Surface Area Analysis %C End Capped Pkg. of9143 Drug Scan 225 mg 50� 60 Å 517 m2/g 8 Yes, Trimethylsilyl 100

B&J SPE CartridgesElement

Cat. No. Description Size Particle Size Pore Size Surface Area Analysis %C End Capped Pkg. of9200 Octadecyl C18 300 mg 30 – 70� 60 Å 400 – 500 m2/g 6 – 7 Yes, Trimethylsilyl 259202 Octadecyl C18 600 mg 30 – 70� 60 Å 400 – 500 m2/g 6 – 7 Yes, Trimethylsilyl 259204 Octadecyl C18 900 mg 30 – 70� 60 Å 400 – 500 m2/g 6 – 7 Yes, Trimethylsilyl 259210 Octyl C8 300 mg 35 – 75� 60 Å 450 – 550 m2/g 5 – 7 Yes, Trimethylsilyl 259212 Octyl C8 600 mg 35 – 75� 60 Å 450 – 550 m2/g 5 - 7 Yes, Trimethylsilyl 259214 Octyl C8 900 mg 35 – 75� 60 Å 450 – 550 m2/g 5 - 7 Yes, Trimethylsilyl 259220 Ethyl C2 300 mg 50� 60 Å 500 m2/g 5.5 Yes, Trimethylsilyl 259230 Silica SI 300 mg 50� 60 Å 500 m2/g NA NA 259232 Silica SI 600 mg 50� 60 Å 500 m2/g NA NA 259234 Silica SI 900 mg 50� 60 Å 500 m2/g NA NA 259240 Cyanopropyl CN 300 mg 35 – 75� 60 Å 450 – 550 m2/g 5 – 6 Yes, Trimethylsilyl 259250 Aminopropyl NH2 300 mg 35 – 75� 60 Å 400 – 500 m2/g 4.5 – 6 No 259260 Florisil 300 mg 75 – 150� 60 Å 300 m2/g NA NA 259264 Florisil 900 mg 75 – 150� 60 Å 300 m2/g NA NA 259290 Alumina (Acidic) 300 mg 60 – 200� 100 Å 110 m2/g NA NA 259304 Alumina (Neutral) 900 mg 60 – 200� 100 Å 110 m2/g NA NA 25

Product Lines | B&J Solid Phase Extraction (SPE) Columns and Cartridges Burdick & Jackson Solvent Guide 33

B&J SPE Vacuum Manifold and AccessoriesCat. No. Description Pkg. of9400 12-Port Vacuum Manifold* 19402 Glass Chamber for 12-Port Vacuum Manifold 19404 Cover with Gasket and 12 Stopcocks9406 Gaskets for 12-Port Manifold 29408 Vacuum Gauge and Valve9412 Stainless Steel Needles 129413 Polypropylene Needles 129414 Collection Rack: contains support rods (3),

bottom plate, center plate, top plates (3), 12 retaining clips9416 Plate for Volumetric Flask 19418 Plate for 16 mm Test Tube 19420 Plate for Autosampler Vials 19422 Retaining Clips 129424 5mL Collection Tubes 129425 Cover Inserts (2 top and 2 bottom pieces)9426 One-Way Stopcock 129430 Adapter 159401 24-Port Vacuum Manifold* 19403 Glass Chamber for 24-Port Vacuum Manifold 19405 Cover with Gasket and 24 Stopcocks9407 Replacement Gaskets for 24-Port Manifold 29415 Collection Rack: contains support rods (3),

bottom plate, center plate, top plates (3), 12 retaining clips9419 Top Plate for 16 mm Test Tube 19421 Top Plate for 13 mm Test Tube 19427 PTFE Port for Manifold Cover 19429 PTFE Valve for Manifold 19431 PTFE Ports for Manifold Cover 69433 PTFE Valves for Manifold 6

* Vacuum Manifold comes with cover, gasket, vacuum gauge, valve, glass block, 12 or 24 needles and stopcocks, collection racks (1 each size).

B&J SPE Column Packing Kits, Filter Columns and FritsCat. No. Description Pkg. of9434 75 mL Reservoir (no frits) 1009436 1.5 mL Reservoir (no frits) 1009438 4.0 mL Reservoir with 100 frits 509440 8.0 mL Reservoir with 100 frits 509442 75 mL Reservoir with 200 frits 1009444 Frit, fits 75 mL 1009446 Filter Column 1.5 mL (2 frits/column, inserted) 1009448 Filter Column 4.0 mL (2 frits/column, inserted) 509450 Filter Column 8.0 mL (2 frits/column, inserted) 509452 Frit: fits 1.5 mL Reservoir 1009454 Frit: fits 4.0 mL Reservoir 1009456 Frit: fits 8.0 mL Reservoir 100

34 Burdick & Jackson Solvent Guide Product Lines | B&J Gel Permeation Chromatography (GPC) Columns and Accessories

B&J Gel Permeation Chromatography

(GPC) Columns and Accessories

The Burdick & Jackson™ GPC column line is designed for quantitative analytical work. A major advantage of these columns is that the polystyrene/divinylbenzene copolymer is stable in over twenty typical organic solvents and over a wide temperature range.Because these columns offer maximum flexibility, the additional expense of dedicatedcolumn banks is not required.

B&J GPC columns are compatible with a wide range of solvents and may be used atelevated temperatures up to 140°C. Every column is individually tested to guaranteereproducible column-to-column performance.

With proper care, B&J GPC columns will give many months or even years of qualityperformance, despite regular solvent and temperature alterations.

Each column is individually tested to ensure that the response of the column (log MWversus retention time working curve) is reproducible from column to column. Each resinis manufactured and tested to guarantee optimal performance for banks of columns ofincreasing pore size. Misleading chromatographic effects caused by poorly matchedresins are therefore avoided.

A complete range of pore sizes from 50Å to 106Å is available in both 10µ particle sizesfor less demanding work and 5µ particle sizes for high-resolution work. Mixed-bedcolumns enable the analyst to rapidly obtain the general composition of a given polymermixture and focus in on the molecular weight regions of greatest interest.

Being satisfied with GPC columns that limit operating flexibility is now a thing of thepast. Choose a column that gives you the power to maximize your lab’s results andminimize the cost of your analyses.

ADVANTAGES

Compatible with a wide range of solvents

Reliable performance at elevatedtemperatures — up to 140°C

Tested to guarantee reproduciblecolumn-to-column performance

Packed with PL gel


Product Lines | B&J Gel Permeation Chromatography (GPC) Columns and Accessories Burdick & Jackson Solvent Guide 35

B&J GPC Columns (PL Gel)Columns contain a polystyrene/divinylbenzene copolymer, which is compatible with a wide range of solvents and can be used at elevated temperatures up to 140ºC.

Cat. No. Description Size Particle Size Pore Size9700 Molecular Weight Range: 10 – 1000 30 cm x 7.5 mm 10� 50 Å9705 Molecular Weight Range: 10 – 1000 30 cm x 7.5 mm 5� 50 Å9710 Molecular Weight Range: 50 – 1500 30 cm x 7.5 mm 10� 100 Å9715 Molecular Weight Range: 50 – 1500 30 cm x 7.5 mm 5� 100 Å9720 Molecular Weight Range: 100 – 104 30 cm x 7.5 mm 10� 500 Å9725 Molecular Weight Range: 100 – 104 30 cm x 7.5 mm 5� 500 Å9730 Molecular Weight Range: 200 – 3 x 104 30 cm x 7.5 mm 10� 103 Å9735 Molecular Weight Range: 200 – 3 x 104 30 cm x 7.5 mm 5� 103 Å9740 Molecular Weight Range: 5 x 103 – 6 x 105 30 cm x 7.5 mm 10� 104 Å9745 Molecular Weight Range: 5 x 103 – 6 x 105 30 cm x 7.5 mm 5� 104 Å9750 Molecular Weight Range: 5 x 104 – 4 x 106 30 cm x 7.5 mm 10� 105 Å9755 Molecular Weight Range: 5 x 104 – 4 x 106 30 cm x 7.5 mm 5� 105 Å9760 Molecular Weight Range: 2 x 105 – 1 x 107 30 cm x 7.5 mm 10� 106 Å9770 Molecular Weight Range: 5 x 104 – 1 x 107 30 cm x 7.5 mm 10� Mixed9775 Molecular Weight Range: 2000 – 4 x 106 30 cm x 7.5 mm 5� Mixed

B&J GPC AccessoriesCat. No. Description Pkg. of9790 10� GPC Guard Column (5 cm x 7.5 mm) 19795 5� GPC Guard Column (5 cm x 7.5 mm) 1

36 Burdick & Jackson Solvent Guide Product Lines | B&J HPLC Columns and Accessories

B&J HPLC Columns and Accessories

Burdick & Jackson™ offers a wide range of reversed phase and normal phase HPLCcolumns. All packing materials are based on a 5µ porous spherical silica support. Thecolumns are available in either 15 or 25 cm lengths, both having 4.6 mm inner diameters.

All tubing and endfitting components are 316 stainless steel. A set of nuts and ferrules is included to enable easy and rapid connection of the column into any LC system.Included with each column are guidelines for usage and storage plus a solvent miscibility table.

Each column type and length has a unique set of rigorously controlled specifications.The test solutes are chosen to characterize the column in terms of hydrophobic andpolar retention mechanisms.

These solutes are specially selected to probe significant chromatographic properties ofthe packed column. The number of theoretical plates (N), skew (A/B) and separationfactors (�) are guaranteed to meet stringent specifications.

Each column includes:

° An actual test chromatogram

° Quality assurance to meet B&J performance specifications

° Support by B&J’s technical hotline for HPLC applications

B&J Pharmaceutical C18 HPLC Column (Cat. No. 9588)

The B&J pharmaceutical C18 HPLC column is based on an improved 10µ irregularparticle diameter technology. This, coupled with rigorous production specification andtesting, gives the B&J pharmaceutical C18 HPLC column superior reproducibility fromcolumn-to-column and lot-to-lot. In addition, the improved-base silica extends columnlifetime, yielding a more cost-effective product.

The B&J pharmaceutical C18 HPLC column meets or exceeds the minimum performancestandards for a large number of documented USP methods that reference theµBondapak® C18 column. These include such multi-analyte tests as theophylline/caffeine/guanenesin, salicylic acid/aspirin/benzoic acid (internal standard) andniacinamide/pyridoxine/riboflavin/ thiamine. Many single analyte (plus internal standard)methods have also been tested.

ADVANTAGES

Quality assurance to meet B&Jperformance specifications

Tested to guarantee reproduciblecolumn-to-column performance


Tested to meet exceedingly rigorous specifications using specially

selected test solutes

Specially selected phases for unique separations

Product Lines | B&J Biosyn Solvent Burdick & Jackson Solvent Guide 37Product Lines | B&J HPLC Columns and Accessories Burdick & Jackson Solvent Guide 37

B&J HPLC ColumnsElement

Cat. No. Description Size Particle Size Pore Size Surface Area Analysis %C End Capped9501 Silica SI 15 cm x 4.6 mm 5� 100 Å 200 m2/g NA NA9506 Silica SI 25 cm x 4.6 mm 5� 100 Å 200 m2/g NA NA9511 Octyl HLD* OC5 15 cm x 4.6 mm 5� 120 Å 160 m2/g 7 No9516 Octyl HLD* OC5 25 cm x 4.6 mm 5� 120 Å 160 m2/g 7 No9512 Octyl OC5 15 cm x 4.6 mm 5� 90 Å 225 m2/g 9 Yes, Trimethylsilyl9517 Octyl OC5 25 cm x 4.6 mm 5� 90 Å 225 m2/g 9 Yes, Trimethylsilyl9521 Cyanopropyl CN5 15 cm x 4.6 mm 5� 100 Å 200 m2/g 4 No9526 Cyanopropyl CN5 25 cm x 4.6 mm 5� 100 Å 200 m2/g 4 No9551 Phenyl PL5 15 cm x 4.6 mm 5� 120 Å 160 m2/g 7 Yes, Trimethylsilyl9556 Phenyl PL5 25 cm x 4.6 mm 5� 120 Å 160 m2/g 7 Yes, Trimethylsilyl9561 Aminopropyl CA AM5 15 cm x 4.6 mm 5� 120 Å 170 m2/g 2 No9566 Aminopropyl CA AM5 25 cm x 4.6 mm 5� 120 Å 170 m2/g 2 No9570 Octadecyl OD5 15 cm x 4.6 mm 5� 80 Å 225 m2/g 12.5 Yes, Trimethylsilyl9575 Octadecyl OD5 25 cm x 4.6 mm 5� 80 Å 225 m2/g 12.5 Yes, Trimethylsilyl9588 Octadecyl OD10 30 cm x 3.9 mm 10� irregular 125 Å 300 m2/g 10 Yes, Trimethylsilyl

* HLD (High Ligand Density) – 50% of available silanol groups are derivatized with octyl moiety.

B&J HPLC Column AccessoriesCat. No. Description Pkg. of9810 Guard Column Housing 19812 Silica Guard Column, 1 cm 39814 Reversed Phased Guard Column, 1 cm 39816 Normal Phase Guard Column, 1 cm 3

38 Burdick & Jackson Solvent Guide Product Lines | B&J Narrowbore HPLC Columns

B&J Narrowbore HPLC Columns

Burdick & Jackson™ offers a line of narrowbore HPLC columns to complement theexisting line of conventional analytical HPLC columns. B&J narrowbore columns have aninner diameter of 2.1 mm and a length of 10 cm. To increase efficiency, a 3µ particle sizehas been selected for all columns. As with B&J’s conventional columns, each narrowboreHPLC column is pretested to meet exceedingly rigorous specifications.

Increased Sensitivity

When the sample volume is maintained from an analytical packed-column method to a narrow-column method, the peak volumes of the components are reduced. Thedecreased flow rate through the narrowbore column maintains the same retention timesof each component. Also, because less solvent is used to move the components alongthe column, the components are not diluted as much as they would be in analyticalcolumn methodologies, which results in increased sensitivity. With narrowbore columns,peak area is concentrated approximately five times when sample components gothrough the detector, in comparison to analytical column methods.

ADVANTAGES

Tested to meet exceedingly rigorousspecifications using specially

selected test solutes

Require less solvent than analytical HPLC columns

Connect or interface with unique orspecial detectors (e.g., MS)

Increase sensitivity


B&J Narrowbore HPLC ColumnsCat. Particle Pore Surface ElementNo. Description Size Size Size Area Analysis %C End Capped9600 Silica SI3 10 cm x 3� 100 Å 200 m2/g NA NA

2.1 mm9610 Octyl OC3 10 cm x 3� 90 Å 225 m2/g 9 Yes,

2.1 mm Trimethylsilyl9620 Cyanopropyl 10 cm x 3� 100 Å 200 m2/g 4 No

CN3 2.1 mm9650 Phenyl PL3 10 cm x 3� 120 Å 160 m2/g 7 Yes,

2.1 mm Trimethylsilyl9670 Octadecyl 10 cm x 3� 80 Å 225 m2/g 12.5 Yes,

OD3 2.1 mm Trimethylsilyl

Product Lines | B&J Narrowbore HPLC Columns Burdick & Jackson Solvent Guide 39

Lower Solvent Consumption

Narrowbore columns require less solvent. The particle size of the stationary-phase packing and the internal diameter of the column determine the optimum linear velocity of the mobile phase. The optimum linear velocity determines the actual flow rate. The flow rate for narrowbore columns is typically 0.2 – 0.5 mL/min in comparison to 1.0 – 3.0 mL/min for analytical columns, resulting in significantly less solvent consumption.

Other Advantages

Smaller sample size and less of sample preparation reagents are two more narrowbore advantages.Since the component’s concentration is enhanced due to a decrease in peak volume, a smaller samplesize can be used in comparison to analytical packed-column methods. A smaller sample size meanssmaller amounts of reagents may be used for smaller sample work-ups.

Another advantage is the ability to connect or interface with unique or special detectors. LC-MS andLC-NMR are much easier to use with the narrowbore columns due to the advantages of lower flow rates and decreased peak volume.

Solvent Packaging | Packaging Alternatives Burdick & Jackson Solvent Guide 45

B&J Stainless Steel Pressure Dispense System (SSPDS) Containers

Pressurizable 56L, 200L and 1250L B&J Stainless SteelPressure Dispense System (SSPDS) containers are theultimate packages for maintaining high solvent purity.Constructed of durable, inert materials, these systemsincorporate quick-connect inert gas and solvent couplingsfor minimal solvent loss and air inclusion when connectingand disconnecting the container at operating pressure (<15 psig). Rigorously cleaned PTFE hoses and accessoriesensure no contamination is introduced when delivering high-purity solvent from a B&J SSPDS container directly to aninstrument or fume hood dispenser.

B&J Makes Packaging Alternatives Easy

Burdick & Jackson™ offers comprehensive technicalassistance with B&J NOWPak®, NOWPak II and SSPDScontainers concerning:

° regulatory support

° installation recommendations

° components for direct instrument connection

° serial number container tracking systems

° round-trip shipping programs for easy return of empty containers

56L B&J SSPDS

1250L B&J SSPDS200L B&J SSPDS


See pages 57–70 for B&J Stainless Steel PressureDispense System (SSPDS) containers anddispensing options.

B&J TECHNICAL AND CUSTOMER SERVICE

Contact B&J at 800-368-0050 for high-puritysolvents in intermediate bulk containers (IBC)larger than 200L.

O CH3

O

O

PURE FACTS

The total length of the world’scoastlines is approximately 313,000miles — enough to circle the equatortwelve times. As acknowledged inthe 1997 Guinness Book of Records,Canada has the longest coastline ofany country, with a total of 152,094miles including islands.

Solvent Packaging

Traditional Packaging Options 42

Anhydrous Solvent Packaging 43

Packaging Alternatives 44

B&J NOWPak® and 46NOWPak II Containers

B&J NOWPak and 50NOWPak II Dispensing Options

Other B&J NOWPak Accessories 56

B&J Stainless Steel Pressure 57Dispense System (SSPDS)

B&J SSPDS Dispensing 62and Accessories

B&J SSPDS Installation 68and Operation

B&J SSPDS Round-Trip Program 69

B&J SSPDS Support 70

B&J HandleLock® SolView B-Jacket® 71

42 Burdick & Jackson Solvent Guide Solvent Packaging | Traditional Packaging Options

Traditional Packaging Options

B&J Solvent Packaging Options

B&J solvents are available in a variety of packaging optionsfrom lab size to manufacturing scale. In addition to familiarbottles, cans and drums, Burdick & Jackson™ offersinnovative, returnable containers that maintain solventpurity and reduce packaging waste. These containersprovide an environmentally responsible way to enhance lab safety and convenience, especially when using largersolvent volumes.

Standard Glass Bottles

B&J solvents are packaged in several sizes of glass bottles,the industry standard for high-purity solvents because oftheir amber color and inert quality. These containers areeasily handled, occupy minimal bench space and can be readily connected to the tubing assemblies of labequipment like HPLC instruments and DNA synthesizers.As a safety precaution when using 4L glass bottles, Burdick & Jackson recommends placing them in the B&JHandleLock® SolView B-Jacket® (B&J Cat. No. S1337-20), an OSHA-approved type of secondary containment.

B&J Metal Cans and Drums

B&J 5-gallon can and 54-gallon drum interiors have a solvent-resistant coating to provide a superior packagecompared with unlined cans and drums. This coatingguards against rust particle formation and the introductionof contaminants commonly found in ordinary cans anddrums. The 5-gallon B&J cans have a convenient handleand a splashless pour spout that is resealable to maintainsolvent purity. The 54-gallon drums are equipped with w"and 2" tapered pipe thread fittings. Numerous dispensingsystems are commercially available to remove solvent from either of these containers.


See page 71 for B&J HandleLock SolViewB-Jackets as secondary containment for4L glass solvent bottles.

