- 218 -

Burgandy

8.5RP2.0/2.5. Burgandy

Hagen-Poiseuille

Hagen-Poiseuille's law

Q =4

8

QRP

l

1839 G.Hagen1840 J.Poiseuille

4R

permanent red 4R

JIS K 5209-1971 4R3--4-

pearl grey

2.5 Y 6.5/0.5

pearl finishing

5.0 YR 3.5/4.5

10.0R 4.5/7.5

coordinate bond

()

HCIO CI

CIO

CI

- 219 -

excluded volume effect

8 1

4

pH

high solid lacquer

20

1/41/6

-

electron

high build coating

1

breaking energy

-

- 220 -

kgcm/cm3

peeling

white point

whiteness

explosion limit

(flammable range)(explosion

range)

()

2.5 13.0

1.2 7.0

1.8 11.5

1.2 7.6

mesopic vision

2

peeling

remover

1)

- 221 -

2 )

brush

* * *

brushability

blushing

brush mark

crosslinked polymer

crosslinking index

n

B2 B

2

1 x AB 1 B 1

X1

=

cissingcrawlingfisheyes

5.0YR8.0/5.0

- 222 -

blushingblooming

fire point

J I S K 22 7 4 - 1 96 2

(

)

5

166C 174C

()

anti-blushingproperty

*

J I S K 5 5 3 9 - 1 9 6 1 4 . 6

10g

250c c (

1 ) 3 0 g ( 2 ) 2 0 g

2330C 8793%

(160120mm)

1

()

14

10

15

5

6

3

47

2

()

15

10

5

70

luminescent pigment

( )

**

JIS K 5671-1971

luminescent finish

chromophore

( )

O ( ) ( )

( )

( )

*

rusting

vat pigment

- 223 -

*

* (

) * *

foaming type coating

CO2

C O 2

intumescent paint

putty

2 . 0 P 4 . 0 / 3 . 5 .

blooming

( ) ( )

( ) ( )

buff

8.5 YR 6.5/5.0

buff

baryte barium sulfate BaSO4

3.94.5 1.64

*

J IS K 5115-1965(

) ( % ) 0 . 5 ( % ) 0 . 5

(%)95

- 224 -

Barus effect

M e r r i n g t o n e f f e c t

paraffin

300C

4 56 5 C

para-phenyl phenolic resin

100*

( )

( )

(bu rn i s h ing )

0 .5

2%

halogenated hydrocarbon

(Cl )(Br)

* * *

(

)

(JIS K 5400)

semigloss

60 3070

70 high gloss

30~70 semi gloss

6~30 egg shell

2~6 egg shell or flat

~2 flat

()

spot test

J IS K 5400-1970

5 .5 (

11cm) 0.2ml

2

J I S K 5 5 3 8 - 1 9 6 1

*

hansa ye11ow

( f as t y e l l o w)

- 225 -

*

*

1 0G ( )5 ( )

1.0P2.5/10.0

reflective coating

hammer tone coating

BET

BET adsorption isotherm

1938 S.BrunauerP.H.EmmettE.Teller

(0 )=

1

+

1

0

P

P0 T m

c e(E1EL/RT)

E 1 1

1mol E L

R

( )

=P/P0

v =

1

1 ( + 1) + +1

1 + ( 1) +1

n

n =

n=1

peacock green

7.7BG 4.5/9.0

peach

3.5 YR 8.0/3.5.

heat reflowing coating

100 C

(ref low)

80110C 15 ,

130150

C 30

(B .S ,B )

- 226 -

peeling

nonyellowing polyurethane resin coating

( ) ( )

24-

44-

i )

()

()

( ) ( )

i i

()

i )

(HMDI)ii)244( 224)

(TMDI)iii)

26 (LOI) iv)

(DDI)

i )

-44 (CHMDIii

(HTDI) i i i ) -

1-355-

( I P D I )

( X D I )

80100C

leather coating

light curing unsaturated polyester resin coating

()

- 227 -

- N O 2

- N H 2 - CO

E D -

TA

( P VA )

P VA

10%

300400nm

23

10 20

5c m10c m

7cm20cm

photosensitizer

30004000A-

diphenyl di-

sulfidedibenzyl disulfidedesyl arylsulfide

sulfide benzyl cyclohexanone benzoinbenz-

ophenone carbonyl

10%

( 2 3 m m )

