oled 구조 및 구동원리 -...

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김광영 [email protected] OLED Business Team Digital Display Company LG Electronics Inc. OLED 구조 및 구동 원리 2006. 02. 08 20.1”, 1280X800, AMOLED LPL/LGE, 2004 (20062FPD 전문가 양성 세미나)

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  • [email protected]

    OLED Business TeamDigital Display Company

    LG Electronics Inc.

    OLED

    2006. 02. 08

    20.1, 1280X800, AMOLEDLPL/LGE, 2004

    (2006 2 FPD )

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    - OLED - OLED Display - (Panel Module) -

    Contents

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    from IEC/TC 110/PT 62341, Terminology and letter symbols

    Terminology

    3.1.28organic electroluminescenceemission of light from organic materials by injecting current 3.1.29organic electroluminescent displaydisplay showing visual information in which organic electroluminescence occurs3.1.30organic light emitting diodelight emitting device in which light is emitted from organic materials, possessing properties of diode3.1.31organic light emitting diode displaydisplay showing visual information in which organic light emitting diode is applied3.1.32organic light emitting diode display devicegeneric term for organic light emitting diode display panel and organic light emitting diode display module3.1.33organic light emitting diode display moduleorganic light emitting diode display panel and its driving electronics3.1.34organic light emitting diode (display) paneldisplay panel of an organic light emitting diode display without external drivers

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    OLED

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    ITO

    HIL

    HTL

    ETL

    EIL

    EML

    Al

    Exciton

    +

    (ITO)

    (HIL)

    (HTL)

    (EML)

    (ETL)

    (EIL)

    OLED Mechanism

    Conduction Band (LUMO)

    Valence Band (HOMO)

    LUMO : Lowest Unoccupied Molecular OrbitalHOMO : Highest Occupied Molecular Orbital

    ITO : Indium Tin OxideHIL : Hole Injection LayerHTL : Hole Transport LayerEML : Emitting LayerETL : Electron Transport LayerEIL : Electron Injection Layer

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    exciton

    or

    Triplets

    Singlet

    >>>( >+ )

    >( >- )

    hole electron

    21 21

    Charge

    transfer

    &

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    Emission Mechanism

    Singlet Exciton

    Electron - hole

    Triplet Exciton

    h Phosphorescence(, ~1sec)Fluorescence(, ~nsec)

    Charg

    e sep

    aratio

    nCh

    arge r

    ecom

    binati

    on

    Charge separation(Photoconductivity)

    Charge injection

    Intersystemcrossing

    Thermaldeactivation

    Ground State

    25% 75%

    Thermaldeactivation

    h

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    Emission Mechanism

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    Power efficiency (unit: /W)

    power = r PL V() ext

    where : charge balancing factor (~100%)r : fraction of neutral excited states formed as singlet

    excitons via the electrical current ( 25%, 100%)

    PL : photoluminescence (PL) quantum efficiency, the fraction of energy released from fluorescent or phosphorescent material as light (~100%)

    V() : eye response curve (At peak visual response 555nm, 1W=683lm)

    ext : the fraction of emitted photons that are coupled out of the device. ~1/ (2n2) (

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    ( : n =1.46 )

    ( ITO: n = 1.8 ~ 2.1)

    ( n ~ 1.7)

    cathode51% waveguided

    31.5% waveguided or emitted from sides

    17.5% coupled out

    Out-coupling

    Internal QE

    External QE

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    Emission Efficiency of OLED

    External quantum efficiency(ext)Max. ext = rs qf coupling = 5%

    Charge injection & transfer

    e-h Pair(Exciton) formation()Max. = 100%

    Singlet Exciton formation(rs)Max. rs = 25%

    Triplet Exciton formation (rt) Max. rt + Max. rs = 75% + 25% = 100%

    Fluorescence Emission(qf)Max. qf = 100%

    Phosphorescence Emission (qp)Max. qp = 100%

    Optical Coupling(coupling)coupling = 20%

    Optical Coupling(coupling)coupling = 20%

    External quantum efficiency(ext)Max. ext = rt qpcoupling = 20%

    O

    X

    Flourescence

    G: 19%R: 7%B: 5~6%

    Phosphorescence

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    OLED Display

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    OLED Panel Structure : PM, Bottom Emission