Glass Bottles

5-Gallon Can

54-Gallon Drum

B&J Anhydrous Solvent Glass Bottles

The anhydrous solvent line is packaged in speciallydesigned septum-sealed bottles to maintain low watercontent and ensure product integrity. Convenient packagingfeatures a double closure, which includes an easy-slip-onvinyl cap with a Teflon® liner and screw-on phenolic capwith an 18 mm hole. The large septum surface allows foreasy access as well as enough space for repeatedpunctures.

Figure 1 (right). Anhydrous Solvent Bottle Assembly.

A

B

C

D

E

A. Outer closure. Blackeasy-slip-on vinyl cap.

B. Teflon liner

C. Black screw-on phenoliccap with 18 mm hole

D. Teflon-faced septumreinforced with nitrilerubber

E. Glass bottle

Solvent Packaging | Anhydrous Solvent Packaging Burdick & Jackson Solvent Guide 43

Anhydrous Solvent Packaging

How to use B&J’s anhydrous solvent bottle assembly:

1. Remove outer closure.

2. Fill a dry syringe with dry inert gas (argon or nitrogen).

3. Pierce the septum with the syringe. Use a fresh locationeach time to prolong product quality.

4. Push the gas from the syringe into the bottle, then slowlywithdraw the required amount of solvent.

5. Carefully remove the syringe from the bottle.

6. Dispense the required solvent.

7. After each use, put the outer closure back to further protect the solvent from moisture.

Note: To prolong the quality of the solvent and optimizeresealability, use smaller-diameter needles.

Packaging heading

44 Burdick & Jackson Solvent Guide Solvent Packaging | Packaging Alternatives

Packaging Alternatives

20L B&J NOWPak 20L B&J NOWPak II

B&J NOWPak® and NOWPak II Containers

High-purity solvent is contained in an inert, specially cleanedliner inside rigid 10L and 20L high-density polyethylene(HDPE) or 20L stainless steel overpacks. Solvents packagedin B&J NOWPak and NOWPak II containers are suitable forhigh-purity applications, including DNA or peptide synthesis,liquid chromatography and pharmaceutical manufacturing.The inert, particle-free nature of the liner also makes B&J NOWPak the ideal package for solvents used in HPLC analysis.

The B&J NOWPak HDPE overpack is used in dispensingapplications where pressure is required intermittently up to 10 psig or the solvent is withdrawn by an HPLC pump or bottletop dispenser.

The B&J NOWPak II stainless steel container is designed forsituations requiring continuous pressure less than 15 psig,such as direct connection to DNA and peptide synthesizers.The B&J NOWPak II overpack also safely contains high-vapor-pressure solvents such as pentane and dichloromethaneduring shipping and storage.

B&J Entegris Containers

High-purity solvent blends with corrosive properties, orother blends incompatible with metals, are suitable for 175LEntegris containers with an inert PFA lining and durablepolyethylene overpack. The special 175L (46-gallon) designenables the container to fit into existing, standard-size bulkchemical delivery system cabinets. These reusablecontainers can be pressurized up to 10 psig and use theEntegris Quick Connect System for convenient dispensing.

10L B&J NOWPak

175L Entegris Container


See pages 46–56 for B&J NOWPak and NOWPak IIcontainers and dispensing options.

Solvent Packaging | Packaging Alternatives Burdick & Jackson Solvent Guide 45

B&J Stainless Steel Pressure Dispense System (SSPDS) Containers

Pressurizable 56L, 200L and 1250L B&J Stainless SteelPressure Dispense System (SSPDS) containers are theultimate packages for maintaining high solvent purity.Constructed of durable, inert materials, these systemsincorporate quick-connect inert gas and solvent couplingsfor minimal solvent loss and air inclusion when connectingand disconnecting the container at operating pressure (<15 psig). Rigorously cleaned PTFE hoses and accessoriesensure no contamination is introduced when delivering high-purity solvent from a B&J SSPDS container directly to aninstrument or fume hood dispenser.

B&J Makes Packaging Alternatives Easy

Burdick & Jackson™ offers comprehensive technicalassistance with B&J NOWPak®, NOWPak II and SSPDScontainers concerning:

° regulatory support

° installation recommendations

° components for direct instrument connection

° serial number container tracking systems

° round-trip shipping programs for easy return of empty containers

56L B&J SSPDS

1250L B&J SSPDS200L B&J SSPDS


See pages 57–70 for B&J Stainless Steel PressureDispense System (SSPDS) containers anddispensing options.


Contact B&J at 800-368-0050 for high-puritysolvents in intermediate bulk containers (IBC)larger than 200L.

46 Burdick & Jackson Solvent Guide Solvent Packaging | B&J NOWPak and NOWPak II Containers


A recyclable packaging alternative to glass bottles, the B&J NOWPak container maintains solvent purity,increases lab safety and maximizes efficiency when usinglarger solvent volumes. High-purity solvent is contained inan inert, specially cleaned liner inside a rigid high-densitypolyethylene (HDPE) or 304 stainless steel overpack (Figure 2).

Inert, Specially Cleaned PTFE Liners

The inner liner of the B&J NOWPak container is afluoropolymer compatible with virtually all high-puritysolvents. The liners are constructed inside Class 100cleanrooms and are cleaned using a proprietary methodthat removes particles down to the sub-micron level. All seams are fusion sealed without applying adhesives, and each liner is thoroughly leak tested before and afterinsertion into the overpack.

Two Break-Resistant Overpack Configurations

Two B&J NOWPak overpack configurations are available,providing virtually break-proof secondary containment for the storage and handling of solvents as required byOSHA laboratory standards (29 CFR 1910.1450). TheHDPE B&J NOWPak overpack is used in dispensingapplications requiring intermittent pressurization of less than 10 psig or if the solvent is withdrawn by an HPLC pumpor bottletop dispenser. The stainless steel B&J NOWPak IIcontainer is designed for applications requiring continuouspressure less than 15 psig, such as direct connection to DNA and peptide synthesizers. The B&J NOWPak IIoverpack also safely contains high-vapor-pressure solventssuch as pentane and dichloromethane during shipping andstorage. Solvent-specific stainless steel overpack fleets are tracked by serial number.

B&J Solvents in NOWPak Containers

Solvents packaged in B&J NOWPak and NOWPak IIcontainers are suitable for high-purity applications includingliquid chromatography, pharmaceutical manufacturing andDNA and peptide synthesis.

Two Burdick & Jackson™ high-purity product lines areavailable in the B&J NOWPak container system.

B&J Brand® – For HPLC, gas chromatography, pesticideresidue analysis and spectrophotometry.

B&J BioSyn® – For biosynthetic applications requiringextremely low water content.

A

B

C

Figure 2. 20L B&J NOWPak Container Diagram.

A. Polypropylene closure with PTFE seal

B. Precleaned, inert inner liner

C. Reusable/recyclable high-density polyethylene (HDPE) overpack

instruments such as HPLC units and DNA synthesizers can run five times longer without changing solventreservoirs. Productivity is greater when less lab time isspent handling solvent containers and instruments can run unattended overnight.

Sealed Dispensing Systems

All B&J NOWPak dispensing options except the pour spoutform a sealed system by preventing the reentry of air into theliner as solvent is withdrawn from the container. Sealeddispensing not only reduces exposure to solvent vapors, it also increases the useful shelf life of solvents. Airborneimpurities or other liquids cannot be inadvertently introducedinto the container. Using the B&J NOWPak system eliminatesconcern over the purity of opened bottles and solventdisposal expense, should contamination occur.

4 x 4L 10L B&J NOWPak 20L B&J NOWPak 20L B&J NOWPak II Case Container* Container Container

Volume 16 liters 10 liters 20 liters 20 liters4.2 gallons 2.6 gallons 5.3 gallons 5.3 gallons

Overpack Material High-density High-density Stainless polyethylene polyethylene steel

Approximate Weight 16.0 lbs. 1.7 lbs. 4.2 lbs. 16.5 lbs.When Empty 7.3 kg 0.8 kg 1.9 kg 7.5 kgApproximate Full Weight 44.0 lbs. 19.0 lbs. 39.0 lbs. 52.0 lbs.When Containing Methanol 20.0 kg 8.6 kg 17.7 kg 23.6 kgDOT/UN Packaging UN4G/Y37/S UN4G/X42.7/S UN1H1/Y1.9/100 UN1A1/X1.9/300Specification

* Sold in 2 x 10L cartons

15.3"/38.9 cm width 9.0"/22.9 cm 12.0"/30.5 cm 11.0"/27.9 cm

20.3

"/51

.6 c

m

16.4

"/41

.7 c

m

13.8

"/35

.1 c

m

17.0

"/43

.2 c

m

6.3"/16.0 cm

13.5

"/34

.3 c

m

15.3"/38.9 cm depth

B&J Container Specifications

Solvent Packaging | B&J NOWPak and NOWPak II Containers Burdick & Jackson Solvent Guide 47

Improved Lab Safety

Several B&J NOWPak® system features enhance overall lab safety and streamline solvent storage and handling.Break-resistant B&J NOWPak containers reduce the numberof glass bottles on benchtops and in fume hoods. Becauseof its overpack and liner construction, secondary solventcontainment is built into this package. Sealed systemsformed by B&J NOWPak solvent dispensers and adaptersreduce the amount of solvent vapor in the workplace.

Increased Storage Space and Time Efficiency

More solvent can be stored in a smaller area because 20LB&J NOWPak containers are 61% more space efficient than glass bottles packaged in 4 x 4L cases. Not only isstoreroom space maximized when five 4L bottles arereplaced by one 20L B&J NOWPak container, but lab

48 Burdick & Jackson Solvent Guide Solvent Packaging | B&J NOWPak and NOWPak II Containers

(continued)


Solvent Packaging Waste Reduction

Sixteen liters of bottled solvent generate a total of 16pounds of corrugated cartons, expanded polystyreneinserts and amber glass bottles that must be removed froma facility and sent to a landfill. Some localities even requirebottles to be triple rinsed prior to disposal, creating aRCRA-regulated solvent waste stream. The B&J NOWPakcontainer components can be recycled without triplerinsing, and no packaging waste is produced when youuse the B&J NOWPak Container Return Program. Even ifyou do not participate in the return program, the B&JNOWPak system generates 75% less packaging wastethan 4L glass bottles in conventional shipping cartons.

Five 4 x 4L cases of solvent create 80 pounds of packagingwaste compared to no waste for your lab when you participate inthe B&J NOWPak Container Return Program and send the emptycontainers back to Burdick & Jackson.

B&J NOWPak Container Return Program

Decrease your total operational costs by saving disposal feeexpenses and reallocating the labor currently spent handlingand discarding packaging materials. The B&J NOWPakContainer Return Program completely eliminates packagingwaste. Drained B&J NOWPak containers from qualifiedcustomers can be consolidated and sent back to Burdick & Jackson™ with the liners still inside. To ensure solventintegrity, the liners are used only once for high-puritysolvent, then added to B&J’s recycling program. ContactB&J Technical and Customer Service for additional detailson the B&J NOWPak Container Return Program.


For technical and customer service, call us toll-free at 800-368-0050.

Solvent Packaging | B&J NOWPak and NOWPak II Containers Burdick & Jackson Solvent Guide 49

Packaging heading

B&J Brand Methanol in a B&J NOWPak Container after 7 Months

B&J Original Lot B&J NOWPak ContainerTest Specification Analysis after 7 MonthsWater (by Karl Fischer titration) <0.05% 0.017% 0.017%UV Cutoff (1 cm cell) <205 nm 204 nm 204 nmRefractive Index 1.3284 ± 0.0004 1.3284 1.3285Residue (detection limits <1 mg/L) <1 mg/L None detected None detectedGC Purity >99.9% 99.9+% 99.9+%GC-ECD (as heptachlor epoxide) <10 ng/L Passes test Passes test

B&J Brand Acetonitrile UV in a B&J NOWPak Container after 5 Months

B&J 4L Glass Bottle B&J NOWPak ContainerTest Specification after 5 Months after 5 MonthsWater (by Karl Fischer titration) <0.01% 0.004% 0.005%UV Cutoff (1 cm cell) <190 nm 189 nm 189 nmRefractive Index 1.3440 ± 0.0006 1.3440 1.3440Residue (detection limits <1 mg/L) <1 mg/L None detected None detectedGC Purity >99.9% 99.9+% 99.9+%GC-ECD (as heptachlor epoxide) <10 ng/L Passes test Passes test

Figure 3. B&J Acetone.

Glass Bottle0

5

10

15

20

25

■ >0.50µm ■ >0.75µm ■ >1.00µm ■ >2.00µm ■ >5.00µm

Par

ticl

es/m

L

0

5

10

15

20

25

B&J NOWPak

Par

ticl

es/m

L

— —

— —

Solvent Stability in B&J NOWPak® Containers

Laboratory stability studies confirm B&J NOWPak containers maintain solvent lot-to-lot consistency, purity, water content and particulate levels over time. One study shows how solvents packaged in B&J NOWPak containers are idealfor particulate-sensitive applications such as HPLC (Figure 3). Another study shows how B&J Brand® methanol stored in a B&J NOWPak container (B&J Cat.No. NP230-20) for 7 months is unchanged in quality from the original lot analysis (see chart below and Figure 4). Additionally, samples of the same B&J Brandacetonitrile UV lot stored in a B&J NOWPak container (B&J Cat. No. NP015-20)and a glass bottle (B&J Cat. No. 015-4) for 5 months are virtually identical (seechart below and Figure 5).

■ ■ ■

■ ■

— —

Figure 5. Acetonitrile UV Absorbance.

Wavelength (nm)

0.0

0.2

0.4

0.6

0.8

1.0

— Original lot analysis — B&J NOWPak after 5 months

Ab

sorb

ance

200 250 300 350 400

■ ■ ■

■ ■

Figure 4. Methanol UV Absorbance.

Wavelength (nm)

0.0

0.2

0.4

0.6

0.8

1.0

— Original lot analysis — B&J NOWPak after 7 months

Ab

sorb

ance

200 250 300 350 400

— —

50 Burdick & Jackson Solvent Guide Solvent Packaging | B&J NOWPak and NOWPak II Dispensing Options

B&J NOWPak® and NOWPak II Dispensing OptionsFor rapid, unmetered high-volume dispensing.

Innovative Dispensing Options

Dispensers for removing solvent from B&J NOWPak containers areconstructed only of inert, solvent-compatible materials to guaranteecontaminant-free operation. Theyhave been designed to interface withcommercially available dispensingequipment and laboratoryinstrumentation.

° The B&J NOWPak Solvent DispenseModule provides rapid, unmeteredsolvent delivery at the touch of abutton.

° Piston-style bottletop dispenserscan be used for low-volume,metered dispensing.

° Cap adapters connect B&J NOWPakcontainers directly to HPLC andGPC instruments as well as peptideand DNA synthesizers.

If your specific application requires acustomized dispenser, B&J TechnicalService is available to exploremodifications to meet your particularrequirements.

Unique B&J NOWPak Storage Option

Safety is enhanced by storing the B&J NOWPak containers inside aflammable liquid storage cabinet whiledispensing solvent. A dispensingcabinet system manufactured byJustrite® is available with Pass-Thruvalves installed in the cabinet wall. The Pass-Thru valves (Figure 6) arespecially designed stainless steelfittings that connect the solvent andpressure tubing from the B&J NOWPakcontainer through the cabinet wall to adispenser located in a fume hood. Thesolvent Pass-Thru valve incorporates a unique, non-contaminating checkvalve. The inert gas Pass-Thru containsan integral flame arrestor. The entiresystem with factory-installed fittings isFactory Mutual Research Corporation(FM) approved (Report OY6A3.AF).

Pass-Thru valves are also available forretrofitting existing solvent storagecabinets. Field installation of Pass-Thruvalves maintains cabinet compliancewith the OSHA Flammable LiquidsStorage Cabinet Specifications (29 CFR 1910.106). Retrofitted cabinets,however, do not carry FM approval.

Dispenser Mounting Brackets

Limited hood space is maximized by storing B&J NOWPak containersunderneath the fume hood andeliminating the clutter of breakableglass bottles. Their compact size allows mounting of up to four B&JSolvent Dispense Modules or bottletopdispensers on a bracket. Portable metalstands are also available for mountingup to two dispensers, eliminating theneed to attach a bracket to the fumehood wall permanently.

Flow

B&J Solvent Dispense Modules for rapid,high-volume dispensing are mounted on abracket (top) or a metal stand and adapterplate (detail above). See Solvent DispenseModules, opposite page.

Figure 6. Justrite Pass-Thru Valve Diagram.

Solvent Packaging | B&J NOWPak and NOWPak II Dispensing Options Burdick & Jackson Solvent Guide 51

The B&J NOWPak® Solvent DispenseModule provides convenient and inert sealed dispensing from B&JNOWPak containers. The SolventDispense Module (B&J Cat. No. NP517)contains a gas pressure regulator thatdelivers adjustable, on-demand inertgas through a cap connector (B&J Cat.No. NP518 or NP519) to the B&JNOWPak or NOWPak II container.Incoming regulated gas pressure of 15 to 55 psig can be used with thissystem. A manual regulator on theSolvent Dispense Module controls thepressure applied to the inside of thecontainer so that it does not exceed 10 psig for HDPE B&J NOWPakcontainers or 15 psig for stainless steel B&J NOWPak II containers. Onlyinert gases such as nitrogen, heliumand argon should be used. Pressurizedair is not recommended.

As the outside of the liner iscompressed, solvent flows throughinert tubing to the dispenser valve.Flow rates can be varied from zero to four liters per minute by changingthe amount of pressure applied to thecontainer. When pressed, a toggle valveon the Solvent Dispense Modulesimultaneously opens the gas valve topressurize the B&J NOWPak containerand the chemical valve to initiatesolvent flow. Pressure is applied to thecontainer only during dispensing. Whenthe toggle valve is not engaged, solventflow is stopped and the containerautomatically depressurizes. The manualregulator also acts as an overnightshut-off valve. As an additional safetyfeature, a pressure relief valve on theNP518 or NP519 cap connectorensures the B&J NOWPak containercannot become overpressurized.

Solvent Dispense Module PressureDispense ConnectorB&J Cat. No. NP518 for HDPE B&J

NOWPak containersB&J Cat. No. NP519 for stainless steel

B&J NOWPak II containers

The solvent and inert gas tubing andcap assembly connects the B&JNOWPak container to the SolventDispense Module. Each consists of:

° A cap connector with a s" PFAelbow solvent fitting, a 4" inert gaspressure fitting and a 10 psig (B&JCat. No. NP518) or 15 psig (B&J Cat.No. NP519) pressure relief valve.

° An FEP diptube sized for either theHDPE B&J NOWPak or stainlesssteel B&J NOWPak II container.

° A 10' harness of s" FEP solventtubing and 4" nylon pressuretubing.

B&J Cat. Nos. NP517 and NP526

Solvent Dispense Module (SDM) B&J Cat. No. NP517

The Solvent Dispense Moduleregulates solvent flow as well as gaspressurization and venting of the B&JNOWPak container. The NP518 orNP519 Pressure Dispense Connectoris required to complete the SolventDispense Module dispensing system.

Solvent Dispense Module Flexible Extension Nozzle B&J Cat. No. NP526

The 18" flexible FEP extension nozzlefits over the Solvent Dispense Moduledispenser spout to facilitate filling tall or non-standard glassware.

(continued on next page)

Abbreviation GuideHDPE High-Density PolyethylenePTFE PolytetrafluoroethylenePFA PerfluoroalkoxyFEP Fluorinated Ethylene PropyleneNPT National Pipe Thread

B&J Cat. No. NP518

52 Burdick & Jackson Solvent Guide Solvent Packaging | B&J NOWPak and NOWPak II Dispensing Options

B&J NOWPak and NOWPak II Dispensing OptionsFor precise, repetitive low-volume dispensing.

Piston-style bottletop dispensers offera precise, inert method for repeatedlydispensing smaller solvent volumes.Adapters enable the dispensers to be either directly connected to B&JNOWPak and NOWPak II containersor mounted up to eight feet away.


