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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 1 [ Lihat halaman sebelahSULIT

    4541/3/PPPeraturan PermarkahanKimiaKertas 3OKT/NOV 2012

    MPSM PAHANG

    MARKING SCHEME

    PEPERIKSAAN PERCUBAAN SPM 2012

    TINGKATAN 5

    CHEMISTRY

    Paper 3

    Kertas skema permarkahan ini mengandungi 14 muka surat bercetak.

    Amaran

    Peraturan pemarkahan ini adalah SULIT.

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 2 [ Lihat halaman sebelahSULIT

    Question Mark scheme score

    1(a) Able to state three observations.

    Sample answer

    Test tube I Intensity of blue colour produce is very high //

    - Does not produce pink colour.

    Test tube II Intensity of pink colour produce is very high //

    - Does not produce blue colour.

    Test tube III intensity of blue colour produce is very high //

    - Does not produce pink colour.

    3

    Able to state any two correct observations. 2

    Able to state any one correct observation 1

    No response or wrong response 0

    1(b) Able to state one inference for each experiment

    Sample answer:

    Test tube I : iron rust/oxidised // iron atom released electron//

    iron(II) ions/ Fe2+ formed// iron(II) ions

    present// rusting occur

    Test tube II : iron does not rust// iron(II) ions are not present

    // zinc corrode // zinc atom release

    electron// zinc ions formed // zinc oxidised

    Test tube III : iron rust/oxidised // iron atom released electron

    // iron(II) ions/ Fe2+ formed // iron(II) ions

    present // rusting occur

    3

    Able to state any two inferences 2

    Able to state any one inference 1

    No response or wrong response 0

    1(C Able to state the hypothesis accurately

    Sample answer:

    When a more/ less electropositive metal is in contact with

    iron/ferum/Fe, the metal inhibits/ (speeds up) rusting/ corrosion

    of iron //

    3

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 3 [ Lihat halaman sebelahSULIT

    When a more/ less electropositive metal is in contact with

    iron/ferum/Fe, rusting of iron/ferum/Fe is slower/faster

    If the metal in contact with iron is higher/lower than

    iron/ferum/Fe in electrochemical series, the rusting/corrosion of

    iron is slower/faster//

    The higher/lower the metal in contact with iron in

    electrochemical series/than iron/ferum/Fe, the rusting/corrosion

    of iron/ferum/Fe is slower/faster

    Able to state the hypothesis correctly

    Sample answer:

    When a more/less electropositive metal, the metal inhibits/

    (speeds up) rusting/corrosion of iron//

    If the metal in contact with iron is higher than iron/ferum/Fe in

    reactivity series, the rusting/corrosion of iron is slower/faster//

    The rusting of iron/ferum/Fe is faster/slower, if a less / more

    electropositive metal is in contact with iron/ferum/Fe

    2

    Able to state the idea of hypothesis

    Sample answer

    Different metal in contact with iron, will cause iron to rust//

    Metal can cause iron to rust.

    1

    No response or wrong response 0

    1 (d) Able to state the three variables correctly

    Sample answer:

    (i) Manipulated variable:

    Type/different metals// position of metal in

    electrochemical series

    (ii) Responding variable:

    3

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 4 [ Lihat halaman sebelahSULIT

    Rusting/ corrosion// presence of blue/pink colour

    (iii) Constant variable:

    Size/mass of iron nail// type of nail// clean iron nails//

    temperature// medium in which the iron nails are kept

    Able to state any two variables correctly 2

    Able to state any one variable correctly 1

    No response or wrong response 0

    1(e) Able to give the operational definition accurately.

    Sample answer:

    When iron is in contact with metal lower than iron in

    electrochemical series, blue colouration indicates rusting//

    Rusting occurs when iron nail is in contact with copper/tin/less

    electropositive metal and form blue colouration//

    Blue colouration is formed when iron is in contact with metal

    lower than iron in electrochemical series.

    3

    Able to give the operational definition correctly.

