· web viewmaleic anhydride 108-31-6 ใช เป น additives 211 sodium tartrate 6106-24-7...

แบบสอบถามขอมลเพอนำามาปรบปรงประกาศกระทรวงสาธารณสข (ฉบบท 295) พ.ศ. 2548

เรอง กำาหนดคณภาพหรอมาตรฐานของภาชนะบรรจททำาจากพลาสตก

ขอมลทวไปของผใหขอมล

1. ชอ-นามสกล ...............................................................................................................................................................

ตำาแหนง................................................................................... เบอรโทรศพท...........................................................

เบอรโทรสาร..............................................................................E-mail address ……………………………….…………….2. บรษท...........................................................................................................................................................................

ทอย............................................................................................................................................................................. .............................................................................................................................................................................

เบอรโทรศพท..............................................................................เบอรโทรสาร………………..………………………………….ผผลต เปนผผลตพลาสตกชนด PET เปนผผลตพลาสตกชนด HDPE เปนผผลตพลาสตกชนดอน (โปรดระบ).............................................................................................................

หนา 1 จาก 78

เปนผผลตภาชนะบรรจ /วสดสมผสอาหารททำาจากพลาสตกชนด PET เปนผผลตภาชนะบรรจ /วสดสมผสอาหารททำาจากพลาสตกชนด HDPE เปนผผลตภาชนะบรรจ /วสดสมผสอาหารททำาจากพลาสตกชนดอน (โปรดระบ)………………………………………………………………….. ผนำาเขา เปนผนำาเขาพลาสตกชนด PET เปนผนำาเขาพลาสตกชนด HDPE เปนผนำาเขาพลาสตกชนดอน (โปรดระบ) เปนผนำาเขาภาชนะบรรจ /วสดสมผสอาหารททำาจากพลาสตกชนด PET เปนผนำาเขาภาชนะบรรจ /วสดสมผสอาหารททำาจากพลาสตกชนด HDPE เปนผนำาเขาภาชนะบรรจ /วสดสมผสอาหารททำาจากพลาสตกชนดอน (โปรดระบ)…………………………………………………..…………..

คำาอธบายแบบสอบถามน จดทำาขนเพอใชประกอบการปรบปรงประกาศกระทรวง

สาธารณสข วาดวยเรอง กำาหนดคณภาพหรอมาตรฐานของภาชนะบรรจททำาจากพลาสตก ในประเดนการทบทวนพจารณาอนญาตภาชนะบรรจพลาสตกททำาจากเมดพลาสตกรไซเคล โดยเบองตนไดมขอเสนอจากภาคอตสาหกรรมใหการพจารณาอนญาตภาชนะบรรจททำาจากพลาสตกรไซเคลชนดพอลเอทลนเทเรฟทาเลต (Polyethylene terephthalate; PET) และ ชนดพอลเอทลนความ หนาแนนสง (High Density Polyethylene; HDPE)

ดงนน สำานกงานคณะกรรมการอาหารและยาจงมความจำาเปนตองสอบถามขอมลเกยวกบสารตงตน สารเคมทผประกอบการมการใชในการผลตพลาสตกทง 2 ชนด เพอใชเปนขอมลในการพจารณากำาหนดหรอมาตรฐานความปลอดภยสำาหรบภาชนะททำาจากพลาสตกทง 2 ชนด ตอไป โดยเบองตน ไดรวบรวมขอมลสารเคมทอาจมการใชในการผลตพลาสตกชนด PET และชนด HDPE ทงกรณทเปนเมดพลาสตก virgin และเมดพลาสตกรไซเคล รวมถงสารเคมทอาจมการใชสารเคมในการผลตเปนภาชนะบรรจททำาจากพลาสตกทง 2 ชนด

ทงน สำานกงานคณะกรรมการอาหารและยา จะนำาขอมลทไดรบจากการสอบถามครงน จดทำาเปนขอมลและขอเสนอใหกบคณะทำางาน คณะอนกรรมการดานวชาการ คณะอนกรรมการดานบรหารจดการ คณะกรรมการอาหาร พจารณาตามขนตอนการจดทำากฎหมายตอไป


โปรดใหขอมลและขอคดเหนตามเอกสารแนบ และตอบแบบสอบถามตามทแนบมาน

Polyethylene terephthalate; PET ขอ 1. ทานมการใชสารเคมเหลานในการผลตเมดพลาสตกชนด PET ทงกรณทเปน virgin PET และ recycled PET หรอใชในการผลตภาชนะบรรจ /วสดสมผสอาหารททำาจากพลาสตกชนด virgin PET หรอไม หากมการใชโปรดระบ ในตาราง

ตารางท 1 สารเคมทใชในการผลต [อางอง Voluntary Standards PL (Positive Lists) Japan Hygienic Olefin and Styrene Plastics Association]

Substance CAS No.

หมายเหต virgin

PETrecycled PET

ภาชนะบรรจจาก

virgin PET

กรณใชในการผลตโปรดระบ



1 พลวง (Antimony) 7440-36-0

2 เจอรเมเนยม (Germanium) 7440-56-4

3 Terephthalic acid 100-21-0

ใชเปน Base polymer

4 Dimethyl terephthalate 120-61-6


5 Ethylene glycol 107-21-1


6 Bis (2 hydroxyethyl) terephthalate

959-26-2


7 Adipic acid 124-04-9

ใชเปน acid component

8 Isophthalic acid 121-91-5


9 Dimethyl isophthalate 1459-93-4


10

Sebacic acid 111-20-6



Substance CAS No.


PETrecycled PET


virgin PET




11

Trimellitic anhydride 552-30-7


12

Diethylene glycol 111-46-6

ใชเปน Diol component

13

1,4-butanediol 110-63-4


14

Neopentyl glycol 126-30-7


15

1,4-cyclohexane dimethanol

105-08-8

16

Polyethylene glycol 25322-68-3

17

Trimethylol propane หรอ 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol

77-99-6

ใชเปน starting substance และ additive

18

Dimethyl 2,6-naphthalene dicarboxylic acid

840-65-3

19

Unsaturated fatty acid(C18) dimer hydrogenated

68783-41-5

20

Poly{oxyterephthaloyloxy-alt-[ethylene;(2,2-dimethylethylene)-2,4,8,10-tetraoxaspiro[5,5]undecane-3,9- diyle (1,1-dimethylethylene)]

-

21

phosphoric acid 7664-38-2

-

22

Phosphorous acid - ใชเปน catalyst

23

Calcium -

2 Magnesium -หนา 4 จาก 78

Substance CAS No.


PETrecycled PET


virgin PET




425

Lithium -

26

Zinc -

27

Cobalt -

28

Manganese -

29

Titanium -

30

Antimony -

31

Germanium -

32

Aluminium -

33

Potassium sorbate 590-00-1

ใชเปน Additives: Stabilizers (Metallic Compounds)

34

Cobalt neodecanoate 27253-31-2


35

Cobalt stearate 13588-84-0


36

Cobalt octoate 136-52-7


37

Epoxydized soybean oil 8013-07-8

ใชเปน Additives: Stabilizers (Epoxy compounds)

8013- ใชเปน Additives: หนา 5 จาก 78

Substance CAS No.


PETrecycled PET


virgin PET




07-8 Stabilizers (Epoxy compounds)

8013-07-8


38

Epoxydized linseed oil 8016-11-3


39

3-(2-Xenoxyl)-1,2-epoxypropane

7144-65-2


40

Poly[6-[(1,1,3,3-tetramethyl butyl)amino]-1,3,5-triazine-2,4-diyl]-[(2,2,6,6-tetramethyl-4- piperidyl)-imino]hexamethyl-ene[(2,2,6,6-tetramethyl-4- piperidyl) imino]

71878-19-8

ใชเปน Additives: Stabilizers (Nitrogen Compounds)

70624-18-9


41

2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-hexyloxyphenol

147315-50-2


42

Cyclohexane-1,1’-methylenebis[4-isocyanato-, homopolymer, cyclohexylamine-terminated

- ใชเปน Additives: Stabilizers (Nitrogen Compounds)

43

Distearylpentaerythritol diphosphite or cyclic neopentane tetraylbis (octadecylphosphite)

3806-34-6

ใชเปน Additives: Stabilizers (Phosphor Compounds)


Substance CAS No.


PETrecycled PET


virgin PET




44

Tris(2,4-di-t-butylphenyl) phosphite

31570-04-4


45

Mixture of 1,1,3-Tris(2-methyl-4-di-tridecylphsphite- 5-t-butylphenyl) butane and diphenylphosphite

6895897-4


46

Cyclic neo pentanetetrayl bis(2,4-di-t butylphenylphophite)

26741-53-7


47

Bis (2,4-bis(1-methyl-1-phenylethyl) phenoxy)- 2,4,8,10-teraoxa-3,9-diphosphaspiro[5.5]undecane

154862-43-8


48

Bis(2,6di-tert-butyl-4-methylphenyl) pentaerythritol diposphite

80693-00-1


49

Carbethoxymethyl diethyl phosphonate

867-13-0


50

Dilauryl-3,3’-thiodipropionate

123-28-4

ใชเปน Additives: Stabilizers (Sulfur Compounds)

51

Distearyl-3,3’-thiopropionat

693-36-7

ใชเปน Additives: Stabilizers (Sulfur Compounds)

52

Butylated hydroxytoluene

128-37-0

ใชเปน Additives:


Substance CAS No.