Bottletop Dispensette III and cap adapters are available from BrandTech Scientific.

(continued)

B&J NOWPak®

and NOWPak IIDispensing OptionsFor rapid, unmetered high-volume dispensing.

B&J Cat. No. NP531

B&J Cat. No. NP528

Two-Place Mounting Bracket Kit B&J Cat. No. NP528

This bracket and hardware kit allowsup to two Solvent Dispense Moduleunits or bottletop dispensers to bemounted on a fume hood wall. A four-place dispenser bracket (B&JCat. No. NP524) is also available.

Metal Stand and Adapter Plate for Solvent Dispense Modules B&J Cat. No. NP531

This portable stand and adapter plateholds up to two Solvent DispenseModules and does not require drillingholes to mount a bracket. Whenmounted on the stand, the dispenserspout is 19" above the base.

Solvent Packaging | B&J NOWPak and NOWPak II Dispensing Options Burdick & Jackson Solvent Guide 53

B&J NOWPak®

and NOWPak IIDispensing OptionsFor direct instrument connection using a pump or vacuum to supply solvents.

Cap adapters easily connect B&JNOWPak and NOWPak II containersdirectly to analytical HPLC instruments,preparative scale HPLC instruments,GPC instruments and other equip-ment using pumps or vacuum tosupply solvent.

HPLC Sparging AdapterB&J Cat. No. NP512

A standard HPLC 4L bottlecapsparging assembly (not included) canbe connected directly to the B&JNOWPak container for feeding singleor multiple HPLC and GPC instru-ments. This adapter consists of a cap closure and PTFE adapter with a 38 mm thread pattern.

Cap Adapter with 8" TubingB&J Cat. No. NP514

This connector is suitable for use with low-flow pump or vacuumapplications where sparging is notrequired. The adapter includes:

° A cap closure and PTFE adapterwith an 8" PFA solvent tube fitting.

° A 10' piece of 8" FEP solventtubing with a 40-micron stainlesssteel frit to prevent drips whilechanging containers.

ABBREVIATION GUIDE

HDPE High-Density PolyethylenePTFE PolytetrafluoroethylenePFA PerfluoroalkoxyFEP Fluorinated Ethylene PropyleneNPT National Pipe Thread

B&J Cat. No. NP514B&J Cat. No. NP512


Contact B&J Technical Serviceat 800-368-0050 for tips onlinking a single B&J NOWPakcontainer to multiple pieces ofdispensing equipment orinstrumentation.

Cap Adapter for 4" TubingB&J Cat. No. NP500 for HDPE B&J

NOWPak containers

This adapter is suitable for use withhigh-flow pump or vacuum applicationswhere sparging is not required. Itcomes with:

° A cap closure and PTFE adapterwith a 4" PFA elbow solvent fitting.

° An FEP diptube with a 40-micronstainless steel frit to prevent dripswhile changing containers.

The 4" elbow fitting can be replacedwith any standard 4" male NPT fittingfor adaptation to other tubing sizes.

B&J Cat. No. NP500

Packaging heading

54 Burdick & Jackson Solvent Guide Solvent Packaging | B&J NOWPak II Dispensing Options

B&J NOWPak® IIDispensing OptionsFor direct instrument connection using continuous pressure to supply solvents.

Biotech Pressure Dispense ConnectorsB&J Cat. Nos. NP516, NP529, and NP538

Solvent can be dispensed at pressuresless than 15 psig from B&J NOWPak IIcontainers connected directly to DNAand peptide synthesizers. Eachadapter consists of:

° A pressure dispense cap with PFA solvent fitting, an inert gaspressurization fitting and a 15 psig pressure relief valve.


B&J Cat. No. NP516B&J Cat. No. NP515

Pressure dispense connectors (photoat right) can easily attach stainlesssteel B&J NOWPak II containers toDNA synthesizers, peptide synthesizersand other equipment using continuouspressure to supply solvent.

The HDPE B&J NOWPak overpacks are not recommended for continuouspressurization, only intermittentpressurization of less than 10 psig.

General Purpose Pressure Dispense Connector B&J Cat. No. NP515

This connector allows for generalpurpose dispensing of solvent fromB&J NOWPak II containers using up to 15 psig pressure. It consists of:

° A cap connector with a 4" PFAelbow solvent fitting, a 4" inert gaselbow pressure fitting and a 15 psigpressure relief valve.


° A 10' harness of 4" FEP solventtubing and 4" nylon pressuretubing.

° NP516 – a 5' harness of 8" FEPtubing for solvent and inert gaspressure delivery with 4" flaredfittings (4" – 28 thread) that attachto the instrument.

° NP529 – a 4000 mm harness of 2.7 mm PFA tubing for solvent andinert gas pressure delivery with M6fittings that attach to the instrument.

° NP538 – a 10' harness of 4.6 mmPFA tubing for solvent and inert gaspressure delivery.

Shutoff Valves B&J Cat. Nos. NP533 and NP537

These valves are used to isolate theNOWPak II solvent containers fromthe DNA and peptide synthesizers.The NP533 has fittings to be usedwith the NP529 2.7 mm tubing, andthe NP537 has fittings sized for theNP538 4.6 mm tubing.

Solvent Packaging | B&J NOWPak II Dispensing Options Burdick & Jackson Solvent Guide 55

Digital Scale with Remote ReadoutB&J Cat. No. NP525

Solvent levels in B&J NOWPak® IIcontainers are easily monitored usingthis load cell. The scale can beoperated on AC power or a 9V DCbattery. It features:

° A 124" x 12" platform that stands24" high.

° A digital remote readout with a 5' cord.

Laminated weight-to-volumeconversion cards are available for B&J NOWPak II solvents.

B&J Cat. No. NP525 B&J Cat. No. NP536

Cascading DispenserB&J Cat. No. NP536

Two stainless steel B&J NOWPak IIcontainers can be connected in aseries using the Cascading Dispenserfor a 40-liter reservoir of solvent. Itcomes with:

° Two pressure dispense caps.

° 8" PFA tubing for pressurizationand solvent dispensing.

Other B&J NOWPak® Accessories

56 Burdick & Jackson Solvent Guide Solvent Packaging | Other B&J NOWPak Accessories

Stainless Steel Tilt CradleB&J Cat. No. NP523

When using the NP503 PTFE PourSpout Closure, this metal cradle aids pouring solvent from 20L B&JNOWPak containers. Due to overpacksize differences, the NP523 TiltCradle can be used with HDPE 20LB&J NOWPak containers only.

B&J Cat. No. NP523

B&J Cat. No. NP503 B&J Cat. No. NP527

PTFE Pour Spout ClosureB&J Cat. No. NP503

The PTFE Pour Spout Closureconnects to the neck of the B&JNOWPak liner for inert, splashlesspouring by either lifting or using theNP523 Tilt Cradle. An attached capallows the container to be resealedafter each use without detaching thepour spout.

B&J NOWPak Drain ToolB&J Cat. No. NP527

This polypropylene tool allows thedraining of residual solvent fromempty B&J NOWPak containers priorto return. Because it is not made ofinert material, the NP527 Drain Toolcannot be substituted for the NP503PTFE Pour Spout Closure undernormal dispensing operations. If theresidual solvent is being used forhigh-purity applications, the NP503PTFE Pour Spout Closure isrecommended for draining B&JNOWPak containers.

Abbreviation Guide

HDPE High-Density PolyethylenePTFE PolytetrafluoroethylenePFA PerfluoroalkoxyFEP Fluorinated Ethylene PropyleneNPT National Pipe Thread

Additional AvailableAccessories

B&J Cat. No. DescriptionNP508 Empty containers

with closure, 2 x 10LNP509 Empty container

with closure, 20LNP510 Empty 20L liners, 5/pkg.

Solvent Packaging | B&J Stainless Steel Pressure Dispense System (SSPDS) Burdick & Jackson Solvent Guide 57

B&J Stainless SteelPressure DispenseSystem (SSPDS)

B&J Solvents in SSPDS Containers

B&J Brand® and B&J BioSyn® high-purity solvent lines are both availablepackaged in B&J SSPDS containers.Each B&J SSPDS container comeswith a Certificate of Analysis printedon the product label.

B&J SSPDS Components

The B&J Stainless Steel PressureDispense System is engineered forshipping, storing and dispensing high-purity solvents. Each system feature(Figure 7) maintains solvent purity and meets UN, US DOT and OSHAstandards for flammable and com-bustible liquids. The entire system ofthe 56L and 200L containers hasreceived Factory Mutual ResearchCorporation (FM) approval, ensuringthat it meets all stated safety, qualityand performance specifications.

° The 56L, 200L and 1250L B&JSSPDS containers are made from304 or 316 stainless steel, speciallycleaned to eliminate all contaminationprior to solvent filling.

The B&J Stainless Steel PressureDispense System (SSPDS) providesan environmentally responsible way to safely meet your large-volume, high-purity solvent needs. Thesecustomer-dedicated 56L, 200L and1250L containers are reusable andgenerate no packaging waste.Dispensing from a fully sealed, break-resistant system reduces employeeexposure and increases the usefulshelf life of solvents. You can alsoeliminate solvent pumps, anotherpotential contaminant source, sincethe B&J SSPDS is pressurized byinert gas.

Figure 7. B&J SSPDS Container Diagram.

° Tamper-evident wires and sealsverify the delivery of high-quality, uncontaminated B&J solvent fromeach B&J SSPDS container.

° Each container has an appropriatelysized pressure relief valve thatcomplies with National FirePrevention Association (NFPA) andAmerican Society of Materials andEngineering (ASME) standards.

° Specially keyed inert gas andsolvent quick-connect couplingsensure minimal air inclusion andsolvent loss when connecting anddisconnecting the container atoperating pressure (<15 psig).

° Thoroughly cleaned PTFE-linedhoses and non-contaminatingsolvent dispensers deliver solventdirectly to instruments anddispensing stations.

° In addition to system installationrecommendations, B&J offersregulatory assistance, training on safe container usage and aconvenient round-trip shippingprogram.

1. Quick-connect coupling protective caps

2. Male inert gas quick-connect coupling

3. Male solvent quick-connect coupling

4. Solvent dip tube

5. Optional level sensor

6. Pressure gauge

7. Pressure relief valve

8. 304 or 316 stainless steel container body

1

2

3

4

8

7

6

5

Disposing of fifty 4L glass bottles, 12.5 cardboard cartons and 12.5 expanded polystyrenebox inserts is more time-consuming and generates more packaging waste than simplyreturning a single 200L B&J SSPDS container for refilling with B&J high-purity solvent.

58 Burdick & Jackson Solvent Guide Solvent Packaging | B&J Stainless Steel Pressure Dispense System (SSPDS)

B&J High-Purity SSPDS Solvents

Solvent dispensed from B&J SSPDScontainers meets or exceeds B&J’salready demanding glass bottlespecifications. Unlike a glass bottle,which must be opened, B&J SSPDScontainers are a sealed system,protecting solvent from atmosphericmoisture and maintaining extremelylow water content. Three 200L B&JSSPDS containers (Figure 8) werefilled with the same B&J BioSyn® low-water-content acetonitrile lot. Eachcontainer was sampled and analyzedfor water content in triplicate usingcoulometric Karl Fischer titration. Thechart in Figure 8 not only demonstratesBurdick & Jackson™ can reproduciblyfill ultra-low-water-content solventinto B&J SSPDS containers, it alsovalidates our sampling techniquesand shows the B&J SSPDSdispenses solvent without introducingany water contamination.

An excellent indicator of solventpurity is UV absorbance. Again, three200L B&J SSPDS containers werefilled with the same B&J BioSynacetonitrile lot. A UV scan of solventfrom each container was recordedusing a 5 cm path length quartz cell(Figure 9). The UV cutoffs for eachcontainer are identical, and the threeUV curves are virtually the same.

B&J BioSyn low-water-content acetonitrile UV spectra in 5 cm path length quartz cells are almost identical for three consecutively filled 200L B&J SSPDS containers. (B&J Cat. No. BC017-200).

(continued)

B&J Stainless Steel Pressure Dispense System (SSPDS)

Ab

sorb

ance

Figure 9. UV Spectra for Consecutively Filled B&J BioSyn Acetonitrile SSPDS Containers.

Wavelength (nm)

— SSPDS #2— SSPDS #1 — SSPDS #3

0.0

0.2

0.4

0.6

0.8

1.0

195 250 300 350 400

Wat

er C

ont

ent

(pp

m)

■■ First Water Measurement

SSPDS #2 SSPDS #3SSPDS #10

2

4

6

8

10

12

B&J Specification

Figure 8. Water Content for Consecutively Filled B&J BioSyn Acetonitrile SSPDS Containers.

■ ■ Second Water Measurement ■ Third Water Measurement

Multiple water measurements from three consecutively filled 200L B&J BioSyn low-water-content acetonitrile SSPDS containers (B&J Cat. No. BC017-200) demonstrate thereproducibly low water content that you can expect from solvent packaged in a B&J SSPDS container.


B&J SSPDS Solvent Stability Studies

Laboratory stability studies (Figures10–13) confirm B&J SSPDS containersmaintain solvent purity over time. Topreserve solvent integrity, the B&JSSPDS container is constructed fromspecially cleaned 304 or 316 stainlesssteel and all solvent flow pathsurfaces are 304 or 316 stainlesssteel, polytetrafluoroethylene (PTFE)or fluoroelastomer. Unlike non-pressurized drums, which breathe and allow contaminants such aswater and air to enter, B&J SSPDScontainers and fittings are designedfor a pressure-tight seal. This inert,pressurized dispensing systemdelivers solvent that is:

° Exceptionally low in water contentfor DNA manufacturing and otherwater-sensitive applications.

° Free from peaks detected by GC-ECD and GC-FID for pesticideresidue analysis.

° Highly UV transparent for analytical,preparative and process liquidchromatography.

° Protected from airborne impuritiesand oxidation by the inert gasblanket inside the container.

Figure 10. B&J Brand® Acetonitrile UV in an SSPDS Container after 5 Months.

Test Original Lot Analysis After 5 MonthsWater by Karl Fischer Titration 0.001% 0.001%

MetalsAn ICP analysis for the following metals was done on B&J Brand Acetonitrile UV packaged in a B&J SSPDScontainer for over 5 months. None of the following metals were detected (detection limit 10 ppb):

Aluminum Barium Boron Cadmium Calcium Chromium Cobalt CopperGold Iron Magnesium Manganese Nickel Strontium Tin Zinc

Ab

sorb

ance

Figure 11. Acetonitrile UV Absorbance Measured in a 5 cm Cell.

— Original Lot Analysis — After 5 Months

Wavelength (nm)

0.0

0.2

0.6

1.0

250195 300 350 400

0.8

0.4

DetectionMetal Limit ResultAluminum 0.05 ppb not detectedAntimony 0.05 ppb not detectedArsenic 0.10 ppb not detectedBarium 0.01 ppb not detectedBeryllium 0.05 ppb not detectedBismuth 0.05 ppb not detectedBoron 0.10 ppb not detectedCadmium 0.01 ppb not detectedCalcium 0.10 ppb not detectedChromium 0.05 ppb not detectedCobalt 0.01 ppb not detectedCopper 0.05 ppb not detectedGallium 0.01 ppb not detectedGermanium 0.05 ppb not detectedGold 0.10 ppb not detectedIron 0.10 ppb not detectedLead 0.05 ppb not detectedLithium 0.05 ppb not detectedMagnesium 0.05 ppb not detectedManganese 0.05 ppb not detectedMolybdenum 0.05 ppb not detectedNickel 0.05 ppb not detectedNiobium 0.05 ppb not detectedPotassium 0.10 ppb not detectedSilver 0.05 ppb not detectedSodium 0.10 ppb not detectedStrontium 0.01 ppb not detectedTantalum 0.05 ppb not detectedThallium 0.01 ppb not detectedTin 0.05 ppb not detectedTitanium 0.05 ppb not detectedVanadium 0.05 ppb not detectedZinc 0.05 ppb not detectedZirconium 0.01 ppb not detected

10 ng/L Heptachlor Epoxide

Figure 12. Acetonitrile GC-ECD Chromatogram After 5 Months.

Calcium, iron and potassium were analyzed by graphite furnace atomic absorptionspectroscopy (GFAAS). All other elements were analyzed by inductively coupled plasmaemission spectroscopy (ICP-MS).

The test results shown (figures 10, 11 and 12)indicate no contamination in B&J Brand AcetonitrileUV (B&J Cat. Nos. CS015-56 and CS015-200) afterbeing stored 5 months in a B&J SSPDS container.

Figure 13. Elemental Analysis ofHexane Stored in a B&J SSPDSContainer for 6 Months.

60 Burdick & Jackson Solvent Guide Solvent Packaging | B&J Stainless Steel Pressure Dispense System (SSPDS)

B&J SSPDS Pallet With Feet

The B&J 200L SSPDS is alsoavailable with pallet feet for use with a pallet jack.

Tamper-Evident Wires and Seals

Tamper-evident wires secure all portson the B&J SSPDS container toguarantee solvent integrity and GMPtraceability during container shippingand storage. The seal conditionshould be verified upon containerreceipt and the seals removed onlywhen ready to dispense solvent.

(continued)

B&J Stainless Steel Pressure Dispense System (SSPDS)

Factory Mutual ResearchCorporation (FM) Approved System

The B&J 56L and 200L SSPDS hassuccessfully undergone the FactoryMutual Research Corporation’s designverification and audit process forflammable liquid containers underpressure (Report J.I. 1Y2A9.AF). TheFMRC is an independent laboratorythat tests products for conformance tospecific safety, quality and performancestandards. FMRC’s audit processincludes a survey of the manufacturingfacility in order to document the qualitycontrol parameters under which theproduct is manufactured. FMRCapproval is nationally recognized byinsurance underwriters and federalregulatory agencies such as OSHA.

B&J SSPDS Container Body

The B&J SSPDS container is con-structed from 14 gauge 304 or 316stainless steel. The maximum servicepressure to be applied to the B&JSSPDS container during solventdispensing is not to exceed 15 psig.The container, however, has a hydro-statically tested proof pressure of 90 psig. It passes DOT/UN PackingGroup I drop testing for highlyhazardous material in a closed-headsteel drum—dropping the containerbearing a 566 lb. load with allcomponents in place from a height of six feet onto a solid surface. TheB&J SSPDS container also meetsOSHA 29 CFR 1910.106 standardscovering the storage of up to 60 gallons (227 liters) of flammable or combustible liquid.


Built-In Pressure Gauge

A stainless steel pressure gauge with an easy-to-read dial allows continuouscontainer pressure monitoring. All B&JSSPDS containers are filled and shippedwith a 3–5 psig blanket of inert gas.Along with the tamper-evident wires and seals, the pressure gauge providesverification that positive pressure wasmaintained during transit and solventquality has not been compromised.

Burdick & Jackson’s™ ResealingPressure Relief Valve

The B&J SSPDS is an exceptionally safebulk delivery system. An appropriatelysized pressure relief valve on the B&JSSPDS maintains safe containerpressure levels during gas regulatormisadjustment or unprotected fireexposure. B&J SSPDS emergencyventing complies with ASME Boiler and Pressure Vessel Code Section VIIIspecifications (120% of containerdesign pressure) and is sized to provideventing capacity in excess of thatdetermined by the heat absorption and vapor generation formulasspecified in NFPA 30.

The B&J SSPDS pressure relief valveeliminates the explosion dangerassociated with non-vented orinadequately vented storage containersduring unprotected fire exposure. Incontrast to the B&J SSPDS pressurerelief valve, burst disks or undersizedrelief valves on other pressurizedsolvent containers represent a serioushazard. A boiling liquid expanding vaporexplosion (BLEVE) can occur when aninsufficiently vented vessel contains a

superheated liquid. Because the liquid is heated above its normalboiling point, flash vaporizationoccurs. This rapid gas generationfrequently creates pressures highenough to destroy the vessel.