    Sample answer:

    Blue colouration indicates rusting//

    Rusting occurs when iron nail is contact with copper/tin/less

    electropositive metal

    2

    Able to give an idea of the operational definition.

    Sample answer:

    Rusting occurs when the colour of solution changes.//

    Rusting occurs.

    1

    No response or wrong response 0

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 5 [ Lihat halaman sebelahSULIT

    1(f) Able to predict any one the observations based on the

    laboratory experiment correctly

    Sample answer:

    Intensity of blue colour higher //

    Iron nail becomes smaller//

    Lead strip remains unchanged

    3

    Able to predict one observation less correctly

    Sample answer:

    Pink spot/colouration

    2

    Able to give an idea of observation

    Sample answer:

    Iron rusts // brown deposit/spot

    1

    No response or wrong response 0

    Question Details Score

    2.a) Able to record all readings accurately to one decimal point with

    unit.

    Sample answer:

    Set Initial thermometer

    reading,C

    Highest thermometer

    reading,C

    I 27.0 53.0

    II 29.0 57.0

    III 27.0 59.0

    3

    Able to record all readings correctly.

    # readings to one decimal point without unit.

    # readings without decimal point with / without unit.

    Sample answer:

    Set Initial thermometer

    reading

    Highest thermometer

    reading

    I 27.0 53.0

    II 29.0 57.0

    III 27.0 59.0

    2

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 6 [ Lihat halaman sebelahSULIT

    OR

    Set Initial thermometer

    reading

    Highest thermometer

    reading, C

    I 27 53

    II 29 57

    III 27 59

    Able to record three or five readings correctly 1

    No response or wrong response 0

    Question Details Score

    2.b) Able to construct a table to record the initial temperature of

    water, highest temperature of water and increase in temperature

    for Set I, Set II and Set III

    1.correct titles

    2. readings and units

    Sample answer:

    Set I II III

    Initial temperature, C 27.0 29.0 27.0

    Highest temperature, oC 53.0 57.0 59.0

    Increase in temperature, oC 21.0 29.0 32.00

    3

    Able to construct a less accurate table that contains the

    following:

    1. Titles

    2. Readings

    Sample answer:

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 7 [ Lihat halaman sebelahSULIT

    I II III

    Initial temperature 27C 29 27C

    Highest temperature 53.0 57.0 59.0

    Increase in temperature 26C 28 32C

    2

    Able to construct a table with at least one title/ reading.

    Sample answer :

    I II III

    Increase in temperature

    1

    No response or wrong response 0

    2.c) Able to sketch the graph of heat of combustion of alcohols

    against number of carbon atoms per molecule.

    The graph must have the following information:

    1. The axes are labeled correctly

    2. Correct unit

    3. Correct curve

    Sample answer:3

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 8 [ Lihat halaman sebelahSULIT

    Able to sketch the graph of heat of combustion against number

    of carbon atoms

    i. without units on y-axis

    ii. correct curve

    sample answer:2

    Able to sketch the graph with only one correct information.

    Sample answer:

    1

    Heat of combustion, KJmol-1

    1 2 3 4

    Number of C atom per molecule

    Heat of combustion

    1 2 3 4Number of carbon atom

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 9 [ Lihat halaman sebelahSULIT

    Or

    No response or wrong response 0

    2.d) Able to state three correct information from the diagram.

    Sample answer:

    1. The reaction is an exothermic reaction // heat energy is

    released to the surrounding.

    2. 726 KJ of heat is released when one mole of methanol is

    burnt.

    3. Total energy of reactant is higher than the products.

    3

    Able to state any two correct information. 2

    Able to state any one correct information. 1

    No response or wrong response. 0

    2.e) Able to classify all carbon compounds correctly.