PETrecycled PET


virgin PET




Stabilizers (Phenolic Compounds)

53

n-Octadecyl-beta-(4’-hydroxy-3’,5'-di-t- butylphenyl)propionate

29874-14-4

ใชเปน Additives: Stabilizers (Phenolic Compounds)

54

Calcium salt of monoethyl 3,5-di-t-butyl-4-hydroxybenzyl-phosphonate

65140-91-2


55

Triethyleneglycolbis-3-(3-t-butyl-4-hydroxy-5-methyl phenyl) propionate

36443-68-2


56

N,N’-propane-1,3-diylbis[3-(3,5-di-tert-butyl-4- hydroxyphenyl)propionamide]

69851-61-2


57

1,3,5-Trimethyl-2,4,6-tris(3,5-di-t-butyl-4 hydroxybenzyl) benzene

1709-70-2


58

Tetrakis(methylene-3-[3’,5'-di-t-butyl-4'- hydroxyphenyl] propionate)methane

6683-19-8


59

1,3,5-Tris(3’,5'-di-t-butyl-4'-hydroxybenzyl)-s-triazine-2,4,6-(1H,3H,5H)trione

27676-62-6


60

2-Hydroxy-4-methoxybenzophenone

157-57-7

ใชเปน Additives: Stabilizers (UV Absorbers)


Substance CAS No.


PETrecycled PET


virgin PET




61

2,2'-Dihydroxy-4-methoxybenzophenone

157-53-3


62

2-Hydroxy-4-n-octoxybenzopehenone

1843-05-6


63

p-t-Butylphenylsalicylate

87-78-3


64

2-(2’-Hydroxy-5’ methylphenyl)benzotriazole

2440-22-4


65

2-(2’-Hydroxy-3'-t-butyl-5'-methyl phenyl)-5-chlorobenzotriazole

3986-11-5


66

Phenylsalicylate 118-55-8


67

2-(2H-Benzotirazole-2-yl)-4,6-bis(1methyl-1- phenylethyl) phenol

70321-86-7


68

4-Benzoxazoyl-(2)-4’-[5-methyl -benzoxazoyl-(2)] stilbene

5242-49-9


69

2,2’-methylenebis[6-(2H-benzotriazol-2-yl)-4- (1,1,3,3-tetramethylbutyl)phenol]

102597-45-1


70

2,4-di-t-butyl-6-(5-chloro-benzotriazol-2yl)phenol

3864-99-1


7 2-Cyano-3,3- 6197- ใชเปน Additives: หนา 9 จาก 78

Substance CAS No.


PETrecycled PET


virgin PET




1 diphenylacrylic acid 2-ethylhexyl ester

30-4 Stabilizers (UV Absorbers)

72

Carbon black 1333-86-4

ใชเปน Additives: Stabilizers (Other Adjuvants)

73

Methyl p-oxybenzoate 99-76-3


74

Propyl p-oxybenzoate 94-13-3


75

Sorbic acid 110-44-1


76

Glycerin fatty acid esters

31566-31-1

ใชเปน Additives: Surface Active Agents

77

Sorbitan fatty acid (C8-C22) esters

1338-43-8


77

Sucrose fatty acid (C8-C22) esters

- ใชเปน Additives: Surface Active Agents

78

Citric acid mono-(di- or tri-) stearyl ester


79

Pentaerythritol fatty acid (C8-C18) esters

205243-77-2


80

Polyglycerin fatty acid (C8-C22) esters

9007-48-1



Substance CAS No.


PETrecycled PET


virgin PET




Surface Active Agents

81

Polyoxyethylene (20 moles) sorbitan fatty acid (C12-C18) esters

9005-67-8


82

Polyethylene glycol fatty acid (C8-C22) esters

9004-99-3

ใชเปน Additives: Surface Active Agents9004-

99-083

Polyoxyethylene fatty alcohol (C12-C20) ethers

69013-19-0


84

Polyoxyethylene (4-14 moles) fatty alcohol (C5-C18) ethers

9002-93-1


85

Polyoxyethylene (4-50 moles) alkyl( C7) phenyl ethers


86

N,N-Bis(2-hydroxyethyl) fatty (C8-C18) amine

10213-78-2


87

Condensates of fatty acids (C12-C18) with diethanol amine

120-40-1


88

Polyoxypropylene polyoxyethylene block copolymer

9003-11-6


89



90

Polypropylene glycol 25322-69-4


91

Polyethylene oxide 25322-68-3



Substance CAS No.


PETrecycled PET


virgin PET




Surface Active Agents

92

Isopropyl alcohol 67-63-0


93

Reaction product of N,N-dimethylaminoethyl methacrylate-2-hydroxyethyl methacrylate-methyl methacrylate copolymer with sodium monochloroacetate

72765-59-4


94

N-2-hydroxyethyl-N-(2-hydroxyalkyl) amine

84836-93-1


84-156975-13-4

95

Ethanol 64-17-5


96

Alkyl (C10-C20) sulfates(Na) salts

977180-90-7


87-097

Alkyl (C9-C20) benzene sulfonates (Na) salts

68411-30-3


98

Dodecyl benzene sulfonates (Mg, Zn)


99

Alkyl naphthalene sulfonic acid Na salt

577-11-7



Substance CAS No.


PETrecycled PET


virgin PET




100

Sodium dialkyl(C4-C16) sulfosuccinate


101

Alkyl (C12-C16) sulfates (Na) salts

151-47-7


102

Polyoxyethylene fatty alcohol (C12-C20) ether sulfates (Na, NH4)


103

Polyoxyethylene (4-50 moles) alkyl ( C7) phenylether sulfates (Na, NH4)

55348-40-8


104

Fatty acid (C8-C22) salts (Na, K)


105

Dimethyl dialkyl (C8-C18) ammonium chloride

61789-77-3


61789-80-8


106

Carboxymethyl cellulose and its sodium salt

9000-11-7


107

Methyl Cellulose 9004-67-5


108

Polyvinyl alcohol 9002-89-5


109

Polyvinyl pyrrolidone 9003-39-8



Substance CAS No.


PETrecycled PET


virgin PET




110

Polyvinylpolypyrrolidone

25249-54-1


111

Liquid paraffin 8002-74-2

ใชเปน Additives: Slippery Agents

112

Synthetic paraffin 8002-74-2


113

Petroleumwax 8002-74-2


63231-60-7


114

Polyethylene wax 9002-88-4


115

Hydrogenated polybutene

68937-10-0


116

Higher fatty acid (C8-C22)

- ใชเปน Additives: Slippery Agents

117

Higher fatty acid (C8-C22) aluminum salts

637-12-7


118

Higher fatty acid (C8-C22, Ricinol) calcium salts

1592-23-0


119

Higher fatty acid (C8-C22) magnesium salts

557-04-0


120

Higher fatty acid (C18)zinc salts

557-05-1


12

Behenic acid zinc salts - ใชเปน Additives:


Substance CAS No.


PETrecycled PET


virgin PET




1 Slippery Agents122

Straight-chain fatty monohydric alcohols (C8-C18)

56-81-5


123

Glycerin 56-81-5


124

Propylene glycol 57-55-6


125

Triethylene glycol 112-27-6


126

Higher fatty acid (C4-C22) esters of straight-chain fafty monohydric alcohols (C2-C18)


127

Ethanediol montan wax acid ester

68476-05-1


128

1,3-Butanediol esters of montan wax acids

68308-29-2


129

Isobutyl stearate 646-13-9


130

Polyester of adipic acid and lauric acid with propylene glycol

42615-42-9


27194-74-7


131

Polyester of adipic acid with octanol, I ,3-butylene glycol and 1,4-butylene glycol


13

Rice bran wax 3016-60-2



Substance CAS No.


PETrecycled PET


virgin PET




2133

Hydrogenated castor oil

8001-78-3


134

Carnauba wax 8015-86-9


135

Acetylated monoglycerides

68990-54-5


136

Ethylene bis-fatty acid (C18) amide

110-31-6


110-30-5


137

Higher fatty acid (C8-C22) amide


138

Dimethyl polysiloxane 63148-62-9


139

Methyl phenyl polysiloxane

9005-12-5


140

Montan wax acid 506-48-9


141

Montan wax acid sodium salt


142

Montan wax acid calcium salt

68308-22-5


143

Magnesium oxide 1309-48-4

ใชเปน Additives: Fillers

1 Aluminium oxide 1344- ใชเปน Additives: หนา 16 จาก 78

Substance CAS No.


PETrecycled PET


virgin PET




44

28-1 Fillers

145

Silicon oxide 7631-86-9


146

Calcium oxide 1305-78-8


147

Titanium oxide 13463-67-7


148

Chromium oxide (lll) 1308-38-9


149

lron oxide 1309-37-1

lron (III) oxide


150

Zinc oxide 1314-13-2


151

Cobalt oxide 1308-06-1


152

Niobium oxide 1313-96-8


153

Nickel oxide 12035-36-8


154

Antimony oxide 1327-33-9 antimony trioxide


1309-64-4 antimony trioxide



Substance CAS No.