When a burst disk ruptures to ventexcess pressure, solvent in thecontainer becomes easily accessible to fire. The B&J pressure relief valve is spring loaded and automaticallyreseals once internal containerpressure drops below 30 psig whencooled by a fire hose or sprinkler. Its threaded valve opening can beconnected to a suitable vent system for solvent and vapor removal withoutproviding additional fuel to a fire.

Figure 14. Top View of SSPDS.

1. Resealing pressure relief valve

2. Built-in pressure gauge

3. Optional level sensor port

4. Male solvent quick-connect coupling

5. Tamper-evident wires and seals

6. Male inert gas quick-connect coupling

1 2 3 4 5 6

62 Burdick & Jackson Solvent Guide Solvent Packaging | B&J SSPDS Dispensing and Accessories

Air Inclusion0.01 mL 0.40 mL

B&J SSPDSQuick–ConnectCoupling

SwagelokQT–4

Figure 15. B&J SSPDS Quick-Connect Coupling Diagram.

Figure 16. B&J SSPDS quick-connectcouplings release one-tenth the solventthat Swagelok QT-4 fittings do whensolvent containers are disconnected.

B&J SSPDS quick-connect couplingsmaintain solvent purity while reducingvapor emission in the workplace.

Figure 17. Swagelok QT-4 fittingsincorporate 40 times more air uponconnection than B&J SSPDS quick-connect couplings.

Solvent Spillage0.02 mL 0.20 mL

B&J SSPDSQuick–ConnectCoupling

SwagelokQT–4

Epsilon Coupling HalfB&J Cat. No. CA1250

The Epsilon Dry-Break couplings onthe 1250L SSPDS containersmaximize throughput with a straight-through ball-valve design. Thesecouplings also minimize spillage andincrease worker safety with automaticsaftey interlocks.

Burdick & Jackson’s™ SSPDSQuick-Connect Couplings

Solvent is dispensed from B&J SSPDScontainers using color-coded and keyedquick-connect couplings. Since they aredeveloped specifically for high-puritysolvents, all internal quick-connectcoupling surfaces are 316 stainlesssteel or polytetrafluoroethylene (PTFE).These rugged, highly reliable connectorsmaintain solvent purity and are pressurerated to 150 psig.

The flat-faced male and female quick-connect couplings automatically resealupon disconnecting and can be easilywiped clean to remove any particlespicked up from the surroundings (Figure 15). Their automatic shutofffeature allows hoses to be connectedor disconnected from the pressurizedB&J SSPDS container without requiringmanual venting. The high qualityconstruction of the quick-connectcouplings eliminates both leakage andthe need for any secondary containershutoff valves. Compared to commonSwagelok fittings (Figure 16), the flat-faced design of the B&J quick-connectcoupling minimizes liquid loss upondecoupling from the B&J SSPDScontainer. Air inclusion of less than 0.01 mL during coupling (Figure 17)virtually eliminates moisturecontamination and makes purgingsolvent lines unnecessary whenchanging containers.

The potential for incorrect connectionand solvent cross-contamination iseliminated when using B&J SSPDSquick-connect couplings, color-codedand keyed with a unique pattern foreach solvent (shown right).

B&J SSPDS Dispensing and Accessories

B&J Cat. No. CA1250

Solvent Packaging | B&J SSPDS Dispensing and Accessories Burdick & Jackson Solvent Guide 63

B&J Specially Cleaned SSPDS Hoses

Burdick & Jackson™ uses a proprietarycleaning process to remove tracecontaminants from the hosesattached to female quick-connectcouplings. The cleaning processenables these hoses to maintain evenpesticide residue analysis solventstandards. B&J can provide hoses cut to any desired length in twodiameters, 4" and 2". B&J SSPDShoses are pressure rated to 1500psig, and the inert PTFE inner tubingis protected from damage and kinkingby a flexible stainless steel outerbraid. The hose includes two sets ofend fittings—one set to attach theinert gas or solvent female quick-connect coupling and another set toconnect the hose to either an inertgas source or a solvent dispenser.

Low-Pressure (<15 psig) Dispensing

The B&J SSPDS is capable ofdelivering much greater flow ratesthan are normally used in laboratoryand manufacturing dispensing (Figure18, next page). Because the B&JSSPDS does not necessitate usingexcessive pressure, safety anddegassing problems are avoided.Most laboratory and manufacturingapplications do not require B&JSSPDS operating pressures toexceed 15 psig. For example, HPLC instruments typically use flowrates of 2 mL/min., a DNA synthesizerrequires approximately 120 mL/min.and general dispensing intolaboratory glassware or other vesselscan safely be done only with a

B&J SSPDS hoses are available in 4" and2" diameters. B&J recommends includingan in-line swivel (B&J Cat. No. CA0311)when using the 2" hose to increaseflexibility when aligning the quick-connectcoupling key pattern.

Each female B&J SSPDS quick-connectcoupling is attached to a PTFE hoseencased in a flexible stainless steel outerbraid to prevent hose damage and kinkingduring use.

B&J can attach a wide range of end-fittings to your B&J SSPDS inert gas hosefor easy connection to gas regulators ormanifolds.

maximum flow rate of 2–3 L/min.Therefore, it is not necessary topressurize the B&J SSPDS containerabove 15 psig. Other manufacturers,however, require higher-pressure,ASME-certified containers to achievecomparable flowrates.

B&J Cat. No. CA0309

B&J TECHNICAL ANDCUSTOMER SERVICE

Contact B&J Technical Serviceat 800-368-0050 to discuss theexact fittings you require and to specify the hose inner diameter you need.

B&J SSPDS Solvent Dispensing Toggle ValveB&J Cat. No. CA0309 – 4" (pictured)

B&J Cat. No. CA0316 – 2"

For added convenience, a hand-heldSolvent Dispensing Toggle Valveallows control of solvent flow with the touch of a finger. This toggle valvedispenser is non-contaminating andconnects directly to a B&J SSPDSsolvent hose.

The Solvent Dispensing Toggle Valvewith Swivel allows hand-held solventdispensing using the 4" or 2" hose.

(continued)



Flo

w R

ate

(L/m

in.)

Figure 18. 4" and 2" B&J SSPDS Hose Flow Rates.

— Half-Full Container— Full Container — Nearly Empty Container

Pressure (psig)

0

2

4

6

8

10

12

14

16

15105

A 200L B&J SSPDS container was filled with approximately 20ºC water and pressurized with helium to 5, 10 and 15 psig. Flow rates for 4" and 2" hoses were measured at all three pressures when the container was full, half-full and nearly empty.

Available B&J SSPDSAccessories

B&J Cat. No. DescriptionCA0309 4" Toggle valve with swivelCA0311 2" Swivel to facilitate

alignment of female couplerwith keyed male connector on container

CA0313 Installation kit for APB OligoPilot™ II (no hoses)

CA0315 Pelouze digital scale for 56-liter SSPDS containers

CA0316 2" Toggle valve with swivel

Available B&J SSPDSHose Lengths

B&J Cat. No. DescriptionCA-5H Up to a 5-foot customized,

precleaned B&J SSPDS hosewith end-fittings

CA-10H Up to a 10-foot customized, precleaned B&J SSPDS hosewith end-fittings

CA-15H Up to a 15-foot customized, precleaned B&J SSPDS hosewith end-fittings

CA-20H Up to a 20-foot customized,precleaned B&J SSPDS hosewith end-fittings


B&J SSPDS Direct Instrument Connection

The B&J SSPDS maintains solventpurity and low water content byconnecting directly to synthesizers and other instruments. Because theB&J SSPDS container serves as a large reservoir, instruments can rununattended longer and less time isspent changing solvent containers.

B&J Technical Service can provideinstallation recommendations andsystem components for delivering high-purity solvent to several instrumentssimultaneously. Dispensing systemscan also include multiple B&J SSPDScontainers manifolded together. B&Jhas designed a container switchingmechanism to automatically changefrom an empty to a full container withno interruption in solvent delivery.

B&J SSPDS Electronic Level Sensors

To reliably monitor solvent volume insideB&J SSPDS containers, Burdick &Jackson™ offers an electronic levelsensor that determines liquid levelsusing capacitance differences. Twoversions of the probe are available, onefor solvents with dielectric constantsless than five and the other for solventswith dielectric constants greater thanfive. Each B&J SSPDS container uses a permanently mounted level sensorprobe, but all electronic components arecontained in one stationary pulse card.A cable, available in several lengths,connects the container and pulse cardto the level sensor control box.

A level sensor probe measures capacitancedifferences between full and emptycontainers of solvent. Solvent levels aredisplayed on the level sensor control box.

Sealed solvent dispensing directly into DNA synthesizers maintains the lowest possible water content.Solvent levels are monitored by an electronic probe system.

Connections between instrument tubingand B&J SSPDS hoses are dripless and air-tight.

Available B&J SSPDSCapacitance Level SensingEquipment

B&J Cat. No. DescriptionCA0094LS Level sensor control boxCA0095LS Pulse cardCA0096LS Level sensor probe

(for solvents with dielectricconstants less than 5) for 56L or 200L container

CA0097LS Level sensor probe (for solvents with dielectricconstants greater than 5) for 56L or 200L container

CA0098LS Level sensor probe (for solvents with dielectricconstants less than 5) for 1250L container

CA0099LS Level sensor probe (for solvents with dielectricconstants greater than 5) for 1250L container

CA-20C 20 ft. Level sensor cableCA-25C 25 ft. Level sensor cableCA-30C 30 ft. Level sensor cableCA-40C 40 ft. Level sensor cable

(continued)



B&J SSPDS Float-Type Level Sensors

Burdick & Jackson™ also offers anelectronic level sensor that determinesliquid levels using float-type levelswitches. A float encircling a stationarystem is equipped with a permanentmagnet. As the float rises or lowerswith liquid level, the magnet within the float actuates reed switches withinthe stem. This design provides aconsistent vertical accuracy of 8" with repeatability of no more than 1% deviation. A cable connecting acontainer to a B&J Float Level SensorDisplay Box will provide accurate digitalreadout of the liquid level. Two cablesconnecting two containers to a B&JLiquid Level Sensor Control Box willprovide accurate continuous digitaland pictorial readout of the liquid levelin both containers and will operate asolenoid valve to switch betweenempty and full containers. Available B&J SSPDS Float

Level Sensing Equipment

B&J Cat. No. DescriptionCA0080LS Float level sensor control

box (includes two 20 ft.cables; different lengthsavailable upon request)

CA0081LS Float level sensor display box

CA0082LS Float level sensor probe for 56L container



B&J Cat. No. CA0090LS

Float Level Sensor Control Box (shown with probes)B&J Cat. No. CA0090LS

Float-type level sensor probemeasures the liquid level in containersand sends the information to thecontrol box for a continuous digitaland pictorial readout of twocontainers. Control box can operate a solenoid valve to switch betweenempty and full containers.

B&J Cat. No. CA0091LS

Float Level Sensor Display Box (shown with probes)B&J Cat. No. CA0091LS

Float-type level sensor probemeasures the liquid level incontainers and sends the informationto the display box for a continuousdigital readout.


The load cell with ramp for 200L B&JSSPDS containers (B&J Cat. No. CA4050)provides reliable solvent level sensing that can be computer integrated using anRS232 computer interface.

The digital indicator unit is easilyprogrammed using the integral keyboardand can be mounted remotely from theload cell base.

B&J Cat. No. CA4050

Digital Load Cells

Burdick & Jackson™ can provide aload cell with a low-profile base anddigital indicator unit to monitorcontainer liquid levels. B&J hasdetermined this load cell and indicatorwill consistently perform under thedemanding conditions found inindustrial laboratory and manu-facturing environments.

The load cell base has an accuracy of one part in five thousand and willweigh up to 1000 lbs. The load cellbase and ramp are constructed from diamond plate steel coated with a protective water-resistantpolyurethane membrane. The rampattaches to all sides of the load cellbase, giving four-way access formaximum flexibility. The load cellfeatures positive overload protectionto allow overweight situations duringcontainer loading and unloading.

The digital indicator unit with integralkeyboard has a 0.02% accuracy andcan be mounted in a dust-tight,NEMA-rated enclosure. The digitaloutput is either displayed in easilyread, blue fluorescent numerals or fed to a printer or computer via aserial ASCII 20 mA current loop forrecording solvent consumption. Zero,tare net/gross and print functions can be remotely controlled, allowingmonitoring and operating of the base unit from other locations.

B&J Cat. No. CA000-SA

68 Burdick & Jackson Solvent Guide Solvent Packaging | B&J SSPDS Installation and Operation

Easy B&J SSPDS Installation and Operation

1. When you receive a B&J SSPDScontainer, verify the serial number.Each container is tracked by serialnumber and dedicated to a singlecustomer and solvent.

2. Using a suitable cart (such as B&JCat. No. CA2375), move the unit tothe area where it will be used.Ensure that the B&J SSPDS isproperly secured while transportingto prevent accidental loss of controland possible personnel injury.

3. Place the container on a levelsurface to ensure stability. Clamp a ground wire to the main body of the container. The originatingend of the ground wire must beattached to a proper ground perstandard facility procedure.

4. Remove the protective plastic lidfrom the chime and inspect thecondition of the tamper-evidentwiring and seals. Note any obvioussigns of external containerdamage. Keep the envelopecontaining two tamper-evidentwires for securing the malecoupling caps and three plasticties for reattaching the protectiveshipping lid when returning theempty container.

5. After the B&J SSPDS container has equilibrated to room tem-perature, verify that the containerpressure gauge registers positivepressure, ensuring the solvent has remained under an inert gasblanket and no contamination has occurred during shipping.

6. Cut the tamper-evident wires onboth the inert gas and solventmale quick-connect couplingcaps. Push down lightly on thecap tops to remove their securitypins, and lay the pins inside thecontainer’s protective chime.

7. If a quality control sample isrequired prior to using the solvent,connect the B&J SSPDS SamplingAdapter (B&J Cat. No. CA000-SA)to the male solvent quick-connectcoupling. The gas pressure inside

the B&J SSPDS when it is shippedshould be sufficient to withdraw atleast four liters of liquid from thecontainer.

8. To connect the green male inertgas quick-connect coupling to the green female quick-connectcoupling, wipe both flat-facedsurfaces with a clean, lint-freecloth and align the female couplingpins with the male couplinggrooves, pushing straight downuntil the couplings click. B&Jrecommends using an inert gas,preferably helium, with a puritylevel of 99.9999% and very lowwater content. Make certain thepressure regulators used aredesigned for high-purity gas. The regulators must be oil-freewith stainless steel componentsand inert seals to avoidintroducing contaminants.

9. Connect the male solvent quick-connect coupling to the femalesolvent coupling as in step 8. Each solvent has a unique keypattern and color code to avoidcross-connection.

10. Once the inert gas pressure lineand the solvent dispense line are connected, pressurize thecontainer to the desired operatingpressure by first opening the gas pressure regulator and thenopening the regulator shutoffvalve. Do not exceed 15 psigwhen pressurizing the B&J SSPDS container.

Burdick & Jackson™ has speciallydesigned a cart to conveniently and safelymove 200L B&J SSPDS containers aroundtight areas and over uneven surfaces suchas door frames and ramps.

A sampling adapter is available forwithdrawing a QC sample from the B&J SSPDS container.

B&J SSPDS containers are shipped withsufficient pressure to allow QC samplingprior to connecting the inert gas source.

B&J Cat. No. CA2375

B&J SSPDSInstallation and Operation

Solvent Packaging | B&J SSPDS Round-Trip Program Burdick & Jackson Solvent Guide 69

B&J SSPDS Round-Trip Shipping Program

The B&J SSPDS is not only safe andeasy to use, but also convenient toreturn for refilling. Burdick & Jackson™

has established a round-trip shippingprogram that simplifies containerreturn. A common carrier has beenpreselected based on the shippingcompany’s ability to handle the B&JSSPDS container and the bestavailable rate to you. Under thisprogram, B&J provides the return billof lading and attaches it to the B&JSSPDS container. When the containeris empty, complete the bill of ladingand call the carrier designated on theshipping papers. Round-trip shippingcosts are added to your solventinvoice. This program expedites emptycontainer return and helps ensure anuninterrupted solvent supply.

Simple B&J SSPDS Container Return

Only a few easy steps are required toprepare the B&J SSPDS container forreturn and refilling at B&J.

1. Remove as much solvent aspossible from the container,verifying that inert gas pressurestill remains inside. To meetDOT/UN regulations, the pressuremust be under 10 psig. B&Jchecks the pressure gauge whenreceiving containers to makecertain no contamination hasoccurred during shipping.

2. Disconnect the female inert gasand solvent quick-connectcouplings and hoses by pullingback on the coupling sleeve. The coupling will spring apart.Disconnect the grounding wire.

This top view of a B&J SSPDS containershows the connection of the inert gas andsolvent quick-connect couplings.

Figure 19. This schematic diagram shows a typical B&J SSPDS lab installation.

3. Replace the male quick-connectcoupling caps, inserting thesecurity pins to hold them inplace. Attach the tamper-evidentwires and crimp the seals that areprovided with the shipping papersin the B&J SSPDS return envelope.

4. Replace the plastic lid to protectthe container fittings duringshipment. B&J provides ties tosecurely attach the lid to thecontainer chime.

5. When you are ready to have acontainer picked up, simply call the carrier designated on theshipping papers.

B&J SSPDS Round-Trip Program

Regulator (0–15 psig)

Valve

Inert gas(He)

Gas quick-connectcoupling

Solvent quick-connectcoupling

Solvent hose

Ground cables

Pressure relief valve

B&J SSPDS Support

70 Burdick & Jackson Solvent Guide Solvent Packaging | B&J SSPDS Support

B&J SSPDS System Support

B&J’s technical staff will assist you inestablishing a B&J SSPDS installationplan that meets your storage anddispensing needs. Together, we will:

° Review your application in detail.

° Assess your solvent purityrequirements.

° Discuss your anticipated solventusage patterns and volume.

° Determine the number of B&JSSPDS containers in your fleet.

° Establish plumbing requirements for system hook-up.

° Review safety and regulatory issues.

° Address any special deliveryarrangements such as dockside lift gate service.

and filling. The B&J SSPDS containerfleet size necessary for yourapplication will be determined fromyour solvent volume requirements, theshipping time to and from your facility,your on-site storage capacity andyour desired safety stock level.

Your B&J SSPDS Fleet

To eliminate cross-contamination andprovide GMP traceability, each B&JSSPDS container is dedicated to asingle customer and a single solvent.Every container is tracked by serialnumber, with Burdick & Jackson™

keeping complete records of handling

21.8" / 55.3 cm

51.8

" /

132

cm

73.5

" /

187

cm

15.5" / 39.4 cm

28.5

" /

72.4

cm

56L SSPDS 200L SSPDS 1250L SSPDSVolume 56 liters 200 liters 1250 liters

14.8 gallons 52.8 gallons 330.3 gallonsApproximate Weight 50 lbs. 107 lbs. 529 lbs.When Empty 22.7 kg 48.5 kg 240 kgApproximate Full Weight 147 lbs. 455 lbs. 2710 lbs.When Containing Methanol 67 kg 206 kg 1229 kgDOT/UN Packaging UN1A1/X2.8/900 UN1A1/X2.0/900 UN31A/YSpecification

44.9" / 114 cm

B&J Container Specifications

Solvent Packaging | B&J HandleLock SolView B-Jacket Burdick & Jackson Solvent Guide 71

B&J HandleLock®

SolView B-Jacket®

Although glass bottles are clean,dependable containers for high-puritysolvents, they present serious safetyhazards when dropped. By containingsolvent spills and broken glass, the B&JHandleLock SolView B-Jacket protectspeople and property from a brokenbottle of flammable or hazardous liquid.

Absorbs Shocks and Minimizes Spills

The B-Jacket acts as a shock absorberto help prevent bottle breakage due tominor jolts such as hitting the edge of a lab bench or knocking one bottleagainst another. If a bottle does break,the B-Jacket contains the glass shardsand minimizes the solvent spill. Labpersonnel are protected from shatteringglass and solvent contact.