    Anode(ITO)

    Cathode(metal)

    (Cathode

    Separator)

    Glass Substrate

    (Insulator)

    Getter

    (ETL)

    (EML)

    (HTL)

    (HIL)

    (EIL)

    Sealant

    RGB(Full Color)

    Encap-sulation

    Cathode

    Separator

    Organic EL

    ITO

    Glass

    Polarizer

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    (ETL)

    (EML)

    (HTL)

    Anode

    Cathode

    -

    +

    -+

    : 100 ~ 200 nm

    Exciton

    Lightoutput

    OLED Device Materials

    (from KETI, 2005)

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    N

    O

    N

    OAl

    O

    N

    NN

    DNTPD(HIL) Alq3(ETL)-NPD(HTL)

    mQD (Green)DCJTB(Red) DPVBi(Blue)

    N

    N

    N

    N

    O

    N

    CNNC

    N O

    S

    N

    O

    Organic Materials

    UV UV UV

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    25%

    100%

    Fluorescence & Phosphorescence Emitter

    Singlet Exciton Max. s = 25%

    ( & )

    - Pair(Exciton) ()Max. = 100%

    Singlet/Triplet Exciton Max. (s + t)=25% +75% =100%

    (Fluorescence) (Phosphorescence)

    4 R, G .

    GroundState

    S0

    S1

    SingletExcitedState

    T1

    TripletExcitedState

    SingletExciton

    h()

    S0

    S1T1

    TripletExciton

    h()

    h()

    SingletExciton

    ThermalDecay

    Radiative Non-radiative Radiative Radiative

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    ()( & )

    Fast decay time(

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    Efficiency(lm/W)

    RedPh. 6.6

    Green

    Ph. 15.5

    BluePh.

    Life time(hr)(@ Full White 100 nit)

    13,000(@ 520 nit/pixel)

    4,000(@ 960 nit/pixel)

    Comparison of power consumption in Ph. & Fl.

    2.0Fl. 46,700(@ 520 nit/pixel)

    5.9Fl. 32,000(@ 960 nit/pixel)

    Fl.

    300(@ 390 nit./pixel)

    11,000(@ 390 nit./pixel)

    3.1

    2.6

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    - EML Dopant : Ir based metal complex- Hole Blocking Layer(HBL) - Identical charge transfer layer with flourescence emiier

    NIr

    3

    Ir(ppy)3

    NN

    HIL(CuPc)

    NNCH3H3C

    Device ITO/CuPc/NPD/CBP+Dopant/BAlq/Alq3/Cathode(B:MgAg, RG:LiF/Al) -

    HBLBCP Data . BAlq

    NO

    AlN

    O

    NO

    NCu

    N

    N

    NNN

    N

    N

    N N

    CBP

    BAlq

    Green Ir(ppy)3 (ppy)2Ir(acac) Red HTL, ETL Codep. Red PtOEP(x=0.71, y=0.29, ext=2.2%, 70 cd/m2) (btp)2Ir(acac) Blue

    (btp)2Ir (acac) Firpic

    N

    Ir

    NO O

    N

    F

    F

    F

    F2

    N

    IrO

    O

    (ppy)2Ir (acac)

    NOAl

    ON O

    S

    N

    IrO

    O

    2

    HTL(NPD) HBL ETL(Alq3)

    BCP

    Host G Dopant R Dopant B Dopant

    Phosphorescence Emitter

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    (Panel Module)

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    OLED Process(PM)

    R/G/B source

    Evaporation Loading

    PLASMA

    O2

    Plasma

    Seal Sealing Canister Getter

    TAB Pol Cell Cell Aging

    Encap.