PETrecycled PET


virgin PET




1314-60-9 Antimony(V) oxide


155

Tungsten oxide 1314-35-8


156

Tin oxide with Antimony doped

68187-54-2


12673-86-8


157

Titan yellow 8007-18-9


158

Cobalt blue 1345-16-0


159

Antimony trioxide 1309-64-4


160

Silicon dioxide, silanated

1309-64-4 Antimony trioxide


161

Manganese oxide 1313-13-9


162

Aluminium hydroxide 21645-51-2


163

Magnesium carbonate 546-93-0


164

Calcium carbonate 471-34-1


1 Calcium sulfate 7778- ใชเปน Additives: หนา 18 จาก 78

Substance CAS No.


PETrecycled PET


virgin PET




65

18-9 Fillers

166

Barium sulfate 7727-43-7


167

Sodium silicate 1344-09-8


168

Magnesium silicate 1343-88-0


169

Aluminium silicate 12068-56-3


170

Calcium silicate 1344-95-2


171

Aluminosilicate (Ca) (Zeolite)

68989-22-0


172

Aluminium and calcium silicates

1344-00-9


173

Silicates or mixed silicates of sodium, potassium, calcium, magnesium, aluminium and iron

- ใชเปน Additives: Fillers

174

Mica 12001-26-2


175

Clay 1332-58-7


176

Diatomaceus earth 7631-86-9



Substance CAS No.


PETrecycled PET


virgin PET




177

Kaolin (porcelain clay) 1332-58-7


178

Talc 14807-96-6


179

Glass (glass fibers /glass microballs)


180

Cellulose 7782-42-5


181

Graphite 1309-37-1


182

Sienna 1309-37-1


977139-25-5

183

Raw sienna 1309-37-112000-57-6


184

Calcined amber - ใชเปน Additives: Fillers

185

Complex oxide pigments


186

Aluminium 7429-90-5


187

Silver 7440-22-4


1 Copper 7440- ใชเปน Additives: หนา 20 จาก 78

Substance CAS No.


PETrecycled PET


virgin PET




88

50-8 Fillers

189

ทองเหลอง (Brass) 12597-71-6


190

Zinc sulfide 8053-60-9


191

Ultramarine 1314-98-3


192

Carbon fibres 57455-37-5


193

Magnesium-sodium-fluoride-Silicate

37296-97-2


194

Citric acid 77-92-9

ใชเปน Additives: Blowing Agents

195

Aliphatic (≤C7) hydrocarbons

- ใชเปน Additives: Blowing Agents

196

Sodium hydroxide 1310-73-2

ใชเปน Additives

197

Potassium hydroxide 1310-58-3


198

Sodium carbonate 144-55-8


199

Potassium carbonate 584-08-7


20

Magnesium chloride 100043-52-4



Substance CAS No.


PETrecycled PET


virgin PET




0201

Sodium sulfate 7757-82-6


202

Magnesium sulfate 7487-88-9


203

Magnesium sulfate anhydride

7487-88-9


204

Burntalum 1043-67-1


205

Aluminium sulfate 10043-01-3


206

Sodium acetate 127-09-3


207

Sodium benzoate 532-32-1


208

Potassium acetate 127-08-2


209

Magnesium acetate 142-72-3


210

Maleic anhydride 108-31-6


211

Sodium tartrate 6106-24-7


212

Pyromellitic (1,2,4,5-Benzenetetracarboxylic) anhydride

89-32-7



Substance CAS No.


PETrecycled PET


virgin PET




213

Hydrotalcite 11097-59-9


214

Cyclodextrin(α,ß,f) 10016-20-3


7585-39-917465-86-0

215

Polyphosphoric acids 8017-16-1


216

Boron nitride 10043-11-5


217

methacrylic acid, methyl esterหรอ methyl methacrylate

80-62-6

ใชเปน starting substance

218

methacrylic acid, 2,3-epoxypropyl ester หรอ glycidyl methacrylate

106-91-2


219

Tin(IV) Oxide (CAS Reg. No. 18282-10-5)

18282-10-5

FCN Notifications

220

Phosphonic acid, [[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl]-, diethyl esterหรอ diethyl[[3,5-bis (1,1-dimethylethyl)-4-hydroxyphenyl]methyl] phosphonate

976-56-7

FCN NotificationsEU : ใชเปน Additives

22

Phenol,2,2'-methylenebis(6-(2H-

103597-45-1

FCN Notifications


Substance CAS No.


PETrecycled PET


virgin PET




1 benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyly)

222

2-Propenoic acid, 2-cyano-3,3-diphenyl-,2,2-bis{[(2-cyano-1-oxo-3, 3-diphenyl-2-propenyl)oxy]methyl}-1,3-propanediyl ester

178671-58-4

FCN Notifications

223

Octadecanoic acid, 1-(12-acetyloxy)-, 2,3-bis(acetyloxy) propyl ester; 1-(12-acetoxystearoyl)-2,3-diacetyl glycerolหรอ glycerides, castor-oil mono-, hydrogenated, acetates

736150-63-3


224

2,2'-(1,4-Phenylene)bis[4H-3,1-benzoxazin-4-one]หรอ 2,2′-(1,4-phenylene)bis[4H-3,1-benzoxazin-4-one]

18600-59-4

ใชเปน starting substance

225

Nylon MXD6 blended with the Montmorillonite atlevels not exceed 5wt%, the Montmorillonite (CAS Reg. No. 1318-93-0) surface treated witheither quaternary ammonium compounds,(hydrogenated tallow

- FCN Notifications･For use as a gas barrier in monolayer PET bottles.


Substance CAS No.


PETrecycled PET


virgin PET




alkyl)bis (hydroxyethyl) methyl chlorides (CAS Reg. No. 68607-27-2) or 1-octadecanaminium, N, N-bis(2-hydroxyethyl)-Nmethylchloride (CAS Reg. No. 3010-24-0).

ขอ 2 ทานมการใชสารเคมเหลานในการผลตเมดพลาสตกชนด PET ทงกรณทเปน virgin PET และ recycled PET หรอใชในการผลตภาชนะบรรจ /วสดสมผสอาหารททำาจากพลาสตกชนด virgin PET หรอไม หากมการใชโปรดระบ ในตารางตารางท 2 รายชอสารท EU อนญาตใหใชเฉพาะในพลาสตกชนด PET จำานวน 24 รายการ (Only use in PET)

Substance CAS No.

หมายเหต virgin PET

recycled PET


virgin PET




Only use in PET in EU1 Polyethylene glycol (EO

= 1-30, typically 5) ether of butyl 2-cyano 3-(4-hydroxy-3-

- ใชเปน additive or polymer production aid


Substance CAS No.


recycled PET


virgin PET




methoxyphenyl) acrylate

2 Polyethyleneglycol (EO = 1-30, typically 5) ether of butyl-2- cyano-3-(4-hydroxyphenyl) acrylate


3 2-aminobenzamide 88-68-6

ใชเปน additive or polymer production aid

4 Resorcinol diglycidyl ether

101-90-6

ใชเปน Use as monomer or other starting substance

5 N-(2-aminoethyl) ethanolamine

111-41-1

ใชเปน monomer or other starting substance

6 2-aminoethanol 141-43-5

ใชเปน additive or polymer production aidใชเปน monomer or other starting substance

7 Iron phosphide 12751-22-3


8 Charcoal, activated 64365-11-3,7440-44-0


9 Mono-n-dodecyltintris (isooctyl mercaptoacetate)

67649-65-4



Substance CAS No.


recycled PET


virgin PET




10

Di-n-dodecyltinbis(isooctyl mercaptoacetate)

84030-61-5


11

N,N′-bis[4-(ethoxycar-bonyl)phenyl]-1,4,5,8-naphtha lenetetracarboxydiimide

132459-54-2

ใชเปน co-monomer

12

Glycolic acid 79-14-1


13

Triethyl phosphonoacetate

867-13-0


14

Titanium nitride, nanoparticles


15

N-(2,6-di isopropylphenyl)-6-[4- (1,1,3,3-tetramethyl butyl)phenoxy]-1H-benzo[de]iso quinolin-1,3(2H)-dione

852282-89-4


16

(ethyl acrylate, methyl methacrylate) copolymer

9010-88-2


17

Cyclic oligomers of (butylene terephthalate)

263244-54-8


18

Trimethylolpropane, mixedoctanoic and n-decanoic acids


19

(Polyethylene terephthalate,

-. ใชเปน additive or polymer


Substance CAS No.


recycled PET


virgin PET




hydroxylated polybutadiene, pyromellitic anhydride) copolymer

production aid

20

Diethyl[[3,5-bis(1,1-dimethyl ethyl)-4-hydroxyphe-nyl]methyl]phosphonate

976-56-7


21

Mixturecomposedof 97% tetraethyl orthosilicate (TEOS) with CAS No 78-10-4 and 3 % hexamethyldisilazane (HMDS) with CAS No 999-97-3

- ใชเปน Use as monomer or other starting substance

22

[3-(2,3-epoxypropoxy)propyl] trimethoxy silane

2530-83-8


23

amines, bis(hydrogenated tallow alkyl) oxidised

143925-92-2


24

poly(12-hydroxystearic acid)-polyethyleneimine copolymer

124578-12-7


25

mixture composed of 97 % tetraethyl orthosilicate (TEOS) with CAS No 78- 10-4 and 3 % hexamethyldisilazane (HMDS) with CAS No 999-97-3



ขอ 3. กรณทานมการใชสารเคมทนอกเหนอจากทระบในตารางท 1 และ 2 ในการผลตเมดพลาสตกชนด PET ทงกรณทเปน virgin PET และ recycled PET หรอใชในการผลตภาชนะบรรจ /วสดสมผสอาหารททำาจากพลาสตกชนด virgin PET โปรดระบขอมล

Substance CAS. No.

