Study on Electronic Properties of Composite Clusters toward Nanoscale Functional Advanced Materials

Atsushi NakajimaBull. Chem. Soc. Jpn. 2013, 86, 414–437.

Toward an Atomic-Level Understanding of Size-Specific Properties of Protected and Stabilized Gold Clusters

Tatsuya Tsukuda

Electroconductive π-Junction Au Nanoparticles

Masayuki Kanehara; Jun Takeya; Takafumi Uemura; Hideyuki Murata; Kazuo Takimiya; Hikaru Sekine; Toshiharu Teranishi

Nanooptical Studies on Physical and Chemical Characteristics of Noble Metal Nanostructures

Hiromi OkamotoBull. Chem. Soc. Jpn. 2013, 86, 397–413.

doi: 10.1246/bcsj.20120298

doi: 10.1246/bcsj.20110227

doi: 10.1246/bcsj.20120103

doi: 10.1246/bcsj.20120268

Award Accounts Open Access

Open Access Award Accounts

Nanoclusters

CSJ Journal Report

H. Okamoto

Nanocluster Surface

photon/ spin

Gas Phase Synthesisof Composite Clusters

Na

Al13

SAMSelf-Assembled

Monolayer

Substrate

Selective Soft-Landing

-1

+2+2

+2+2

-2-2-2-1

SubstrateMolecular Self-Assembly

100 nm 200 nm

gold nanorod gold nanosphere dimers

E

Award Accounts Open Access

A. Nakajima

Carrier Conduction

e-

Open Access Selected Papers

M. Kanehara

T. Tsukuda

Near-Field Nanooptics

Composite Clusters

Au Nanoparticles

Size-Controlled Au Clusters

− 1 −

Bull. Chem. Soc. Jpn. 2012, 85, 957–961.

Bull. Chem. Soc. Jpn. 2012, 85, 151–168.

CSJ Journal Report

Eff ect of Charge of a Matrix Polymer on the Electronic States of Single-Walled Carbon Nanotubes

Yasuhiko Hirana; Yasuro Niidome; Naotoshi Nakashima

Formation of Au Nanostructure by Electrodeposition in a Mesoporous Silica Film with Interconnected Cage-Type Mesopores

Yosuke Kanno; Kazuyuki Kuroda

Fabrication and Photocatalytic Properties of TiO2 Nanotube Arrays Modifi ed with Phosphate

Kazuya Nakata; Baoshun Liu; Yosuke Ishikawa; Munetoshi Sakai; Hidenori Saito; Tsuyoshi Ochiai; Hideki Sakai; Taketoshi Murakami; Masahiko Abe; Katsuhiko Takagi; Akira Fujishima

CVD Synthesis of Highly Graphitized Single-walled Carbon Nanotubes Using Nitrogen-pretreated Fe–Mo/MgO Catalyst

Gaurav Patil; Chetan Sarode; Rahul Patil; Suresh Gokhale

doi: 10.1246/bcsj.20120116

doi: 10.1246/bcsj.20120358

doi: 10.1246/cl.2011.1107

doi: 10.1246/cl.2012.871

BCSJ Award Article

Letter

Editor’s Choice Open Access

Selected Papers

Nanotubes

S. Gokhale

Open Access

Mesoporous Materials

Nitrogen pretreatment of Fe–Mo/MgO catalyst promotes the growth of SWNTs. It enhances the structural features, graphitization, and thermal properties of the nanotubes.

TiO2 nanotube arrays prepared by anodization in HF/H3PO4 mixed electrolyte show highly efficient photocatalytic decomposition of acetaldehyde. The combined morphology of the TiO2 nanotubes and presence of phosphorus ions on their surface may contribute to their excellent photocatalytic performance.

N. Nakashima

K. Kuroda

K. Nakata

Nanoarchitectonics for Mesoporous Materials

Katsuhiko Ariga; Ajayan Vinu; Yusuke Yamauchi; Qingmin Ji; Jonathan P. Hill

doi: 10.1246/bcsj.20110162 Open Access Accounts

K. Ariga

Solubilized SWNT

Graphitized SWNT

TiO2 Nanotube

Silica Film

Nanoarchitectonics

− 2 −

Bull. Chem. Soc. Jpn. 2012, 85, 1262–1267.

