nier-sp2012-334 11-1480523-001362-01 -...

11-1480523-001362-01

NIER-SP2012-334

수질유해물질 확대지정 및 기준안 설정 연

제 장 조사대상 물질선정 및 시료채취 지점의 선정1


1

A

1 + ( )

+ ( )

2A ( B

)

2B ( B

)

3A

3B

1-1.

BCF( )

EPA

IRISAIRC Report PBT PBT

( ) ( )

1

Se (Selenium)1)

20

D 3 4.8 - - / /

Benzene1) A 1 5.2** 8.7 38 / / /

Carbon Tetrachloride1) B2 2B 18.75** 30 60 / / /

Dichloromethane1) B2 2B 0.9 1.8 38 / / /

1,1-Dichloroethylene1) C - 5.6 8.7 38 / /

Chloroform1) B2 2B 3.75* 6.6 38 / / /

Ethylbenzene D 2B 37.5** 53 15

Styrene C 2B - 37 15 ( )

1,1,1-Trichloroethane D 3 - 16 60 ( )/

Toluene D 3 10.7 25 15

Vinyl Chloride A 1 1.17 3.6 15 ( )/ ( )/ ( )

Xylene - 3 - 50 15

Acrylonitrile B1 2B 30* 3.2 15 ( )

1,2-Dichloroethane1)

B2 2B - 2.8 38 / /

2,4-Dinitrotoluene B23)

2B 3.8 6.7 38 -

Nitrobenzene D 2B 2.89 5.3 15 -

Antimony - 3 1 - - / ( )

Bromoform B2 3 3.75 14 38 ( )

Bis(2-Ethylhexy)Phthalate B2 3 130 310 15 ( )/ / ( )

1,4-Dioxane2)

B2 2B - 3.2 15 ( )

1-2.

) 1.

2.

3. 2,4-DNT & 2,6-DNT mixture


BCF( )

EPA


( ) ( )

2A

Asbestos

14

A 1 - - -

Dichlorobromomethane B2 2B 3.75 6.9 38

2,6-Dinitrotoluene B2 2B - 8.3 38 -

Hexachloroethane C 2B 86.9 310 180 -

Ni (Nickel) (A,B2)4)(1,2B) 47 - -

1,4-Dichlorobenzene - 2B 55.6 89 38 -

3,3-Dichlorobenzidine B2 2B 312* 100 60 -

Naphthalene C 2B - 69 38 -

Acrylamide2)

B2 2A - - - -

Epichlorohydrin*2)

B2 2A - 3.2 15 -

Formaldehyde2)

B1 1 - 3.2 15 -

Nitrilotriacetic acid (NTA)2)

- 2B - - - -

Chlorothalonil2)

- 2B - 45 180 -

Dichlorvos2)

B2 2B 0.45 38 -

2B

Be (Berylium)

23

B1 1 - - - -

2,3,7,8-TCDD B 1 - - - -

Chloroethane (=Ethyl chloride) - 3 - 2.5 15 ( )

Chlorophenol - - - - - ( )

2,4-Dichlorophenol - 2B 40.7** 18 38 ( )

1,2-Dichloropropane - 3 4.1 6.7 38 -

1,3-Dichloropropylene B2 2B 1.9 6.7 38 -

2,4,6-Trichlorophenol B2 2B 150 55 60 ( )

pentachlorophenol B2 2B 11 700 180(0~0.013 ***) ( )

Benzo(a)Anthracene B2 2B 30 5400 60 -

Benzo(a)Pyrene B2 1 - 10000 60 ( )

Benzo(b)Fluoranthene B2 2B 30 5600 60 -

Benzo(k)Fluoranthene B2 2B 30 10000 60 -

Chrysene B2 2B 30 5900 60 -

Dibenzo(a,h)Anthracene B2 2A 30 22000 60 -

Hexachlorobenzene B2 2B 17.5 5200 180 -

Indeno(1,2,3-cd)Pyrene B2 2B 30 29000 60 -

Benzidine A 1 87.5* 2.2 38 -

Bis(2-Chloroethyl)Ether (=BCEE) B2 3 6.9 2 38 -

1,2-Diphenylhydrazine B2 - 24.9 37 15 -

N-Nitrosodimethylamine B2 2A 0.026 3.2 38 -

N-Nitrosodi-n-Propylamine B2 2B 1.13 2.2 38 -

N-Nitrosodiphenylamine B2 3 - - - -

1-2. ( )

) 1.