- 228 -

23

nonpolar solvent

* ( * * )

( - C H 2 - ) * (

* * )

*

pigm t shock

B

A B

s e e d i n g

A B

A B

B A

A B

seed

specjfic gravity

4C

non aqueous dispersion (paint)

N A D ( N A D )

(

0.10.8 )

(1)

(2) 66

(3) 2coat 1bake

(3)

IC I ( )

NAD

hysteresis

A

B A

A B

A

bisphenol A

2

A

- 229 -

150155C

strain

bitumen

pickling

tensile strength

modulus in tension

non-Newtonian flow

( )

(plastic f low)

(pseudo-plastie f low)

(d i l a t a n t f l o w)

(

)

( )

vinyl coating

-

8595% 1520%

1020%

vinyl sol coating

- 230 -

(20% )

vinyl butyral resin

vinyl antifouling paint

1

1

specific heat

1 g 1

ca l /Kg

C p C o

specific viscosity

0

(-0)/0=r

nonfoaming type fire retardant paint

(

) (

)

(

)

rack coating

castol oil fatty acid

8087%

C 1 8 10% 23%

185195 100

90

- 231 -

100%

100%phenolic resin

induced colour

1 )

2 )

specified achromatic light

(CIE)1931

ABC 3

A 2854K

B A

4870K

C A

6740K

relative luminous efficiency

1924 CIE

colour specification

bleached lac

25

7595, 200215

8.59.5 7478CJIS K 5911

()

(

)

surface tension

(

dyn/cm) 72.75(20C) 487(15C)

22.3(20C)

surface rheology

- 232 -

pyrasolone pjgment

1.41.5

*

viridian

8.5G4.0/6.0

Hildebrands equation

(E /V ) 1 / 2 ( E

V )

E=Hvap-RT

H v a p T K R =

1.986cal /C 25C

E25=Hvap25-600

H25 Hi ldebrand

H25=23.7Tb+0.02Tb2-2950

T b

Hi ldebrand

1.0GY7.5/8.0

Bingham yield value

f=pD f

f

- 233 -

Bingham flow

E. C. Bingham

f f

D

f =

p D

p

(plast ic viscosity)

(Bing-

h a m f l u i d )

pink

2.5 R 7.0/5.0

pinhole

poor solvent

*

*

fast yellow

Hoechst ( ) Permanent Ye l low FGL

fast sky blue

J I S K 5 2 4 3 - 1 9 7 1

furnace black

*

(channel ) (

) ( )

( 2 0 7 0

m ) p H

69

( 1 02 7 m )

pH 35

( ) ( lampblack )

van der Waals force

7

- 234 -

Ficks law

J

C grad C

J=-D grad C

D

Hooker method

()

phenylsilane resin

(

)

( C H 3 )

(C6H5)

CH3/C6H5

( )

()

phenyl glycidyl ether

*

( 2 0 C ) 1 . 1 0 9 ( c s p ) 7 . 0 5

(20C) 245C 152

phenyl resin

( C 6 H 5 )

1 0 0%

( -CH 3 )

( - ) ( )

phenolic resin coating

- 235 -

1 0 0 %

1 0 0%

2

phenolic modified alkyd resin

voigt model

( r e t a r d e d

e las t i c i t y )

S=

Gr (dr/dt ) S r

t G

= /G ( re tardat ion t ime)

G

addition polymerization

( )

addition polycondensation

cracking

nondrying oil

100

( ) *

7 59 08 291

816

complex elastic modulus

S r

S=G* r G*

G*=G i G G

G

G

blister blistering

- 236 -

10.0 PB 6.5/6.5

9.0 PB 4.5/7.5

corrosion

* *

corrosion blister

corrosion inhibitor

J IS K 3211 -19 64( )

(a n od i c

inh ibi to r ) NaOHNa 2 CO 3

( )

2

dibutylphthlalate

-35C 339C

n -

(DMP)

dimethylphthalate

O-C6H4(CO2CH3)2

5.5C 284C 1.19

5 15% 30

phthalic resin paint

- 237 -

phthalocyanine green

* 4

(CI )

12 ( 14 )

C I ( B r )

J IS K 52 4 2 - 1 97 1

2.7% 10.0

1.5pH4.08.0

phthalocyanine blue

( )

