dip-pen nanolithography (1)
DESCRIPTION
nanoscienceTRANSCRIPT
![Page 1: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/1.jpg)
Rajiv Gandhi Institute of Technology
Department Of Mechanical Engineering
Sarath Krishna. M.ES7 Mechanical
Roll No: 45
![Page 2: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/2.jpg)
INTRODUCTION Invented by Alois Senefelder in
Germany in 1798 Fundamentally new printing
technology Mechanical Plano graphic process in
which the printing and non-printing areas of the plate are all at the same level
![Page 3: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/3.jpg)
Dip-Pen Nanolithography
DPN is a unique modification of atomic force microscope (AFM) instrumentation.
High-resolution patterning capabilities for a number of molecular and biomolecular ‘inks’ on a variety of substrate types such as metals, semiconductors, and monolayer functionalized surfaces.
![Page 4: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/4.jpg)
Atomic Force Microscope (AFM)
![Page 5: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/5.jpg)
![Page 6: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/6.jpg)
![Page 7: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/7.jpg)
Techniques in AFM DC mode AFM AC mode AFM
![Page 8: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/8.jpg)
Characteristics of AFM Works by measuring local properties -
such as height, optical absorption, or magnetism - with a probe or "tip" placed very close to the sample.
The small probe-sample separation makes it possible to take measurements over a small area
![Page 9: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/9.jpg)
Measurement of topography with a force probe
AFM operates by measuring attractive or repulsive forces between a tip and the sample.
![Page 10: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/10.jpg)
Concept of AFM In principle, AFM resembles the record
player as well as the stylus profilometer. However, AFM incorporates a number of refinements that enable it to achieve atomic-scale resolution:
Sensitive detection Flexible cantilevers Sharp tips High-resolution tip-sample positioning Force feedback
![Page 11: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/11.jpg)
Types of AFM tips
Normal tip (3 µm tall) supertip (3 µm tall) Ultralever (3 µm tall).
![Page 12: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/12.jpg)
Working of DPN
Illustration of molecular deposit of DPN tip
![Page 13: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/13.jpg)
Images of dots and lines of magnetic nanoparticles created using DPN
![Page 14: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/14.jpg)
![Page 15: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/15.jpg)
AFM image showing lattice-resolved monolayer of octadecanethiol patterned on gold via DPN.
![Page 16: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/16.jpg)
A)Ultra-high resolution pattern of mercaptohexadecanoic acid on atomically flat gold
surface.B) DPN generated multi-component nanostructure with
two aligned alkanethiol patterns.
![Page 17: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/17.jpg)
Applications of DPN
![Page 18: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/18.jpg)
Limitations Slow process Cannot be used in Vaccum
![Page 19: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/19.jpg)
A Multipen Plotter for Parallel Patterning
Schematic of two-pen DPN plotter
![Page 20: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/20.jpg)
Conclusion Dozens of research groups worldwide
are working on DPN applications to develop even better techniques
The tDPN technique, an improvement to DPN could be used to produce features too small to be formed with light-based lithography, and as a nanoscale soldering iron for repairing circuitry on semiconductor chips
![Page 21: Dip-Pen Nanolithography (1)](https://reader036.vdocuments.pub/reader036/viewer/2022062522/577cc6ba1a28aba7119f0016/html5/thumbnails/21.jpg)
Thank you