    PHOTO&

    ETCHINGITO sputtering ITO patterning Metal patterning

    UV

    AM AM

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    ModuleFactory

    INPUTAM TFT

    EL HIL, HTL, RGB EML

    ETL (shadow mask)

    Al Encapsulation

    sealing

    SCRIBE &BREAKING

    Cutting the combined glassinto screen units

    FINALINSPECTION

    Inspecting the TFT panel while regular display signal is applied

    OLED Process (AM)

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    ITO Strip(anode)

    Buffer Layer

    Metal Strip(Cathode)

    Separator()

    Patterning

    Photo Encap.

    Cathode(Al) Patterning ,

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    PRINCIPLE O2, Ar Gas RF Power Plasma , .

    RAW MATERIALO2, Ar Gas

    TARGETITO Work Function OELD Device .

    Plasma Treatment

    PLASMA

    Gas RF

    Pre-treatment

    PRINCIPLEO2 Gas UV Ozone ().

    RAW MATERIALO2, UV Lamp

    TARGET Device .

    UV Cleaning

    O2

    UV

    Photo Encap.

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    Evaporation

    PRINCIPLE Termally Heating .

    RAW MATERIALAlq3, R/G/B dopant, CuPc, -NPD, LiF, Al

    APPLYING PROCESS, Metal .

    Thermal Evaporation

    Organicmaterial

    Crucible

    Cold trap

    Shutter

    GlassSubstrate

    PRINCIPLEMagnetic Field Electron Beam .

    RAW MATERIALLiF, Al

    APPLYING PROCESS, Metal .

    E-beam Evaporation

    Vacuum Pump

    GlassSubstrate

    ElectronBeam

    ElectronBeam Source

    Crucible

    Ingot Rod

    MoltenPool

    FluxProfile

    Photo Encap.

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    OLED Pixellation : Full Color

    CCM C/F ,CCM

    Color filter white 1/3

    Differential degra., R,G,B

    , display

    , display

    , display

    Application

    ,R,G,B shadow mask

    R,G,B shadow mask ,

    ()

    (C/F )

    ( )

    (Color Satu.)

    Color ChangeMedium (CCM)

    White + Color Filter

    Side-by-SideDeposition

    GR

    B B B

    B

    R G B

    GR B

    Photo Encap.

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    --

    --- Patterning

    - 370x400mm - 550x650 for C/F

    LITI

    --

    - Shadow mask * 730x920 Glass 100~130 ppi(Max. 40 inch Wide)* < 23m

    --

    - OLED -

    - 370x470mm - 2,000x2,000 (for C/F)

    Ink-Jet

    - 370x470mm (Max. 20.1 inch Display)

    - 730x920

    Thermal Evaporation(Shadow Mask)

    OLED Photo Encap.

    (LITI: Laser Induced Thermal Imaging)

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    SDI, KDC 2005

    Photo Encap.

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    Thin Film Encapsulation

    TFT- LCD

    GlassTFT GlassBack Light

    20 grams

    5 mm

    10%

    $18.00

    20 grams

    5 mm

    10%

    WeightThicknessBreakage

    Cost

    OLED

    GlassTFT Glass

    Flexible OLED

    Flexible TFT Glass

    2010

    OLED

    TFT Glass

    2005

    5mm

    0.2mm

    Photo Encap.

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    Encapsulation Panel , Panel .

    Aging

    O/S

    Probe TEST

    Cleaning

    Breaking

    Pol.

    Cell .

    Panel .

    Glass Cell Crack .

    Scribing Glass

    Polarizer Chip .

    , Film .

    Scribing

    Panel Pad , Line, Open/ Short .

    Photo Encap.

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    Line Fail?

    Pixel - Short Panel .

    - Pixel (Anode, ITO) : Data Line

    - Pixel (Cathode, Al) : Scan Line

    Line Fail Aging

    Data Line ( m )

    Scan Line (n-1)

    Scan Line ( n )

    Scan Line (n+1)

    Line Fail Short PixelH

    H

    L

    Driver IC Short Pixel Scan Line High Voltage

    Scan Line n+1 Select

    Scan Line n Select

    Line Fail

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    Glass View Polarizer .

    Panel Polarizer Align .

    * Protecting Film

    * Polarizer Panel AttachingAttaching

    Alignment Alignment

    Function of PolarizerFunction

    of Polarizer

    Polarizer ,

    .