( 2030 35

) 1.60

170190C

4

( C I )

( )

( ) ( )

( )

( )

( )

( )

** ( )

J IS K 5 2 4 1 - 1 9 7 1

adhesion

()

butyral resin

( )

polyvinyl butyral resin coating

( )

butyl alcohol butanoI CH3(CH2)2CH2OH

* *

( )

- 238 -

*28.9C ()

*334C*50(=100)

2

4

100ppm * 1.45%

11.25%()

( )

* *

J I S K 5 0 4 - 1 9 5 9 (

)

butylated urea resin

butylated melamine resin

*

butyl titanate resin

*

Hookes law

R.Hooke

fluoroethylene resin

( )

(kel F)

( 230C )

4

(20/20) 0.8100.815

115(cc) 0

115 118

(cc)

95.0

120(cc) 0

(%) 0.005

()% 0.01

- 239 -

object colour

boiling point

1

butoxy methylol melamine

* 1

56

1

butoxyl

C 4 H 9 O - n -CH 3 C H 2 C

H2CH2O-

6

10() 48% 0.81.0

1

buton resin

300

(90C )30

buton resin coating

Esso ResearchEngineering

80%

20%

8,00010,000 1.4

1.2

nonflammable coating non burning coating

- 240 -

tack-free dry

40mm 500g

unsaturated polyester resin

(

) ( )

( )

* ( )

( )

2 3

unsaturated polyester resin coating

2

2

100

primer

primersurfacer

plastisol

1 mm

plastisol coating

coating for plastic surface

- 241 -

FRPSMC

( )

blast cleaning

1870

( )

( )

( ) (

)

( * * )

1 1

flashed colour

( )

( )

36

(

)

blushing

flower spot

4

5 2mm

- 242 -

( )

furan resin

furan resin coating

bleed

1 )

2 )

flicker

()

80100 150200

325

J IS K J IS 5101 (

)

J IS Z 8801 ( ) 44 (

75mm) 105110

C

15

1mg

( )

100ml

50ml

50ml

120mm

15mm

1 20

40

105110C

30

1mg

(%)

I =J

S 100

()

10g

20g

5~10g

10g

20g

5~10g

5g

0.2

1.0

0.3

0.2

1.1

0.3()

2.0(2)

- 243 -

J ( g )

S ( g )

blueing effect

(

)

(

)

blooming

1) blushingchi l l ing

2 ) g um b l us h

resin blush

3) cotton

blush

purkinje phenomenon

-

()

flaking

flame cleaning

1

6

()

prepolymer

paint applied by flow coater

1mm

30cm

- 244 -

flow point

//

(

) (

+ )

(

)

%

60%50%40%30

%20%

%

20g 30%

20g

/ /=20/6/14

flocculation

blocking

( )

block copolymer

1 2 (

A B )

(AAA) (BBB) (AAA)

(BBB)

A B

A B

vinyl propionic acid emulsion

(CH 2=CHOCOC 2 H5 )

propyl alcohol CH3CH2CH2OH

(20C/20C)0.786(nD20)1.377

( 1 ) J ISK8838 -1961

n ( n )

( 12)

propylene glycol

(20C /20C)1.0381 187.3C

((nD20)1.4326 104C

4 3

(20C

0.08mmHg)

blown asphalt

- 245 -

350~370C

250C

bronzing

0.1

( )

C

chalking

polarization

1)

2)

spectral reflection factor

spectral reflection curve

(a)

1. 5.

2. 6. C

3. 10R 7.

4. 8.

(b)

1. 10G 5. G

2. 5G 6.

3. 7.

4. 10G

- 246 -

(C)

1. 4.

2. 5.

3. () 6.

(d)

1. 4.

2. 5.

3. 6.

dispersion

1 ( )

(e)

1. 5. B

2. 6.

3. 7.

4.

(f)

1. () 5.

2. () 6.

3. 7.

4. 8.