2.

3. 2,4-DNT & 2,6-DNT mixture

4. Nickel carbonyl : B2,Nickel refinery dust : A, Nickel subsulfide : A, Nickel(soluble salts) : Information

reviewed

: , : , ( ): , : , :

, ( ):

* BCF ** BCF ***


BCF ( )

EPA


( ( )

3A

Bis(2-Ethylhexy)adipate

21

C 3 - 61 8.7 ( )

Butylbenzyl Phthalate C 3 - - - -

Hexachlorocyclopentadiene E - - - - -

B (Boron) - - - - - -

Acrolein - 3 - - - -

Methyl Chloride D 3 - - - -

Nonyl Phenols - - - 540 60 -

Octyl Phenols - - - 340 15 -

Isophorone C - - - - -

Carbaryl2) - - - 13 38 -

Carbofuran2) - - - - - -

Diquat2)

- - - - - -

Chlorpyrifos2)

- - - 1300 180 -

2,4-D (=2,4-Dichlorophenoxyacetic acid)2)

- - - 3.2 38 ( )

Diazinon2)

- - - 170 38 ( )/

-Endosulfanα2)

- - - - - -

-Endosulfanβ2)

- - - - - -

EPN2)

- - - 960 38 -

Fenitrothion2)

- - - 71 15 -

Iprobenfos2)

- - - 74 38 -

Perchlorate2)

- - - - - ( )

3B

Pentachlorobenzene

42

D - 2125 1900 180 -

Anthracene D 3 - - - -

Di-n-Butyl Phthalate D - 89 580 8.7 -

Fluoranthene D 3 1150 1900 60 -

Pyrene D 3 - - - -

Tl (thallium) D - - - - -

Ag (silver) D - - - - -

Ti (titanium) - 2B5) - - - -

Mo (Molybdenum) - - - - - -

Chlorobenzene D - 10.3 31 15 -

Chlorodibromomethane C 3 3.75 9.2 38 -

1,1-Dichloroethane C - - 4.8 38 -

cis-1,2-Dichloroethylene D - - 8.1 38 -

Methyl Bromide (=Bromomethane) D 3 3.75 1.6 15 -

1,1,2,2-Tetrachloroethane C 3 - - - -

1,2-Trans-Dichloroethylene - - 1.58 8.1 38 -

1,1,2-Trichloroethane C 3 4.5 5.7 38 -

2,4-Dimethylphenol - - 93.8* 12 15 -

2-Methyl-4,6-Dinitrophenol - - 5.5 8.6 38 -

2,4-Dinitrophenol - - 1.5 3.8 38 -

1-2. ( )

) 2.

5. Titanium dioxide

: , : , ( ): , : , :

, ( ):

* BCF ** BCF ***


BCF( )

EPA


( ) ( )

3B

2-Nitrophenol

42

- - - 4.8 15 -

4-Nitrophenol - - - 5.9 15 -

3-Methyl-4-Chlorophenol - - - 49 38 -

Acenaphthene - 3 242 210 38 -

Acenaphthylene D - - - - -

Benzo(g,h,i)Perylene D 3 - - - -

Bis(2-Chloroethoxy)Methane D - - 2 38 -

Bis(2-Choroisopropyl)Ether D - 2.47 16 38 -

4-Bromophenyl Phenyl Ether - - - 1300 38 -

2-Chloronaphthalene - - - - - -

4-Chlorophenyl Phenyl Ether - - - 830 38 -

1,2-Dichlorobenzene D 3 55.6 87 38 -

1,3-Dichlorobenzene D - 55.6 100 38 -

Diethyl Phthalate D - 73 15 15 -

Dimethyl Phthalate D - 36 3.4 15 -

Di-n-Octyl Phthalate - - - 64 15 -

Fluorene D 3 30 330 15 -

Hexachlorobutadiene C 3 2.78** 960 180 -

Phenanthrene D 3 - - - -

1,2,4-Trichlorobenzene D - 114 250 60 -

Tributyltin compounds D6) - - - - -

2-Chloroethylvinyl Ether - - - 1.6 15 -

1-2. ( )

