cheminform abstract: cobalt-catalyzed reductive mannich reactions of 4-acryloylmorpholine with...

2008 Amines Q 0120 Cobalt-Catalyzed Reductive Mannich Reactions of 4-Acryloylmorpholine with N-Tosyl Aldimines. — The process affords the acyclic anti-β-aminoamides (III) as the major products. It complements existing syn-selective reactions and Morken's methol- ogy that gives β-lactams. It also shows higher diastereoselectivities compared with existing anti-selective reductive Mannich reactions. — (PRIETO, O.; LAM*, H. W.; Org. Biomol. Chem. 6 (2008) 1, 55-57; Sch. Chem., Univ. Edinburgh, Edinburgh EH9 3JJ, UK; Eng.) — Kieslich 24- 069

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Page 1: ChemInform Abstract: Cobalt-Catalyzed Reductive Mannich Reactions of 4-Acryloylmorpholine with N-Tosyl Aldimines

2008

AminesQ 0120 Cobalt-Catalyzed Reductive Mannich Reactions of 4-Acryloylmorpholine with

N-Tosyl Aldimines. — The process affords the acyclic anti-β-aminoamides (III) as the major products. It complements existing syn-selective reactions and Morken's methol-ogy that gives β-lactams. It also shows higher diastereoselectivities compared with ex-isting anti-selective reductive Mannich reactions. — (PRIETO, O.; LAM*, H. W.; Org. Biomol. Chem. 6 (2008) 1, 55-57; Sch. Chem., Univ. Edinburgh, Edinburgh EH9 3JJ, UK; Eng.) — Kieslich

24- 069

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