9.

conductive paint of dispersed type

- 247 -

30~

50%

0.1

2

dispersion effect

(d ispers ion fore)

intermolecular force

5

(

)

a b 2

D

A DA

D+A

molecular refraction

R0

N 0

(4 /3 )N 0

2

molecular volume

1moI

molecular weight distribution

M

wM

n

M

w /M

n

- 248 -

film applicator

J ISK5400

A B

a 1005 mm 1005 mm

b 783 783

c 302 302

d 6.50.5 41

e 172

f 302 302

g 231 231

g` 252

h 1005 752 1003 752

(

Baker f i lm appl i

catorDocter film applicator

0~10mil

JIS

Ford cup viscometer

( )

( )

No.4 No.4No.3

No.4

25C 20

~100 300

( s t ream )

( s e c )

- 249 -

JISK5400 1

-

JISK5400

2

plastometer

2

Brookfield viscometer

B

flow point

( )

20g

( 5 ~ 4 0 % )

()

1 ~ 2

1~2

5~10%

( )

20

10( 15%) (

)

flow meter

- 250 -

(Gardner f lowmeter )

spectrophotometer

spectral colorimetry

J I S

3

100V

70kV~140kV

50~1000g/min

()

electrophoretic powder coating (EPC)

1) 1/3

(15~20 )

2 )

3)

4)

5 )

6 ) (

)7)

1)

2 )

3)

- 251 -

4 ) ( )

10.1~0.3

powder coating

100%

1950 Irwin Gemmer

1962 SAMES

100

50

polyethylene powder

Pfund wet film gage

L T 1 T 1

T 2 T 1

T 2 S

T 2

S

T 1

- 252 -

t

t = D2/16R D

R

levelling leveling

average (mean) molecular weight

parallel plate plastometer

beilby layer

30~40

2 ~ 3

Baker film applicator

3

0 ~ 1 0 m i l ( 1 m i l = 1 / 1 0 0 0

inch)

2

beige

1.0Y6.5/2.5

paste resin

0 . 1 ~ 2

pH

pH-value

p H

= log 1 / [H + ] 1 l

pH=7

pH

pH

baby pink

3 . 5 R 8 . 5 / 4 . 0

- 253 -

baby blue

10.0 B 7.5/3.0

hexahydrophthalic anhydride

35~36C 1.18

hexamethylenediisocyanate (HMDI)

OCN-(-CH2)6-NCO

( T D I )

( )

hexamethoxy methyl melamine

C ym e l (

)300

55C

( 2 0 C ) 1 . 1 7 ~ 1 . 2 1

n-hexyl alcohol n-hexanol. CH3(CH2)4CH2OH

n -

0.8203~0.8208(20/20C) 157.1C 59.4

C ( )73,9C ( )

()

n- 2-

(CH 3 CH(C2 H 5 )CH 2 CH 2 OH)

0.8328(20/

20C) 147.0C 58C()

crater, cratering

7.0 R 5.0/14.0

- 254 -

( )

Hellige colour comparator

JISK 5400

perylene perinone pigment

( )

Ho

c hs t ( )BASF( )Harm on

Perinone orange

Perylene

O C

R

CH3 ( BASF Pali

ogen Maroon G) Ho

ch

s t Permanent Red BL)

( P V F as t R ed B )

H5 ( BASF Pal io

gen Red GG)

8.5R3.5/5.5

F e 2 O 3

benzyl alcohol

1.044~1.058(25/

25C) 205.3C 96C()100.5C(

2

( )

J I S K 8 8 5 4 (

)

()

oxide red red iron oxide

2 (

F e 2 O 3 )

(

)

- 255 -

( )

( )

JISK5109 2

3

2 98.5%

1 96%

2 80%

benzidine yellow

J I SK 5 2 2 0 - 1 9 7 1 ( )

33 -

G GR 1.3~1.4

benzidine orange

J I S K 5 2 2 1 - 1 9 7 1 ( )

33 1 3

5

1.4

benzyl cellulose

3

90~95C

C6H9O4OH+CICH2C6H5 C6H9O4OCH2C6H5

+HCL

discoloration

( fading)

( y e l l o w i n g )

(discoloration)

- 256 -

2

modified alkyd resin

modified drying oil

,

benzenebenzol

11.1C

538C 1.5vol% 8.0vol%

(

( ) 2 5 p p m

200ppm )

J ISK2430-66

(1)

1)

80.1C

0.1deg

(2) 90%

(15/4C) 0.850~0.890

()

75C

100C 90%()

120C

[mg/l] 50

() 6

(3mg/l)

(3) 60%

- 257 -

(15/4C) 0.850~0.880

()