) 6. Tributyltin oxide (TBTO)

: , : , ( ): , : , :

, ( ):

* BCF ** BCF ***


/

EPA1)IARC

2)( )

3)( )

3

(Zinc)D -

,

1


/

EPA1) IARC 2)( )

3)( )

(Styrene)- 2B

1

1,2-

(1,2-Dichloropropane)B2 3

,

DEHA

Bis(2-ethylhexyl)adipateB2 3

,

Perchlorate- -

) 1) USEPA. IRIS(In tegrated Risk Information System ) web-site; USEPA 2010d . Available from

http://cfpub.epa.gov/ncea/ iris/ index .cfm

2) . (2006), ; 2008.

3) USEPA . TRI explorer (Release : Chem ical report); USEPA , 2010d. Available from

http://www .epa.gov/ triexplorer


2010 / ( , 2012)

4 1


2010 / ( , 2012)


2010 ( , 2012)


・


( )

3 1

제 장 특정수질유해물질 지정체계 및 배출허 기준 설정체계2


× ×

×

: (N on linear Low -Dose Extrapolation )

× ×

×

: (L inear Low -Dose Extrapolation)

×

×

위해도 or or


10-6

10-5

10-4

Cancer risk

Cancer risk

Recommended value

Required value

Maximum value

Sound &

Sustainable

Water Environment

Threatened

Water Environment

Risk reduction

10-6

10-5

10-4

Cancer risk

Cancer risk

Recommended value

Required value

Maximum value

Sound &

Sustainable

Water Environment

Threatened

Water Environment

Risk reduction

2-3.


Austrailian and New Zealand Guidelines for Fresh and Marine W ater Quality(ANZECC & ARMCANZ, 2000)


(AF)

1000 LC50

OECD100 LC50 ( , , 3 )

100 1 NOEC( , , 1 )

EC50 2 NOEC( , , 2 )

10 3 NOEC( , , 3 )

Guidance Document for Aquatic E ffects Assessm ent(OECD, 1995)

Technical Gu idance Document on Risk Assessment(EC, 2003)


2-5.

제 장 물질별 분석방법 및 분석결과3


Ω

제 장 조사대상 물질 별 특정수질유해물질 지정 안 및 배출허 기준 안4 ( ) ( )


v

v

v

v

v

v

v

v

v

v

v

) 1. ×10 .


) 1. (INORGAN IC CHEM ICALS MANUFACTURING POINT SOURCE CATEGORY, HE

CENTRALIZED WASTE TREATMENT POINT SOURCE CATEGORY, ELECTRICAL AND ELECTRON IC

COMPONENTS POINT SOURCE CATEGORY)


v

v

v

v

v

v

) 1. ×10 .


) 1. ×10 .

v

v

v

v

v

v

v


v

v

v

v

) 1. ×10 .


수질준거치 × ×

×

RfD : (mg/kg/day)

RSC :

BW : (kg)

DI : (L/day)

FI : (kg/day)

BAF : (L/kg)


- NOEC = 0.06 /L

- 1 ( 1 )

=


v

v

v

v

v

) 1. ×10


수질준거치 ×

×

RSD : (mg/kg/day)

= (10-5)/ (q1)

BW : (kg)

DI : (L/day)

FI : (kg/day)

BAF : (L/kg)

××


- NOEC = 32,621 /L

- 1 ( 1 )

=


v

v

v

) 1. ×10


수질준거치 ×

×

RSD : (mg/kg/day)

= (10-5)/ (q1)

BW : (kg)

DI : (L/day)

FI : (kg/day)

BAF : (L/kg)

×


- LC 50 = 780 /L

- 1 ( 1 )

=


DEHA(Bis(2-ethylhexyl)adipate)


DEHA(Bis(2-ethylhexyl)adipate) 5 2

>

.