Meets OSHA Requirements for Secondary Containment

The B-Jacket is a virtually break-proof secondary container for thestorage and handling of 4L solventbottles as mandated by OSHALaboratory Standards (29 CFR1910.1450 Appendix A).

Shows Solvent Labels and Liquid Levels

The product label and solvent level can be seen through the translucentpolyethylene bottle cover. Solvent usersdo not need to remove the bottle fromthe B-Jacket to identify the type andamount of solvent it contains.

Features Easy-to-Use HandleLock Mechanism

The top of the B-Jacket securelylocks to the bottom and will notdisengage if the container is dropped.The lugs on the handle audibly clickinto place, indicating that the top issecurely attached.

Is Environmentally Responsible

Because most recycling programsrequire the separation of glass andplastics, safety-coated bottles poserecycling problems. The durable,solvent-resistant construction of the B-Jacket allows long-term reusewith recyclable glass bottles.

Won’t Contaminate High-Purity Solvents

Burdick & Jackson™ has found thatthe PVC coating process maycontaminate safety-coated bottles,rendering them an unsuitable packagefor very-high-purity solvents. The B-Jacket has no effect on solvent quality.

The B&J HandleLock SolView B-Jacketprovides convenient secondarycontainment for 4L solvent bottles.

B&J Cat. No. S1337-20

72 Burdick & Jackson Solvent Guide Solvent Packaging | B&J HandleLock SolView B-Jacket

(continued)

B&J HandleLock® SolView B-Jacket®

Six Easy Steps to Greater Lab Safety

Step 1.

Position the shock-absorbing disk insert inthe bottom of the HandleLock SolView B-Jacket with “This Side Up” notation visible.

Step 2.

Carefully place the bottle in the bottomportion of the B-Jacket.

Step 3.

Lower the B-Jacket top over the neck of the bottle. Line up the indicator arrowsto ensure proper assembly.

Step 4.

While holding the bottom handle with onehand, turn the top handle with the otherhand in a clockwise direction until the lugsclick into place.

Step 5.

Lock the top of the container to the bottomby pressing the handle lock mechanismuntil it snaps together. Ensure that thelocking mechanism is engaged beforecarrying or dispensing solvents.

Step 6.

When the bottle is empty, place the B-Jacket on a flat surface to disengage.Hold the bottom handle with one hand.Using the other hand, rotate the top in a counter-clockwise direction until the lugs are disengaged. Remove the top from the bottom.

PURE FACTS

Many of the world’s spectacularwaterfalls found in mountains wereformed originally by glaciers. Wheresmaller tributary accumulations offrozen pure water once joined amain valley glacier, the shallowerdepression cut leaves a cliff or shelfof rock, which subsequently forms a waterfall when the ice is gone.

Solvent Specifications

B&J Solvent Specification inside Quick-Reference Guide front cover

Cross-References 74for Solvent Names

Solvent Specifications 76

CH2Cl2

Cross-References for Solvent Names

74 Burdick & Jackson Solvent Guide Solvent Specifications | Cross-References for Solvent Names

If looking for: See instead:Acetic Acid n-Butyl Ester n-Butyl AcetateAcetic Acid Ethyl Ester Ethyl AcetateAcetone *Acetonitrile *Azabenzene PyridineAzine Pyridine

1-Butanol n-Butyl Alcoholn-Butanol n-Butyl Alcohol2-Butanone Methyl Ethyl Ketonen-Butyl Acetate *n-Butyl Alcohol *n-Butyl Chloride *Butyl Ethanoate n-Butyl Acetatet-Butyl Methyl Ether Methyl t-Butyl Ether

Carbinol MethanolChlorobenzene *1-Chlorobutane n-Butyl ChlorideChloroform *Cyanomethane AcetonitrileCyclohexane *Cyclopentane *

DCM DichloromethaneDMA Dimethyl AcetamideDMAC Dimethyl AcetamideDMF N,N-DimethylformamideDMSO Dimethyl Sulfoxide1,2-Dichlorobenzene o-Dichlorobenzeneo-Dichlorobenzene *1,2-Dichloroethane Ethylene DichlorideDichloromethane *Diethyl Ether Ethyl EtherDiethylene Dioxide 1,4-DioxaneDiethylene Ether 1,4-Dioxane

* See product of same name.

If looking for: See instead:Diethylene Oxide TetrahydrofuranN,N-Diethylethanamine TriethylamineDimethyl Acetamide *Dimethyl Formamide N,N-DimethylformamideDimethyl Ketone AcetoneDimethyl Sulfoxide *N,N-Dimethylacetamide Dimethyl Acetamide1,2-Dimethylbenzene o-XyleneN,N-Dimethylformamide *1,4-Dioxane *p-Dioxane 1,4-Dioxane

Ethanol Ethyl AlcoholEther Ethyl EtherEthoxyethane Ethyl EtherEthyl Acetate *Ethyl Alcohol *Ethyl Carbinol n-Propyl AlcoholEthyl Ethanoate Ethyl AcetateEthyl Ether *Ethylene Chloride Ethylene DichlorideEthylene Dichloride *

Heptane *Hexahydrobenzene CyclohexaneHexane *Hydroxybutane n-Butyl Alcohol

Iso-Octane *Isobutanol Isobutyl AlcoholIsobutyl Alcohol *Isobutyltrimethylmethane Iso-OctaneIsopropanol Isopropyl AlcoholIsopropyl Acetone Methyl Isobutyl KetoneIsopropyl Alcohol *Isopropyl Myristate *

Solvent Specifications | Cross-References for Solvent Names Burdick & Jackson Solvent Guide 75

If looking for: See instead:Lactol Isopropyl AlcoholLigroin Petroleum Ether

MEK Methyl Ethyl KetoneMIBK Methyl Isobutyl KetoneMTBE Methyl t-Butyl EtherMethanol *2-Methoxy-2-Methylpropane Methyl t-Butyl EtherMethyl Alcohol MethanolMethyl t-Butyl Ether *Methyl Carbinol Ethyl AlcoholMethyl Cyanide Acetonitrile4-Methyl-1,3-Dioxolan-2-one Propylene CarbonateMethyl Ethyl Ketone *Methyl Isobutyl Ketone *2-Methyl-2-Methoxypropane Methyl t-Butyl Ether4-Methyl-2-Pentanone Methyl Isobutyl Ketone2-Methyl-1-Propanol Isobutyl Alcohol1-Methyl-2-Pyrrolidinone N-MethylpyrrolidoneN-Methyl-2-Pyrrolidinone N-Methylpyrrolidone1-Methyl-2-Pyrrolidone N-MethylpyrrolidoneN-Methyl-2-Pyrrolidone N-MethylpyrrolidoneMethyl Sulfoxide Dimethyl SulfoxideMethylbenzene TolueneMethylene Chloride DichloromethaneMethylene Dichloride DichloromethaneN-Methylpyrrolidinone N-MethylpyrrolidoneN-Methylpyrrolidone *Methylsulfoxide Dimethyl SulfoxideMonochlorobenzene ChlorobenzeneMyristic Acid Isopropyl Ester Isopropyl Myristate

NMP N-Methylpyrrolidone

* See product of same name.

If looking for: See instead:Pentane *Perfluoroacetic Acid Trifluoroacetic AcidPetroleum Ether *Petroleum Spirits Petroleum EtherPhenylmethane Toluene1-Propanol n-Propyl Alcohol2-Propanol Isopropyl Alcoholn-Propanol n-Propyl Alcohol2-Propanone Acetonen-Propyl Alcohol *Propyl Carbinol n-Butyl AlcoholPropylene Carbonate *Pyridine *

Reagent Alcohol Ethyl Alcohol

TEA TriethylamineTFA Trifluoroacetic AcidTHF TetrahydrofuranTMP Iso-OctaneTetradecanoic Acid Isopropyl Ester Isopropyl MyristateTetradecanoic Acid 1-Methylethyl Ester Isopropyl MyristateTetrahydrofuran *Tetramethylene Oxide TetrahydrofuranToluene *1,2,4-Trichlorbenzene *Trichloromethane ChloroformTriethylamine *Trifluoroacetic Acid *2,2,4-Trimethylpentane Iso-Octane

Water *Wood Alcohol Methanol

o-Xylene *

B&J Brand®

SpecificationsPacked under nitrogenWater Less than 0.50%

by infrared absorptionUV cutoff 330 nmRefractive index 1.3586 ± 0.0003 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysis,

excluding waterElectron capture GC No residue peaks greater than 10 ng/L

as heptachlor epoxideAlso available in stainless steel returnable drums.

Suggested ApplicationsFor HPLC, gas chromatography, pesticide residue analysis and spectrophotometry.

Acetone

Typical Ultraviolet Spectrum

B&J Brand in Stainless Steel Pressure Dispense System



excluding water

Suggested ApplicationsHigh-purity solvent packaged for pressure dispensing.

AcetoneFor Non-Pesticide Residue Analysis Applications

76 Burdick & Jackson Solvent Guide Solvent Specifications | Acetone

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400

UV AbsorbanceWavelength, nm330340350375400

SpecificationsMaximumAbsorbance1.0000.0600.0100.0050.005

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




1L Bottle

010-1

4L Bottle

010-4

10L NOWPak

NP010-10

20L NOWPak

NP010-20

56L SSPDS

CS010-56

200L SSPDS

CS010-200

B&J Brand®

in Stainless Steel Pressure Dispense System



excluding waterElectron capture GC No residue peaks greater than 10 ng/L

as heptachlor epoxide

Suggested ApplicationsHigh-purity solvent for pesticide residue analysis in pressure dispense system.

AcetoneFor Pesticide Residue Analysis

ACS/HPLC Certified

SpecificationsMeets ACS Specifications for UV UseWater Less than 0.50%

by infrared absorptionUV cutoff 330 nmRefractive index 1.3586 ± 0.0003 at 20°CResidue Less than three mg/LPurity Greater than 99.9% GC analysis,

excluding waterSolubility in water Passes testColor (APHA) Less than 10Titrable acid Less than 0.3 µeq/gTitrable base Less than 0.6 µeq/gAldehyde Less than 0.002% as HCHOIsopropyl alcohol Less than 0.05%Methanol Less than 0.05%Substances reducing Passes testpermanganate

Suggested ApplicationsFor HPLC, spectrophotometry and applications requiring ACSReagent Grade solvent.

Acetone

Solvent Specifications | Acetone Burdick & Jackson Solvent Guide 77

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





56L SSPDS

CS011-56

200L SSPDS

CS011-200

4L PVC-Coated

AH010-4PC

4L Bottle

AH010-4

GC2®


by infrared absorptionRefractive index 1.3586 ± 0.0003 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysis,

excluding waterElectron capture GC No residue peaks greater than

two ng/L as lindaneFlame ionization GC No peaks greater than one ng/mL,

having a retention time of greater thandiacetone alcohol, on a crossbonded 5% diphenyl/95% dimethyl polysiloxanecapillary column for a splitless injectionof a 1000-fold sample concentrate afterexchange into hexane

Suggested ApplicationsFor trace analysis at or below the part-per-billion level.

Acetone

Capillary GC-FID Chromatogram of 1000-Fold Concentration

Purified Plus®

SpecificationsMeets ACS Specifications for General Use Water Less than 0.50%

by infrared absorptionRefractive index 1.3586 ± 0.0010 at 20°CResidue after Less than five mg/LevaporationAssay Greater than 99.9% by GC analysis,

excluding waterSolubility in water Passes testColor (APHA) Less than 10Titrable acid Less than 0.3 µeq/gTitrable base Less than 0.6 µeq/gAldehyde Less than 0.002% as HCHOIsopropyl alcohol Less than 0.05%Methanol Less than 0.05%Substances reducing Passes testpermanganatePlease inquire if you have any additional specificationrequirements.

Suggested ApplicationsFor specialty organic synthesis, preparative-scale HPLC, glasswarecleaning and applications requiring ACS Reagent Grade solvent.

Acetone

78 Burdick & Jackson Solvent Guide Solvent Specifications | Acetone

One ppb

GC010-4

4L Bottle

PP010-19 PP010-204

5 Gal Can 54 Gal Drum

B&J Brand®

SpecificationsWater Less than 0.01%

by Karl Fischer titrationUV cutoff 190 nmRefractive index 1.3440 ± 0.0006 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysisElectron capture GC No residue peaks greater than 10 ng/L

as heptachlor epoxide, based on a 1:1petroleum ether extract

HPLC gradient elution No UV absorbing peak greater than0.005 absorbance unit (1 cm pathlength) at 215 nm, or 0.001absorbance unit at 254 nm in agradient from 70% water to 100%acetonitrile on a 15 cm x 4.6 mmcolumn with 5 µm HLD C8 packing

Fluorescence No impurity greater than 0.3 ppb asquinine base at emission of 450 nmafter excitation at 350 nm

Also available in stainless steel returnable drums.


Acetonitrile UV



by Karl Fischer titrationUV cutoff 190 nmRefractive index 1.3440 ± 0.0006 at 20°CResidue Less than one mg/LPurity Greater than 99.9%

by GC analysis


Acetonitrile UV

Solvent Specifications | Acetonitrile UV Burdick & Jackson Solvent Guide 79

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400


SpecificationsMaximumAbsorbance1.0000.0500.0100.0050.0050.005

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



NP015-20015-1 NS015-20015-4 NP015-10

1L Bottle 4L Bottle 10L NOWPak 20L NOWPak 20L NOWPak II

CS015-56 CS015-200

56L SSPDS 200L SSPDS



B&J Brand®


by Karl Fischer titrationUltraviolet absorbance Optical transparency is not controlled.

For spectrophotometric applicationsuse Acetonitrile UV (Product Number 015).

Refractive index 1.3440 ± 0.0006 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysisElectron capture GC No residue peaks greater than 10 ng/L

as heptachlor epoxide, based on a 1:1petroleum ether extract

Suggested ApplicationsFor gas chromatography and pesticide residue analysis.

AcetonitrileNon-Spectrophotometric Grade

Typical GC-ECD Chromatogram of 400-Fold Concentration of a 1:1 Petroleum Ether Extract

B&J Brand


by Karl Fischer titrationUV cutoff 190 nmRefractive index 1.3440 ± 0.0006 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysis

Suggested ApplicationsFor applications requiring extremely low water content.

AcetonitrileLow Water ContentMeets UV Specifications

80 Burdick & Jackson Solvent Guide Solvent Specifications | Acetonitrile

10 ng/L heptachlor epoxide

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




016-4

4L Bottle

NP017-20017-4 NP017-10

4L Bottle 10L NOWPak 20L NOWPak

B&J Brand®


SpecificationsWater Less than 10 ppm




B&J Brand

SpecificationsPurified for applications requiring solvent free of trace aldehydes and ketonesWater Less than 0.01%

by Karl Fischer titrationUV cutoff 190 nmRefractive index 1.3440 ± 0.0006 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysisHPLC gradient elution No UV absorbing peak greater than

0.005 absorbance unit (1 cm pathlength) at 215 nm, or 0.001absorbance unit at 254 nm in agradient from 70% water to 100%acetonitrile on a 15 cm x 4.6 mmcolumn with 5 µm HLD C8 packing

Carbonyl compounds No UV absorbing peak greater than 10ppb (as formaldehyde) at 360 nm afterderivatization with dinitrophenylhydra-zine in a gradient from 50/50 to 25/75of A/B (V/V), where A is water with10% methanol and B is acetonitrile, on a 25 cm x 4.6 mm column with 5 µm C18 packing

AcetonitrileCarbonyl-FreeMeets UV Specifications

Solvent Specifications | Acetonitrile Burdick & Jackson Solvent Guide 81

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





CS017-56 CS017-200


018-1 018-4

1L Bottle 4L Bottle

Suggested ApplicationsFor applications sensitive to trace aldehydes and ketones.

BioSyn®



Suggested ApplicationsFor biosynthetic and other applications requiring extremely lowwater content.



BioSynin Stainless Steel Pressure Dispense System



Suggested ApplicationsFor production-scale biosynthetic applications using pressure delivery and other applications requiring extremely low water content.



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




BC017-56 BC017-200


BN017-20BB017-4

4L Bottle 20L NOWPak II

Anhydrous

SpecificationsAppearance ClearColor (APHA) Less than 10Water Less than 50 ppm

by Karl Fischer titration (100 mL)Less than 10 ppmby Karl Fischer titration (1 L)

Residue Less than three mg/LPurity Greater than 99.9% by GC analysis

Suggested ApplicationsFor organic synthesis, organometallic, oligonucleotide, andcombinatorial chemistry and other applications requiring extremely low water content.

Acetonitrile

ACS/HPLC Certified

SpecificationsMeets ACS Specifications for UV and Liquid ChromatographyAppearance ClearWater Less than 0.05%

by Karl Fischer titrationUV cutoff 190 nmRefractive index 1.3440 ± 0.0006 at 20°CResidue Less than three mg/LPurity Greater than 99.9% by GC analysisColor (APHA) Less than 10Titrable acid Less than 8 µeq/gTitrable base Less than 0.6 µeq/gHPLC gradient elution Passes test

Suggested ApplicationsFor HPLC, spectrophotometry and applications requiring ACS Reagent Grade solvent.

Acetonitrile

Solvent Specifications | Acetonitrile Burdick & Jackson Solvent Guide 83

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



AS017-1

1L Bottle

AS017-0100

100mL Bottle

AH015-4PC

4L PVC-Coated

AH015-4

4L Bottle


Purified Plus®

SpecificationsMeets ACS Specifications for General UseAppearance ClearWater Less than 0.10%

by Karl Fischer titrationRefractive index 1.3440 ± 0.0010 at 20°CResidue after Less than five mg/LevaporationAssay Greater than 99.8% by GC analysisColor (APHA) Less than 10Titrable acid Less than eight µeq/gTitrable base Less than 0.6 µeq/gPlease inquire if you have any additional specificationrequirements.

Suggested ApplicationsFor specialty organic synthesis, preparative-scale liquidchromatography, glassware cleaning and applications requiringACS Reagent Grade solvent.