Chem. Lett. 2012, 41, 871–873.

Bull. Chem. Soc. Jpn. 2013, 86, 583–585.

Bull. Chem. Soc. Jpn. 2012, 85, 1–32.

Chem. Lett. 2011, 40, 1107–1109.

Supramolecules

Metal–Organic Frameworks (MOF)

Organic FET

CSJ Journal Report

Bioinspired Supramolecular Materials

Masato Ikeda

Organic Single-Crystal Transistors Based on π-Extended Heteroheptacene Microribbons

Yu Seok Yang; Takuma Yasuda; Chihaya Adachi

Control over Flexibility of Entangled Porous Coordination Frameworks by Molecular and Mesoscopic Chemistries

Shuhei Furukawa; Yoko Sakata; Susumu Kitagawa

Elaborate Metallosupramolecular Architectures through Desymmetrization Self-assembly of Symmetric Building Blocks

Takashi Nakamura; Hitoshi Ube; Mitsuhiko Shionoya

doi: 10.1246/bcsj.20120254

doi: 10.1246/bcsj.20120178

doi: 10.1246/cl.130357

doi: 10.1246/cl.130189

Award Accounts

BCSJ Award Article

Highlight Review

Open Access

Open Access

M. Shionoya

Highlight Review

M. Ikeda

T. Yasuda

S. Kitagawa

Nanospace

Bioinspired Materials

Single-Crystal Transistors

Entangled Porous Frameworks

− 3 −

Chem. Lett. 2013, 42, 328–334.

Bull. Chem. Soc. Jpn. 2013, 86, 10–24.

Chem. Lett. 2013, 42, 570–576.

Bull. Chem. Soc. Jpn. 2012, 85, 1186–1191.

C–H Bond Activation

CSJ Journal Report

Cu–Rh Redox Relay Catalysts for Synthesis of Azaheterocycles via C–H Functionalization

Shunsuke Chiba

Oxidative C–H/C–H Coupling of Azine and Indole/Pyrrole Nuclei: Palladium Catalysis and Synthesis of Eudistomin U

Atsushi D. Yamaguchi; Debashis Mandal; Junichiro Yamaguchi; Kenichiro ItamiChem. Lett. 2011, 40, 555–557.

Ruthenium-catalyzed Oxidative Alkenylation of Arenes via Regioselective C–H Bond Cleavage Directed by a Nitrogen-containing Group

Yuto Hashimoto; Takumi Ueyama; Tatsuya Fukutani; Koji Hirano; Tetsuya Satoh; Masahiro Miura

doi: 10.1246/cl.2012.1554

doi: 10.1246/cl.2011.555

doi: 10.1246/cl.2011.1165

Highlight Review

Editor’s Choice

Letter

Open Access

N

N2 cat. [Cp*RhCl2]2 cat. Cu(OAc)2

AcOH

DMF, 90 °C

NR'

R"

R

H

R

NOAc

R'

R"

+

cat. [Cp*RhCl2]2 cat. Cu(OAc)2

DMF, 60 °C

NR'

R"

RR

Oximessyn -anti mixtures

H

Cu-Rh relay catalysts

R'

R"

+

Vinyl Azides2 Cu(I)

2 Cu(II) Rh(I)

Rh(III)process Ireduction

process IIoxidationS. Chiba

K. Itami

M. Miura

Cu–Rh Redox Catalysis

Pd Catalysis

Ru Catalysis

− 4 −

Chem. Lett. 2011, 40, 1165–1166.

Chem. Lett. 2012, 41, 1554–1559.

Cross Coupling

Efficient Synthesis

C–C Bond Activation

CSJ Journal Report

Cross-coupling Reactions of Organoboranes: An Easy Method for C–C Bonding

Akira Suzuki; Yasunori Yamamoto

1,3-Dipolar Cycloaddition-based Synthesis of Diverse Heterocyclic Scaffolds

Wei Zhang

Nickel/Lewis Acid-Catalyzed Carbocyanation of Unsaturated Compounds

Yoshiaki Nakao

Kumada–Tamao–Corriu Coupling of Alkyl Halides Catalyzed by an Iron–Bisphosphine Complex