    Light Source

    InterceptTransmit

    polarizer

    Polarizer Attachment

    SUCTION BLOCK

    Pol

    Photo Encap.

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    Circular Polarizer Photo Encap. : Contrast Ratio

    : Panel (50% )

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    TAB

    Panel Module ACF PanelPAD

    Panel ACF COF Panel Pad .

    ACF

    Panel module Pattern .

    Seal/Tape TAB Seal Tape .

    Case Set EL , Case Panel .

    // , .

    Photo Encap.

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    Module Process

    1. Module

    ; SET .

    ) LCD Monitor LCD Module. Hand Phone STN LCD Module

    2. OLED Module

    OEL Panel

    Driver/ControllerIC

    FPC

    FPC : Driver/Controller IC Panel PCB

    Driver IC : Panel IC( Scan Data )

    Controller IC : Driver IC MPU Data IC

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    OLED PanelOLED Panel

    Data IC

    Data IC

    Scan IC

    Inter-face

    &DC/DC

    Conv-erter

    Controller

    R,G,B Data

    R,G,B Data

    Synch./ Control Signal/ Power

    Synch./ Control Signal/ Power

    Synch./ControlSignal

    R,G,BData

    Memory

    Data

    Power

    CPU

    Data/Synch.

    ---- General Module -------- Extended Module ----

    :::

    :::

    Frame, CLK..

    Module Block Diagram

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    1. Module

    1) TAB (Tape automatic bonding) : Film Interface Drive IC .

    2) COG (Chip On Glass) : LCD Glass IC .

    3) COF (Chip On FPC) : LCD Interface FPC IC .

    4) COB (Chip On Board) : Main Board Control PCB PCB

    5) OLB(Out Lead Bonding)

    ; FPC TCP Panel ACF

    6) SMT(Soldering Mount Technique)

    ; FPC PCB

    7) Module Assembly (Module )

    ; COF, OLB, SMT Module

    2. Module

    OLED Module

    COF or TCP

    OLED PanelOLB FOB

    PCB

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    FOG

    Sub-Unit Sub-KIT

    ++ FOB

    OLED Product Assembly Process

    +

    ILB

    +

    SMT

    Bare PCB

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    (PM, AM)

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    OLED Display

    I [A/cm2]

    L [Cd/m2]

    Approximate linear relationship between light intensity vs. current density.

    Easy gray scale realization with current control. Vmin

    Voltage

    Current

    Imax

    IminVmax

    I-V characteristics like a diode

    OELCPIXEL

    Circuit model

    Opto-Electrical characteristics

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    OLED

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    Cathode

    Organicfilm

    AnodeGlasssubstrate

    Glasssubstrate

    TFT

    OLED

    Matrix EL device

    Line Emission

    Passive Matrix (PM) Active Matrix (AM)

    Matrix EL TFT

    Frame time Emission

    1)

    1) TFT : Thin Film Transistor

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    Passive Matrix

    Scan 1

    Scan 2

    Scan 3

    Scan 4

    Data 1

    Data 2

    Data 3

    Data 4

    t1 t2 t3 t4 t5

    Data 5

    Data 6

    Scan Line , Data Line Pixel

    Data

    1 2 3 4 5 6

    Scan

    1

    2

    3

    4

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    Passive Matrix OLEDs Requires cathode patterning High pulsed drive currents (proportional to row counts) Higher drive voltage than active matrix display Higher power consumption Shorted pixels result in cross-talk or line defects Simple structure/fabrication (low fabrication cost) Small sized panel

    + + + + + +

    Data Lines (Anodes)

    Scan L

    ines (

    Cath

    odes)

    Programmable current source

    OEL Cpara

    PMOLED

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    Scan 1

    Scan 2

    Scan 3

    Scan 4

    Data 1

    Data 2

    Data 3

    Data 4

    t1 t2 t3 t4 t5

    Data 5

    Data 6

    Scan Line , Data Line Pixel (( Frame)Frame)