หมายเหตFunction of

use

ใชในการผลต

virgin PET


recycled PET


ภาชนะบรรจจาก virgin PET


Substance CAS. No.


use


virgin PET


recycled PET


ภาชนะบรรจจาก virgin PET

High Density Polyethylene; HDPE ขอ 4. ทานมการใชสารเคมเหลานในการผลตเมดพลาสตกชนด HDPE ทงกรณทเปน virgin HDPE และ HDPE หรอใชในการผลตภาชนะบรรจ /วสดสมผสอาหารททำาจากพลาสตกชนด virgin HDPE หรอไม หากมการใชโปรดระบ ในตาราง ตารางท 3 สารเคมทใชในการผลต [อางอง Voluntary Standards PL

(Positive Lists) Japan Hygienic Olefin and Styrene Plastics Association]Substance CAS

No.หมายเหต virgi

n HDPE

recycled

HDPEภาชนะบรรจจาก

virgin HDPE




1 5-ethylidene-2-norbornene หรอ

16219-75-3

ใชเปน monomer or other starting


Substance CAS No.


HDPErecycled


virgin HDPE




5-ethylidenebicyclo[2,2,1] hept-2-ene

substance

2 5-methylene-2-norbornene

694-91-7


3 Vinyl alcohol 9002-89-5


4 vinyl acetate 108-05-4


5 Acrylic acid 79-10-7


6 Methacrylic acid 108-31-6


7 vinyltrimethoxysilane 2768-02-7


8 Potassium sorbate 24634-61-5

ใชเปน additive : Stabilizers (Metallic Compounds)

9 Zinc 2-ethylhexoate 136-53-8


10

Calcium 12-hydroxystearate

3159-62-4


11

Calcium stearyl-2-lactylate

5793-94-2



Substance CAS No.


HDPErecycled


virgin HDPE




12

Cobalt distearate 1002-88-6


13

Epoxydized soybean oil

8013-07-8

ใชเปน additive : Stabilizers (Epoxy Compounds)

14

Epoxydized linseed oil 8016-11-3


15

Epoxydized octyl stearate (Including isooctyl ester)

106-84-3


16

3-(2-Xenoxyl)-1,2-epoxypropane

7144-65-2


17

urea 57-13-6

ใชเปน additive : Stabilizers (Nitrogen Compounds)ใชเปน starting substance

18

Condensate of dimethyl succinate with 2-(4-hydroxy-2,2,6,6-tetramethylpiperidine) ethanol

65447-77-0

ใชเปน additive : Stabilizers (Nitrogen Compounds)

19

Poly[[6-[(1,1,3,3-tetramethylbutyl) amino]-1,3,5-triazine-2,4-diyll [(2,2,6,6-tetramethyl-4-piperidyl) imino] examethylene[(2,2,6,6-tetramethyl-4-

71878-19-8


70624-18-9



Substance CAS No.


HDPErecycled


virgin HDPE




piperidyl)imino]]20

Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate

52829-07-9


21

N,N',N'',N'''-Tetrakis(4,6-bis(butyl-(N-methyl-2,2,6,6-tetramethylpiperidin-4-yl)amino)-triazin-2-yl)-4,7-diazadecan-1,10-diamine

106990-43-6


22

Condensate of dibutylamine-1,3,5-triazine-N,N'-bis(2,2,6,6-tetramethyl-4-piperidil‐1,6‐hexamethylenediamine-N-(2,2,6,6-tetramethyl-4-piperidil)butylamineหรอpoly-[[6-[N-(2,2,6,6-tetramethyl-4-piperidinyl)-n-butylamino]-1,3,5-triazine-2,4-diyl][(2,2,6,6-tetramethyl-4-piperidinyl)imino]-1,6-hexanediyl[(2,2,6,6-tetramethyl-4-piperidinyl) imino]]-α-[N,N,N′,N′-tetrabutyl-″-(2,2,6,6-tetramethyl-4-piperidinyl)-″-[6-

192268-64-7



Substance CAS No.


HDPErecycled


virgin HDPE




(2,2,6,6-tetramethyl-4-piperidinylamino)-hexyl]-[1,3,5-triazine-2,4,6-triamine]-ω-N,N,N′,N′-tetrabutyl-1,3,5-triazine-2,4-diamine]

23

1-[2-{3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy}ethyl]-4-{3-(3,5-di-tbutyl-4-hydroxyphenyl) propionyloxy}-2,2,6,6-tetramethylpiperidine

073754-27-5


24

7-Oxa-3,20-diazadispiro-[5.1.11.2]-heneicosan-21-one,2,2,4,4-tetramethyl-,hydrochloride, reaction products with epichlorohydrin, hydrolyzed, polymerized

202483-55-4


25

Cyclohexane, 1, 1'-methylenebis[4-isocyanato-,homopolymer, cyclohexylamine-terminated

315207-86-4


26

Poly{3-eicosyl(tetracosyl)-1-[2,2,6,6-tetramethylpyperidine-4-yl]pyrolydine-2,5-di-one}

- ใชเปน additive : Stabilizers (Nitrogen Compounds)


Substance CAS No.


HDPErecycled


virgin HDPE




27

Tris(mixed, mono- and di-) nonylphenylphosphite

54771-30-1

ใชเปน additive : Stabilizers (Phosphor Compounds)

Distearylpentaerythritol diphosphite or cyclic neopentane tetraylbis (octadecylphosphite)

3806-34-6


28

Tris(2,4-di-t-butylphenyl)phosphiteหรอphosphorous acid, tris(2,4-di-tert-butylphenyl)ester

31570-04-4


29

4,4'-Butylidene-bis(3-methyl-6-t-butyl phenyl-ditridecyl phosphite)หรอ4,4′-butylidene-bis(6-tert-butyl-3-methylphenyl-ditridecyl phosphite)

13003-12-8


30

Mixture of 1,1,3-Tris(2-methyl-4-ditridecylphosphite-5-t-butylphenyl) butane and diphenyl phosphite

68958-97-4


31

Tetrakis(2,4-di-t-butylphenyl)-4,4'-biphenylenediphosphinate

38613-77-3


32

Cyclic neopentanetetraylbis(2,4-di-

26741-53-7

ใชเปน additive : Stabilizers (Phosphor


Substance CAS No.


HDPErecycled


virgin HDPE




tbutylphenylphophite) Compounds)33

2-t-Butyl-α-(3-t-butyl-4-hydroxyphenyl)-pcumenylbis(p-nonylphenyl)phosphite

20227-53-6


34

Tris-[2-(2,4,8,10-tetrabutyl-5,7-dioxa-6-phosphodibenzo{a,c}cyclohepten-6-yl-oxy)-ethyl]amineหรอ2,2′,2′-nitrilo(triethyl tris(3,3′,5,5′-tetra-tert-butyl-1,1′-bi-phenyl-2,2′-diyl) phosphite)

80410-33-9


35

Bis-[2-methyl-bis-(1,1-dimethylethyl)phenyl]ethylphophiteหรอphosphorous acid, bis(2,4-di-tert-butyl-6-methylphenyl) ethyl ester

145650-60-8


36

Bis(2,4-bis(1-methyl-1-phenylethyl) phenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecaneหรอbis(2,4-dicumylphenyl) pentaerythritol-diphosphite

154862-43-8


37

6-[3-(3-t-Butyl-4-hydroxy-5-methylphenyl) propoxy]-

203255-81-6



Substance CAS No.


HDPErecycled


virgin HDPE




2,4,8,10-tetra-t-butyldibenz[d,f][1,3,2]Dioxaphosphepinหรอ3,3′,5,5′-tetrakis(tert-butyl)-2,2′-dihydroxybiphenyl, cyclic ester with [3-(3-tert-butyl-4-hydroxy-5-methylphenyl) propyl]oxyphosphonous acid

38

9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide

35948-25-5


39

4,6-di-tert-butyl-m-cresol, reaction products with biphenyl –phosphorus trichloride reaction products ; predominant product: bis [bis (2,4-di-tertbutyl-5-methylphenoxy) phosphino] biphenyl

178358-58-2


40

Bis(2,6-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphite

80693-00-1


41

2,2'-methylenebis(4,6-di-tert-butylphenyl)-2-ethylhexyl phosphite

126050-54-2


42

Dilauryl-3,3'-Thiodipropionate

123-28-4

ใชเปน additive : Stabilizers (Sulfur


Substance CAS No.


HDPErecycled


virgin HDPE




หรอthiodipropionic acid, didodecyl ester

Compounds)

43

Dimyristyl-3,3'-thiopropionateหรอ thiodipropionic acid, ditetradecyl ester

16545-54-3

ใชเปน additive : Stabilizers (Sulfur Compounds)

44

Distearyl-3,3'-thiopropionateหรอ thiodipropionic acid, dioctadecyl ester

693-36-7


45

Dioctadecylsulphite รอ dioctadecyl disulphide

2500-88-1


46

Butylated hydroxytolueneหรอ 2,6-di-tert-butyl-p-cresol

128-37-0

ใชเปน additive : Stabilizers (Phenolic Compounds)

47

4-Hydroxymethyl-2,6-di-t-butylphenolหรอ thiodipropionic acid, ditetradecyl ester

16545-54-3


48

2,6-Di-t-butyl-4-ethylphenol


49

n-Octadecyl- beta -(4'-hydroxy-3',5'-di-tbutylphenyl) propionate

29874-14-4


50

Tocopherol 59-02-9

10191-41-0



Substance CAS No.