75C

100C 60~90%()

140C

[mg/l] 50

() 8

(5mg/l)

benzoguanamine resin coating

NH 2 3

1

2

NH 2

4

( C H 2 )

-

NH 2 1

6 4

pentaerythrit pentaerythritol

4

(25 /4 C ) 1 . 38 ( )180 ~24 0 C

J ISK1510 -1963

1 2

(%) 87 82

(%) 47 45

() (C) 180 170

pentachlorophenol

190C

bentonite

4 ~ 8

( A I 2 O 3 5 S i O 2 2 H 2 O ) (

)

2 . 4 1

- 258 -

boiled oil

( )

( ) 100 C

(

)

( )

antifouling paint

2 2 A/F

1 ( )

J IS

JISK 5630

JISK 5631

JISK 5632

JISK 5634

JISK 5635

JISK 5638

3mm

antimildew paintantifargus paint

(60~95%) 15C

( P C P )

aromatic alcohol

aromatic hydrocarbon

( ) (

)

radiation curing

- 259 -

anticorrosion effect

()

saturated fatty acid

(C8H16O2)

CnH2n+1COOH

[COOH]

C15H31COOH C17H35COOH

ball mill

bone blackanimal blackdrop black

2.2~2.6 88~85%

12~23%

(15~22gal /100 1b)

( i v o r y b l a c k )

ASTMD21047 (105C

)88% 3.0%

2.0%No.325 2.0%

touch up

complementary color

2

2

- 260 -

Steam phosphating

1960

2

peony purple

3.0RP5.0/14.5

(

)

hot spray

1939 (Charles Bogin)

bottle green

5.0G2.5/3.0

pot mill

potlife

body varnish

2 1

1

J I SK 54 4 3

homopolymer

M

A B

a) MMMMMMM

b) AMMMMMMB

MNMMMNMM

( copolymer)

- 261 -

( graf t pol ymer)

polyamide resin coating

2 1

1

nHOOC(CH2)4COOH+nH2N(CH)6NH2

[OC(CH 2 )4 CONH(CH 2)6NH ] n+nH 2O

mNH2(CH2)5COOHH[HN(CH2)5CONH

( ) (CH 2 ) 5 CO] m / 2 OH+m H 2 O

6

66

9000

polyurethane resin

polyurethane resin coating

1 2

ASTM 1

2

(

)

2

( n + 1 )O C N R NC O+ n HO R O H

R N C O (T DI )

( H M D I )

3 NCO

1

150C

A r O H ( )

- 262 -

4

5

2

2 3

polyester

C O O

(

) ( )

( )

( )

2 3

polyester resin coating

2

(

)

( )

1 ~ 2%

100%

po!yester putty

100

%

polyethylene glycol

HO(CH2CH2O)nH

190 2

n=4 2 50 Cn =5

281C

( 190~630)

( 950

polycondensation reaction ()

1 2 (COO

H) 2 (OH)

- 263 -

()

polyvinyl alcohol

( p o v a l )

1.21~1.31

polishing compound

#300~

#600

10B

bordeaux 10B

J I S K 5 2 1 5 1 9 7 1 1 0 B ( )

1.69

formalin

(HCHO) 37% 1.14

( 1 8 C / 4 C )

J ISK 1 5 02 19 5 8 (

% ) 3 7 . 0 0 . 5 ( ) ( g / 1 0 0 c c ) 0 . 0 8

whitingnatural calciumcarbonate

( CaCO 3 )

( )

2.7~2.9 1.5~12pH 8.6

0 . 15~0 .23 1 .48~1 .68 6~15(16 /

1001b) CaCO3 20% MgCO3

A S T MD 1 9 9 6 9 Ty p e P C

TypeGC

(g round m ine ra l p rodu c t )

4 ( Fine Paint Grade Coarse

Paint Grade Filler Grade Putty Powder

G r a d e )

BONmaroon

J ISK52231971 M( )

- 264 -

( )

( B . 0 . N . )

( )

(Bonmaroon L)

(Bon m aro on D)

(Bon m aro on M)

( )

( )

1.6~1.7

()

microcapsule

2

micromeritics

pretreatment

film thickness gauge

( )

(

)

Maxwell model

J . C .Ma xw e l l

ds / d t = G ( d / d t ) S / )S

t G = /G

( )S = G