    Sample answer:

    Hydrocarbon Non-hydrocarbon

    Ethene, C2H4 Propanol, C3H7OH

    Methanoic acid, HCOOH

    Prophyl ethanoate,

    CH3COOC3H7

    3

    Heat of combustion KJmol-1

    Number of C atom

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 10 [ Lihat halaman sebelahSULIT

    Able to classify at least three carbon compounds correctly. 2

    Able to classify any one carbon compound correctly. 1

    No response or wrong response. 0

    Question

    Number

    Rubric Score

    3(a) Able to give the statement of problem correctly.

    Sample answer:

    Does all nitrate, sulphate, carbonate and chloride salts aresoluble in water?

    3

    Able to give the statement of problem correctly.

    Sample answer:

    Does all salts are soluble in water?

    2

    Able to give the statement of problem correctly.

    Sample answer:

    Salt are soluble and insoluble in water

    1

    No response or wrong response 0

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 11 [ Lihat halaman sebelahSULIT

    3(b) Able to state all variables correctly

    Sample answer:

    Manipulated variable: Type of salt

    Responding variable: Solubility of salt

    Constant variable: volume of water/ mass of

    salt/temperature

    3

    Able to state any two variables above correctly 2

    Able to state any one variables above correctly 1

    No response or wrong response 0

    3 Able to give hypothesis accurately.

    Sample answer:

    Some of salts soluble in water but other salts insoluble in water// all nitrate salts are soluble in the water but the other saltsinsoluble in water.

    3

    Able to give the statement of hypothesis correctly.

    Sample answer:

    All nitrate salt are soluble in water

    2

    Able to give idea of hypothesis.

    Sample answer:

    Different salts produce different solubility in water

    1

    No response or wrong response 0

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 12 [ Lihat halaman sebelahSULIT

    3(d) Able to list completely the materials and apparatus

    Sample answer:

    Material:

    1. Any suitable nitrate, sulphate, carbonate and chloride

    salts soluble and insoluble in water

    2. Distilled water

    Apparatus:

    1. Test tube

    2. Spatula

    3

    Able to list incompletely materials and apparatus.

    Sample answer:

    Materials:

    1. Incomplete salt :

    List only 3 type of salt Eg zinc nitrate, lead (II) sulphate,

    calcium carbonate

    2. Distilled water

    Apparatus:

    1. Test tube

    2. Spatula

    2

    Able to give an idea of materials and apparatus.

    Sample answer:

    Materials:

    1. Incomplete salt :

    List only 2 type of salt Eg zinc nitrate, plumbum (II)

    sulphate, calcium carbonate

    1

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 13 [ Lihat halaman sebelahSULIT

    2. No distilled water

    Apparatus:

    1. Test tube

    2. Spatula

    No response or wrong response 0

    3 (e) Able to state all procedures completely and correctly

    Sample answer:

    1. Half a spatula of (nitrate salt) powder is added in a test

    tube

    2. Pour 5 cm3 of distilled water into the test tube

    3. Shake the test tube.

    4. Observe the solubility of salt and record in the table.

    5. Experiment is repeated using various salt powder.

    3

    Able to state procedures incompletely.

    Sample answer:

    1. Half a spatula of (nitrate salt) powder is added in a test

    tube

    2. Pour 5 cm3 of distilled water into the test tube

    3. Observe the solubility of salt and record in the table.

    2

    Able to give an idea of the procedure.

    Sample answer:

    1. Half a spatula of (nitrate salt) powder is added in a test

    tube

    1

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    SULIT 4541/3/PP

    @ 2012 Hak Cipta MPSM Pahang 14 [ Lihat halaman sebelahSULIT

    2. Pour 5 cm3 of distilled water into the test tube

    No response or wrong response 0

    3(f) Able to exhibit the tabulation of data correctly.

    Sample answer:

    Salt Solubility of salt in water

    Zinc nitrate

    Magnesium chloride

    Sodium chloride

    Lead (II) sulphate

    Copper (II) sulpahte

    Potassium carbonate

    2

    Able to exhibit the tabulation of data less accurately.

    Sample answer:

    Salt Solubility of salt in water

    1

    No response or wrong response 0

    END OF MARKING SCHEME