HDPErecycled


virgin HDPE




51

2,4-Bis(octylthiomethyl)-6-methyl phenol

110553-27-0


52

2,4-bis[(dodecylthio)methyl]-6-methyl phenol

110675-26-8


53

2,2-Methylenebis(4-methyl-6-t-butyl phenol)

119-47-1


54

2,2'-Methylenebis(4-ethyl-6-t-butyl phenol)

88-24-4


55

4,4'-methylenebis(2,6-di-t-butyl phenol)

118-82-1


56

4,4'-Butylidenebis(6-t-butyl-m-cresol) or 1,1-bis(2'-methyl-4'-hydroxy-5'-t-butylphenyl)butane

85-60-9


57

4,4'-Thiobis(6-t-butyl-m-cresol) or 4,4'-thiobis(3-methyl-6-t-butylphenol)

96-69-5


58

N,N'-Hexamethylenebis(3,5-di-t-butyl-4-hydroxyhydrocinnamide)

23128-74-7


59

Calcium salt of monoethyl 3,5-di-t-butyl-4-hydroxybenzyl-

65140-91-2



Substance CAS No.


HDPErecycled


virgin HDPE




phosphonate60

2,2'-Oxamidebis[ethyl-3-(3,5-di-t-butyl-4-hydroxy phenyl) propionate]

70331-94-1


61

2,2'-Ethylidenebis(4,6-di-t-butyl phenol)

35958-30-6


62

1,1,3-Tris(2-methyl-4-hydroxy-5-t-butyl phenyl)butane

1843-03-4


63

2-Propenoic acid, 2-1(1,1-dimethylethyl)-6-3[[3-(1,1-dimethylethyl)-2-hydroxy-5-methylphenyl]methyl]-4-methyl phenyl ester

61167-58-6


64

1,3,5-Trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl) benzene

1709-70-2


65

Tetrakis(methylene-3-[3',5'-di-t-butyl-4'-hydroxyphenyl] propionate) methaneหรอ pentaerythritol tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)-propionate]

6683-19-8


66

2,2' -Methylenebis [6-(1-methylcyclohexyl)-p-cresol]

77-62-3

ใชเปน additive : Stabilizers (Phenolic


Substance CAS No.


HDPErecycled


virgin HDPE




หรอ 2,2′-methylenebis(4-methyl-6-(1-methylcyclohexyl)phenol)

Compounds)

67

Glycol ester of bis[3,3-bis(4'-hydroxy-3'-tbutylphenyl) butanoic acid]หรอ ethylene glycol bis[3,3-bis(3-tert-butyl-4-hydroxyphenyl)butyrate]

32509-66-3


68

[2-(1,1-Dimethylethyl)-6-[[3-(1,1-dimethylethyl)-2-hydroxy-5-methyl phenyl] methyl]-4-methylphenyl]-1 ,4-benzenedicarbonateหรอ terephthalic acid, diester with 2,2′-methylenebis(4-methyl-6-tert-butylphenol)

57569-40-1


69

N,N-Bis[3-(3,5-di-t-butyl-4-hydroxy phenyl)propionyl] hydrazineหรอ N,N′-bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl)hydrazide

32687-78-8


70

3,9-Bis{2-[3-(3-t-butyl-4-hydroxy-5-

90498-90-1

ใชเปน additive : Stabilizers


Substance CAS No.


HDPErecycled


virgin HDPE




methylphenyl) propionyloxy]-1,1-dimethylethyl}-2,4,8,10- tetraoxaspiro [5.5] undecane

(Phenolic Compounds)

71

1,3,5-Tris(3',5'-di-t-butyl-4'-hydroxy benzyl)-striazine-2,4,6-(1H,3H,5H) trione

27676-62-6


72

1,3,5-Tris(4-t-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)trione

40601-76-1


73

1,3,5-Tri-2-propenyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione

1025-15-6


74

2-[4,6-Bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(octyloxy)phenol

2725-22-6


75

2,4-di-tert-pentyl-6-(1-(3,5-di-tert-pentyl-2-hydroxyphenyl)ethyl)phenyl acrylate

123968-25-2


76

2-Hydroxy-4-methoxybenzophenone

131-57-7

ใชเปน additive : Stabilizers (UV Absorbers)

77

2,2'-Dihydroxy-4-methoxybenzophenone

131-53-3


78

2-Hydroxy-4-n-octoxybenzophenone

1843-05-6


7 p-t- 87-18- ใชเปน additive : หนา 42 จาก 78

Substance CAS No.


HDPErecycled


virgin HDPE




9 Butylphenylsalicylate 3 Stabilizers (UV Absorbers)

80

2,4-Di-t-butylphenyl-3,5-di-t-butyl-hydroxybenzoateหรอ 3,5-di-tert-butyl-4-hydroxy benzoic acid, 2,4-di-tert-butylphenyl ester

4221-80-1


81

2-(2'-Hydroxy-5'-methylphenyl)benzotriazole

2440-22-4


82

2-(2'-Hydroxy-3'-t-butyl-5'-methyl phenyl)-5-chlorobenzotriazole

3986-11-5


83

2,5-Bis [5'-t-butyl benzoxazolyl-(2)]thiophene

7128-64-5


84

Nickel salt of bis(monoethyl 3,5-di-t-butyl-4-hydroxybenzyl- phosphonate)

30947-30-9


85

Mixture of 2-ethoxy-5-t-butyl-2'-ethyloxalic acid bisanilide(85-90%) and 2-ethoxy-5-t-butyl-2'-ethyl-4'-tbutyloxalic acid bis-anilide(15-10%)

35001-52-6


86

Poly[(6-morpholino-s-triazine-2,4-diyl)[(2,2,6,6-tetramethyl-4-piperidyl) imino]hexamethylene [(2,2,6,6-tetramethyl-

82451-48-7



Substance CAS No.


HDPErecycled


virgin HDPE




4-piperidyl) imino)]87

4-benzoxazoyl-(2)-4'-[5-methyl-benzoxazoyl-(2)]-stilbene

5242-49-9


88

1,6-Hexanediamine, N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-, Polymers with morpholine-2,4,6-trichloro-1,3,5-triazine

193098-40-7


89

Copolymer with 2-(2'-hydroxy-5'-methacryloxyethyl-phenyl)-2H-Benzotriazol and methylmethacrylate

- ใชเปน additive : Stabilizers (UV Absorbers)

90

Carbon black 1333-86-4

ใชเปน additive : Stabilizers (Other Adjuvants)

91

Methyl p-oxybenzoate 99-76-3


92

Propyl p-oxybenzoate 94-13-3


93

Sorbic acid 110-44-1


94

triisopropanolamine 122-20-3


95

Reaction products of 3-Hydroxy-5,7-ditert. butylbenzo-furan-2-on with o-Xylene

181314-48-7



Substance CAS No.


HDPErecycled


virgin HDPE




96

Glycerin fatty acid esters

31566-31-1

ใชเปน additive : Surface Active Agents

97

Sorbitan fatty acid (C8-C22)esters

1338-43-8


98

Propylene glycol fatty acid (C8-C22) esters

067784-83-2067784-79-6026403-62-3


99

Sucrose fatty acid (C8-C22)esters

- ใชเปน additive : Surface Active Agents

100

Citric acid mono- (di-or tri-) stearyl esters

- ใชเปน additive : Surface Active Agents (Nonionic Surface Active Agents)

101

Pentaerythritol fafty acid (C8-C18)esters

205243-77-2


102

Trimethylol propane fatty acid (C8-C18)esters

130-68-9


103

Polyglycerin fatty acid (C8-C22) esters

9007-48-1


104

Polyoxyethylene (20 moles) glycerin fatty acid (C12-C18) esters

68201-46-7


105

Polyoxyethylene (20 moles) sorbitan fatty acid (C12-C18) esters

9005-67-8


10

Polyethylene glycol fatty acid (C8-C22)

9004-99-3

ใชเปน additive : Surface Active


Substance CAS No.


HDPErecycled


virgin HDPE




6 esters 9004-99-0

Agents

107

Polypropylene glycol fatty acid (C10-C18) esters


108

Polyoxyethylene fatty alcohol (C12-C20) ethers

69013-19-0


109

Polyoxyethylene (4-14moles)fatty alcohol (C5-C18) ethers

9002-93-1


110

Polyoxyethylene (4-50 moles) alkyl(≧C7)phenyl ethers

9002-93-1


111

N,N-Bis(2-hydroxyethyl) fatty(C8-C18) amine

10213-78-2


112

Condensates of fatty acids (C12-C18)with diethanol amine

120-40-1


113

Polyoxypropylene polyoxyethylene block copolymer

9003-11-6


114



115

Polypropylene glycol 25322-69-4


116

Esters of Polyoxyethylene (5) Coconut tree amine and caprylic acid


117

Esters of Polyoxyethylene (2-3) Stearyl amine and



Substance CAS No.