Acetonitrile

B&J Brand®


by Karl Fischer titrationUV cutoff 254 nmRefractive index 1.3937 ± 0.0010 at 20°CPurity Greater than 99.0% by GC analysis

Suggested ApplicationsFor HPLC, gas chromatography and spectrophotometry.

n-Butyl Acetate


-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



PP016TC19 PP016-204


030-4

4L Bottle


B&J Brand®



Suggested ApplicationsFor HPLC, gas chromatography, spectrophotometry and non-aqueous titrations.

n-Butyl Alcohol

B&J Brand


by Karl Fischer titrationUV cutoff 220 nmRefractive index 1.4017 ± 0.0008 at 20°CResidue Less than one mg/LAcidity Not detectable (limit one mg/L as HCl)Chloride Not detectable (limit 10 mg/L)Purity Greater than 99.5% by GC analysis


n-Butyl Chloride

Solvent Specifications | n-Butyl Chloride Burdick & Jackson Solvent Guide 85

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





024-1 024-4

1L Bottle 4L Bottle

034-1 034-4

1L Bottle 4L Bottle

B&J Brand®




Chlorobenzene


B&J Brand

SpecificationsPacked under nitrogenPreservative Amylene and 1% ethanolWater Less than 0.02%

by Karl Fischer titrationUV cutoff 245 nmRefractive index 1.4447 ± 0.0004 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysis,

excluding ethanolSuitability for use in Passes testdithizone testsSubstances darkened Passes testby sulfuric acidAcidity Not detectable (limit one mg/L as HCl)Chloride Not detectable (limit 10 mg/L)Electron capture GC No residue peaks greater than 10 ng/L



ChloroformContains Amylene and 1% Ethanol Preservatives

86 Burdick & Jackson Solvent Guide Solvent Specifications | Chlorobenzene

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




043-4

4L Bottle

048-1 048-4 NP048-10

1L Bottle 4L Bottle 10L NOWPak

B&J Brand®

SpecificationsPacked under nitrogenPreservative AmyleneWater Less than 0.02%

by Karl Fischer titrationUV cutoff 245 nmRefractive index 1.4459 ± 0.0005 at 20ºCResidue Less than one mg/LPurity Greater than 99.9% by GC analysisSuitability for use in Passes testdithizone testsSubstances darkened Passes testby sulfuric acidAcidity Not detectable (limit one mg/L as HCl)Chloride Not detectable (limit 10 mg/L)Electron capture GC No residue peaks greater than 10 ng/L

as heptachlor expoxide


ChloroformContains Amylene Preservative

Solvent Specifications | Chloroform Burdick & Jackson Solvent Guide 87

049-1 049-4 NP049-10


NP049-20

20L NOWPak

B&J Brandin Stainless Steel Pressure Dispense System

SpecificationsPreservative AmyleneWater Less than 0.02%

by Karl Fischer titrationUV cutoff 245 nmRefractive index 1.4459 ± 0.0005 at 20ºCResidue Less than one mg/LPurity Greater than 99.9% by GC analysisSuitability for use in Passes testdithizone testsSubstances darkened Passes testby sulfuric acidAcidity Not detectable (limit one mg/L as HCl)Chloride Not detectable (limit 10 mg/L)



CS049-200

200L SSPDS

CS049-56

56L SSPDS

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





ACS/HPLC Certified

SpecificationsMeets ACS Specifications for UV and Liquid ChromatographyPreservative AmyleneWater Less than 0.02%

by Karl Fischer titrationUV cutoff 245 nmRefractive index 1.4459 ± 0.0005 at 20°CResidue Less than three mg/LPurity Greater than 99.9% by GC analysisColor (APHA) Less than 10Acetone and aldehyde Passes test [limit about 0.005%

as (CH3)2CO]Acid and chloride Passes testFree chlorine (Cl) Passes testLead (Pb) Less than 0.05 ppmSuitability for Passes testdithizone tests



88 Burdick & Jackson Solvent Guide Solvent Specifications | Chloroform

Anhydrous

SpecificationsPreservative AmyleneAppearance ClearColor (APHA) Less than 10Water Less than 50 ppm


Residue Less than three mg/LAcidity Not detectable (limit one mg/L as HCl)Chloride Not detectable (limit 10 mg/L)Purity Greater than 99.9% by GC analysis



AS049-1

1L Bottle

AS049-0100

100mL Bottle

AH049-4PC

4L PVC-Coated

AH049-4

4L Bottle

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




GC2®

SpecificationsPacked under nitrogenPreservative AmyleneWater Less than 0.02%

by Karl Fischer titrationRefractive index 1.4459 ± 0.0005 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysisAcidity Not detectable (limit one mg/L as HCl)Chloride Not detectable (limit 10 mg/L)Electron capture GC No residue peaks greater than


having a retention time of toluene or greater, on a crossbonded 5% diphenyl/95% dimethylpolysiloxane capillary column for a splitless injection of a 1000-foldsample concentrate after exchangeinto hexane



Purified Plus®

SpecificationsMeets ACS Specifications for General UsePreservative AmyleneWater Less than 0.05%

by Karl Fischer titrationRefractive index 1.4459 ± 0.0020 at 20°CResidue after Less than five mg/LevaporationAssay Greater than 99.9% by GC analysisColor (APHA) Less than 10Acetone and aldehyde Passes test [limit about 0.005% as

(CH3)2CO]Acid and chloride Passes testFree chlorine Passes testLead Less than 0.05 ppmSuitability for use in Passes testdithizone testsPlease inquire if you have any additional specificationrequirements.



Solvent Specifications | Chloroform Burdick & Jackson Solvent Guide 89

One ppb

PP049TC19 PP049-204


GC049-4

4L Bottle

Capillary GC-FID Chromatogramof 1000-Fold Concentration

B&J Brand®





Cyclohexane


Anhydrous



Residue Less than five mg/LPurity Greater than 99.5% by GC analysis


Cyclohexane

90 Burdick & Jackson Solvent Guide Solvent Specifications | Cyclohexane

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



053-1

1L Bottle

AS053-1

1L Bottle

AS053-0100

100mL Bottle

053-4

4L Bottle

B&J Brand®


by Karl Fischer titrationUV cutoff 198 nmRefractive index 1.4015 ± 0.0050 at 20°CResidue Less than one mg/LPurity Greater than 75% cyclopentane and

99.9% cyclopentane and saturated C5

hydrocarbons by GC analysisElectron capture GC No residue peaks greater than 10 ng/L



Cyclopentane

B&J Brand



Suggested ApplicationsFor HPLC, GPC, gas chromatography and spectrophotometry.

o-Dichlorobenzene

Solvent Specifications | o-Dichlorobenzene Burdick & Jackson Solvent Guide 91

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





057-4

4L Bottle

061-4

4L Bottle

B&J Brand®

SpecificationsPreservative CyclohexeneWater Less than 0.01%

by Karl Fischer titrationUV cutoff 233 nmRefractive index 1.4241 ± 0.0005 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysis Acidity Not detectable (limit one mg/L as HCl)Chloride Not detectable (limit 10 mg/L) Electron capture GC No residue peaks greater than 10 ng/L



DichloromethaneContains Cyclohexene Preservative


B&J Brand in Stainless Steel PressureDispense System


by Karl Fischer titrationUV cutoff 233 nmRefractive index 1.4241 ± 0.0005 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysisAcidity Not detectable (limit one mg/L as HCl)Chloride Not detectable (limit 10 mg/L)


DichloromethaneContains Cyclohexene Preservative For Non-Pesticide Residue Analysis Applications

92 Burdick & Jackson Solvent Guide Solvent Specifications | Dichloromethane

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




NS300-20300-1 300-4

1L Bottle 4L Bottle 20L NOWPak II

CS300-56 CS300-200


B&J Brand®

in Stainless Steel PressureDispense System


by Karl Fischer titrationUV cutoff 233 nmRefractive index 1.4241 ± 0.0005 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysisAcidity Not detectable (limit one mg/L as HCl)Chloride Not detectable (limit 10 mg/L)Electron capture GC No residue peaks greater than 10 ng/L


Suggested ApplicationsHigh-purity solvent for pesticide residue analysis in pressuredispense system.

DichloromethaneFor Pesticide Residue AnalysisContains Cyclohexene Preservative

B&J Brand in Stainless Steel PressureDispense System




DichloromethaneLow Water ContentContains Cyclohexene Preservative

Solvent Specifications | Dichloromethane Burdick & Jackson Solvent Guide 93

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





CS298-56 CS298-200


CS301-56 CS301-200


B&J Brand®



as heptachlor epoxideFlame ionization GC No peaks greater than five ng/mL,

having a retention time of toluene orgreater, on a cross-bonded 5%diphenyl/95% dimethyl polysiloxanecapillary column for a splitless injectionof a 500-fold concentrate of sample


DichloromethaneContains Amylene Preservative







DichloromethaneFor Pesticide Residue AnalysisContains Amylene Preservative


-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




299-4

4L Bottle

CS299-56 CS299-200


BioSyn®

SpecificationsPreservative CyclohexeneWater Less than 20 ppm


Suggested ApplicationsFor biosynthetic and other applications requiring extremely low water content.


BioSynin Stainless Steel Pressure Dispense System

SpecificationsPreservative CyclohexeneWater Less than 20 ppm





-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



BB301-4 BN301-20


BC301-56 BC301-200




Anhydrous

SpecificationsPreservative AmyleneAppearance ClearColor (APHA) Less than 10Water Less than 50 ppm


Residue Less than three mg/LPurity Greater than 99.9% by GC analysisAcidity Not detectable (limit one mg/L as HCl)Chloride Not detectable (limit 10 mg/L)



ACS/HPLC Certified

SpecificationsMeets ACS Specifications for UV and Liquid ChromatographyPreservative CyclohexeneAppearance ClearWater Less than 0.02%

by Karl Fischer titrationUV cutoff 233 nmRefractive index 1.4241 ± 0.0005 at 20°CResidue Less than three mg/LPurity Greater than 99.9% by GC analysisColor (APHA) Less than 10Titrable acid Less than 0.3 µeq/gFree halogens Passes test




-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




AS299-1

1L Bottle

AS299-0100

100mL Bottle

AH300-4

4L Bottle

AH300-4PC

4L PVC-Coated

GC2®


by Karl Fischer titrationRefractive index 1.4241 ± 0.0005 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysisAcidity Not detectable (limit one mg/L as HCl)Chloride Not detectable (limit 10 mg/L)Electron capture GC No residue peaks greater than


having a retention time of toluene or greater, on a crossbonded 5% diphenyl/95% dimethylpolysiloxane capillary column for asplitless injection of a 1000-foldsample concentrate



Purified Plus®

SpecificationsMeets ACS Specifications for General UsePreservative CyclohexeneAppearance ClearWater Less than 0.02%

by Karl Fischer titrationRefractive index 1.4241 ± 0.0010 at 20°CResidue after Less than five mg/LevaporationAssay Greater than 99.9% by GC analysisColor (APHA) Less than 10Titrable acid Less than 0.3 µeq/gFree halogens Passes testPlease inquire if you have any additional specificationrequirements.




One ppb

GC299-4

4L Bottle

PP300-19 PP300-204



B&J Brand®


by Karl Fischer titrationUV cutoff 268 nmPurity Greater than 99.5% by GC analysisGC impurities eluting None greater than 0.5 mg/Lbefore solvent


Dimethyl Acetamide


B&J Brandin Stainless Steel Pressure Dispense System


by Karl Fischer titrationUV cutoff 268 nmPurity Greater than 99.5% by GC analysis


Dimethyl Acetamide

98 Burdick & Jackson Solvent Guide Solvent Specifications | Dimethyl Acetamide

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




NP071-20071-4 NP071-10

4L Bottle 10L NOWPak 20L NOWPak

CS071-56 CS071-200


Anhydrous


by Karl Fischer titrationResidue Less than five mg/LPurity Greater than 99.8% by GC analysis


Dimethyl Acetamide

B&J Brand®


by Karl Fischer titrationUV cutoff 268 nmPurity Greater than 99.9% by GC analysisGC impurities eluting None greater than 0.5 mg/Lbefore solventAlso available in stainless steel returnable drums.

Suggested ApplicationsFor HPLC, gas chromatography, spectrophotometry and non-aqueous titrations.

N,N-Dimethylformamide

Solvent Specifications | N,N-Dimethylformamide Burdick & Jackson Solvent Guide 99

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




AS071-1

1L Bottle

AS071-0100

100mL Bottle

076-1

1L Bottle

076-4 NP076-10

4L Bottle 10L NOWPak

NP076-20

20L NOWPak

B&J Brand®



by Karl Fischer titrationUV cutoff 268 nmPurity Greater than 99.9% by GC analysisAmines Less than three ppm as dimethylamineGC impurities eluting None greater than 0.5 mg/Lbefore solvent




SpecificationsPacked under nitrogenWater Less than 150 ppm

by Karl Fischer titrationUV cutoff 268 nmResidue Less than five mg/LPurity Greater than 99.9% by GC analysisAmines Less than three ppm as dimethylamine

Suggested ApplicationsFor biosynthetic and other applications requiring extremely lowwater content.

N,N-DimethylformamideLow Water Content

100 Burdick & Jackson Solvent Guide Solvent Specifications | N,N-Dimethylformamide

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



CS076-56 CS076-200


BB075-4 BN075-20


BioSyn®


BioSyn®



by Karl Fischer titrationUV cutoff 268 nmResidue Less than five mg/LPurity Greater than 99.9% by GC analysisAmines Less than three ppm as dimethylamine


N,N-DimethylformamideLow Water Content

Anhydrous


by Karl Fischer titrationResidue Less than five mg/LPurity Greater than 99.9% by GC analysis



Solvent Specifications | N,N-Dimethylformamide Burdick & Jackson Solvent Guide 101

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




BC075-56 BC075-200


AS076-1

1L Bottle

AS076-0100

100mL Bottle

B&J Brand®




Dimethyl Sulfoxide





Dimethyl Sulfoxide

102 Burdick & Jackson Solvent Guide Solvent Specifications | Dimethyl Sulfoxide

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




081-4 081-4PC

4L Bottle

081-1

1L Bottle 4L PVC-Coated

CS081-56 CS081-200



BioSyn®


by Karl Fischer titrationUV cutoff 268 nmRefractive index 1.4785 ± 0.0015 at 20°CResidue Less than five mg/LPurity Greater than 99.5% by GC analysis


Dimethyl SulfoxideLow Water Content

Anhydrous


by Karl Fischer titration Residue Less than five mg/LPurity Greater than 99.9% by GC analysis


Dimethyl Sulfoxide

Solvent Specifications | Dimethyl Sulfoxide Burdick & Jackson Solvent Guide 103

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




BB082-4

4L Bottle

AS081-1

1L Bottle

AS081-0100

100mL Bottle

B&J Brand®


by Karl Fischer titrationUV cutoff 215 nmRefractive index 1.4216 ± 0.0010 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysisPeroxides Less than two mg/L as H2O2 at time

of packaging

Suggested ApplicationsFor HPLC, gas chromatography, spectrophotometry and liquidscintillation counting.

1,4-Dioxane


B&J Brand





Ethyl Acetate

104 Burdick & Jackson Solvent Guide Solvent Specifications | 1,4-Dioxane

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




087-1 087-4

1L Bottle 4L Bottle

NP100-20100-1 NS100-20100-4 NP100-10

1L Bottle 4L Bottle 10L NOWPak 20L NOWPak 20L NOWPak II

B&J Brand®





Ethyl Acetate

B&J Brand

SpecificationsPurified for applications requiring solvent free of trace aldehyde,ketone, acid or alcoholWater Less than 0.05%


as heptachlor epoxideColor with sulfuric Passes testacidSubstances reducing Passes testpermanganate


Ethyl AcetateCarbonyl-FreeMeets UV Specifications

Solvent Specifications | Ethyl Acetate Burdick & Jackson Solvent Guide 105

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





CS100-56 CS100-200


099-4

4L Bottle

Anhydrous


by Karl Fischer titration Residue Less than five mg/LPurity Greater than 99.8% by GC analysis


Ethyl Acetate

ACS/HPLC Certified


by Karl Fischer titrationUV cutoff 256 nmRefractive index 1.3723 ± 0.0003 at 20°CResidue Less than three mg/LPurity Greater than 99.5% by GC analysisColor (APHA) Less than 10Titrable acid Less than 0.9 µeq/gSubstances darkened Passes testby sulfuric acid


Ethyl Acetate

106 Burdick & Jackson Solvent Guide Solvent Specifications | Ethyl Acetate

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




AS100-1

1L Bottle

AS100-0100

100mL Bottle

AH100-4PC

4L PVC-Coated

AH100-4

4L Bottle


GC2®


by Karl Fischer titrationRefractive index 1.3723 ± 0.0003 at 20°CResidue Less than one mg/LPurity Greater than 99.5% by GC analysisElectron capture GC No residue peaks greater than


having a retention time of toluene orgreater, on a crossbonded 5%diphenyl/95% dimethyl polysiloxanecapillary column for a splitless injectionof a 1000-fold sample concentrate afterexchange into hexane


Ethyl Acetate

Purified Plus®

SpecificationsMeets ACS Specifications for General UseWater Less than 0.10%

by Karl Fischer titrationRefractive index 1.3723 ± 0.0010 at 20°CResidue after Less than five mg/LevaporationAssay Greater than 99.5% by GC analysisColor (APHA) Less than 10Titrable acid Less than 0.9 µeq/gSubstances darkened Passes testby sulfuric acidPlease inquire if you have any additional specificationrequirements.


Ethyl Acetate

Solvent Specifications | Ethyl Acetate Burdick & Jackson Solvent Guide 107

One ppb

GC100-4

4L Bottle

PP100-19 PP100-204



ACS/HPLC Certified

SpecificationsMeets ACS SpecificationsAssay Within 94.0 – 96.0% (v/v) methanol

and ethyl alcohol and 4.0 – 6.0% (v/v)isopropyl alcohol by GC analysis

Ethyl alcohol 90.0 ± 1%Methanol 5.0 ± 1%Isopropyl alcohol 5.0 ± 1%

Water Less than 0.20%by Karl Fischer titration

UV cutoff 210 nmResidue Less than one mg/LColor (APHA) Less than 10Specific gravity 0.790 ± 0.005(25°C/25°C)


Ethyl Alcohol, ReagentAnhydrous


B&J Brand®

SpecificationsPacked under nitrogenPreservative 2% (v/v) ethanolWater Less than 0.03%

by Karl Fischer titrationUV cutoff 215 nmRefractive index 1.3528 ± 0.0005 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysis,

excluding ethanolPeroxides Less than one ppm as H2O2 at time

of packagingElectron capture GC No residue peaks greater than 10 ng/L



Ethyl EtherContains 2% Ethanol Preservative

108 Burdick & Jackson Solvent Guide Solvent Specifications | Ethyl Alcohol, Reagent

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




AH090-4PC

4L PVC-Coated

AH090-4

4L Bottle

NS106-20106-1 106-4


B&J Brand®

SpecificationsPacked under nitrogenPreservative NoneWater Less than 0.03%

by Karl Fischer titrationUV cutoff 215 nmRefractive index 1.3521 ± 0.0005 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysisPeroxides Less than one ppm as H2O2 at time

of packagingElectron capture GC No residue peaks greater than 10 ng/L



Ethyl EtherContains No Preservative



by Karl Fischer titrationUV cutoff 215 nmRefractive index 1.3521 ± 0.0005 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysis Peroxides Less than one ppm as H2O2 at time

of packaging


Ethyl EtherContains No Preservative

Solvent Specifications | Ethyl Ether Burdick & Jackson Solvent Guide 109

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





107-1 NS107-20107-4


CS107-56 CS107-200


ACS/HPLC Certified

SpecificationsMeets ACS SpecificationsPreservative 2% (v/v) ethanolWater Less than 0.03%

by Karl Fischer titrationUV cutoff 215 nmRefractive index 1.3528 ± 0.0005 at 20°CResidue Less than three mg/LPurity Greater than 99.9% by GC analysis,

excluding ethanolPeroxides Less than one ppm as H2O2

at time of packagingColor (APHA) Less than 10Titrable acid Less than 0.2 µeq/gCarbonyl compounds Less than 0.001% as HCHOSubstances darkened Passes testby sulfuric acid


Ethyl EtherContains 2% Ethanol Preservative


Purified Plus®

SpecificationsMeets ACS SpecificationsPreservative One ppm butylated hydroxytoluene

(BHT)Water Less than 0.03%

by Karl Fischer titrationRefractive index 1.3528 ± 0.0010 at 20°CResidue after Less than five mg/LevaporationAssay Greater than 99.9% by GC analysisPeroxide Less than one ppm as H2O2

at time of packagingColor (APHA) Less than 10Titrable acid Less than 0.9 µeq/gCarbonyl compounds Less than 0.001% as HCHOAlcohol Passes test (limit about 0.05% as

CH3CH2OH)Substances darkened Passes testby sulfuric acidPlease inquire if you have any additional specificationrequirements.

Suggested ApplicationsFor specialty organic synthesis, preparative-scale HPLC,glassware cleaning and applications requiring ACS ReagentGrade solvent.