Takuji Hatakeyama; Yu-ichi Fujiwara; Yoshihiro Okada; Takuma Itoh; Toru Hashimoto; Shintaro Kawamura; Kazuki Ogata; Hikaru Takaya; Masaharu Nakamura

doi: 10.1246/cl.2011.894

doi: 10.1246/cl.130504

doi: 10.1246/bcsj.20120081

doi: 10.1246/cl.2011.1030

Highlight Review

Highlight Review

Award Accounts

Letter

Open Access

Open Access

Open Access

B R B B RC B

X R X X RCR-X

R-B

C-X

C-

NH

R1

CO2R

R2

NR3

O

O

R1

N

NHO

OR2

R3

O

R2

N N

O

O R4

N

O

O

N

R1 CO2R

O

OR3

H

R2

R1

R4 R3

[3+2] adductsN

O

ON

R2'

N

O

O

R2

R3 R3'R1

C CNR R

C CNRR+

Ni/Lewis acidcooperative

catalysis

Alkyl X + Alkyl Ar

cat. [FeCl2(SciOPP)](0.5–3.0 mol%)

THF, 25–40 °Cslow additionX = Cl, Br, I

ArMgBr PP

t-Bu

t-Bu

t-Bu

t-Bu

t-Bu

t-Bu

t-Bu

t-Bu

Fe

Cl Cl

[FeCl2(SciOPP)]

74–98% yield10 examples

A. Suzuki

W. Zhang

Y. Nakao

M. Nakamura

Suzuki Coupling

1,3-Dipolar Cycloaddition

Ni/Lewis Acid Catalysis

Fe Catalysis

− 5 −

Chem. Lett. 2011, 40, 894–901.

Chem. Lett. 2011, 40, 1030–1032.

Chem. Lett. 2013, 42, 676–681.

Bull. Chem. Soc. Jpn. 2012, 85, 731–745.

Asymmetric Catalysis

CSJ Journal Report

Stable Axial Chirality in Metal Complexes Bearing 4,4ʹ-Substituted BIPHEPs: Application to Catalytic Asymmetric Carbon–Carbon Bond-Forming Reactions

Kohsuke Aikawa; Yoshitaka Miyazaki; Koichi Mikami

Asymmetric Induction Arising from Enantiomerically Enriched Carbon-13 Isotopomers and Highly Sensitive Chiral Discrimination by Asymmetric Autocatalysis

Tsuneomi Kawasaki; Kenso Soai

Chemistry of Concerto Molecular Catalysis Based on the Metal/NH Bifunctionality

Takao Ikariya

Platinum Metals in the Catalytic Asymmetric Isomerization of Allylic Alcohols

Luca Mantilli; Clément Mazet

doi: 10.1246/bcsj.20110309

doi: 10.1246/bcsj.20110120

doi: 10.1246/bcsj.20100249

doi: 10.1246/cl.2011.341

Selected Papers

Award Accounts

Award Accounts

Highlight Review

Open Access

Open Access

Ph2P

PPh2

PdCl2

R

steric and electronic effect

t1/2 at 27 °C

R = t-Bu: 7 years

H: 17 years

Pd cat*

O

H CO2Et

OH

CO2EtOO

SiMe3

O

F3C 2Et CO2Et

HO CF3

0.05 mol%

Pd cat*

0.01 mol%

Pd cat*

up to 98% ee

up to 98% ee

+

+

TOF 58,200 h-1

R

CF3: 56 years

*

chirally stable

CO

X ∗ Y

12C 13C

Chiral Carbon Isotopomer

X ∗ Y

13C 12C

N

N

t-Bu

CHON

N

t-Bu

∗

OH

+ i-Pr2Zn

Asymmetric Autocatalysiswith Amplification of ee

R2 OH

R1

R2 O

R1

R3 R3

H/R4 H/R4Rh

Ru

Ir

K. Mikami

K. Soai

T. Ikariya

C. Mazet

C– C Bond-Forming Reactions

Asymmetric Autocatalysis

M/NH Bifunctional Catalysis

Asymmetric Isomerization

− 6 −

Bull. Chem. Soc. Jpn. 2012, 85, 201–208.

Bull. Chem. Soc. Jpn. 2011, 84, 879–892.

Chem. Lett. 2011, 40, 341–344.

Bull. Chem. Soc. Jpn. 2011, 84, 1–16.