HDPErecycled


virgin HDPE




Stearic acid118

Esters of Polyoxyethylene(2) oleic amine and lauric acid

52497-24-2


119

Esters of polyoxyethylene (2) stearyl amine and behenic acid


120

Polyethylene oxide 25322-68-3


121

Castor oil ethylene oxide addition compound

103479-06-7


122

Isopropyl alcoholหรอ 2-propanol

67-63-0


123

Aziridine polymer, reaction products withoxilanemethanol


124

Reaction product of N,N-dimethylaminoethyl methacrylate-2-hydroxyethyl methacrylate-methylmethacrylate copolymer with sodium monochloroacetate

72765-59-4


125

Polyoxyethylene (6) myristyamine

51230-09-2


126

N-2-hydroxyethyl-N-(2-hydroxyalkyl) amine

84836-93-1



Substance CAS No.


HDPErecycled


virgin HDPE




2615-84-1

56975-13-4

127

Ethanol 64-17-5


128

Alkyl (C10-C20) sulfates (Na, K, NH4) salts

977180-90-7

27176-87-0


129

Alkyl (C9-C20) benzene sulfonates (Na, K, NH4) salts

68411-30-3


130

Dodecyl benzene sulfonates(Mg, Zn)


131

Alkyl (C10-C20) naphthalene sulfonate Na,Salt

577-11-7


132

Sodium dialkyl (C4-C16) sulfosuccinate


133

Alkyl (C8-C20) sulfates (Na, K, NH4) salts

151-47-7


134

Polyoxyethylene fatty alcohol (C12-C20) ether sulfates (Na, NH4)

55348-40-8


135

Polyoxyethylene (4-50 moles) alkyl (≧C7) phenylether sulfates (Na, NH4)

55348-40-8


1 Fatty acid (C8-C22) - ใชเปน additive : หนา 48 จาก 78

Substance CAS No.


HDPErecycled


virgin HDPE




36

salts (Na, K, NH4) Surface Active Agents

137

Mixture of α-(p-nonylphenyl)-ω-hydroxypoly(oxyethylene)phosphate 2-hydrogene ester and 1-hydrogen ester


138

N-Acyl (C8-C18) sarcosinate

137-16-6


139

Reaction product of boric acid with glycerol monoglyceride

72905-86-3


140

Dimethyl dialkyl (C8-C18) ammonium chloride

61789-77-361789-80-8


141

Choline ester chloride of natural straight-chain fatty acid of mainly saturated C8-C18


142

Carboxymethyl cellulose and its sodium salt

9000-11-7

ใชเปน additive : Surface Active Agents (Other Adjuvants)

143

Methyl Cellulose 9004-67-5


144

Polyvinyl alcohol 9002-89-5


1 Polyacrylic acid and 9003- ใชเปน additive :


Substance CAS No.


HDPErecycled


virgin HDPE




45

its sodium salt 04-7 Surface Active Agents (Other Adjuvants)

146

Polyvinyl pyrrolidone 9003-39-8


147

Copolymer of N-Methacryloyloxyethyl-N,Ndimethylammonium-α-N-methyl carboxylate chloride sodium salt, octadecyl methacrylate, ethyl methacrylate, cyclohexyl methacrylate,N-vinyl-2-pyrrolidone

66822-60-4


148

Copolymer of Cyclohexylmethacrylate-[2-N,Ndimethyl-N-(2-Hydroxy-3-N',N',N'-Trimethylammonium-propyl)ammonium]Ethylmethacrylate=dichloride-Ethylmethacrylate-Octadecylmethacrylate

- ใชเปน additive : Surface Active Agents (Other Adjuvants)

149

Polyvinylpolypyrrolidone

25249-54-1


150

Liquid paraffin 8002-74-2

ใชเปน additive : Slippery Agents

1 Synthetic paraffin 8002- ใชเปน additive : หนา 50 จาก 78

Substance CAS No.


HDPErecycled


virgin HDPE




51

74-2 Slippery Agents

152

Synthetic isoparaffin petroleum hydrocarbons

68551-17-7


153

White mineral oil 8042-47-5


154

petrolatum 8009-03-8


155

Petroleum wax 8002-74-2,

63231-60-7


156

Microcrystalline wax 63231-60-7


157

Montan wax 8002-53-7


158

Polyethylene wax 9002-88-4


159

Odorless light hydrocarbons

- ใชเปน additive : Slippery Agents

160

Hydrogenated polybutene

68937-10-0


161

Higher fatty acid (C8-C22)

- ใชเปน additive : Slippery Agents (Higher fatty acid)

162

Higher fatty acid (C8-C22) aluminium salts

637-12-7

ใชเปน additive : Slippery Agents (Higher fatty


Substance CAS No.


HDPErecycled


virgin HDPE




acid)163

Higher fatty acid (C8-C22 and recinolic acid) calcium salts

1592-23-0

ใชเปน additive : Slippery Agents (Higher fatty acid)

164

Higher fatty acid (C8-C22) magnesium salts

557-04-0


165

Higher fatty acid (C8,C18)zinc salts

557-05-1


166

Behenic acid zinc salts - ใชเปน additive : Slippery Agents (Higher fatty acid)

167

Higher fatty acid (C8-C22) lithium salts

- ใชเปน additive : Slippery Agents (Higher fatty acid)

168

Straight-chain fatty monohydric alcohols (C8-C18)

56-81-5

ใชเปน additive : Slippery Agents (Fatty Alcohols and Polyglycols)

169

Glycerin 56-81-5


170

Propylene glycol 57-55-6


171

Pentaerythritol 115-77-5



Substance CAS No.


HDPErecycled


virgin HDPE




172

Higher fatty acid (C18) esters of straight-chain fatty alcohols (C2,C4,C5)

- ใชเปน additive : Slippery Agents (Fatty Acid Esters with Mono- and Polyhydric Alcohols)

173

Tributyl acetylcitrateหรอtri-n-butyl acetyl citrate

77-90-7

ใชเปน additive : Slippery Agents (Fatty Acid Esters with Mono- and Polyhydric Alcohols)

174

Di-2-ethylhexyl adipate

103-23-1


175

Ethanediol montan acid ester

68476-05-1


176

Poly(1,3-butanediol adipate)

24937-93-7


177

Methyl acetylricinolate

140-03-4


17

Polyester of adipic acid and lauric acid

42615-42-9



Substance CAS No.


HDPErecycled


virgin HDPE




8 with propylene glycol27194-

74-7

(Fatty Acid Esters with Mono- and Polyhydric Alcohols)

179

Polyester of adipic acid with octanol, I ,3-butylene glycol and 1,4-butylene glycol


180

Rice bran wax 3016-60-2


181

Diisodecyl adipate 27178-16-1


182

Polyesters of 1,2-propanediol and/or 1,3- and/or 1,4-butanediol and/or polypropyleneglycol with adipic acid, which may be end-capped with acetic acid or fatty acids C12-C18 or n-octanol and/or ndecanol


183

Hydrogenated edible oil and fat

- ใชเปน additive : Slippery Agents (Triglycerides and Waxes)

1 Hydrogenated castor 8001- ใชเปน additive : หนา 54 จาก 78

Substance CAS No.


HDPErecycled


virgin HDPE




84

oil 78-3 Slippery Agents (Triglycerides and Waxes)

185

Castor oil 8001-79-4

ใชเปน additive : Slippery Agents (Triglycerides and Waxes)

186

Spermaceti wax 8002-23-1


187

Carnauba wax 8015-86-9


188

Acetylated monoglycerides

68990-54-5


189

Ethylene bis-fatty acid (C16-C18) amideหรอ N,N′-ethylenebisoleamide

110-31-6

ใชเปน additive : Slippery Agents (Higher Fatty Acid Amides)

190

Ethylene bis-fatty acid (C16-C18) amideหรอ N,N′-ethylenebisstearamide

110-30-5


191

Higher fatty acid (C8-C22) amide

- ใชเปน additive : Slippery Agents (Higher Fatty Acid Amides)

192

Stearyl erucamide 10094-45-8


1 Oleyl parmmitamide 16260- ใชเปน additive : หนา 55 จาก 78

Substance CAS No.


HDPErecycled


virgin HDPE




93

09-6 Slippery Agents (Higher Fatty Acid Amides)

194

Decanedioic acid, polymer with 1,2-ethanediamine,octadecanoate

- ใชเปน additive : Slippery Agents (Higher Fatty Acid Amides)

195

Methyl hydrogene polysiloxane

63148-57-2

ใชเปน additive : Slippery Agents (Silicon Oils)

9004-73-3


196

Dimethyl polysiloxane 63148-62-9


197

Methyl phenyl polysiloxane

9005-12-5


198

Polyoxyalkylene (C2-C4) dimethyl polysiloxane

68937-54-2


199

Polyoxyethylene-grafted polydimethylsiloxane

68937–54–2


200

Linear or branched and/or cyclicorganopolysiloxanes with methyl groups alone or with n-alkyl(C2-C32), attached to the silicon atom, and their condensation products

- ใชเปน additive : Slippery Agents (Silicon Oils)

20

Rosin and its derivatives

- ใชเปน additive : Slippery Agents


Substance CAS No.


