[s2．1．3]重質原油の高分解を達成するrfccトー...
TRANSCRIPT
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RHYCRFCCLGC C 12vol% 2.5vol% 6wt%
RHYCRFCC
RHRFCC RH RHYC RFCC RHYCRHRFCC
RHYCRFCC
LGC
RHYC RH
10vol%
91
-
RFCC
RFCC 2.5vol% RFCC 2vol%
LGCRFCC C4
90wt%6wt%
RFCC RFCC
RHYCRHYC
RHYC
NiMo NiMo
RHYC HDMHDS
RFCC
92
-
4003 1,000
1203 UD: Unitcell Diameter
XRD: X-ray Diffraction
RHYC 100cc
AR-AH
WAT 390400410LHSV 0.3 h-1 12.8 MPa 1,000 Nm3/kL
343
JIS-K-2601 15 C4- C5150 150250 250343343+RHYC
RHYC RHYC LHSV0.160.30 h-1 814 MPa 6001,100Nm3/kLWAT: Weight Average Temperature 355400 343+
RHYC RHYC RHDSARS=0.3wt%
93
-
HDM HDS(1) RHYC HDS(2)
HDSDSAR RFCCHDS
RHYC
H-NMR
S, V, Ni
RFCC
RFCC LPG
UD
94
-
RFCC
20m150m RFCC RFCC RFCC RFCC
LGC
1-2- RFCC C4 RFCC RFCC C4 45wt%C1C3
BTX
95
-
ZSM-5 ZSM-5 International Zeolite Association MFIHMFI SiO2Al2O330200
ZSM-5 MFI BTX
MFI
2
550 0.1MPa GHSV5,000h-1
BTX
RHYCRHYC CoMo NiMo
RHYC
96
-
RHYC
RHYC
130% RHYC
RHYC HDMHDS R-HYC (A)(B)(C)
Base
+ 2
+ 4
+ 6
+ 8
HDMHDS-1XHDS-2 X
A R-HYC BCA R-HYC DSAR RFCC HDCCRHDMB
C
R-HYC
Base
+10
+20
+30
+40
97
-
C HDM-1 HDS-1 HDS-2 HDM-1 V HDS-1 NiMo HDS-3 R-HYC RHYC HDS HDS WATWeight Average Temperature380WAT=40011vol% RHYC 10vol%
6 4570
75
80
85
90
95
100
Base
+10
+20
+30 11vol%
Base
+10
+20
+30
RHYC
RHYC RHYC HDS RHYC HDM HDS DSARS=0.3wt%WAT
98
-
RHYC HDS WAT DSARDSGODSN RHYC HDS RH
RH DSAR0.3wt% RHYC HDS DSAR S=0.3wt%WATDSAR
RHYC
RHYC
Base
+10
+20
+30
+40
+50
RHYC
HDS
MOR
99
-
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
0.00 0.10 0.20 0.30 0.40
mmol/g)
0.00
10.00
20.00
30.00
40.00
50.00
60.00
mmol/g0.0 0.1 0.2 0.3 0.4
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
0.00 0.10 0.20 0.30 0.40
mmol/g)
0.00
10.00
20.00
30.00
40.00
50.00
60.00
mmol/g0.0 0.1 0.2 0.3 0.4
160 MORDSNDSGO DSAR HDS
MOR
RHYC HDS DSAR RFCC RFCC RHYC DSAR RFCC
RFCC
RFCC RFCC
100
100
-
4590
2.0 wt% 2.0 wt%
101
-
4577% 1.8vol% 2.0vol% 1.0vol%C4 0.5vol%60% 100%
LGC
SiAl
BTX BTX
102
-
AgZrP
La
PLaAgZr
PLa(Zr)Yield
FFresh DDeactivate LGC-04 LGC-05 LGC-04 LGC-05 A DFresh F B D
C40.5 0.7nm
C2/C3
ZrAgP
La)
103
-
B
FDFFresh DDeactivate Fresh Deactivate
0
20
40
60
80
100
LGC-05
F F
F
F
F
DD
DD
DD
DDDD
LGC-04
H21
0
20
40
60
80
100
F
DDDD
F
DDF
DD
F
A: B:
LGC-40F: Fresh
D: Deactivate
104
-
A BLGC-40
LGC-40 RFCC LGC-40 2,400
RGReGenerationBTX 90wt%
90wt%
4 8,000 0.75 1 T 5
RG: 100
90
80
70
60
50
40
30
20
10
00 400 800 1200 1600 2000 2400
Total
LGC-40 RFCC
90wt% C4
105
-
C4 (RFCC-BB) 50wt% 50wt%H2O/RFCC-BB Feed 0.51(wt)
(Catalytic Reforming)(Continuous Catalyst Regeneration)
T
(BTX)(Battery Limit)(Quench Tower)
RFCC-BB
H2O/RFCC-BB 0.7(wt)
RFCC-BB
Feed WaterRecycleWater
Quench Tower-1 -2 -3
Air / N2
RFCC-BB
Feed WaterRecycleWater
Quench Tower-1 -2 -3
Air / N2
ButeneEthylene 16%Propylene 34%BTX 40%Total 90%
106
-
in-house
C4 35
C4
/kg
107
-
RHYC
RH RHYC
RH 10vol%@400
RH
DSAR RFCC
RHYC RHYC RHYC
RHYC
RFCC
RFCC RFCC
2.5vol 2vol
RFCC
108
-
LGC
P-La-Ag 2,400 90%1
109