Ethyl EtherContains BHT Preservative

110 Burdick & Jackson Solvent Guide Solvent Specifications | Ethyl Ether

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



AH106-4PC

4L PVC-Coated

AH106-4

4L Bottle

PP108-19

5 Gal Can

PP108-204

54 Gal Drum

B&J Brand®




EthyleneDichloride

B&J Brand


by Karl Fischer titrationUV cutoff 200 nmRefractive index 1.3878 ± 0.0006 at 20°CResidue Less than one mg/LPurity Greater than 99.0% n-heptane and

99.9% n-heptane and saturated C7

hydrocarbons by GC analysisElectron capture GC No residue peak greater than two µg/L



99% n-Heptane

Solvent Specifications | 99% n-Heptane Burdick & Jackson Solvent Guide 111

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





200-4

4L Bottle

207-1 207-4

1L Bottle 4L Bottle

NP207-20

20L NOWPak

NP207-10

10L NOWPak

B&J Brand®



by Karl Fischer titrationUV cutoff 200 nmRefractive index 1.3878 ± 0.0006 at 20°CResidue Less than one mg/LPurity Greater than 99.0% n-heptane and


hydrocarbons by GC analysis


99% n-Heptane


Anhydrous

SpecificationsAppearance ClearWater Less than 50 ppm

by Karl Fischer titration (100 mL)Less than 10 ppm by Karl Fischer titration (1 L)

Residue Less than three mg/LPurity Greater than 99.0% n-heptane and


isomers by GC analysis


Heptane

112 Burdick & Jackson Solvent Guide Solvent Specifications | 99% n-Heptane

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



CS207-56 CS207-200


AS206-1

1L Bottle

AS206-0100

100mL Bottle

Purified Plus®

SpecificationsAppearance Clear, colorless liquidWater Less than 0.01%

by Karl Fischer titrationRefractive index 1.3878 ± 0.0010 at 20°CResidue after Less than five mg/LevaporationPurity Greater than 99.0% n-heptane and



Suggested ApplicationsFor specialty organic synthesis, preparative-scale HPLC andglassware cleaning.

99% n-Heptane

B&J Brand®


by Karl Fischer titrationUV cutoff 195 nmRefractive index 1.3780 ± 0.0020 at 20°CResidue Less than one mg/LBenzene Less than one mg/LPurity Greater than 85.0% n-hexane and

99.9% n-hexane and saturated C6




Hexane UV

Solvent Specifications | Hexane UV Burdick & Jackson Solvent Guide 113

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



PP206-19 PP206-204


216-1 216-4

1L Bottle 4L Bottle

NP216-20 NS216-20

20L NOWPak 20L NOWPak II

NP216-10

10L NOWPak


B&J Brand®



by Karl Fischer titrationUV cutoff 195 nmRefractive index 1.3780 ± 0.0020 at 20°CResidue Less than one mg/LBenzene Less than one mg/LPurity Greater than 85.0% n-hexane and




Hexane UVFor Non-Pesticide Residue AnalysisApplications


B&J Brand



For spectrophotometric applications,use Hexane UV (Product Number 216).

Refractive index 1.3780 ± 0.0020 at 20°CResidue Less than one mg/LBenzene Less than 10 mg/LPurity Greater than 85.0% n-hexane and





HexaneNon-Spectrophotometric Grade

114 Burdick & Jackson Solvent Guide Solvent Specifications | Hexane UV

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




Typical GC-ECD Chromatogram of 400-Fold Concentration

CS216-56 CS216-200


217-1 217-4

1L Bottle 4L Bottle

NP217-20

20L NOWPak


B&J Brand®




For spectrophotometric applications,use Hexane UV in SSPDS (ProductNumber CS216).





HexaneNon-Spectrophotometric GradeFor Non-Pesticide Residue Analysis Applications

B&J Brand®




For spectrophotometric applications,use Hexane UV in SSPDS (ProductNumber CS216).





Suggested ApplicationsHigh-purity solvent for pesticide residue analysis in pressure dispense system.

HexaneNon-Spectrophotometric GradeFor Pesticide Residue Analysis Applications

Solvent Specifications | Hexane Burdick & Jackson Solvent Guide 115


CS217-56 CS217-200


CS218-56 CS218-200


Typical GC-ECD Chromatogram of 400-Fold Concentration

Anhydrous



Residue Less than three mg/LPurity Greater than 85.0% n-hexane and




Hexane

ACS/HPLC Certified

SpecificationsMeets ACS Specifications for UV and Liquid ChromatographyWater Less than 0.01%

by Karl Fischer titrationUV cutoff 195 nmRefractive index 1.3780 ± 0.0020 at 20°CResidue Less than three mg/LPurity Greater than 85.0% n-hexane and


hydrocarbons by GC analysisColor (APHA) Less than 10Water-soluble Less than 0.3 µeq/gtitrable acidSulfur compounds Less than 0.005% as SThiophene Passes test


Hexane

116 Burdick & Jackson Solvent Guide Solvent Specifications | Hexane

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




AH216-4

4L Bottle

AH216-4PC

4L PVC-Coated

AS217-1

1L Bottle

AS217-0100

100mL Bottle

GC2®


by Karl Fischer titrationRefractive index 1.3780 ± 0.0020 at 20°CResidue Less than one mg/LPurity Greater than 85.0% n-hexane and


hydrocarbons by GC analysisElectron capture GC No residue peaks greater than


having a retention time of toluene orgreater, on a crossbonded 5%diphenyl/95% dimethyl polysiloxanecapillary column for a splitless injectionof a 1000-fold sample concentrate


Hexane

Purified Plus®


by Karl Fischer titrationRefractive index 1.3780 ± 0.0020 at 20°CResidue after Less than five mg/LevaporationAssay Greater than 85.0% n-hexane and


isomers by GC analysisColor (APHA) Less than 10Water-soluble Less than 0.3 µeq/gtitrable acidSulfur compounds Less than 0.005% as SThiophene Passes testPlease inquire if you have any additional specificationrequirements.


Hexane

Solvent Specifications | Hexane Burdick & Jackson Solvent Guide 117

0.5 ppb

GC217-4

4L Bottle

PP217-19 PP217-204



B&J Brand®


by Karl Fischer titrationUV cutoff 215 nmRefractive index 1.3915 ± 0.0008 at 20°CResidue Less than one mg/LPurity Greater than 99.0% by GC analysisElectron capture GC No residue peaks greater than

two µg/L as heptachlor epoxide


Iso-Octane


Purified Plus®


by Karl Fischer titrationRefractive index 1.3915 ± 0.0008 at 20°CResidue after Less than five mg/LevaporationAssay Greater than 99.0% by GC analysisColor (APHA) Less than 10Water-soluble Less than 0.3 µeq/gtitrable acidSulfur compounds Less than 0.005% as SPlease inquire if you have any additional specificationrequirements.


Iso-Octane

118 Burdick & Jackson Solvent Guide Solvent Specifications | Iso-Octane

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



362-1 362-4

1L Bottle 4L Bottle

NP362-20

20L NOWPak

NS362-20

20L NOWPak II

NP362-10

10L NOWPak

PP362TC19 PP362-204


B&J Brand®




Isobutyl Alcohol

B&J Brand


by Karl Fischer titrationUV cutoff 205 nmRefractive index 1.3772 ± 0.0006 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysisElectron capture GC No residue peak greater than two µg/L



Isopropyl Alcohol

Solvent Specifications | Isopropyl Alcohol Burdick & Jackson Solvent Guide 119

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





220-4

4L Bottle

323-1 323-4 NP323-10


NP323-20 NS323-20


B&J Brand®





Isopropyl Alcohol


B&J Brand



Suggested ApplicationsFor applications requiring extremely low water content.

Isopropyl AlcoholLow Water Content

120 Burdick & Jackson Solvent Guide Solvent Specifications | Isopropyl Alcohol

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




CS323-56 CS323-200


324-4

4L Bottle

Anhydrous





Isopropyl Alcohol

ACS/HPLC Certified


by Karl Fischer titrationUV cutoff 205 nmRefractive index 1.3772 ± 0.0006 at 20°CResidue Less than three mg/LPurity Greater than 99.9% by GC analysisSolubility in water Passes testColor (APHA) Less than 10Titrable acid or base Less than 0.1 µeq/gCarbonyl compounds Less than 0.002% each as acetone

or propionaldehyde


Isopropyl Alcohol

Solvent Specifications | Isopropyl Alcohol Burdick & Jackson Solvent Guide 121

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




AH323-4PC

4L PVC-Coated

AH323-4

4L Bottle

AS323-1

1L Bottle

AS323-0100

100mL Bottle


Purified Plus®


by Karl Fischer titrationRefractive index 1.3772 ± 0.0010 at 20°CResidue after Less than five mg/LevaporationAssay Greater than 99.9% by GC analysisColor (APHA) Less than 10Titrable acid or base Less than 0.1 µeq/gCarbonyl compounds Less than 0.002% each of acetone or

propionaldehydeSolubility in water Passes testPlease inquire if you have any additional specificationrequirements.


Isopropyl Alcohol

B&J Brand®

SpecificationsA specially purified solvent intended for sterility testing ofophthalmic ointmentspH of water extract Greater than 6.5Appearance Clear, colorless liquidInfrared absorbance Equivalent to standard

Suggested ApplicationsFor sterility testing of ophthalmic ointments.

Isopropyl Myristate

122 Burdick & Jackson Solvent Guide Solvent Specifications | Isopropyl Alcohol

PP323-19 PP323-204


225-4

4L Bottle

B&J Brand®



as heptachlor epoxideHPLC gradient elution No UV absorbing peak greater than

0.005 absorbance unit (1 cm pathlength) at 220 nm or 0.001 absorbanceunit (1 cm path length) at 254 nm in agradient from 95% water to 100%methanol on a 15 cm x 4.6 mm columnwith 5 µm HLD C8 packing


Also available in stainless steel returnable drums.


Methanol





Methanol

Solvent Specifications | Methanol Burdick & Jackson Solvent Guide 123

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





230-1 230-4 NP230-10


NP230-20 NS230-20


CS230-56 CS230-200


B&J Brand®


by Karl Fischer titrationRefractive index 1.3284 ± 0.0004 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysis

Volatile organics by purge and trap GCALL AROMATICS Less than one ng/mL

KETONES2-Butanone Less than 100 ng/mLAcetone Less than 50 ng/mLMethyl isoamyl ketone Less than 50 ng/mLAll other detectable Less than 50 ng/mLketones

CHLOROHYDROCARBONS (NON-AROMATIC)Dichloromethane Less than 50 ng/mLChloroform Less than 50 ng/mLCarbon tetrachloride Less than 50 ng/mLAll other detectable Less than 50 ng/mLchlorohydrocarbons

ALKANESPentane Less than 50 ng/mLHexane Less than 50 ng/mLHeptane Less than 50 ng/mLIso-octane Less than 50 ng/mLAll other detectable Less than 50 ng/mLalkanes

ALL OTHER DETECTABLE PEAKS(as hexane) Less than 50 ng/mL

Suggested ApplicationsFor analysis of trace volatile organic compounds using purge and trap methods.

MethanolFor Purge and Trap Analysis

BioSyn®




MethanolLow Water Content

124 Burdick & Jackson Solvent Guide Solvent Specifications | Methanol

235mL Bottle

232-235 232-1

1L Bottle

BN233-20BB233-4


-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




BioSyn®





Methanol

Anhydrous





Methanol

Solvent Specifications | Methanol Burdick & Jackson Solvent Guide 125

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




BC233-56 BC233-200


AS230-1

1L Bottle

AS230-0100

100mL Bottle

ACS/HPLC Certified

SpecificationsMeets ACS Specifications for UV and Liquid ChromatographyAppearance ClearWater Less than 0.05%

by Karl Fischer titrationUV cutoff 205 nmRefractive index 1.3284 ± 0.0004 at 20°CResidue Less than three mg/LPurity Greater than 99.9% by GC analysisSubstances darkened Passes testby sulfuric acidSubstances reducing Passes testpermanganateColor (APHA) Less than 10Solubility in water Passes testCarbonyl compounds Less than 0.001% each of acetone,

formaldehyde and acetaldehydeTitrable acid Less than 0.3 µeq/gTitrable base Less than 0.2 µeq/gHPLC gradient elution Passes test


Methanol


GC2®


by Karl Fischer titrationRefractive index 1.3284 ± 0.0004 at 20°CResidue Less than one mg/LPurity Greater than 99.9% by GC analysisElectron capture GC No residue peaks greater than


having a retention time of toluene or greater, on a crossbonded 5% diphenyl/95% dimethylpolysiloxane capillary column for a splitless injection of a 1000-fold sample concentrate after exchange into hexane


Methanol

126 Burdick & Jackson Solvent Guide Solvent Specifications | Methanol

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



0.5 ppb


AH230-4PC

4L PVC-Coated

AH230-4

4L Bottle

GC230-4

4L Bottle

Purified Plus®

SpecificationsMeets ACS Specifications for General UseAppearance ClearWater Less than 0.10%

by Karl Fischer titrationRefractive index 1.3284 ± 0.0010 at 20°CResidue after Less than five mg/LevaporationAssay Greater than 99.9% by GC analysisSubstances darkened Passes testby sulfuric acidSubstances reducing Passes testpermanganateColor (APHA) Less than 10Solubility in water Passes testCarbonyl compounds Less than 0.001% each of acetone,

formaldehyde and acetaldehydeTitrable acid Less than 0.3 µeq/gTitrable base Less than 0.2 µeq/gPlease inquire if you have any additional specificationrequirements.

Methanol

B&J Brand®


by Karl Fischer titrationUV cutoff 210 nmRefractive index 1.3690 ± 0.0010 at 20°CResidue Less than one mg/LPurity Greater than 99.0% by GC analysisPeroxide Less than one mg/L as H2O2

Electron capture GC No residue peaks greater than 10 ng/L as heptachlor epoxide


Methyl t-ButylEther

Solvent Specifications | Methyl t-Butyl Ether Burdick & Jackson Solvent Guide 127

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



PP230-19 PP230-204


242-1 242-4

1L Bottle 4L Bottle



B&J Brand®




Methyl Ethyl Ketone


B&J Brand


by Karl Fischer titrationUV cutoff 334 nmRefractive index 1.3954 ± 0.0006 at 20ºCPurity Greater than 99.0% by GC analysis

Suggested ApplicationsFor HPLC, gas chromatography, spectrophotometry and metalcomplex extraction for atomic absorption spectroscopy.

Methyl Isobutyl Ketone

128 Burdick & Jackson Solvent Guide Solvent Specifications | Methyl Ethyl Ketone

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




247-4 NP247-10


NP247-20

20L NOWPak

NP253-20

20L NOWPak

253-4 NP253-10


B&J Brand®


by Karl Fischer titrationUV cutoff 285 nmRefractive index 1.4700 ± 0.0020 at 20°CPurity Greater than 99.5% by GC analysisAlso available in stainless steel returnable drums.


N-Methylpyrrolidone





N-Methylpyrrolidone

Solvent Specifications | N-Methylpyrrolidone Burdick & Jackson Solvent Guide 129

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





304-4 NP304-10


304-1

1L Bottle

NS304-20

20L NOWPak II

NP304-20

20L NOWPak

CS304-56 CS304-200


BioSyn®


by Karl Fischer titrationUV cutoff 285 nmRefractive index 1.4700 ± 0.0020 at 20°CResidue Less than five mg/LPurity Greater than 99.5% by GC analysisAmines Less than three ppm as dimethylamine


N-MethylpyrrolidoneLow Water Content


BioSyn in Stainless Steel Pressure Dispense System


by Karl Fischer titrationUV cutoff 285 nmRefractive index 1.4700 ± 0.0020 at 20°CResidue Less than five mg/LPurity Greater than 99.5% by GC analysisAmines Less than three ppm as dimethylamine

Suggested ApplicationsFor production-scale biosynthetic applications using pressure delivery and other applications requiring extremelylow water content.

N-MethylpyrrolidoneLow Water Content

130 Burdick & Jackson Solvent Guide Solvent Specifications | N-Methylpyrrolidone

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




BN305-20BB305-4


BC305-56 BC305-200


Anhydrous


by Karl Fischer titrationPurity Greater than 99.5% by GC analysis


N-Methylpyrrolidone

B&J Brand®


by Karl Fischer titrationUV cutoff 190 nmRefractive index 1.3576 ± 0.0003 at 20°CResidue Less than one mg/LPurity Greater than 98.0% n-pentane and

99.9% n-pentane and saturated C5




Pentane

Solvent Specifications | Pentane Burdick & Jackson Solvent Guide 131

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




AS304-1

1L Bottle

AS304-0100

100mL Bottle

312-1 312-4

1L Bottle 4L Bottle

NS312-20

20L NOWPak II

B&J Brand®



by Karl Fischer titrationUV cutoff 190 nmRefractive index 1.3576 ± 0.0003 at 20°CResidue Less than one mg/LPurity Greater than 98.0% n-pentane and




Pentane


Anhydrous



Residue Less than three mg/LPurity Greater than 98.0% n-pentane and




Pentane

132 Burdick & Jackson Solvent Guide Solvent Specifications | Pentane

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



CS312-56 CS312-200


AS312-1

1L Bottle

AS312-0100

100mL Bottle

GC2®


by Karl Fischer titrationRefractive index 1.3576 ± 0.0003 at 20°CResidue Less than one mg/LPurity Greater than 98.0% n-pentane and


hydrocarbons by GC analysisElectron capture GC No residue peaks greater than


having a retention time of toluene or greater, on a crossbonded 5% diphenyl/95% dimethylpolysiloxane capillary column for a splitless injection of a 1000-fold sample concentrate


Pentane

B&J Brand®


by Karl Fischer titrationUltraviolet absorbance Optical transparency is not controlledRefractive index 1.3650 ± 0.0050 at 20°CResidue Less than one mg/LPurity Greater than 99.0% total pentane and

hexane isomers by GC analysisElectron capture GC No residue peaks greater than 10 ng/L



Petroleum Ether

Solvent Specifications | Petroleum Ether Burdick & Jackson Solvent Guide 133

0.5 ppb


Typical GC-ECD Chromatogramof 400-Fold Concentration


GC312-4

4L Bottle

317-1 NS317-20317-4


B&J Brand®



by Karl Fischer titrationUltraviolet absorbance Optical transparency is not controlledRefractive index 1.3650 ± 0.0050 at 20°CResidue Less than one mg/LPurity Greater than 99.0% total pentane

and hexane isomers by GC analysis


Petroleum EtherFor Non-Pesticide Residue AnalysisApplications

B&J Brand®



by Karl Fischer titrationUltraviolet absorbance Optical transparency is not controlledRefractive index 1.3650 ± 0.0050 at 20°CResidue Less than one mg/LPurity Greater than 99.0% total pentane and

hexane isomers by GC analysis Electron capture GC No residue peaks greater than 10 ng/L



Petroleum EtherFor Pesticide Residue AnalysisApplications

134 Burdick & Jackson Solvent Guide Solvent Specifications | Petroleum Ether


CS317-56 CS317-200


CS318-56 CS318-200


Typical GC-ECD Chromatogramof 400-Fold Concentration

Anhydrous


by Karl Fischer titration Residue Less than three mg/LBoiling range 35–60°C

Suggested ApplicationsFor organic synthesis, organometallic, oligonucleotide,combinatorial chemistry and other applications requiring extremely low water content.

Petroleum Ether

GC2®


by Karl Fischer titrationRefractive index 1.3650 ± 0.0050 at 20°CResidue Less than one mg/LPurity Greater than 99.0% total pentane and

hexane isomers by GC analysisElectron capture GC No residue peaks greater than


having a retention time of toluene or greater, on a crossbonded 5% diphenyl/95% dimethylpolysiloxane capillary column for a splitless injection of a 1000-fold sample concentrate


Petroleum Ether

Solvent Specifications | Petroleum Ether Burdick & Jackson Solvent Guide 135

One ppb


AS317-1

1L Bottle

AS317-0100

100mL Bottle

GC317-4

4L Bottle

Purified Plus®


by Karl Fischer titrationRefractive index 1.3650 ± 0.0050 at 20°CResidue after Less than five mg/L evaporationAssay Greater than 99.0% total pentane and

hexane isomers by GC analysis Color (APHA) Less than 10Boiling range 35-60°CAcidity Passes testPlease inquire if you have any additional specificationrequirements.