HDPErecycled


virgin HDPE




1 (Rosin and its Derivatives)

202

Rosin magnesium salt 68476-03-9

ใชเปน additive : Slippery Agents (Rosin and its Derivatives)

203

Montan wax acid sodium salt

- ใชเปน additive : Slippery Agents (Rosin and its Derivatives)

204

Mixture of benzene-1,2-dimethyl-4,5-bis(1-phenylethyl)(25-45%), Benzene-4-(1,3-diphenylbutyl)-1,2-dimethyl(20-40%), benzene[1-(3,4-dimethylphenyl)ethyl](1-phenylethyl)(25-45%)

51580-93-9

56525-86-1

57213-94-2

ใชเปน additive : Slippery Agents (Rosin and its Derivatives)

205

Magnesium oxide 1309-48-4

ใชเปน additive : Fillers (Oxides)

206

Aluminium oxide 1344-28-1


207

Silicon oxide 7631-86-9


208

Calcium oxide 1305-78-8


209

Titanium oxide 13463-67-7


210

Chromium oxide (lll) 1308-38-9



Substance CAS No.


HDPErecycled


virgin HDPE




211

lron oxide 1309-37-1 lron (III) xide


212

Zinc oxide 1314-13-2


213

Cerium dioxide 1306-38-3


214

Cobalt oxide 1308-06-1


215

Niobium oxide 1313-96-8


216

Nickel oxide 12035-36-8


217

Antimony oxide 1327-33-9

antimony trioxide1309-64-4

antimony trioxide1314-60-9

Antimony(V) oxide


218

Tungsten oxide 1314-35-8


219

Tin oxide with Antimony doped

68187-54-2

12673-86-8



Substance CAS No.


HDPErecycled


virgin HDPE




220

Titan yellow 8007-18-9


221

Cobalt blue 1345-16-0


222

Antimony trioxide 1309-64-4


223

Silicon dioxide, silanated

1309-64-4

Antimony trioxide


224

Manganese oxide 1313-13-9


225

Magnesium hydroxide 1309-42-8

ใชเปน additive : Fillers (Hydroxides)

226

Aluminium hydroxide 21645-51-2


227

Calcium hydroxide 1305-62-0


228

Magnesium carbonate 546-93-0

ใชเปน additive : Fillers (Carbonates)

229

Calcium carbonate 471-34-1


210

Zinc carbonate 12122-17-7


211

Lithium carbonate 554-13-2


2 Calcium sulfate 7778- ใชเปน additive : หนา 59 จาก 78

Substance CAS No.


HDPErecycled


virgin HDPE




12

18-9 Fillers (Sulfates)

213

Barium sulfate 7727-43-7

ใชเปน additive : Fillers (Sulfates)

214

Sodium silicate 1344-09-8

ใชเปน additive : Fillers (Silicates)

215

Magnesium silicate 1343-88-0


216

Aluminium silicate 12068-56-3


217

Calcium silicate 1344-95-2


218

Alumino silicate (Na, Ca) (Zeolite)

68989-22-0


219

Aluminium and calcium silicates

1344-00-9


220

Lithium Silicate 10102-24-6


221

Silicates or mixed silicates of sodium, potassium,calcium, magnesium, aluminium and iron

- ใชเปน additive : Fillers (Silicates)

222

Mica 12001-26-2


223

Clay 1332-58-7

ใชเปน additive : Fillers (Natural Substances)

2 Diatomaceus earth 7631- ใชเปน additive : หนา 60 จาก 78

Substance CAS No.


HDPErecycled


virgin HDPE




24

86-9 Fillers (Natural Substances)

225

Kaolin (porcelain clay) 1332-58-7


226

Talc 14807-96-6


227

Perlite 977116-39-4


228

Glass (glass fibers /glass microballs)

- ใชเปน additive : Fillers (Natural Substances)

229

Wood powder 9004-34-6


230

Cellulose 7782-42-5


231

Graphite 1309-37-1


232

Sienna 1309-37-1


977139-25-5


233

Raw sienna 001309-37-1


977139-25-5


23

Calcined amber - ใชเปน additive : Fillers (Natural


Substance CAS No.


HDPErecycled


virgin HDPE




4 Substances)235

Complex oxide pigments

- ใชเปน additive : Fillers (Coloring Material)

236

Aluminium 7429-90-5

ใชเปน additive : Fillers (Coloring Material)

237

Silver 7440-22-4


238

Copper 7440-50-8


239

Brass 12597-71-6


240

Stainless steel (Only flakes.)

12597-71-6


241

Iron 7440-02-0


242

Zinc sulfide 8053-60-9

ใชเปน additive : Fillers (Sulfides)

243

Ultramarine 1314-98-3

ใชเปน additive : Fillers

244

Carbon fibres 57455-37-5


245

Aluminium borate 11121-16-7


12005-61-7


2 Magnesium-sodium- 37296- ใชเปน additive : หนา 62 จาก 78

Substance CAS No.


HDPErecycled


virgin HDPE




46

fluoride-Silicate 97-2 Blowing Agents (Acids and Bases)

247

Azodicarbonamide 123-77-3

ใชเปน additive : Blowing Agents (Acids and Bases)

248

4,4'-Oxybis(benzenesulfonyihydrazide)

80-51-3


249

Sodium hydrogen carbonate

144-55-8


250

Citric acid 77-92-9


251

Fumaric acid 110-17-8


252

Succinic acid 110-15-6


253

Saturation aliphatic (C3-C7) hydrocarbons

- ใชเปน additive : Blowing Agents (Hydrocarbons)

254

Cycloalkanes - ใชเปน additive : Blowing Agents (Hydrocarbons)

255

Sodium hydroxide 1310-73-2

ใชเปน additive

256

Potassium hydroxide 1310-58-3


257

Sodium carbonate 144-55-8


25

Potassium carbonate 584-08-7



Substance CAS No.


HDPErecycled


virgin HDPE




8259

Magnesium chloride 100043-52-4


260

Calcium chloride 10043-52-4


261

Sodium sulfate 7757-82-6


262

Magnesium sulfate 7487-88-9


263

Magnesium sulfate anhydride

7487-88-9


264

Potassium sulfate 7646-93-7


265

Ferrous sulfate 7720-78-7


266

Burntalum 1043-67-1


267

Aluminium sulfate 10043-01-3


268

Sodium phosphate 7558-80-7


269

Calcium phosphate 7758-87-4


270

Sodium pyrophosphate

7758-16-9



Substance CAS No.


HDPErecycled


virgin HDPE




271

Aluminium tripolyphosphate

29196-72-3


272

Zinc orthophosphate 7779-90-0


273

Aluminium phosphate 7784-30-7


274

Sodium tripolyphosphate

7758-29-4


275

Zirconium phosphate 13772-29-7


276

2-2'-Methylene bis (4,6-di-tert-butylphenyl) sodium Phosphate

85209-91-2


277

Bis(2,4,8,10-tetra-tert-butyl-6-hydroxy-12Hdibenzo[d,g][1,3,2] dioxaphosphocin-6-oxide) aluminium hydroxide

151841-65-5


278

Sodium acetate 127-09-3


279

Sodium benzoate 532-32-1


280

Di-n-octyltindilaurate 3648-18-8


28

Sodium citrate 68-04-2



Substance CAS No.


HDPErecycled


virgin HDPE




1282

Sodium hypophosphite

7681-53-0


283

Dibenzylidenesorbitol 32647-67-9


284

Sodium tartrate 6106-24-7


285

Dibenzyliden sorbitol 32647-67-9


286

Di-p-tolyliden sorbitol 54689-97-4


287

Reaction Product of Sorbitol, p-chlorobenzaldehyde and p-methylbenzaldehyde Mixture of following substances,.①1,3-o-(4-Chlorobenzylidene)-2,4-o-(4-methylbenzylidene) sorbitol and 1,3-o-(4-methylbenzylidene)-2,4-o-(4-Chlorobenzylidene) sorbitol(50-65%)②1,3：2,4-bis(4-Chlorobenzylidene) sorbitol(15-30%)③1,3：2,4-bis(4-methylbenzylidene) sorbitol(15-25%)

- ใชเปน additive

2 Reaction Product of Sorbitol,

- ใชเปน additiveหนา 66 จาก 78

Substance CAS No.


HDPErecycled


virgin HDPE




88

Benzaldehyde and o,p-dimethyl benzaldehyde. Mixture of following substances,①1,3：2,4-Dibenzylidene sorbitol (15-18%)②1,3-(o,p-Dimethylbenzylidene)-2,4-benzylidene-dsorbitol and 1,3-(o,p-dimethylbenzylidene)-2,4-benzylidene-D-sorbitol(50-65%)③1,3：2,4-bis(o,p-Dimethyl benzylidene)-Dsorbitol(20-30%)

289

Hydrotalciteหรอ aluminium magnesium carbonate hydroxide

11097-59-9


290

Cyclodextrin(α, β, γ)α-dextrinβ-dextrin

10016-20-37585-39-917465-86-0


291

Sodium sulfite 7757-83-7


292

Disodium succinateหรอ di-Sodium succinate hexahydrate


293

Boron nitride 10043-11-5



Substance CAS No.


