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  • 1

    Chapter 6

  • 2

  • 3

    IC 40 to 50%

  • 4

    IC

    EDA PR Chip

    EDA: Electronic Design Automation

    PR: Photoresist

  • 5

    IC

    CMP

  • 6

    PR

  • 7

  • 8

  • 9

    /

  • 10

  • 11

  • 12

  • 13

  • 14

  • 15

  • 16

  • 17

    PR

    + PR

  • 18

  • 19

  • 20

    (DUV), 248 nm I-line (365

    nm)

  • 21

    DUV

    (PEB)

  • 22

    + H+

    + H+ PR PR

    PEB PEB

    +

  • 23

  • 24

  • 25

  • 26

  • 27

    P

    USGSTI

  • 28

    P

    USGSTI

  • 29

    P

    USGSTI

  • 30

    P

    USGSTI

  • 31

    P

    USGSTI

  • 32

    P

    USGSTI

  • 33

    P

    USGSTI

  • 34

    P

    USGSTI

  • 35

  • 36

  • 37

    150 C

  • 38

    (Hexamethyldisilazane, HMDS)HMDS

  • 39

    HMDS

  • 40

  • 41

  • 42

    (m

    )

    (rpm)

    0 7k2k 3k 4k 5k 6k

    0.5

    1.0

    1.5

    2.0

    2.5

    3.0

    3.5100 cst

    50 cst

    27 cst20 cst

    10 cst

    5 cst

  • 43

    ~ 500 rpm

    ~ 3000 - 7000 rpm

  • 44

  • 45

    EBR

  • 46

  • 47

  • 48

  • 49

  • 50

  • 51

  • 52

  • 53

  • 54

  • 55

  • 56

  • 57

    Edge Bead Removal (EBR)

    EBREBR

  • 58

  • 59

  • 60

  • 61

    (Wafer edge expose WEE)

  • 62

  • 63

  • 64

  • 65

  • 66

  • 67

  • 68

    2.5106/C8(200 mm) 1 C 0.5 m

  • 69

    IC

  • 70

  • 71

    1970

  • 72

  • 73

    N

    PR

  • 74

    ~ 10 m > 2 m

  • 75

    ~10 m

  • 76

    N

    PR

    ~10 m

  • 77

    111 m

  • 78

  • 79

  • 80

    IC

    0.25 m

  • 81

  • 82

    X

    Y

  • 83

  • 84

    G-(436)

    H-(405)

    I-(365)

    300 400 500 600 (nm)

    (a.u

    )

    (

  • 85

    (nm) (m)

    G-line 436 0.50

    H-line 405

    I-line 365 0.35 to 0.25XeF 351XeCl 308

    KrF (DUV) 248 0.25 to 0.13

    ArF 193 0.15 to 0.07

    F2 157 0.1

  • 86

  • 87

  • 88

    /2nPR

  • 89

    /2nPR

  • 90

    (Post Exposure Bake, PEB )

    (Glass transition) TgTg

  • 91

    DUV PEB

  • 92

    PEB 110130 C1

  • 93

    PEB

  • 94

  • 95

  • 96

    +PR

    (Tetramethyl ammonium hydride, TMAH (CH3)4NOH))

  • 97

    PR PR

    PR

    PR

  • 98

    Positive PR Negative PR

    TMAH Xylene

    DI Water n-Butylacetate

  • 99

  • 100

  • 101

    PR

    PR

  • 102

    100 130 C 1 2

  • 103

  • 104

    PR

    PR

  • 105

    (SEM)

  • 106

    PR

  • 107

    (Critical dimension, CD)

  • 108

    (Run out)

    (Run in)

    X

    Y

  • 109

    (CD)

    CD CD

    PR PR

    PR

  • 110

  • 111

  • 112

  • 113

    (Cost of ownership, COO)

  • 114

  • 115

    (Depth of focus, DOF)

  • 116

  • 117

    ()

  • 118

  • 119

    ()

    ro

    D

  • 120

    (Numerical Aperture)NANA = 2 r0 / D

    r0 : D =

    NA

  • 121

    (Resolution)

    NAK

    R1

    K1NA

    R

  • 122

    NA

    ,

    ,UV DUV, EUV, X-Ray

    K1(Phase shift mask)

  • 123

    RF MW IR UV X-ray

    104 106 108 1010 1012 1014 1016 1018 f (Hz)

    104 102 100 102 104 106 108 1010 (meter)

    -ray

    1012

    1020

    RF: ; MW: ; IR: ; and UV:

  • 124

    (Depth of Focus, DOF)

    22

    )(2 NAK

    DOF

  • 125

    )(22

    NAK

    DOF

    2

  • 126

  • 127

  • 128

    NA.

    DOF

    (CMP)

  • 129

    I- I-line, 365 nm

    0.35 m

    DUV KrF , 248 nm0.25 m, 0.18 m and 0.13 m

    ArF ,193 nm< 0.13 m

    F2,157 nm< 0.10 m

  • 130

    I-

    < 180 nm, SiO2 UV157 nm F2

    OH (CaF2)

    ,0.035 m

  • 131

    1.5

    1.0

    0.8

    0.50.35

    0.250.13 0.10

    0

    0.2

    0.4

    0.6

    0.8

    1

    1.2

    1.4

    1.6

    84 88 90 93 95 98 01 04

    (mm

    )(m

    m)

    07 10

    0.07 0.05

    14

    0.18

  • 132

    (Phase Shift Mask)

    d

    nf

    d(nf 1) = /2

    nf :

  • 133

    d

    ng

    d(ng 1) = /2

    ng:

  • 134

    PR

    PR

    PR

    PR

    I

  • 135

    193 nm157 nm

    CaF2

    (Extreme UV, EUV)X-Ray

  • 136

    (EUV)

    = 10 to 14 nm~ 20100.1 m

  • 137

    EUV

    2 1

  • 138

    X-ray

    X[(Aspect

    ratio)]

  • 139

    X-ray

    X-ray

  • 140

    X-ray

    X-ray

  • 141

    0.014 m

    (Scattering with angular limitationprojection electron lithography, SCALPEL)

  • 142

  • 143

    SCALPEL

  • 144

  • 145

    : : : :