    Data

    1 2 3 4 5 6

    Scan

    1

    2

    3

    4

    Active Matrix

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    Active Matrix OLEDs Common cathode, Display during frame time Low pixel drive voltage/current Low power consumption Full color capability Medium/large sized panel

    AMOLED

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    PM & AM Active MatrixPassive Matrix

    LTPS(TFT) + OLED

    Simple Process Low Cost

    Cost

    & Symmetry

    Driving method

    Panel IC

    = Scan Line

    Scan Line

    Scan Line

    Duty Driving(Scan )

    Scan Line

    Static Driving( )

    Size Display (Mobile, CNS, Notebook, TV )

    2 Mobile Display - Car Audio, ,

    Display

    1) PM (Lp) .Lp = Lo Scan Line PM 1 Pixel ,

    tp = 1 Frame / Scan Line AM 1 Pixel = 1 Frame

    1 Frame (AM)

    LoTime

    Lp

    tp

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    a-Si TFT 100 poly-Si TFT , TFT compact TFT-LCD .

    poly-Si TFT LCD

    Controller, Interface Controller, Interface circuit,circuit,--source, source, Amp, DCAmp, DC--DCDC

    data driver

    gate

    dri

    ver

    Gate

    PCB

    (DC-DC con

    vert, Vc

    om)

    Source PCB (Controller, -source )

    D-IC

    a-Si TFT LCD

    Excimer Laser

    Scan

    poly-Si

    : depo. (poly-Si)film .

    a-Si:H poly-Si Single-Si

    (cm2/Vsec)

    0.5 ~ 1 50 ~ 200 ~ 600

    NMOS NMOS,PMOS NMOS,PMOS

    LTPS (Low Temperature Poly-Si) TFT

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    AMOLED

    Conventional 2T-1C Pixel Structure

    (from Professor Jin Jang, 2005)

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    IR-Drop of VDD Line

    PixelCircuit

    PixelCurrent

    PixelCircuit

    PixelCircuit

    PixelCircuit

    VDD

    ( n ) IPixel

    IPixel

    IPixel

    IPixel

    IPixel

    ( n-1 ) IPixel

    ParasticResistance of

    Pixel VDD Line

    RPixel

    RPixel

    IPixelRPixel

    2 IPixelRPixel

    Worst Case Pixel

    VDD - Vdrop

    2)1(

    ))1(.....21(

    )1(...

    ........2

    +=

    ++++=

    +

    ++=

    nnRI

    nnRI

    RnIRIn

    RIRIV

    pixelpixel

    pixelpixel

    pixelpixelpixelpixel

    pixelpixelpixelpixeldrop

    AMOLED

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    Pixel to Pixel Non-uniformity

    17, 500cd/m2, SXGA, 6bit-gray T1 : 20um/20um , T2 : 5um/10um Pixel Current : 20nA ~ 5.8uA VDD 12V VTH variation +/- 0.3V Mobility variation 10%

    7VDD Line IR Drop

    5Mobility Variation

    25VTH Variation

    Maximum Error (gray)Error Factors

    AMOLED

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    Bottom Emission OLED Top Emission OLED

    Passivation Layer

    Glass Substrate

    getterSealant

    Glass cap or Film type cap

    Driving TR

    Planarization layer

    Glass Substrate

    GetterMetal cap

    Driving TR

    Planarization layer

    Inert gasMetal cathode

    Anode

    Semitransparentcathode

    OrganicLayer

    Pixel

    High aperture ratio No Limitation circuit complexity

    High integral density High resolution

    Low Aperture Ratio Limitation circuit complexity

    AMOLED

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    Consideration for Driving Scheme Decision

    Target Resolution(Line Time)

    Aperture Ratio(# of Pixel Circuit TFT& Control Signal Line)

    Pixel to Pixel Luminance Uniformity

    Data Programming Time Pre-charge Scheme

    (Driver LSI)

    OLED Pixel Current Power, OLED Life time

    IR-Drop of VDD lineTFT Threshold Voltage& Mobility Variations

    Panel Size(Data Line

    Capacitance)

    PanelBrightness

    AMOLED

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    AMOLED History (2005. 2 )

    (from Professor Jin Jang, 2005)

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