HDPErecycled


virgin HDPE




294

Di-t-butyl peroxide 110-05-4

ใชเปน additive: Radical initiator (Dialkyl Peroxides)

295

Dicumyl peroxide 80-43-3


296

1,3-Bis(t-butyl peroxy isopropyl)benzene

2212-81-9


297

2,5-Dimethyl-2,5-di-(t-butyl peroxy)hexane

78-63-7


298

2,5-Dimethyl-2,5-di-(t-butyl peroxy)hexene-3

1068-27-5


299

Dipropionyl peroxide 3248-28-0


300

Benzoyl peroxide 94-36-0


301

t-Butyl peroxyacetate 107-71-1

ใชเปน additive: Radical initiator(Peroxyester)

302

t-Butyl peroxypropionate

- ใชเปน additive: Radical initiator (Peroxyester)

30

t-Butyl peroxybutyrate

18072-84-9

ใชเปน additive: Radical initiator


Substance CAS No.


HDPErecycled


virgin HDPE




3 (Peroxyester)304

t-butyl peroxyisobutyrate

109-13-7

ใชเปน additive: Radical initiator (Peroxyester)

305

t-Butyl peroxydiethylacetate

2550-33-6


306

t-Butyl peroxypivarate 927-07-1


307

t-Butyl peroxy-2-ethyl hexanoate

13467-82-8


308

t-Butyl peroxy-3,5,5-trimethylhexanoate

13122-18-4


309

t-Butyl peroxybenzoate

614-45-9


400

Diisopropyl peroxydicarbonate

105-64-6

ใชเปน additive: Radical initiator (Peroxycarbonates)

401

Di-t-butyl peroxydicarbonate

19910-65-7


402

Di-2-ethylhexyl peroxydicarbonate

16111-62-9


403

Bis(4-t-butylcyclohexyl) peroxy carbonate

15520-11-3


40

t-Butyl peroxy isopropyl carbonate

2372-21-6

ใชเปน additive: Radical initiator


Substance CAS No.


HDPErecycled


virgin HDPE




4 (Peroxycarbonates)

405

t-Butyl hydroperoxide 75-91-2

ใชเปน additive: Radical initiator (Hydroperoxides)

406

p-Menthane hydroperoxide

26762-92-5

ใชเปน additive: Radical initiator (Hydroperoxides)

407

1,1-Di (t-butyloperoxy)cyclohexane

3006-86-8

ใชเปน additive: Radical initiator (Peroxyketal)

408

1,1-Di (t-butyloperoxy)-3,3,5-trimethylcyclohexane

6731-36-8

409

2,2,5,7,8-Pentamethyl-6-chromanolหรอ 2,2,5,7,8-Pentamethyl-6-hydroxy chromanol

950-99-2

FCN

410

2-Propenoic acid, 2-cyano-3,3-diphenyl-,2,2-bis{[(2-cyano-1-oxo-3, 3-diphenyl-2-propenyl)oxy]methyl}-1,3-propanediyl ester

178671-58-4

FCN

411

2-Oxepanone, polymer with 1,4-butanediol

31831-53-5

FCN

412

Ethylene-2-norbornene copolymerหรอ bicyclo{2.2.1} hept-2-ene, polymer with ethene.

26007-43-2

FCN

41

Cis-endo-bicyclo(2.2.1)heptane-

351870-33-2

FCN


Substance CAS No.


HDPErecycled


virgin HDPE




3 2,3-dicarboxylic acid, disodium salt

414

Pyrimido(5,4-g)pteridine-2,4,6,8-tetramine,4-methylbenzene sulfonate, base-hydrolyzed (Pigment Yellow 382E; CAS Reg. No. 346709-25-9),which is a mixture consisting of approximately 65.3%, Pyrimido(5,4-g)pteridine-2,4,6,9-tetramine (CAS Reg. No. 207283-64-5), approximately 7.5%, 2,6,8-triamino-pyrimido(5,4-g) pteridine-4(1H)-one (CAS Reg. No. 335356-94-0), approximately 16.7%, 2,8-diamino-pyrimido(5,4-g)pteridine-4,6(1H, 7H)-dione (CAS Reg. No. 207283-72-5), and approximately 0.3%, 8-amino-pyrimido(5,4-g)pteridine-2,4,6(1H,3H,7H)-trione (CAS Reg. No.207283-92-9).

346709-25-9

FCN

415

Octadecanoic acid, methyl ester, reaction products with 1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethyl-4-piperidinol

300711-92-6

FCN

4 Tin(IV) Oxide 18282- FCN


Substance CAS No.


HDPErecycled


virgin HDPE




16

10-5417

3,6,9-triethyl -3,6,9-trimethyl -1,2,4,5,7,8-hexoxonane

24748-23-0

FCN

418

1,2-Cyclohexanedicarboxylic acid, calcium salt (1:1), (1R, 2S)-rel-

491589-22-1

FCN

419

Benzene, ethenyl-, polymer with 1,3-butadiene,hydrogenated, 4-methyl-1,3,2- dioxaborinan-2-yl 4-methyl-1,3,2-dioxaborolan-2-yl derivatives

500224-31-7

FCN

420

Octadecanoic acid, 1-(12-acetyloxy)-, 2,3-bis(acetyloxy) propyl ester; 1-(12-acetoxystearoyl)-2,3-diacetyl glycerol

736150-63-3

FCN

421

Siloxanes and silicones, di-Me, hydroxylterminated,reaction products with silica

FCN

422

poly(3-nonyl-1,1-dioxo-1-thiopropane-1,3-diyl)-block-poly(x-oleyl-7-hydroxy-1,5-diiminooctane-1,8-diyl), process mixture with x = 1 and/or 5, neutralised with dodecylbenzenesulfonic acid

1010121-89-

7ใชเปน additive

423

cis-endo-bicyclo[2.2.1]heptane-2,3-dicarboxylic acid, salts

- ใชเปน additiveRef EU 817


ขอ 5 ทานมการใชสารเคมเหลานในการผลตเมดพลาสตกชนด HDPE ทงกรณทเปน virgin HDPE และ HDPE หรอใชในการผลตภาชนะบรรจ /วสดสมผสอาหารททำาจากพลาสตกชนด virgin HDPE หรอไม หากมการใชโปรดระบ ในตาราง ตารางท 5 รายชอสารท EU อนญาตใหใชเฉพาะในพลาสตกชนด Polyolefin จำานวน 9 รายการ (Only use in Polyolefin)

Substance CAS No.


HDPErecycled

HDPEภาชนะ

บรรจจาก virgin HDPE




Only use in Polyolefin in EU

1 phthalic acid, dibutyl ester

84-74-2


2 amines, bis(hydrogenated tallow alkyl) oxidised

143925-92-2


3 mixture of methyl- branched and linear C14-C18 alkanamides, derived from fatty acids

85711-28-0


4 ethylene-vinyl acetate copolymer wax

24937-78-8


5 montmorillonite clay modified by dimethyldialkyl (C16-C18) ammonium chloride


6 α-tocopherol acetate

7695-91-2

ใชเปน additive or polymer production


Substance CAS No.


HDPErecycled

HDPEภาชนะ

บรรจจาก virgin HDPE




58-95-7

aid

7 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propanoic acid, esters with C13-C15 branched and linear alcohols

171090-93-0


8 dodecanoic acid, 12-amino-, polymer with ethene, 2,5-furandione, α-hydro-ω-hydroxypoly (oxy-1,2- ethanediyl) and 1-propene

287916-86-3


9 1,7-octadiene 3710-30-3


ขอ 6 กรณทานมการใชสารเคมทนอกเหนอจากทระบในตารางท 3 และ 4 ในการผลตเมดพลาสตกชนด HDPE ทงกรณทเปน virgin HDPE และ HDPE หรอใชในการผลตภาชนะบรรจ /วสดสมผสอาหารททำาจากพลาสตกชนด virgin HDPE โปรดระบขอมล


Substance CAS. No.


useใชในการ

ผลต virgin HDPE


recycled HDPE


ภาชนะบรรจจาก virgin HDPE


ขอ 7 ทานมการใชสารเคมในกลม Phthalates เหลานในการผลตเมดพลาสตก หรอภาชนะบรรจอาหารททำาจากพลาสตก หรอไม หากมการใชโปรดระบ ในตาราง

Substance CAS. No.

หมายเหตFunction of use

PET HDPEใชผลต

virgin

ใชผลตภาชนะบรรจ

ใชผลตrecycled PET

ใชผลต virgin


ใชผลตRecycled

HDPE

1 bis (2-ethylhexyl) phthalate (DEHP)หรอ phthalic acid, bis(2-ethylhexyl) ester

117-81-7


2 dibutyl phthalate (DBP)หรอ phthalic acid, dibutyl ester

84-74-2


3 benzyl butyl phthalate (BBP)หรอ phthalic acid, benzyl butyl ester

85-68-7


4 di-“isononyl” phthalate (DINP)หรอ phthalic acid, diesters with primary, saturated C8-C10 branched alcohols, more than 60 % C9

28553-12-0

68515-48-0


5 di-“isodecyl” phthalate (DIDP)หรอ phthalic

68515-49-1

26761-

ใชเปน additive or polymer


Substance CAS. No.



virgin






HDPE

acid, diesters with primary, saturated C9-C11 alcohols more than 90 % C10

40-0 production aid

6 di-n-octyl phthalate (DNOP)

117-84-0


7 o-phthalic acid 88-99-3

ใชเปน Use as monomer or other starting substanceใชเปน additive or polymer production aid

8 phthalic acid - ใชเปน Use as monomer or other starting substance

9 isophthalic acid

121-91-5

ใชเปน Use as monomer or other starting substanc


Substance CAS. No.



virgin






HDPE

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