) 1. ×10

v

v

v

v

v



×

RfD : (mg/kg/day)

RSC :

BW : (kg)

DI : (L/day)

FI : (kg/day)

BAF : (L/kg)


- NOEC = 21.7 /L

- 1 ( 1 )

=


4-6. (Perchlorate)


4-19. ,


) 1. ×10


×

RfD : (mg/kg/day)

RSC :

BW : (kg)

v

v

v

v

v

v

v

v


DI : (L/day)

FI : (kg/day)

BAF : (L/kg)

×××

- NOEC = 0.75 /L

- 3 ( 1 , 1 , 1 )


= 0.12 mg/ L


1) ,

제 장 연 결과 종합5


○

○ ․


) 1. ×10 .

2. .

○


○ ․

) 1.

○

○ ․


) 1. ( , TBEL)

2. “ ,

” ( 3 , “ : 0.8 mg/L , : 8 mg/L”

)


n

n


n


μ μ μ


( g/L)μ

(%)

( 75~125%) (%)

(±25% )

A B C

Formaldehyde 10 70.1 96.7 112.6 93.13 23.1

Naphthalene

(Headspace)10 71.3 98.3 112.6 94.07 22.3

Naphthalene

(P&T)5 92.2 131.1 97.2 106.8 19.8

Epichlorohydrin 5 102.2 109.0 105.6 105.6 3.2

A B D RSD(%)

( /L)㎍

A23.8 20.9 24.3 8.0

5.3 6.1 5.8 7.1

B61.1 76.9 55.5 17.2

35.7 31.3 32.8 6.8

C111.3 106.4 140.1 15.3

74.5 62.1 94.2 21.1

A

6.3 4.7 7.7 24.5

5.2 4.6 5.7 11.5

B

33.4 28.5 25.1 14.6

10.7 10.0 12.8 13.2

C

16.5 18.6 14.9 11.1

9.1 7.0 13.9 35.3


A B C RSD(%)

MS

(%)

A

77.0 73.6 71.4 3.8

72.8 77.0 83.0 6.6

B

66.6 69.8 72.0 3.9

64.6 64.4 71.8 6.3

C

68.2 62.6 68.8 5.1

77.4 74.4 67.4 7.0

A

59.0 64.8 73.8 11.3

66.8 57.2 64.4 8.0

B

92.2 97.8 113.0 10.7

67.0 74.0 58.0 12.1

C

61.2 71.0 51.0 16.4

64.6 69.4 67.0 3.6

A B D RSD(%)

HS

MS

(%)

A

54.8 65.3 54.3 10.7

59.2 55.0 54.3 4.7

B

50.3 63.7 61.0 12.2

62.5 75.9 47.7 22.8

C

50.3 82.3 49.3 30.9

53.0 80.0 53.7 24.7

A

58.5 93.1 50.3 33.8

52.7 64.6 68.7 13.4

B

57.0 64.0 49.7 12.6

50.7 67.2 58.7 14.1

C

65.7 106.5 59.3 33.1

55.7 93.2 57.0 31.0


A B C RSD(%)

P&T

MS

(%)

A

62.7 58.3 57.2 4.9

60.2 59.9 60.0 0.2

B

69.0 58.3 70.0 9.8

81.8 60.1 68.3 15.7

C

83.2 70.9 69.8 9.9

52.2 69.5 52.7 17.0

A

61.7 58.3 65.0 5.4

70.0 61.9 58.3 9.4

B

71.8 95.2 70.0 17.8

58.3 76.5 56.7 17.2

C

95.8 84.9 94.5 6.5

71.7 52.4 63.3 15.5


5-1. ( )

5-13.


2015 ◎ ◎

1 (2016) ◎ ◎

2 (2017) ◎ ◎

3 (2018) ◎ ◎

4 (2019) ◎ ◎

5 (2020) ◎ ◎◎

()

6 ◎ ◎

7 ◎ ◎

8 ◎ ◎

9 ◎ ◎

10 ◎ ◎

5-14. ( )

nier-sp2012-334 11-1480523-001362-01 -...

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