Petroleum Ether

B&J Brand®


by Karl Fischer titrationUV cutoff 210 nmRefractive index 1.3849 ± 0.0008 at 20°CResidue Less than three mg/LPurity Greater than 99.5% by GC analysis


n-Propyl Alcohol

136 Burdick & Jackson Solvent Guide Solvent Specifications | Petroleum Ether

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



PP317-19 PP317-204


322-1 322-4

1L Bottle 4L Bottle


B&J Brand®



by Karl Fischer titrationRefractive index 1.3849 ± 0.0008 at 20°CResidue Less than three mg/LPurity Greater than 99.5% by GC analysis


n-Propyl Alcohol

Purified Plus®


by Karl Fischer titrationRefractive index 1.3849 ± 0.0010 at 20°CResidue after Less than five mg/LevaporationAssay Greater than 99.5% by GC analysisSolubility in water Passes testColor (APHA) Less than 10Titrable acid Less than 0.4 µeq/gEthyl alcohol Less than 0.01% by GC analysisIsopropyl alcohol Less than 0.05% by GC analysisMethanol Less than 0.01% by GC analysisCarbonyl compounds Less than 0.03% as C2H5CHOPlease inquire if you have any additional specificationrequirements.


n-Propyl Alcohol

Solvent Specifications | n-Propyl Alcohol Burdick & Jackson Solvent Guide 137

CS322-56 CS322-200


PP322-19 PP322-204


B&J Brand®



Suggested ApplicationsFor gas chromatography and spectrophotometry.

PropyleneCarbonate






PropyleneCarbonate

138 Burdick & Jackson Solvent Guide Solvent Specifications | Propylene Carbonate

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




327-1 327-4

1L Bottle 4L Bottle

NP327-10

10L NOWPak

NP327-20

20L NOWPak

CS327-56 CS327-200



Anhydrous




PropyleneCarbonate

B&J Brand®


by Karl Fischer titrationRefractive index 1.5097 ± 0.0012 at 20°CResidue Less than one mg/LPurity Greater than 99.8% by GC analysisAmines Passes test (less than 10 ppm)by ninhydrin testFree acid Passes test

Suggested ApplicationsFor gas chromatography and non-aqueous titrations.

PyridineLow Water Content

Solvent Specifications | Pyridine Burdick & Jackson Solvent Guide 139

AS327-1

1L Bottle

AS327-0100

100mL Bottle

332-1 332-4

1L Bottle 4L Bottle


B&J Brand®






BioSyn®





140 Burdick & Jackson Solvent Guide Solvent Specifications | Pyridine

CS332-56 CS332-200


BN333-20BB333-4




BioSyn®




Suggested ApplicationsFor production-scale biosynthetic applications using pressuredelivery and other applications requiring extremely low water content.


Anhydrous



Residue Less than five mg/LPurity Greater than 99.8% by GC analysis


Pyridine

Solvent Specifications | Pyridine Burdick & Jackson Solvent Guide 141

BC333-56 BC333-200


AS332-1

1L Bottle

AS332-0100

100mL Bottle

ACS/HPLC Certified

SpecificationsMeets ACS SpecificationsWater Less than 0.05%

by Karl Fischer titrationRefractive index 1.5097 ± 0.0012 at 20°CResidue Less than three mg/LPurity Greater than 99.8% by GC analysisAmines Passes test (less than 10 ppm)by ninhydrin testSolubility in water Passes testChloride Less than 0.001%Sulfate Less than 0.001%Ammonia Less than 0.002%Copper Passes test (limit five ppm)Reducing substances Passes test

Suggested ApplicationsFor applications requiring ACS Reagent Grade solvent.

Pyridine



of packaging


Tetrahydrofuran UVContains No Preservative

142 Burdick & Jackson Solvent Guide Solvent Specifications | Pyridine

AH332-4

4L Bottle

AH332-4PC

4L PVC-Coated

340-1 340-4

1L Bottle 4L Bottle

NP340-20 NS340-20


B&J Brand®

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400





B&J Brand®




of packaging


Tetrahydrofuran UVContains No Preservative

B&J Brand

SpecificationsPacked under nitrogenPreservative 250 ppm butylated hydroxytoluene



For spectrophotometric applications,use Tetrahydrofuran UV (ProductNumber 340).

Refractive index 1.4070 ± 0.0005 at 20°CPurity Greater than 99.9% by GC analysisPeroxides Less than two mg/L as H2O2 at time

of packaging

Suggested ApplicationsFor GPC and gas chromatography.

TetrahydrofuranNon-Spectrophotometric GradeContains BHT Preservative

Solvent Specifications | Tetrahydrofuran Burdick & Jackson Solvent Guide 143

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



CS340-56 CS340-200


341-1 341-4

1L Bottle 4L Bottle

NP341-10

10L NOWPak

NS341-20

20L NOWPak II

NP341-20

20L NOWPak



B&J Brand®


SpecificationsPacked under nitrogenPreservative 250 ppm butylated hydroxytoluene


by Karl Fischer titrationUltraviolet absorbance Optical transparancy is not controlled.

For spectrophotometric applications,use Tetrahydrofuran UV (Product Number CS340).

Refractive index 1.4070 ± 0.0005 at 20ºCPurity Greater than 99.9% by GC analysisPeroxides Less than two mg/L as H2O2 at time

of packaging


TetrahydrofuranNon-Spectrophotometric GradeContains BHT Preservative

BioSyn®

SpecificationsPreservative 250 ppm butylated hydroxytoluene

(BHT)Water Less than 100 ppm

by Karl Fischer titrationUltraviolet absorbance Optical transparency is not controlledRefractive index 1.4070 ± 0.0005 at 20°CPurity Greater than 99.9% by GC analysisPeroxides Less than two mg/L as H2O2 at time

of packaging


TetrahydrofuranLow Water ContentContains BHT Preservative

144 Burdick & Jackson Solvent Guide Solvent Specifications | Tetrahydrofuran

CS341-200

200L SSPDS

BN343-20BB343-4



BioSyn®



(BHT)Water Less than 100 ppm

by Karl Fischer titrationUltraviolet absorbance Optical transparency is not controlledRefractive index 1.4070 ± 0.0005 at 20°CPurity Greater than 99.9% by GC analysisPeroxides Less than two mg/L as H2O2 at time

of packaging

Suggested ApplicationsFor production-scale biosynthetic applications using pressuredelivery and other applications requiring exremely low water content.

TetrahydrofuranLow Water ContentContains BHT Preservative

Anhydrous



Residue Less than three mg/LPurity Greater than 99.9% by GC analysisPeroxides Less than 10 ppm as H2O2 at time

of packaging


TetrahydrofuranContains No Preservative

Solvent Specifications | Tetrahydrofuran Burdick & Jackson Solvent Guide 145

BC343-56 BC343-200


AS340-1

1L Bottle

AS340-0100

100mL Bottle

Anhydrous


(BHT)Appearance ClearColor (APHA) Less than 10Water Less than 50 ppm


Residue Less than three mg/LPurity Greater than 99.9% by GC analysisPeroxides Less than 10 ppm as H2O2 at time

of packaging


TetrahydrofuranContains BHT Preservative

146 Burdick & Jackson Solvent Guide Solvent Specifications | Tetrahydrofuran

AS341-1

1L Bottle

AS341-0100

100mL Bottle

ACS/HPLC Certified

SpecificationsMeets ACS SpecificationsPreservative NoneWater Less than 0.03%

by Karl Fischer titrationUV cutoff 212 nmRefractive index 1.4070 ± 0.0005 at 20°CResidue Less than three mg/LPurity Greater than 99.8% by GC analysisPeroxides Less than two mg/L as H2O2 at time

of packagingColor (APHA) Less than 20


TetrahydrofuranContains No Preservative


-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



AH340-4PC

4L PVC-Coated

AH340-4

4L Bottle

Purified Plus®

SpecificationsMeets ACS SpecificationsPreservative 250 ppm butylated hydroxytoluene


by Karl Fischer titrationRefractive index 1.4070 ± 0.0010 at 20°CResidue after Less than 0.03%evaporationAssay Greater than 99.9% by GC analysisColor (APHA) Less than 20Peroxide Less than two mg/L as H2O2 at time

of packagingPlease inquire if you have any additional specificationrequirements.


TetrahydrofuranContains BHT Preservative

B&J Brand®


by Karl Fischer titrationUV cutoff 284 nmRefractive index 1.4967 ± 0.0004 at 20°CResidue Less than one mg/LBenzene Less than 500 mg/LPurity Greater than 99.8% by GC analysisElectron capture GC No residue peak greater than

two µg/L as heptachlor epoxide

Suggested ApplicationsFor HPLC, gas chromatography, pesticide residue analysis,spectrophotometry and liquid scintillation counting.

Toluene

Solvent Specifications | Toluene Burdick & Jackson Solvent Guide 147

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



PP341-19 PP341-204


347-1 NS347-20347-4


NP347-10

10L NOWPak

NP347-20

20L NOWPak


B&J Brand®



by Karl Fischer titrationUV cutoff 284 nmRefractive index 1.4967 ± 0.0004 at 20°CResidue Less than one mg/LBenzene Less than 500 mg/LPurity Greater than 99.8% by GC analysis


Toluene


BioSyn®


by Karl Fischer titrationUV cutoff 284 nmRefractive index 1.4967 ± 0.0004 at 20ºCResidue Less than one mg/LPurity Greater than 99.9% by GC analysis

Suggested ApplicationsFor production-scale biosynthetic applications using pressuredelivery and other applications requiring extremely low water content.

TolueneLow Water Content

148 Burdick & Jackson Solvent Guide Solvent Specifications | Toluene

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




CS347-56 CS347-200


BN346-20 BC346-56 BC346-200

20L NOWPak II 56L SSPDS 200L SSPDS

Anhydrous





Toluene

ACS/HPLC Certified


by Karl Fischer titrationUV cutoff 284 nmRefractive index 1.4967 ± 0.0004 at 20°CResidue Less than three mg/LPurity Greater than 99.8% by GC analysisColor (APHA) Less than 10Substances darkened Passes testby sulfuric acidSulfur compounds Less than 0.003% as S


Toluene

Solvent Specifications | Toluene Burdick & Jackson Solvent Guide 149

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




AS347-1

1L Bottle

AS347-0100

100mL Bottle

AH347-4PC

4L PVC-Coated

AH347-4

4L Bottle

Purified Plus®


by Karl Fischer titrationRefractive index 1.4967 ± 0.0010 at 20°CResidue after Less than five mg/LevaporationAssay Greater than 99.8% by GC analysisColor (APHA) Less than 10Substances darkened Passes testby sulfuric acidSulfur compounds Less than 0.003% as SPlease inquire if you have any additional specificationrequirements.


Toluene

B&J Brand®


by Karl Fischer titrationUV cutoff 308 nmRefractive index 1.5716 ± 0.0005 at 20ºCPurity Greater than 98.0% by GC analysis

Suggested ApplicationsFor GPC, gas chromatography and spectrophotometry.

1,2,4-Trichlorobenzene

150 Burdick & Jackson Solvent Guide Solvent Specifications | Toluene

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



PP347-19 PP347-204


348-4

4L Bottle



BioSyn®

SpecificationsAppearance Clear, colorless liquidWater Less than 0.2%


Suggested ApplicationsFor biosynthetic applications and HPLC mobile phasemodification.

Triethylamine

BioSyn


by Karl Fischer titrationUV cutoff 210 nmPurity Greater than 99.5% by titration

Suggested ApplicationsFor biosynthetic applications and HPLC mobile phasemodification.

Trifluoroacetic Acid

Solvent Specifications | Trifluoroacetic Acid Burdick & Jackson Solvent Guide 151

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400

UV Absorbance(0.1% Solution in Water)Wavelength, nm210230250300

Specifications

MaximumAbsorbance1.0000.1500.0100.005

BB359-1

1L Bottle

BB359P100

100mL Bottle

BB360P500

500mL Bottle

BB360P050

50mL Bottle


B&J Brand®Water


HPLC Certified

Burdick & Jackson HPLC Water has undergone rigorouspurification in order to ensure its suitability for gradientelution HPLC. Negligible UV absorbance makes it the bestchoice for your critical requirements.

SpecificationsNote: HPLC Water does not fall under ACS Certification.UV cutoff 190 nmRefractive index 1.3330 ± 0.0010 at 20°CResidue Less than three mg/LHPLC gradient elution No UV absorbing peak greater than

0.015 absorbance unit at 200 nm in agradient from 100% water to 100%acetonitrile on a 15 cm x 4.6 mm HLDC8 column after an initial loading of 20 mL water

Microbial None detected by epifluorescencecontamination microscopy at time of packagingSpecific conductance Less than 2.0 micromhos at 25°CSubstances reducing Passes testpermanganateTotal organic carbon Less than 50 ppb

Water

152 Burdick & Jackson Solvent Guide Solvent Specifications | Water

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400



365-4 NP365-10


NP365-20

20L NOWPak

AH365-4

4L Bottle

Suggested ApplicationsFor gradient elution high-performance liquid chromatography(HPLC) and spectrophotometry.

Burdick & Jackson™ High Purity Water has undergonerigorous purification in order to ensure its suitability forgradient elution HPLC and other demanding chromatographicapplications. Negligible UV absorbance and extremely loworganic carbon and particulates make it the best choice foryour critical requirements.

SpecificationsUV cutoff 190 nm

Refractive index 1.3330 ± 0.0010 at 20°C

Residue Less than one mg/L

Microbial None detected by epifluorescencecontamination microscopy at time of packaging

Purity by liquid No UV absorbing peak greater thanchromatography 0.005 absorbance unit at 200 nm in a

gradient from 100% water to 100%acetonitrile on a 15 cm x 4.6 mm HLDC8 column with 5 µm packing after aninitial loading of 20 mL water


Suggested ApplicationsFor HPLC and spectrophotometry.



B&J Brand®


by Karl Fischer titrationUV cutoff 288 nmRefractive index 1.5050 ± 0.0010 at 20°CResidue Less than one mg/LPurity Greater than 95.0% o-xylene and

99.0% xylenes by GC analysis


o-Xylene

Solvent Specifications | o-Xylene Burdick & Jackson Solvent Guide 153

370-1 370-4

1L Bottle 4L Bottle

NP370-20

20L NOWPak

-0.1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

190 220 250 280 310 340 370 400




PURE FACTS

The World Energy Council estimates

that two terawatts (2TW) — twice

the current annual global energy

production — could be harvested

from the world’s wave power. If

0.1% of renewable energy within

the oceans could be converted

into electricity, it would satisfy the

present worldwide annual demand

for energy five times over.

Solvent Properties

B&J Solvent Properties Table 156

B&J Solvent Miscibility Table 157

CH3

B&J Solvent Properties Table

156 Burdick & Jackson Solvent Guide Solvent Properties | B&J Solvent Properties Table

Viscosity Boiling Miscibility UV Cutoff Polarity Eluotropic Values (�°) Refractive Flash DensitySolvent (cP at 20°C) Point (°C) Number (M) (nm) Index (P') Alumina C18 Silica Index (at 20°C) Point (°F) (at 20°C)

Acetone 0.36 56.29 15, 17 330 5.1 0.56 8.8 0.53 1.3586 -4 0.7900Acetonitrile 0.38* 81.60 11, 17 190 5.8 0.65 3.1 0.52 1.3441 42 0.7822n-Butyl Acetate 0.74 126.11 22 254 4.0 1.3942 72 0.8796n-Butyl Alcohol 2.98 117.5 15 215 3.9 0.7 1.3993 98 0.8097n-Butyl Chloride 0.45 78.44 220 1.0 0.26 0.20 1.4021 15 0.8862Chlorobenzene 0.80 131.69 21 287 2.7 0.30 1.5248 82 1.1058Chloroform 0.57 61.15 19 245 4.1 0.40 0.26 1.4458 1.4892Cyclohexane 1.0 80.72 28 200 0.2 0.04 0.03 1.4262 -4 0.7785Cyclopentane 0.44 49.26 198 0.1 0.05 1.4064 19 0.7454o-Dichlorobenzene 1.32† 180.48 295 2.7 1.5514 151 1.3058Dichloromethane 0.44 39.75 20 233 3.1 0.42 0.30 1.4241 1.326Dimethyl Acetamide 2.14 166.1 268 6.5 1.4384 158 0.9415N,N-Dimethylformamide 0.92 153.0 12 268 6.4 7.6 1.4305 136 0.9487Dimethyl Sulfoxide 2.24 189.0 9 268 7.2 0.62 1.4793 190 1.10041,4-Dioxane 1.37 101.32 17 215 4.8 0.56 11.7 0.51 1.4224 54 1.0336Ethyl Acetate 0.45 77.11 19 256 4.4 0.58 0.48 1.3724 24 0.9006Ethyl Alcohol 1.10† 78.32 210 1.3614 59 0.7892Ethyl Ether 0.24 34.55 23 215 2.8 0.38 0.43 1.3524 -49 0.7133Ethylene Dichloride 0.79 83.48 228 3.5 0.49 1.4448 56 1.253Heptane 0.42 98.43 29 200 0.1 0.01 1.3876 25 0.6837Hexane 0.31 68.7 29 195 0.1 0.01 0.01 1.3749 -7 0.6594Iso-Octane 0.50 99.24 29 215 0.1 1.3914 10 0.6919Isobutyl Alcohol 107.7 15 220 4.0 1.3959 82 0.8016Isopropyl Alcohol 2.4 82.26 15 205 3.9 0.82 8.3 0.6 1.3772 53 0.7854Isopropyl Myristate 192.6 1.4332 327 0.8532Methanol 0.59 64.7 12 205 5.1 0.95 1.0 0.70 1.3284 52 0.7913Methyl t-Butyl Ether 0.27 55.2 210 2.5 0.35 0.48 1.3689 -18 0.7405Methyl Ethyl Ketone 0.43 79.64 17 329 4.7 0.51 1.3788 16 0.8049Methyl Isobutyl Ketone 0.58 117.4 334 4.2 0.43 1.3957 64 0.8008N-Methylpyrrolidone 1.67† 202.0 285 6.7 1.4700 187 1.0304Pentane 0.23 36.07 190 0.0 0.00 0.00 1.3575 -56 0.6262Petroleum Ether 0.1 1.3650 -57 0.64n-Propyl Alcohol 2.3 97.2 210 4.0 0.82 10.1 1.3856 74 0.8037Propylene Carbonate 241.7 220 6.1 1.4210 275 1.2006Pyridine 0.95 115.25 16 5.3 0.71 1.5102 68 0.9832Tetrahydrofuran 0.55 66.0 17 212 4.0 0.45 3.7 0.53 1.4072 6 0.888Toluene 0.59 110.62 23 284 2.4 0.29 0.22 1.4969 40 0.86691,2,4-Trichlorobenzene 213.5 308 1.5717 222 1.454Triethylamine 0.36† 89.5 1.4010 16 0.7276Trifluoroacetic Acid 0.93 71.8 210 1.2850 1.4890Water 1.00 100.0 190 10.2 1.3330 0.9982o-Xylene 0.81 144.41 288 2.5 0.26 1.5054 63 0.8802

* at 15°C† at 25°C

Missing values indicate data was not available.

Miscibility (M) number:1. All pairs whose M numbers differ by 15 units or less are miscible in all proportions at 15°C.2. Each pair whose M number difference is 16 has a critical solution temperature between 25 and 75°C, generally about 50°C.3. A difference of 17 or more corresponds to immiscibility or to a critical solution temperature above 75°C.

Solvent Properties | B&J Solvent Miscibility Table Burdick & Jackson Solvent Guide 157

Acetone

Acetonitrile

n-Butyl Alcohol

Chloroform

Cyclohexane

Dichloromethane


Dimethyl Sulfoxide

1,4-Dioxane

Ethyl Acetate

Ethyl Alcohol

Ethyl Ether

Ethylene Dichloride

Heptane

Hexane

Iso-Octane

Isopropyl Alcohol

Methanol

Methyl t-Butyl Ether

Methyl Ethyl Ketone

Pentane

Tetrahydrofuran

Toluene

Water

o-Xylene

Miscible

Immiscible

Any two B&J solvents are designatedto be miscible if they can be mixedtogether in all proportions withoutforming two separate phases.

B&J Solvent Miscibility Table

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